Application of HPLC Combined with UPLC–Orbitrap–MS in Chemical Characterization, Quantitative Detection, and Species Authentication of Four Panax-derived Products

Application of HPLC Combined with UPLC–Orbitrap–MS in Chemical Characterization, Quantitative Detection, and Species Authentication of Four Panax-derived Products | Research Square window.SnipcartSettings = { analytics: { enabled: false } }; (function() { var accessVector = localStorage.getItem('access_vector') || ''; window.dataLayer = window.dataLayer || []; if (accessVector) { window.dataLayer.push({ user: { profile: { profileInfo: { snid: accessVector } } } }); } })(); (function(w,d,s,l,i){w[l]=w[l]||[];w[l].push({'gtm.start':new Date().getTime(),event:'gtm.js'});var f=d.getElementsByTagName(s)[0],j=d.createElement(s),dl=l!='dataLayer'?'&l='+l:'';j.async=true;j.src='https://www.googletagmanager.com/gtm.js?id='+i+dl;f.parentNode.insertBefore(j,f);})(window,document,'script','dataLayer','GTM-K279D39R'); Browse Preprints In Review Journals COVID-19 Preprints AJE Video Bytes Research Tools Research Promotion AJE Professional Editing AJE Rubriq About Preprint Platform In Review Editorial Policies Our Team Advisory Board Help Center Sign In Submit a Preprint Cite Share Download PDF Research Article Application of HPLC Combined with UPLC–Orbitrap–MS in Chemical Characterization, Quantitative Detection, and Species Authentication of Four Panax-derived Products Xingwang Leng, Sicheng Wang, Anqi Wang, Bin Li, Lidong Cheng, and 8 more This is a preprint; it has not been peer reviewed by a journal. https://doi.org/ 10.21203/rs.3.rs-7772424/v1 This work is licensed under a CC BY 4.0 License Status: Published Journal Publication published 18 Dec, 2025 Read the published version in Chromatographia → Version 1 posted 9 You are reading this latest preprint version Abstract Panax species are medicinal plants of high pharmaceutical and economic value. However, the high degree of similarity in their chemical compositions often leads to issues of adulteration and challenges in quality control. This study developed an integrated analytical strategy combining high-performance liquid chromatography (HPLC) and ultra-performance liquid chromatography–Orbitrap mass spectrometry (UPLC–Orbitrap–MS) to systematically characterize and differentiate four major Panax species: Panax ginseng (RS), Panax quinquefolius (XYS), Panax notoginseng (SQ), and Panax japonicus (BSQ). The established HPLC method proved robust and reliable, enabling the simultaneous quantification of 13 bioactive compounds, including 11 saponins and 2 polyacetylenes, and demonstrated excellent precision, reproducibility, and accuracy. The approach clearly revealed content variations of major constituents among the different species. Chemical fingerprinting combined with similarity analysis indicated significant interspecies differences. A total of 129 compounds were identified using high-resolution mass spectrometry, covering structure types such as protopanaxadiol-type, protopanaxatriol-type, oleanane-type, ocotillol-type, and C-17 side-chain variant saponins. By elucidating the characteristic fragmentation patterns of representative ginsenosides, this work offered a theoretical foundation for reliable compound identification. The results provided a scientific foundation for quality assessment and species authentication, offering a comprehensive strategy for the standardization of Panax-derived medicinal products. ginsenosides Panax HPLC LC-Orbitrap-MS Figures Figure 1 Figure 2 Figure 3 Figure 4 Figure 5 Figure 6 Figure 7 1. Introduction Plants of the Panax species represent a pharmaceutically significant group with demonstrated therapeutic benefits in human health[ 1 ]. Although the roots of P. ginseng (RS), P. quinquefolius (XYS), P. notoginseng (SQ), and P. japonicus (BSQ), share close genetic relationships and contain similar bioactive compounds, they exhibit distinct properties, flavors, and clinical applications. Different Panax species vary in their traditional Chinese medicine (TCM) nature and core functional properties. RS (warm nature) is well-recognized for its adaptogenic and energy-enhancing effects[ 2 – 4 ]. BSQ (mildly warm) exerts extensive antioxidant, immunomodulatory, and cardioprotective activities[ 5 ]. XYS (cool nature) shows efficacy in anti-fatigue and anti-anxiety applications[ 6 ]. SQ (warm nature) is mainly used for its haemostatic and circulatory benefits[ 7 ]. These four herbal materials are among the most widely used medicinal plants globally and hold significant shares in the natural product market. Growing demand has highlighted differences in their pharmacological effects, indications, and clinical uses, leading to varying medicinal and economic values[ 8 ]. However, their similar chemical profiles have led to widespread issues of adulteration, substitution, and counterfeit products in the market, particularly in powdered formulations and raw materials for proprietary medicines[ 9 ]. For instance, XYS is sometimes adulterated into RS products to reduce costs, and the roots of P. vietnamensis are often mistakenly or intentionally used in place of SQ[ 10 – 12 ]. Such practices compromised therapeutic outcomes and raised safety concerns, damaging the credibility of the herbal supply chain. Thus, there is an urgent need to develop accurate species identification methods and investigate the relationship between chemical composition and quality to ensure efficacy, safety, and market standardization. The establishment of rapid and reliable identification methods and quality assessment protocols for these four Panax species is imperative. Recent advances in analytical techniques have enabled various effective strategies. Chromatographic methods, including high-performance liquid chromatography (HPLC) and ultra-performance liquid chromatography (UPLC), coupled with mass spectrometry (LC–MS) and chemometrics, have shown great promise in the compositional analysis of Panax plants[ 13 – 15 ]. Notably, the integration of chromatographic fingerprinting with high-resolution mass spectrometry (MS) and chemometric analyses, such as principal component analysis (PCA) and orthogonal projection to latent structures–discriminant analysis (OPLS-DA), markedly improves the scientific rigor and reliability of the results[ 16 ]. This combined approach facilitates a transition from single-compound quantification toward holistic quality assessment and enables deeper mechanistic insights into the pharmacological properties of phytochemical compositions. To address quality control and species authentication challenges of Panax-derived products, this study validated an HPLC method for simultaneous quantification of 11 major ginsenosides and 2 polyacetylenes, identified saponins and clarified their fragmentation pathways in four Panax species via high-resolution LC-MS, and screened potential quality markers through chemometric modeling. This work thus holds significance in establishing a more scientific and comprehensive quality evaluation system for Panax plants, a development that aids in resolving quality control and species authentication issues of Panax-derived medicinal products. 