Effect of Temperature on Adhesion Work of Model Organic Molecules on Modified Styrene– Divinylbenzene Copolymer Using Inverse Gas Chromatography

In previous studies, a new methodology was developed to determine the free dispersive and polar energies, the surface energies and Lewis acid‐base parameters of polystyrene‐ divinylbenzene (S‐DVB) copolymer modified by melamine, 5‐Hydroxy‐6‐methyluracil, and 5‐ fluouracil. In this paper, we were interested in the determination of the work of adhesion of solvents on the modified copolymer as a function of temperature and for the different modifiers with the help of the inverse gas chromatography at infinite dilution. The variations of the London dispersive and polar surface properties of copolymers against the temperature led to the determination of the different acid‐base components of their surface energies. Using Fowkes’s equation, van Oss ‘s relation, and Owens’s concept, we obtained the variations of the dispersive and polar works of adhesion of the different solid surfaces as well as the corresponding forces of interaction between the organic solvents and the modified copolymer. It was showed that the work of adhesion is function of two thermodynamic variables: the temperature and the modifier percentage.