Synthesis and salt resistance of non-ionic polymer P (AM/ APEG400/NVP/SM)

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Abstract The non-ionic hydrophobic associative copolymer AANS was synthesized by micellar polymerization using acrylamide (AM), allyl polyoxyethylene ether (APEG400), N-vinyl pyrrolidone (NVP) and stearyl methacrylate (SM) as raw materials, 2, 2'-azobis (2-methylpropionamidine) dihydrochloride (V50) as initiator, sodium dodecyl sulfate (SDS) as surfactant. The temperature resistance, salt resistance and rheological properties of the polymer were tested by viscometer and rheometer. The change of polymer microstructure in salt solution was analyzed by scanning electron microscopy. The viscosity test results showed that when the polymer concentration was higher than CAC, the polymer solution exhibited good salt resistance and presented good salt thickening performance. The effect of temperature on the salt resistance of polymer solution showed different rules. With the increase in temperature, the resistance of the polymer to NaCl decreased gradually, while the resistance of the polymer to CaCl2 increased first and then decreased. The resistance of the polymer to CaCl2 showed a special temperature response. Viscoelastic and shear tests showed that the polymer possessed more robust resistance to extreme sodium chloride concentration than extreme calcium chloride concentration. Electron microscopy analysis suggested that the microstructure of the polymer gradually became dense and compact in the salt solution. The results showed that this novel non-ionic hydrophobically associating polymer possessed potential application value in ultra-high salinity reservoirs.
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Synthesis and salt resistance of non-ionic polymer P (AM/ APEG400/NVP/SM) | Research Square window.SnipcartSettings = { analytics: { enabled: false } }; (function() { var accessVector = localStorage.getItem('access_vector') || ''; window.dataLayer = window.dataLayer || []; if (accessVector) { window.dataLayer.push({ user: { profile: { profileInfo: { snid: accessVector } } } }); } })(); (function(w,d,s,l,i){w[l]=w[l]||[];w[l].push({'gtm.start':new Date().getTime(),event:'gtm.js'});var f=d.getElementsByTagName(s)[0],j=d.createElement(s),dl=l!='dataLayer'?'&l='+l:'';j.async=true;j.src='https://www.googletagmanager.com/gtm.js?id='+i+dl;f.parentNode.insertBefore(j,f);})(window,document,'script','dataLayer','GTM-K279D39R'); Browse Preprints In Review Journals COVID-19 Preprints AJE Video Bytes Research Tools Research Promotion AJE Professional Editing AJE Rubriq About Preprint Platform In Review Editorial Policies Our Team Advisory Board Help Center Sign In Submit a Preprint Cite Share Download PDF Research Article Synthesis and salt resistance of non-ionic polymer P (AM/ APEG400/NVP/SM) Haiyang Tian, Yunfeng Shi, Heng Zhang, Jie Liu, Lie Li, Peng Tang This is a preprint; it has not been peer reviewed by a journal. https://doi.org/ 10.21203/rs.3.rs-4290854/v1 This work is licensed under a CC BY 4.0 License Status: Published Journal Publication published 12 Sep, 2024 Read the published version in Journal of Polymer Research → Version 1 posted 5 You are reading this latest preprint version Abstract The non-ionic hydrophobic associative copolymer AANS was synthesized by micellar polymerization using acrylamide (AM), allyl polyoxyethylene ether (APEG400), N-vinyl pyrrolidone (NVP) and stearyl methacrylate (SM) as raw materials, 2, 2'-azobis (2-methylpropionamidine) dihydrochloride (V50) as initiator, sodium dodecyl sulfate (SDS) as surfactant. The temperature resistance, salt resistance and rheological properties of the polymer were tested by viscometer and rheometer. The change of polymer microstructure in salt solution was analyzed by scanning electron microscopy. The viscosity test results showed that when the polymer concentration was higher than CAC, the polymer solution exhibited good salt resistance and presented good salt thickening performance. The effect of temperature on the salt resistance of polymer solution showed different rules. With the increase in temperature, the resistance of the polymer to NaCl decreased gradually, while the resistance of the polymer to CaCl 2 increased first and then decreased. The resistance of the polymer to CaCl 2 showed a special temperature response. Viscoelastic and shear tests showed that the polymer possessed more robust resistance to extreme sodium chloride concentration than extreme calcium chloride concentration. Electron microscopy analysis suggested that the microstructure of the polymer gradually became dense and compact in the salt solution. The results showed that this novel non-ionic hydrophobically associating polymer possessed potential application value in ultra-high salinity reservoirs. Non-ionic polymer hydrophobic association micellar polymerization salt resistance Full Text Cite Share Download PDF Status: Published Journal Publication published 12 Sep, 2024 Read the published version in Journal of Polymer Research → Version 1 posted Reviewers agreed at journal 14 May, 2024 Reviewers invited by journal 14 May, 2024 Editor invited by journal 27 Apr, 2024 Editor assigned by journal 22 Apr, 2024 First submitted to journal 21 Apr, 2024 You are reading this latest preprint version Research Square lets you share your work early, gain feedback from the community, and start making changes to your manuscript prior to peer review in a journal. As a division of Research Square Company, we’re committed to making research communication faster, fairer, and more useful. We do this by developing innovative software and high quality services for the global research community. Our growing team is made up of researchers and industry professionals working together to solve the most critical problems facing scientific publishing. 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