2. Materials and Methods 2.1 Reagents and Chemicals Methanol and acetonitrile of HPLC grade were sourced from Sigma–Aldrich (St. Louis, USA). Other reagents were procured through the China National Medicines Group Chemical Reagent Co., Ltd. (Shanghai, China). Purified water for all aqueous solutions was supplied by China Resources C’estbon Beverage Co., Ltd. (Shenzhen, China). The Nylon filter (0.22 µm, 13 mm in diameter) was supplied by Hangzhou Special Paper Industry Co., Ltd. (Hangzhou, China). The reference standards, including notoginsenoside R1, ginsenoside Rg1, ginsenoside Re, ginsenoside Rb1, ginsenoside Ro, ginsenoside Rc, ginsenoside Rb2, ginsenoside Rb3, chikusetsusaponin IV, ginsenoside Rd, chikusetsusaponin IVa, panaxydol, and panaxynol, were obtained from Shanghai Yuanye Bio-Technology Co., Ltd. (Shanghai, China). A purity level of over 98% was determined for all reference standards by HPLC analysis. 2.2 Plant Materia A total of 41 medicinal material batches, including 11 batches of BSQ, 10 batches of SQ, 10 batches of XYS, and 10 batches of RS, were collected from Hunan, Hubei, Yunnan, and Jilin provinces in China, as well as Canada and other regions (Table S1 ). Professor Wei Wang from the School of Pharmacy at Hunan University of Chinese Medicine has authenticated all the materials, which are now stored in the TCM and Ethnomedicine Innovation & Development International Laboratory. 2.3 Preparation of Sample and Standard Solution Accurately weighed 1.0 g of powdered sample (passed through a No. 5 sieve) was placed in a stopper-sealed conical flask. Exactly 25 mL of methanol was added, and the total weight was recorded. After ultrasonication (30 min) and cooling to room temperature, the weight was measured again, with any solvent loss compensated by adding methanol. The mixture was vortexed, filtered, and the resulting filtrate was further passed through a 0.22 µm microporous membrane to obtain the final test solution for analysis. Accurately weighed appropriate amounts of the reference standards were separately placed in 5 mL volumetric flasks and dissolved in methanol to prepare stock solutions. These stock solutions were diluted to an appropriate multiple and then used for analysis. 2.4 HPLC analysis The analysis was performed using an Agilent 1260 Infinity II series high-performance liquid chromatography (HPLC) system (Agilent Technologies, Santa Clara, CA, USA), equipped with a binary pump, an autosampler, a thermostatted column compartment, and a diode array detector. Elution was carried out using a gradient program with acetonitrile (A) and 0.1% phosphoric acid in water (B) as the mobile phase at a flow rate of 1 mL/min as follows: 0–20 min, 20–20% A; 20–60 min, 20–40% A; 60–70 min, 40–60% A; 70–75 min, 60–73% A; 75–90 min, 73–95% A; 90–100 min, 95% A. The detection wavelength was set at 203 nm. Both the column and sample compartment temperatures were maintained at 24°C. The injection volume was 5 µL. Separation was achieved using an Agilent Eclipse XDB-C18 column (4.6 mm × 250 mm, 5 µm). For precision evaluation, the identical sample was injected 6 times consecutively. The sample’s stability was determined by conducting analyses at intervals of 0, 4, 8, 12, 24, and 48 h. Reproducibility was tested by preparing 6 parallel samples. Data regarding the retention times and peak areas of corresponding peaks, along with the relative standard deviations for the retention and peak areas of 11 saponins and 2 polyacetylenes, were both logged and computed. Recovery was assessed by spiking at high, medium, and low amounts of standards into weighed samples by 3 replicates, and analyzed by the HPLC method. Recovery was calculated according to the following equation: Recovery (%) = measure amount − original amount spiked amount × 100%. 2.5 LC–MS Conditions Chromatography was conducted on a Hypersil GOLD™ Aq-C18 column (100 mm × 2.1 mm, 1.9 µm) using a Vanquish™ Flex UPLC system at 25℃. The elution utilized a gradient of acetonitrile (A) and 0.1% formic acid in water (B) at 0.3 mL/min: 0–10 min, 20 ~ 20% A; 10–45 min, 20–40% A; 45–50 min, 40–60% A; 50–60 min, 60–95% A; 60–75 min, 95% A. The sample compartment temperature was maintained at 25℃, and the injection volume was 4 µL. The ESI-equipped Orbitrap Exploris 120 mass spectrometer functioned in negative polarity modes, conducting both full scan and data-dependent MS/MS (Full MS/ddMS2 ) analyses with parameters finely tuned for optimal performance. For MS1, the positive mode was set at a spray voltage of 3500 V, while the negative mode was at 2500 V. The gas flow for sheath, auxiliary, and sweep gases were tuned to 50, 10, and 0 Arb, respectively. Meanwhile, the temperatures for the ion transfer tube and vaporizer were stabilized at 325℃ and 350℃, respectively. A resolution of 60,000 and a scanning range of 100–1300 Da were utilized. The HCD Collision Energy for dd-MS2 was set to 30% and the resolution was adjusted to 15,000. 2.6 Data Analysis Similarity analysis was performed using the "Similarity Evaluation System for Chromatographic Fingerprint of Traditional Chinese Medicine (2002A)". The cosine similarity algorithm was applied to calculate the similarity between chromatographic profiles, enabling a comprehensive evaluation of the overall consistency of chromatographic patterns across different samples. Mass spectrometry data were subjected to raw data preprocessing and format conversion using Freestyle 1.8 software under the Thermo Fisher Scientific platform. PCA and OPLS-DA models were analyzed using SIMCA 14.1 software. 3. Results and Discussion 3.1 HPLC fingerprint The HPLC analytical method established in this study achieved satisfactory separation for 13 characteristic components, including notogisenoside R1, ginsenoside Rg1, ginsenoside Re, ginsenoside Rb1, ginsenoside Ro, ginsenoside Rc, ginsenoside Rb2, ginsenoside Rb3, chikusetsusaponin IV, ginsenoside Rd, chikusetsusaponin IVa, panaxydol, and panaxynol, which were unequivocally identified through comparison with reference standards (Fig. 1 ). Among them, ginsenoside Rg1, Re, Rb1, Rd, panaxydol, and panaxynol were identified as common constituents shared by all four medicinal materials. Method validation results (Tables S2-S7) confirmed the excellent performance of the developed method, with precision (RSD 0.01%-1.23%), repeatability (RSD 0.05%-2.15%), stability (RSD 0.12%-3.45% over 24 h), and robustness (RSD 0.15%-4.11%) all meeting the requirements specified in the Chinese Pharmacopoeia (2020 edition). These findings verify the method's reliability and suitability for quality control of Panax medicinal materials. The acquired chromatograms were imported in AIA file format into the "Similarity Evaluation System for Chromatographic Fingerprint of Traditional Chinese Medicine (2004A)" for similarity analysis. Characteristic fingerprints were successfully established for XYS (Fig. S1 ), RS (Fig. S2), SQ (Fig. S3), and BSQ (Fig. S4), with similarity ranges of 0.905–0.987, 0.910–0.966, 0.923–0.991, and 0.911–0.983, respectively. The intra-species similarities of all fingerprints exceeded 0.905, demonstrating good reproducibility and strong specificity of the analytical method. Detailed sample information and similarity data are provided in Tables S7–S10. Using the characteristic fingerprint of XYS as a reference, a common pattern fingerprint (Fig. S5) was generated by comparison with the 3 other medicinal materials. The results revealed that the similarities between BSQ and RS, SQ, and XYS were all below 0.203, indicating significant differences in their chemical compositions. In contrast, the similarity between RS and XYS approached 0.9, reflecting a high degree of chemical consistency between these two species. This observation aligned with their shared phylogenetic classification within the Panax medicinal materials and their similar ginsenoside-rich phytochemical profiles, which also accounted for the frequent substitution and confusion between these two species in the commercial market. 