Adenomyosis: a neglected diagnosis.
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A new method using sequential water-surface deposition of polymer-fullerene blends achieved bilayer-ternary organic solar cells with 5.9% PCE, demonstrating EQEs over 100% under NIR bias light due to interfacial electron transport barriers.
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Abstract
A new method is presented to fabricate bilayer organic solar cells via sequential deposition of bulk-heterojunction layers obtained using spontaneous spreading of polymer–fullerene blends on a water surface. Using two layers of a small bandgap diketopyrrolopyrrole polymer–fullerene blend, a small improvement in power conversion efficiency (PCE) from 4.9% to 5.1% is obtained compared to spin-coated devices of similar thickness. Next, bilayer–ternary cells are fabricated by first spin coating a wide bandgap thiophene polymer–fullerene blend, followed by depositing a small bandgap diketopyrrolopyrrole polymer–fullerene layer by transfer from a water surface. These novel bilayer–ternary devices feature a PCE of 5.9%, higher than that of the individual layers. Remarkable, external quantum efficiencies (EQEs) over 100% are measured for the wide bandgap layer under near-infrared bias light illumination. Drift-diffusion calculations confirm that near-infrared bias illumination can result in a significant increase in EQE as a result of a change in the internal electric field in the device, but cannot yet account for the magnitude of the effect. The experimental results indicate that the high EQEs over 100% under bias illumination are related to a barrier for electron transport over the interface between the two blends.
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- Pregnancy and live birth after focused ultrasound surgery for symptomatic focal adenomyosis: a case report 2006
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- Atypical MR Imaging of Adenomyosis with Endometrial Polyp Mimicking Endometrial Stromal Sarcoma 2004
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