3.2 Contents of 11 saponins and 2 polyacetylenes The recovery rates for 11 saponins and 2 polyacetylenes ranged from 97.49% to 107.32%, with relative standard deviations (RSDs) between 0.99% and 4.54% (Table S8), demonstrating that the method exhibits good sensitivity and accuracy for the detection of saponins and polyacetylenes in Panax species. The linearity of the method was assessed by analyzing 6 standard solutions of different concentrations, and the limits of detection (LOD) and quantification (LOQ) were established using signal-to-noise (S/N) ratios of 3 and 10, respectively (Table 1 ). Table 1 Calibration curves, linear ranges, LOD, and LOQ of the analytes. Analytes Calibration curves R 2 Linear range (mg/mL) Notoginsenoside R1 y = 1482.2x + 3.2034 0.9998 0.07 ~ 0.45 Ginsenoside Rg1 y = 1639x + 21.444 0.9991 0.018 ~ 1.71 Ginsenoside Re y = 1226x + 8.0829 0.9992 0.01 ~ 0.92 Ginsenoside Rb1 y = 1167.9x + 62.751 0.9998 0.03 ~ 1.94 Ginsenoside Ro y = 1691.9x + 92.014 1 0.01 ~ 0.43 Ginsenoside Rc y = 825.47x + 2.5608 0.9996 0.09 ~ 2.8 Ginsenoside Rb2 y = 917.53x + 2.3707 0.9996 0.003 ~ 0.22 Ginsenoside Rb3 y = 883.95x + 1.4466 0.9995 0.006 ~ 0.18 Chikusetsusaponin IV y = 1735.5x + 20.492 0.9991 0.02 ~ 1.68 Ginsenoside Rd y = 1491x + 3.5923 0.9999 0.01 ~ 0.45 Chikusetsusaponin IVa y = 1741.4x + 11.189 0.9991 0.01 ~ 0.82 Panaxydol y = 5183.6x + 6.8628 0.9996 0.1125 ~ 0.16 Panaxynol y = 12488x + 229.58 0.9996 0.002 ~ 0.12 This study employed standard curves for content determination. The significant differences in chemical composition among the four medicinal materials were evident from their respective content chromatograms (Fig. 3 ). SQ was uniquely characterized by a high level of notoginsenoside R1 (6.33–9.30 mg/g), which serves as a specific chemical marker for its identification. BSQ exhibited a distinct chemical profile dominated by exceptionally high concentrations of ginsenoside Ro (68.17–128.57 mg/g) along with significant amounts of chikusetsusaponin IV and IVa, clearly distinguishing it from other species. Although XYS and RS share a similar set of ginsenosides (e.g., Rc, Rb2, Rb3), they can be effectively differentiated by their characteristic ginsenoside Re/Rb1 ratio. XYS showed notably higher levels of ginsenoside Re (7.64–23.44 mg/g), while RS displayed a more balanced distribution of protopanaxadiol- and protopanaxatriol-type ginsenosides. 3.3 LC–MS Analysis The total ion chromatograms (TICs) of the four materials obtained by LC–Orbitrap-MS are presented in Fig. 4 . Data processing, including blank subtraction, deconvolution, peak extraction, and database searching against spectral libraries (mzCloud, mzVault) and a self-built database, was performed using Compound Discoverer. Compounds were initially filtered using thresholds of an mzCloud Best Match score ≥ 80 and mzCloud Best Match confidence ≥ 80, or an mzVault Best Match score ≥ 80. To minimize false positives, constituents with low spectral reliability, such as those exhibiting poor fragmentation or low intensity in MS² spectra, were excluded. The identification accuracy was further improved by requiring a minimum number of matched product ions. A targeted screening approach was enhanced by incorporating literature-derived MS¹ and MS² data on known compounds in these four Panax species. A total of 129 compounds were identified across the four species. Specifically, 81, 78, 83, and 85 compounds were detected in BSQ, RS, SQ, and XYS, respectively. These included 34 protopanaxadiol-type saponins, 26 protopanaxatriol-type saponins, 17 C-17 side-chain varied saponins, 14 oleanane-type saponins, 8 ocotillol-type saponins, and 64 other compounds, as summarized in Table 2 . Representative MS² spectra of selected compounds are provided in Fig. S6. Table 2 The compounds identified by LC-MS. NO. RT [min] Identification Formula Diff. [ppm] m/z Reference Ion Fragments Ions (m/z) BSQ RS SQ XYS 1 1.25 Vinaginsenoside R4 C 47 H 80 O 19 -1.58 993.5292 [M + COOH]- 947.5223,785.4705,767.4596, 635.4165 √ √ 2 1.34 Floralquinquenoside D C 42 H 72 O 15 -1.03 861.4862 [M + COOH]- 653.4216, 491.3742, 391.2861 √ √ √ √ 3 1.61 Yesanchinoside B C 48 H 82 O 20 1.12 1023.5393 [M + COOH]- 977.5334,815.4803,653.4267, 491.3742 √ 4 2.17 Ginsenoside Re5 isomer/ Ginsenjilinol isomer C 42 H 72 O 15 -1.38 861.4865 [M + COOH]- 815.4778,653.4274,491.3739 √ √ √ 5 2.35 Vinaginsenoside R4/ Majonoside F5 C 48 H 82 O 19 1.15 1007.5444 [M + COOH]- 961.5388, 815.4813,799.4864, 653.4271, 491.3731 √ 6 2.58 Ginsenoside Re5 isomer/ Ginsenjilinol isomer C 42 H 72 O 15 3.08 861.4879 [M + COOH]- 815.4824,653.4316,491.3760 √ 7 2.95 Floralginsenoside P isomer C 53 H 90 O 23 1.12 1093.5804 [M-H]- 961.5385,799.4838,637.4329, 475.3789 √ 8 3.72 Majonoside R1 C 42 H 72 O 15 0.79 861.4861 [M + COOH]- 815.4807,653.4271,591.3742, 391.2851 √ 9 3.76 Ginsenoside Re1/Re2/Re3 C 48 H 82 O 19 1.21 1007.5445 [M + COOH]- 961.5393, 799.4906,637.4330, 475.3797 √ √ 10 5.17 Yesanchinoside E C 54 H 92 O 23 0.76 1153.6023 [M + COOH]- 1107.5961,961.5403,783.4889, 637.4313,475.3794 √ √ 11 5.63 Quinquenoside F6 C 47 H 80 O 18 1.30 977.5340 [M + COOH]- 931.5258,799.4898,637.4323, 475.3809 √ √ 12 6.83 Ginsenoside Re4 C 47 H 80 O 18 -1.58 977.5342 [M + COOH]- 931.5295,799.4946,637.4330, 475.3756 √ 13 7.07 Ginsenoside Rg1 isomer C 42 H 72 O 14 -1.35 845.4916 [M + COOH]- 799.4857,653.4272,491.3740, 391.2848 √ √ √ √ 14 7.27 Notoginsenoside N/M C 48 H 82 O 19 1.17 961.5375 [M-H]- 799.4866, 637.4327, 475.3786 √ 15 7.39 Notoginsenoside R1 a C 47 H 80 O 18 -0.99 977.5336 [M + COOH]- 931.5287, 799.4870,769.4736, 637.4327, 475.3797 √ √ √ √ 16 8.74 Ginsenoside Re isomer C 48 H 82 O 18 -2.00 991.5503 [M + COOH]- 945.5449,783.4927,637.4338, 475.3811 √ 17 9.11 Notoginsenoside ST5 C 47 H 80 O 18 1.58 977.5342 [M + COOH]- 931.5308,799.4885,637.4332, 475.3801 √ 18 9.72 Quinquenoside IV C 54 H 90 O 24 1.27 1167.5821 [M + COOH]- 1121.5747,959.5238,797.4669, √ √ √ 19 10.57 Ginsenoside Rg1 isomer C 42 H 72 O 14 0.02 845.4904 [M + COOH]- 815.0154, 799.4916,637.4333, 475.3786 √ √ √ 20 10.57 Ginsenoside Rg1 a C 42 H 72 O 14 -0.77 845.4911 [M + COOH]- 799.4871, 637.4330,475.3794, √ √ √ √ 21 11.59 Ginsenoside Re a C 48 H 82 O 18 -1.09 991.5494 [M + COOH]- 945.5438, 783.4899,637.4331, 475.3796 √ √ √ √ 22 13.86 Ginsenoside Rg1 isomer C 42 H 72 O 14 -1.41 845.4916 [M + COOH]- 799.4854,653.4271,491.3740 √ √ √ √ 23 17.37 Malonylginsenoside Rg1 C 45 H 74 O 17 1.42 885.4866 [M-H]- 637.4338,619.4233,475.3789 √ √ 24 17.58 Vinaginsenoside R13 C 48 H 84 O 20 1.53 979.5468 [M-H]- 817.4965, 799.4860,655.4434, 637.4316 √ √ 25 18.09 Malonylginsenoside Rf C 45 H 74 O 17 1.52 885.4867 [M-H]- 799.4896,637.4344,619.4215, 475.3811 √ √ √ 26 19.34 Malonylginsenoside Re C 51 H 84 O 21 0.86 1031.5441 [M-H]- 945.5436, 783.4910,637.4319, 475.3790 √ √ √ √ 27 19.34 Acetyl ginsenoside Re C 50 H 84 O 19 0.49 987.5539 [M-H]- 945.5434,783.4904,637.4319, 475.3792 √ √ √ 28 19.74 Acetyl notoginsenoside R1 C 50 H 84 O 21 2.00 1019.5453 [M-H]- 931.5303,799.4892,637.4332, 619.4190,475.3795 √ √ 29 22.16 B1-20-Glc-Glc-6-Glc-Glc C 54 H 94 O 24 1.77 1171.6138 [M + COOH]- 1125.6068,963.5540,801.5015, 783.4926 √ √ 30 22.49 Pseudoginsenoside Rt2 C 41 H 70 O 14 -1.81 831.4763 [M + COOH]- 785.4711,653.4276,491.3740 √ √ √ 31 22.64 PseudoginsenosideRC1 C 50 H 84 O 19 1.47 1033.5604 [M + COOH]- 945.5449,783.4912,637.4331, 475.3793 √ √ √ 32 23.11 Majonoside R2 C 41 H 70 O 14 1.03 831.4757 [M + COOH]- 785.4705,653.4280,491.3750 √ √ √ 33 23.27 Pseudoginsenoside Rt C 36 H 62 O 10 -1.07 699.4333 [M + COOH]- 653.4262,491.3764 √ √ √ √ 34 23.94 Ginsenoside Rf isomer C 42 H 72 O 14 -1.62 845.4918 [M-H]- 799.4851,637.4342,619.4222, 475.3797 √ √ 35 24.36 Quinquenoside L11 C 42 H 72 O 14 -0.90 845.4912 [M + COOH]- 799.4858, 653.4275,491.3739, √ √ √ √ 36 24.36 Pseudoginsenoside F11 C 42 H 72 O 14 -6.97 799.4794 [M + COOH]- 653.4275,491.3746,415.3222 √ √ √ 37 25.23 24(R)-pseudoginsenoside F11 C 42 H 72 O 14 0.31 799.4832 [M-H]- 637.4327, 475.3780 √ √ √ √ 38 25.77 Quinquenoside L6 C 48 H 80 O 18 1.48 989.5342 [M + COOH]- 943.5281781.4752,619.4212 √ 39 25.84 Ginsenoside Rf isomer C 42 H 72 O 14 -1.61 845.4918 [M + COOH]- 799.4862, 637.4318, 475.3782 √ 40 26.42 Ginsenoside Rf a C 42 H 72 O 14 1.19 845.4914 [M + COOH]- 799.4896, 637.4313, 475.3786 √ 41 26.43 Ginsenoside Rf isomer C 42 H 72 O 14 -1.21 845.4914 [M + COOH]- 799.4861,637.4318,475.3787 √ √ √ √ 42 27.01 Ginsenoside F5 C 41 H 70 O 13 0.73 815.4806 [M + COOH]- 769.4750, 637.4322, 475.3793 √ √ √ √ 43 27.87 Ginsenoside Rf isomer C 42 H 72 O 14 -1.53 845.4917 [M + COOH]- 799.4960,637.4305,475.3822 √ √ √ √ 44 28.55 Ginsenoside Rg2 isomer C 42 H 72 O 13 1.04 829.4965 [M + COOH]- 783.4905,637.4332,475.3794 √ 45 28.59 Ginsenoside F3 C 41 H 70 O 13 -1.42 815.4810 [M + COOH]- 637.4305,475.3792 √ √ 46 28.74 20(S)-Ginsenoside Rh1 a C 36 H 62 O 9 -0.48 683.4379 [M + COOH]- 637.4282,475.3793 √ √ √ √ 47 29.24 Ginsenoside Rg2 a C 42 H 72 O 13 -1.00 829.4963 [M + COOH]- 783.4911, 637.4327, 475.3796 √ √ √ √ 48 29.38 Ginsenoside Ra3 C 59 H 100 O 27 0.47 1285.6428 [M + COOH]- 1107.5964,945.5447,783.4913, 621.4388 √ √ √ √ 49 29.38 Notoginsenoside R4 C 59 H 100 O 27 -0.58 1285.6430 [M + COOH]- 1239.6398,1107.5957,1077.5864,945.5438,783.4894 √ √ 50 29.68 notoginsenoside R2 C 41 H 70 O 13 -1.75 815.4813 [M + COOH]- 769.4719, 637.4291, 475.3798 √ √ √ 51 29.70 20(R)-Ginsenoside Rh1 C 36 H 62 O 9 -1.27 683.4385 [M + COOH]- 637.4349, 475.3799 √ √ √ 52 30.64 Notoginsenoside Fa C 59 H 100 O 27 0.04 1285.6434 [M + COOH]- 1107.5964,945.5482,783.4912, 621.4382, 459.3853 √ √ √ 53 30.65 Ginsenoside Ro isomer C 48 H 76 O 19 1.25 955.4920 [M-H]- 793.4400,731.4383,631.3849, 567.3701 √ √ 54 30.79 Malony notoginoside R4 C 62 H 102 O 30 -0.26 1325.6380 [M-H]- 1239.6392,1107.5951,945.5432,783.4902,621.4391 √ √ 55 31.02 Ginsenoside Ro isomer C 48 H 76 O 19 1.22 955.4920 [M-H]- 793.4360, 631.3850, 455.3521 √ √ 56 31.19 Ginsenoside Rh7 C 36 H 60 O 9 -0.89 681.4225 [M + COOH]- 635.4201,473.3641 √ √ 57 31.25 Notoginsenoside I C 54 H 92 O 22 0.95 1091.6011 [M-H]- 1091.6027, 929.5491,767.4955, 605.4443 √ √ √ √ 58 31.42 Ginsenoside Ro isomer C 48 H 76 O 19 1.12 955.4919 [M-H]- 793.4396, 731.4379, 613.3751, 569.3850 √ √ √ √ 59 31.99 5,6-Dihydroginsenoside Rb1 C 54 H 90 O 23 1.19 1105.5802 [M-H]- 943.5283, 781.4746, 619.4221, 457.3685 √ √ √ 60 32.03 Ginsenoside Ro isomer C 48 H 76 O 19 1.38 955.4921 [M-H]- 793.4406, 731.4396, 631.3869, 569.3854, 523.3801 √ √ √ 61 32.23 Ginsenoside Rh8 C 36 H 60 O 9 -1.21 681.4228 [M + COOH]- 626.2918,473.3637 √ 62 32.38 Ginsenoside Rb1 a C 54 H 92 O 23 -0.36 1153.6016 [M + COOH]- 1107.5963,945.5442,783.4905, 621.4370 √ √ √ 63 32.54 Yesanchinoside D/ Vinaginsenoside R1 C 44 H 74 O 15 -0.88 887.5018 [M + COOH]- 841.4966,799.4870,653.4386, 587.3959,491.3762 √ √ √ 64 32.58 Malonynotoginoside R4 isomer C 62 H 102 O 30 -0.12 1325.6382 [M-H]- 1239.6395,1107.5956,1089.5851, 945.5433, 783.4905 √ 65 33.18 Ginsenoside F1 C 36 H 62 O 9 -0.33 683.4378 [M + COOH]- 637.4292,475.3796 √ √ √ √ 66 33.51 Ginsenoside Ro isomer C 48 H 76 O 19 1.59 955.4923 [M-H]- 793.4389,731.4380, √ 67 33.59 Ginsenoside Rc a C 53 H 90 O 22 1.01 1123.5919 [M + COOH]- 945.5450, 783.4906, 621.4368, 459.3876 √ √ √ 68 33.59 Ginsenoside V C 54 H 92 O 24 0.23 1123.5908 [M-H]- 1077.5855,945.5249,783.4904, 621.4374,459.3857 √ √ √ 69 33.73 MalonynotoginosideR4 isomer C 62 H 102 O 30 -0.41 1325.6378 [M-H]- 1239.6381,1107.5946,945.5421, 783.4898 √ 70 33.84 Malony ginsenoside Rb1 C 57 H 94 O 26 0.89 1193.5971 [M-H]- 1107.5958, 945.5427,783.4899, 621.4373 √ √ √ 71 33.97 Ginsenoside Ro a C 48 H 76 O 19 1.29 955.4920 [M-H]- 793.4397, 613.3754, 569.3854, 455.3543 √ √ 72 34.24 Malonyginsenoside Rb1 isomer C 57 H 94 O 26 1.09 1193.5974 [M-H]- 1107.5973,1089.5869,945.5444,783.4910, 621.4377,459.3876 √ 73 34.44 Ginsenoside Rs1/ Ginsenoside Rs2 C 55 H 92 O 23 -2.26 1119.5931 [M-H]- 1077.5864,1059.5767,945.5444,783.4908, 765.4805 √ √ 74 34.68 Malony ginsenoside Rb1 isomer C 57 H 94 O 26 1.38 1193.5977 [M-H]- 1107.5973,945.5436,783.4921, 621.4385 √ √ √ √ 75 35.23 Chikusetsusaponin Ⅱ C 42 H 66 O 14 1.27 793.4390 [M-H]- 631.3865, 569.3864, 455.3536 √ √ 76 35.28 Ginsenoside Rb2 a C 53 H 90 O 22 -1.26 1123.5920 [M + COOH]- 1077.5863, 945.5488,783.4912, 621.4350, 459.3821 √ √ √ 77 35.46 Malonyl ginsenoside Ro C 51 H 78 O 22 0.23 1041.4931 [M-H]- 997.5026,937.4821,835.4489, 775.4276,731.4383 √ 78 35.56 Malony ginsenoside Rb1 isomer C 57 H 94 O 26 5.41 1193.5896 [M + COOH]- 1107.5968,1078.5889,945.5440,783.4877,621.4351 √ √ √ √ 79 35.56 Isomeric Ginsenoside V C 54 H 92 O 24 -1.36 1123.5921 [M + COOH]- 1077.5857,945.5440,915.5322, 783.4895,621.4367 √ 80 35.60 Malony ginsenoside Rb1 isomer C 57 H 94 O 26 -7.04 1193.5877 [M-H]- 1107.5960,1078.5892,945.5432,783.4895,621.4338 √ 81 35.64 Malonyl ginsenoside Ro isomer C 51 H 78 O 22 1.63 1041.4929 [M-H]- 997.50305,835.4504,773.4487, 613.3742,569.3854 √ √ 82 35.75 Pseudoginsenoside RT1 a C 47 H 74 O 18 1.32 925.4815 [M-H]- 763.4280, 613.3746, 569.3858 √ √ 83 35.85 Ginsenoside Rb3 a C 53 H 90 O 22 -0.69 1123.5914 [M + COOH]- 1077.5866, 945.5435,783.4907, 621.4376, 459.3900 √ √ √ √ 84 36.03 Chikusetsusaponin IV a C 47 H 74 O 18 0.97 925.4811 [M-H]- 793.4382, 613.3750, 569.3852, 455.3536 √ √ 85 36.28 PPT-Glc-Ace C 38 H 64 O 10 1.19 725.4490 [M + COOH]- 637.4321,475.3799 √ 86 36.74 Quinquenoside R1 C 56 H 94 O 24 -0.96 1195.6129 [M + COOH]- 1107.5967,1089.5863,945.5443,783.4913, 621.4382, 459.3855 √ √ √ √ 87 36.83 Malonyl ginsenoside Rb3 C 56 H 92 O 25 1.04 1163.5867 [M-H]- 1077.5864, 945.4912,765.4815, 621.4384, 459.3872 √ √ 88 37.32 Chikusetsu saponin IVa a C 42 H 66 O 14 1.22 793.4390 [M-H]- 631.3861, 569.3861, 455.3511 √ √ 89 37.60 Yesanchinoside F C 56 H 94 O 24 0.35 1195.6120 [M + COOH]- 1107.5969,1089.5864,945.5446,783.4912,621.4384 √ 90 37.85 Malonyl ginsenoside Rb2 C 56 H 92 O 25 0.27 1163.5858 [M-H]- 1077.5851, 945.5427, 783.4897 √ √ √ 91 37.93 Ginsenoside Rg8/Rg9 C 42 H 70 O 13 1.41 827.4811 [M + COOH]- 781.4754, 619.4219, 457.3698 √ 92 38.01 Chikusetsusaponin IVa isomer C 42 H 66 O 14 1.40 793.4391 [M-H]- 631.3853, 569.3845, 455.3561 √ √ √ 93 38.38 Malonyl ginsenoside Rc C 56 H 92 O 25 2.40 1163.5867 [M-H]- 1077.5867,945.5447,783.4909, 621.4376 √ √ √ 94 38.48 Acetyl ginsenoside Rd C 50 H 84 O 19 -2.68 987.5508 [M-H]- 945.5446,783.4912,621.4378, 459.3848 √ √ √ 95 38.48 Malonyl ginsenoside Rd isomer C 51 H 84 O 21 1.40 1031.5447 [M-H]- 987.5585,945.5449,783.4917, 621.4385,459.3840 √ √ √ √ 96 39.17 Notoginsenoside K C 48 H 82 O 18 -1.73 991.5500 [M + COOH]- 945.5437,783.4903,621.4375, 459.3861 √ √ 97 39.24 Acetyl ginsenoside Rd isomer C 50 H 84 O 19 0.73 987.5552 [M-H]- 945.5456,783.4921,765.4807, 621.4385 √ √ 98 39.42 Malonyl ginsenoside Rd isomer C 51 H 84 O 21 1.45 1031.5447 [M-H]- 945.5434, 783.4896, 621.4358 √ √ 99 39.53 Acetyl ginsenoside Fc C 55 H 92 O 23 0.32 1165.6015 [M + COOH]- 1077.58451059.5743,945.5427, 783.4887, 765.4777 √ √ 100 39.98 Ginsenoside Rd a C 48 H 82 O 18 -5.00 945.5381 [M-H]- 783.4950, 621.4378, 459.3838 √ √ 101 39.99 Gypenoside XVII C 48 H 82 O 18 1.10 945.5401 [M-H]- 945.5480, 783.4895, 621.4382, 459.3840 √ √ √ √ 102 40.28 Quinquenoside Ⅲ C 50 H 84 O 19 -1.76 1033.5607 [M + COOH]- 987.5557,945.5457,783.4915, 621.4384,459.3849 √ √ √ √ 103 40.29 Acetyl ginsenoside Re C 50 H 84 O 19 1.30 1033.5603 [M + COOH]- 987.5538,945.5444,925.5031, 783.4903,621.4377 √ √ √ 104 40.30 PPD-Glc-(Glc-Glc)-2malonyl C 54 H 86 O 24 1.28 1117.5451 [M-H]- 987.5561, 945.5461, 825.5042, 783.4879, 765.4809, 621.4365 √ √ √ √ 105 40.48 Acetyl ginsenoside Rd isomer C 50 H 84 O 19 1.06 987.5543 [M-H]- 945.5440,927.5318,783.4946, 621.4375 √ 106 40.59 Acetyl ginsenoside Rd isomer C 50 H 84 O 19 -0.75 987.5529 [M-H]- 945.5447, 783.4916, 621.4379, 459.3849 √ √ 107 41.00 Notoginsenoside Fe C 47 H 80 O 17 1.81 961.5395 [M + COOH]- 915.5329, 753.4825, 621.4378, 459.3850 √ 108 41.00 Gypenoside XLVI C 48 H 82 O 19 1.60 961.5393 [M-H]- 915.5339, 753.4791, 621.4377, 459.3860 √ √ √ √ 109 41.04 Malonyl ginsenoside Rd isomer C 51 H 84 O 21 1.56 1031.5448 [M-H]- 945.5442,783.4913,621.4382 √ √ √ √ 110 41.91 Malonyl ginsenoside Rd isomer C 51 H 84 O 21 1.47 1031.5448 [M-H]- 945.5435,783.4941,621.4349 √ √ √ 111 42.17 Malonyl ginsenoside Rd isomer C 51 H 84 O 21 1.50 1031.5448 [M-H]- 945.5446, 783.4896, 621.4393 √ √ √ 112 42.45 Vinaginsenoside R3 C 48 H 82 O 17 -1.24 975.5546 [M + COOH]- 929.5486,767.4965,605.4433 √ 113 42.49 Notoginsenoside Ft1 C 47 H 80 O 17 1.05 915.5293 [M-H]- 783.4911, 621.4381, 459.3839 √ √ √ √ 114 43.04 Gypenoside IX C 47 H 80 O 17 1.79 961.5394 [M + COOH]- 915.5339, 783.4954, 621.4392, 459.3845 √ 115 43.65 Gypenoside XLVI isomer C 48 H 82 O 19 1.27 961.5390 [M-H]- 915.5302, 783.4879, 621.4372, 459.3857 √ √ √ √ 116 44.02 Acetyl pseudoginsenside RC1 C 52 H 86 O 20 1.80 1029.5658 [M-H]- 945.5441,927.5289,783.4958, 765.4800,621.4363 √ √ √ 117 44.28 Ginsenoside F4 C 42 H 70 O 12 2.23 811.4868 [M + COOH]- 765.4805,619.4224,457.3719 √ √ 118 46.67 Ginsenoside F2 a C 42 H 72 O 13 -0.95 829.4963 [M + COOH]- 783.4917,621.4370,459.3877 √ √ √ √ 119 47.16 Chikusetsusaponin Ib C 47 H 74 O 18 0.91 925.4811 [M-H]- 793.4390, 731.4374, 569.3846, 455.3529 √ 120 48.97 20(S)-Ginsenoside Rg3 C 42 H 72 O 13 1.52 829.4967 [M + COOH]- 783.4905, 621.4426, 459.3846 √ √ 121 48.98 20(R)-Ginsenoside Rg3 a C 42 H 72 O 13 1.52 829.4967 [M + COOH]- 783.4902, 621.4388, 459.3860 √ √ 122 49.56 Ginsenoside Rk1 C 42 H 70 O 12 1.94 811.4867 [M + COOH]- 765.4808,603.4275 √ 123 49.83 Pseudoginsenoside Rp1 C 41 H 64 O 13 0.79 763.4280 [M-H]- 613.3749, 569.3851, 509.3635, 455.3528 √ √ √ 124 49.92 Ginsenoside Rs5 C 44 H 72 O 13 0.62 807.4906 [M-H]- 765.4796,603.4274 √ 125 50.27 Ginsenoside Rs4 C 44 H 72 O 13 1.09 807.4909 [M-H]- 765.4796,603.4257 √ 126 51.70 20(S)-Ginsenoside Rh2 a C 36 H 62 O 8 -1.06 667.4434 [M + COOH]- 621.4500, 459.3846, 161.0460 √ √ √ √ 127 51.92 Ginsenoside Rg5 C 42 H 70 O 12 1.52 765.4783 [M-H]- 603.4280, 441.3755 √ √ √ √ 128 52.14 Ginsenoside Rg6 C 42 H 70 O 12 1.33 765.4784 [M-H]- 603.4279, 441.3759 √ √ √ √ 129 52.68 Ginsenoside Rh4 C 36 H 60 O 8 -1.13 665.4278 [M + COOH]- 457.3695 √ √ √ √ Note: The superscript letter "a" indicates that the compound was identified by comparison with an authentic reference standard. The check mark (√) indicates that the component was detected in the sample. In negative-ion mode, the MS1 spectra of protopanaxadiol-type ginsenosides were dominated by the formate adduct [M + HCOO]⁻ and the deprotonated ion [M–H]⁻. High-energy collision-induced dissociation (CID) experiments revealed a stepwise loss of sugar substituents, ultimately affording the protopanaxadiol aglycone. Diagnostic fragments appeared at m/z 459.3900. Ginsenoside Rb3 (compound 83) was selected to exemplify the cleavage pattern. It eluted at a retention time (RT) = 35.85 min and exhibited a precursor ion at m/z 1077.5866 ([M + HCOO]⁻, C₅₃H₉₀O₂₂). The MS² spectrum displayed sequential losses of one xylose residue (–C₅H₈O₄) at m/z 945.5435, one glucose residue (–C₆H₁₀O₅) at m/z 783.4907, and two additional glucose units at m/z 621.4376 and 459.3900. These data, together with comparison to the reference standard and literature, unambiguously identified compound 83 as. Its fragmentation pathway is illustrated in Fig. 4 a. Similarly, protopanaxatriol-type ginsenosides yield prominent [M + HCOO]⁻ and [M–H]⁻ ions. Its MS² showed sequential excision of glucose units, termina ginsenoside Rb3ting in the protopanaxatriol aglycone whose characteristic fragments occur at m/z 799.4871, 637.4330, and 475.3794. Ginsenoside Rg1 (compound 21) was eluted at 10.57 min with [M + HCOO]⁻ at m/z 845.4911 (C₄₂H₇₂O₁₄). The spectrum displayed successive losses of two glucose residues (–C₆H₁₀O₅) to produce m/z 637.4330 and 475.3794, confirming compound 21 as ginsenoside Rg1 (Fig. 4 b). Oleanane-type ginsenosides are also detected as [M + HCOO]⁻ and [M–H]⁻ ions. Their sugar moiety is stripped stepwise, delivering the oleanolic acid aglycone (m/z 455). Ginsenoside Ro (compound 71) eluted at 33.97 min with [M–H]⁻ at m/z 955.4920 (C₄₈H₇₆O₁₉). Sequential losses of two glucose units (–C₆H₁₀O₅) and one glucuronic acid residue (–C₆H₈O₆) generated fragments at m/z 793.4397, 631.4370, and 455.3543, identifying compound 71 as ginsenoside Ro (Fig. 4 c). Ocotillol-type ginsenosides also produced abundant [M + HCOO]⁻ and [M–H]⁻ ions. Their MS² revealed progressive removal of glucose units, yielding the ocotillol aglycone (m/z 491). Majoroside R1 (compound 8) was eluted at 3.72 min ([M + HCOO]⁻, m/z 861.4861, C₄₂H₇₂O₁₅). Stepwise loss of two glucose residues afforded m/z 653.4271 and the diagnostic fragment at m/z 491.3742. Subsequent elimination of C₃H₆O and H₂O produced an additional ocotillol-type ion at m/z 415.3212. These data enabled the identification of compound 8 as majoroside R1 (Fig. 4 d). The C-17 side-chain-modified ginsenosides were identified via their representative deprotonated ions ([M + HCOO]⁻ and [M–H]⁻) and a characteristic fragment ion at m/z 455. Ginsenoside Rg5 (compound 128) eluted at 51.92 min ([M–H]⁻, m/z 765.4783). Sequential losses of two glucose units (–C₆H₁₀O₅) yielded fragments at m/z 603.4280 and 441.3755, confirming compound 128 as ginsenoside Rg5 (Fig. 4 e). The peak area data of 129 compounds identified by mass spectrometry were imported into SIMCA 14.1 software for principal component analysis (PCA) and orthogonal partial least squares-discriminant analysis (OPLS-DA). The resulting score plots are shown in Fig. 5 . Both PCA and OPLS-DA facilitate the visualization of overall clustering trends among samples[ 17 ], where the dispersion of points reflects the similarities or differences in composition across samples. In the PCA score plot (Fig. 5 A), Panax japonicus and Panax notoginseng were clearly distinguished from Panax ginseng and Panax quinquefolius; however, RS and Panax XYS were not effectively separated, a finding consistent with the chemical fingerprint similarity assessment. In contrast, the supervised OPLS-DA method effectively reduced errors associated with non-experimental factors, yielding more accurate classification results[ 18 ]. A 200-permutation test confirmed the model’s robustness, with parameters R²Y = 0.982, R²X = 0.806, Q² = 0.964, and P < 0.005, indicating high explanatory and predictive power without overfitting (Figs. 5 C and 5 D)[ 19 ]. Based on a variable importance in projection (VIP) threshold greater than 1.0, 55 differential compounds with contributions were screened, while using a VIP threshold greater than 1.5, 15 significantly contributing differential compounds were identified. The relative abundances of these 15 marker compounds across the four Panax species are visualized in Fig. 6 . As shown in Fig. 7 , the heatmap visually illustrates the differential relative abundance of 55 ginsenosides across four Panax species. The results demonstrate distinct interspecies clustering, indicating that the accumulation patterns of characteristic ginsenosides were markedly species-specific. Specifically, BSQ was significantly enriched in oleanane-type saponins (e.g., chikusetsusaponin IV and IVa), while SQ was characterized by notoginsenoside R1 and Ft1 as its predominant markers. Although XYS and RS shared certain protopanaxadiol- and protopanaxatriol-type ginsenosides, the former exhibited significantly higher levels of malonylated ginsenosides, further delineating the chemical boundaries between the two species. 4. Conclusion In this study, an integrated HPLC and UPLC–Orbitrap–MS strategy was successfully established for the comprehensive chemical characterization, quantitative evaluation, and species authentication of four medicinally important Panax medicines. The validated HPLC method permitted the reproducible quantification of 11 major ginsenosides and 2 polyacetylenes in 41 commercial batches. Similarity evaluation of the generated fingerprints revealed high intra-specific consistency and pronounced inter-specific divergence, underscoring the specificity of the approach. Multivariate modelling (PCA/OPLS-DA) delivered unambiguous species segregation; the final OPLS-DA model possessed excellent explanatory and predictive power and afforded clear chemical distinction even between the closely related RS and XYS[ 20 – 22 ]. Heat-map visualisation further demonstrated species-specific accumulation patterns of these markers, underscoring their utility as quality-control indicators. These findings offer a scientific basis for quality assessment, authentication, and standardization of Panax-derived products. The integrated approach enhanced the capability to detect adulteration and ensure product consistency and supported the development of a more robust quality control system for traditional herbal medicines. Future studies may focus on correlating these chemical markers with pharmacological activities to further validate their roles as quality markers. Declarations Author contributions: Conceptualization, X.L.; methodology, A.W. and L.C.; investigation, X.L. and J.L.; formal analysis, B.L. and J.C.; writing – original draft preparation, S.W. and Y.Q.; writing – review & editing, X.N. and X.B..; project administration, W.W.; supervision, H.Y.; Funding acquisition, C.P. All authors have read and agreed to the published version of the manuscript. Funding: This work was supported by the Natural Science Foundation of Hunan Province [Grant No.2024JJ8237, 2023JJ60130, and 2025JJ80144] and National Natural Science Foundation of China (Grant No. 82405012). Conflicts of Interest: The authors declare that they have no competing interests. References Yang, W.Z.; Hu, Y.; Wu, W.Y.; Ye, M.; Guo, D.A. Saponins in the genus Panax L. (Araliaceae): a systematic review of their chemical diversity. 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6","display":"","copyAsset":false,"role":"figure","size":351133,"visible":true,"origin":"","legend":"\u003cp\u003eSee image above for figure legend\u0026nbsp;\u003c/p\u003e","description":"","filename":"6.png","url":"https://assets-eu.researchsquare.com/files/rs-7772424/v1/165b5e486b07a7400dd6165b.png"},{"id":93953796,"identity":"7469e75d-81a7-4903-bae4-9c84148696bc","added_by":"auto","created_at":"2025-10-20 15:37:55","extension":"png","order_by":7,"title":"Figure 7","display":"","copyAsset":false,"role":"figure","size":1353516,"visible":true,"origin":"","legend":"\u003cp\u003eSee image above for figure legend\u0026nbsp;\u003c/p\u003e","description":"","filename":"7.png","url":"https://assets-eu.researchsquare.com/files/rs-7772424/v1/db7d10ed45af41b5fac89748.png"},{"id":98813846,"identity":"3bf2d606-b491-4f56-8864-8bf3612569ad","added_by":"auto","created_at":"2025-12-22 16:05:07","extension":"pdf","order_by":0,"title":"","display":"","copyAsset":false,"role":"manuscript-pdf","size":5800278,"visible":true,"origin":"","legend":"","description":"","filename":"manuscript.pdf","url":"https://assets-eu.researchsquare.com/files/rs-7772424/v1/042462a7-dd32-4cc5-9f39-6169b8393d31.pdf"},{"id":93953784,"identity":"7f9c2d24-4bb9-421d-816b-614afeb14620","added_by":"auto","created_at":"2025-10-20 15:37:55","extension":"docx","order_by":0,"title":"","display":"","copyAsset":false,"role":"supplement","size":2475326,"visible":true,"origin":"","legend":"","description":"","filename":"SupplementaryMaterials.docx","url":"https://assets-eu.researchsquare.com/files/rs-7772424/v1/a743b66f0aff4c76575e6d08.docx"}],"financialInterests":"No competing interests reported.","formattedTitle":"Application of HPLC Combined with UPLC–Orbitrap–MS in Chemical Characterization, Quantitative Detection, and Species Authentication of Four Panax-derived Products","fulltext":[{"header":"1. Introduction","content":"\u003cp\u003ePlants of the Panax species represent a pharmaceutically significant group with demonstrated therapeutic benefits in human health[\u003cspan citationid=\"CR1\" class=\"CitationRef\"\u003e1\u003c/span\u003e]. Although the roots of P. ginseng (RS), P. quinquefolius (XYS), P. notoginseng (SQ), and P. japonicus (BSQ), share close genetic relationships and contain similar bioactive compounds, they exhibit distinct properties, flavors, and clinical applications. Different Panax species vary in their traditional Chinese medicine (TCM) nature and core functional properties. RS (warm nature) is well-recognized for its adaptogenic and energy-enhancing effects[\u003cspan additionalcitationids=\"CR3\" citationid=\"CR2\" class=\"CitationRef\"\u003e2\u003c/span\u003e\u0026ndash;\u003cspan citationid=\"CR4\" class=\"CitationRef\"\u003e4\u003c/span\u003e]. BSQ (mildly warm) exerts extensive antioxidant, immunomodulatory, and cardioprotective activities[\u003cspan citationid=\"CR5\" class=\"CitationRef\"\u003e5\u003c/span\u003e]. XYS (cool nature) shows efficacy in anti-fatigue and anti-anxiety applications[\u003cspan citationid=\"CR6\" class=\"CitationRef\"\u003e6\u003c/span\u003e]. SQ (warm nature) is mainly used for its haemostatic and circulatory benefits[\u003cspan citationid=\"CR7\" class=\"CitationRef\"\u003e7\u003c/span\u003e].\u003c/p\u003e\u003cp\u003eThese four herbal materials are among the most widely used medicinal plants globally and hold significant shares in the natural product market. Growing demand has highlighted differences in their pharmacological effects, indications, and clinical uses, leading to varying medicinal and economic values[\u003cspan citationid=\"CR8\" class=\"CitationRef\"\u003e8\u003c/span\u003e]. However, their similar chemical profiles have led to widespread issues of adulteration, substitution, and counterfeit products in the market, particularly in powdered formulations and raw materials for proprietary medicines[\u003cspan citationid=\"CR9\" class=\"CitationRef\"\u003e9\u003c/span\u003e]. For instance, XYS is sometimes adulterated into RS products to reduce costs, and the roots of P. vietnamensis are often mistakenly or intentionally used in place of SQ[\u003cspan additionalcitationids=\"CR11\" citationid=\"CR10\" class=\"CitationRef\"\u003e10\u003c/span\u003e\u0026ndash;\u003cspan citationid=\"CR12\" class=\"CitationRef\"\u003e12\u003c/span\u003e]. Such practices compromised therapeutic outcomes and raised safety concerns, damaging the credibility of the herbal supply chain. Thus, there is an urgent need to develop accurate species identification methods and investigate the relationship between chemical composition and quality to ensure efficacy, safety, and market standardization.\u003c/p\u003e\u003cp\u003eThe establishment of rapid and reliable identification methods and quality assessment protocols for these four Panax species is imperative. Recent advances in analytical techniques have enabled various effective strategies. Chromatographic methods, including high-performance liquid chromatography (HPLC) and ultra-performance liquid chromatography (UPLC), coupled with mass spectrometry (LC\u0026ndash;MS) and chemometrics, have shown great promise in the compositional analysis of Panax plants[\u003cspan additionalcitationids=\"CR14\" citationid=\"CR13\" class=\"CitationRef\"\u003e13\u003c/span\u003e\u0026ndash;\u003cspan citationid=\"CR15\" class=\"CitationRef\"\u003e15\u003c/span\u003e]. Notably, the integration of chromatographic fingerprinting with high-resolution mass spectrometry (MS) and chemometric analyses, such as principal component analysis (PCA) and orthogonal projection to latent structures\u0026ndash;discriminant analysis (OPLS-DA), markedly improves the scientific rigor and reliability of the results[\u003cspan citationid=\"CR16\" class=\"CitationRef\"\u003e16\u003c/span\u003e]. This combined approach facilitates a transition from single-compound quantification toward holistic quality assessment and enables deeper mechanistic insights into the pharmacological properties of phytochemical compositions.\u003c/p\u003e\u003cp\u003eTo address quality control and species authentication challenges of Panax-derived products, this study validated an HPLC method for simultaneous quantification of 11 major ginsenosides and 2 polyacetylenes, identified saponins and clarified their fragmentation pathways in four Panax species via high-resolution LC-MS, and screened potential quality markers through chemometric modeling. This work thus holds significance in establishing a more scientific and comprehensive quality evaluation system for Panax plants, a development that aids in resolving quality control and species authentication issues of Panax-derived medicinal products.\u003c/p\u003e"},{"header":"2. Materials and Methods","content":"\u003cdiv id=\"Sec3\" class=\"Section2\"\u003e\u003ch2\u003e2.1 Reagents and Chemicals\u003c/h2\u003e\u003cp\u003eMethanol and acetonitrile of HPLC grade were sourced from Sigma\u0026ndash;Aldrich (St. Louis, USA). Other reagents were procured through the China National Medicines Group Chemical Reagent Co., Ltd. (Shanghai, China). Purified water for all aqueous solutions was supplied by China Resources C\u0026rsquo;estbon Beverage Co., Ltd. (Shenzhen, China). The Nylon filter (0.22 \u0026micro;m, 13 mm in diameter) was supplied by Hangzhou Special Paper Industry Co., Ltd. (Hangzhou, China). The reference standards, including notoginsenoside R1, ginsenoside Rg1, ginsenoside Re, ginsenoside Rb1, ginsenoside Ro, ginsenoside Rc, ginsenoside Rb2, ginsenoside Rb3, chikusetsusaponin IV, ginsenoside Rd, chikusetsusaponin IVa, panaxydol, and panaxynol, were obtained from Shanghai Yuanye Bio-Technology Co., Ltd. (Shanghai, China). A purity level of over 98% was determined for all reference standards by HPLC analysis.\u003c/p\u003e\u003c/div\u003e\u003cdiv id=\"Sec4\" class=\"Section2\"\u003e\u003ch2\u003e2.2 Plant Materia\u003c/h2\u003e\u003cp\u003eA total of 41 medicinal material batches, including 11 batches of BSQ, 10 batches of SQ, 10 batches of XYS, and 10 batches of RS, were collected from Hunan, Hubei, Yunnan, and Jilin provinces in China, as well as Canada and other regions (Table \u003cspan refid=\"MOESM1\" class=\"InternalRef\"\u003eS1\u003c/span\u003e). Professor Wei Wang from the School of Pharmacy at Hunan University of Chinese Medicine has authenticated all the materials, which are now stored in the TCM and Ethnomedicine Innovation \u0026amp; Development International Laboratory.\u003c/p\u003e\u003c/div\u003e\u003cdiv id=\"Sec5\" class=\"Section2\"\u003e\u003ch2\u003e2.3 Preparation of Sample and Standard Solution\u003c/h2\u003e\u003cp\u003eAccurately weighed 1.0 g of powdered sample (passed through a No. 5 sieve) was placed in a stopper-sealed conical flask. Exactly 25 mL of methanol was added, and the total weight was recorded. After ultrasonication (30 min) and cooling to room temperature, the weight was measured again, with any solvent loss compensated by adding methanol. The mixture was vortexed, filtered, and the resulting filtrate was further passed through a 0.22 \u0026micro;m microporous membrane to obtain the final test solution for analysis. Accurately weighed appropriate amounts of the reference standards were separately placed in 5 mL volumetric flasks and dissolved in methanol to prepare stock solutions. These stock solutions were diluted to an appropriate multiple and then used for analysis.\u003c/p\u003e\u003c/div\u003e\u003cdiv id=\"Sec6\" class=\"Section2\"\u003e\u003ch2\u003e2.4 HPLC analysis\u003c/h2\u003e\u003cp\u003eThe analysis was performed using an Agilent 1260 Infinity II series high-performance liquid chromatography (HPLC) system (Agilent Technologies, Santa Clara, CA, USA), equipped with a binary pump, an autosampler, a thermostatted column compartment, and a diode array detector. Elution was carried out using a gradient program with acetonitrile (A) and 0.1% phosphoric acid in water (B) as the mobile phase at a flow rate of 1 mL/min as follows: 0\u0026ndash;20 min, 20\u0026ndash;20% A; 20\u0026ndash;60 min, 20\u0026ndash;40% A; 60\u0026ndash;70 min, 40\u0026ndash;60% A; 70\u0026ndash;75 min, 60\u0026ndash;73% A; 75\u0026ndash;90 min, 73\u0026ndash;95% A; 90\u0026ndash;100 min, 95% A. The detection wavelength was set at 203 nm. Both the column and sample compartment temperatures were maintained at 24\u0026deg;C. The injection volume was 5 \u0026micro;L. Separation was achieved using an Agilent Eclipse XDB-C18 column (4.6 mm \u0026times; 250 mm, 5 \u0026micro;m).\u003c/p\u003e\u003cp\u003eFor precision evaluation, the identical sample was injected 6 times consecutively. The sample\u0026rsquo;s stability was determined by conducting analyses at intervals of 0, 4, 8, 12, 24, and 48 h. Reproducibility was tested by preparing 6 parallel samples. Data regarding the retention times and peak areas of corresponding peaks, along with the relative standard deviations for the retention and peak areas of 11 saponins and 2 polyacetylenes, were both logged and computed. Recovery was assessed by spiking at high, medium, and low amounts of standards into weighed samples by 3 replicates, and analyzed by the HPLC method. Recovery was calculated according to the following equation:\u003c/p\u003e\u003cp\u003eRecovery (%)\u0026thinsp;=\u0026thinsp;measure amount\u0026thinsp;\u0026minus;\u0026thinsp;original amount spiked amount \u0026times; 100%.\u003c/p\u003e\u003c/div\u003e\u003cdiv id=\"Sec7\" class=\"Section2\"\u003e\u003ch2\u003e2.5 LC\u0026ndash;MS Conditions\u003c/h2\u003e\u003cp\u003eChromatography was conducted on a Hypersil GOLD\u0026trade; Aq-C18 column (100 mm \u0026times; 2.1 mm, 1.9 \u0026micro;m) using a Vanquish\u0026trade; Flex UPLC system at 25℃. The elution utilized a gradient of acetonitrile (A) and 0.1% formic acid in water (B) at 0.3 mL/min: 0\u0026ndash;10 min, 20\u0026thinsp;~\u0026thinsp;20% A; 10\u0026ndash;45 min, 20\u0026ndash;40% A; 45\u0026ndash;50 min, 40\u0026ndash;60% A; 50\u0026ndash;60 min, 60\u0026ndash;95% A; 60\u0026ndash;75 min, 95% A. The sample compartment temperature was maintained at 25℃, and the injection volume was 4 \u0026micro;L. The ESI-equipped Orbitrap Exploris 120 mass spectrometer functioned in negative polarity modes, conducting both full scan and data-dependent MS/MS (Full MS/ddMS2 ) analyses with parameters finely tuned for optimal performance. For MS1, the positive mode was set at a spray voltage of 3500 V, while the negative mode was at 2500 V. The gas flow for sheath, auxiliary, and sweep gases were tuned to 50, 10, and 0 Arb, respectively. Meanwhile, the temperatures for the ion transfer tube and vaporizer were stabilized at 325℃ and 350℃, respectively. A resolution of 60,000 and a scanning range of 100\u0026ndash;1300 Da were utilized. The HCD Collision Energy for dd-MS2 was set to 30% and the resolution was adjusted to 15,000.\u003c/p\u003e\u003c/div\u003e\u003cdiv id=\"Sec8\" class=\"Section2\"\u003e\u003ch2\u003e2.6 Data Analysis\u003c/h2\u003e\u003cp\u003eSimilarity analysis was performed using the \"Similarity Evaluation System for Chromatographic Fingerprint of Traditional Chinese Medicine (2002A)\". The cosine similarity algorithm was applied to calculate the similarity between chromatographic profiles, enabling a comprehensive evaluation of the overall consistency of chromatographic patterns across different samples. Mass spectrometry data were subjected to raw data preprocessing and format conversion using Freestyle 1.8 software under the Thermo Fisher Scientific platform. PCA and OPLS-DA models were analyzed using SIMCA 14.1 software.\u003c/p\u003e\u003c/div\u003e"},{"header":"3. Results and Discussion","content":"\u003cdiv id=\"Sec10\" class=\"Section2\"\u003e\u003ch2\u003e3.1 HPLC fingerprint\u003c/h2\u003e\u003cp\u003eThe HPLC analytical method established in this study achieved satisfactory separation for 13 characteristic components, including notogisenoside R1, ginsenoside Rg1, ginsenoside Re, ginsenoside Rb1, ginsenoside Ro, ginsenoside Rc, ginsenoside Rb2, ginsenoside Rb3, chikusetsusaponin IV, ginsenoside Rd, chikusetsusaponin IVa, panaxydol, and panaxynol, which were unequivocally identified through comparison with reference standards (Fig.\u0026nbsp;\u003cspan refid=\"Fig1\" class=\"InternalRef\"\u003e1\u003c/span\u003e). Among them, ginsenoside Rg1, Re, Rb1, Rd, panaxydol, and panaxynol were identified as common constituents shared by all four medicinal materials.\u003c/p\u003e\u003cp\u003e\u003c/p\u003e\u003cp\u003e\u003c/p\u003e\u003cp\u003eMethod validation results (Tables S2-S7) confirmed the excellent performance of the developed method, with precision (RSD 0.01%-1.23%), repeatability (RSD 0.05%-2.15%), stability (RSD 0.12%-3.45% over 24 h), and robustness (RSD 0.15%-4.11%) all meeting the requirements specified in the Chinese Pharmacopoeia (2020 edition). These findings verify the method's reliability and suitability for quality control of Panax medicinal materials.\u003c/p\u003e\u003cp\u003eThe acquired chromatograms were imported in AIA file format into the \"Similarity Evaluation System for Chromatographic Fingerprint of Traditional Chinese Medicine (2004A)\" for similarity analysis. Characteristic fingerprints were successfully established for XYS (Fig. \u003cspan refid=\"MOESM1\" class=\"InternalRef\"\u003eS1\u003c/span\u003e), RS (Fig. S2), SQ (Fig. S3), and BSQ (Fig. S4), with similarity ranges of 0.905\u0026ndash;0.987, 0.910\u0026ndash;0.966, 0.923\u0026ndash;0.991, and 0.911\u0026ndash;0.983, respectively. The intra-species similarities of all fingerprints exceeded 0.905, demonstrating good reproducibility and strong specificity of the analytical method. Detailed sample information and similarity data are provided in Tables S7\u0026ndash;S10.\u003c/p\u003e\u003cp\u003eUsing the characteristic fingerprint of XYS as a reference, a common pattern fingerprint (Fig. S5) was generated by comparison with the 3 other medicinal materials. The results revealed that the similarities between BSQ and RS, SQ, and XYS were all below 0.203, indicating significant differences in their chemical compositions. In contrast, the similarity between RS and XYS approached 0.9, reflecting a high degree of chemical consistency between these two species. This observation aligned with their shared phylogenetic classification within the Panax medicinal materials and their similar ginsenoside-rich phytochemical profiles, which also accounted for the frequent substitution and confusion between these two species in the commercial market.\u003c/p\u003e\u003c/div\u003e\u003cdiv id=\"Sec11\" class=\"Section2\"\u003e\u003ch2\u003e3.2 Contents of 11 saponins and 2 polyacetylenes\u003c/h2\u003e\u003cp\u003eThe recovery rates for 11 saponins and 2 polyacetylenes ranged from 97.49% to 107.32%, with relative standard deviations (RSDs) between 0.99% and 4.54% (Table S8), demonstrating that the method exhibits good sensitivity and accuracy for the detection of saponins and polyacetylenes in Panax species. The linearity of the method was assessed by analyzing 6 standard solutions of different concentrations, and the limits of detection (LOD) and quantification (LOQ) were established using signal-to-noise (S/N) ratios of 3 and 10, respectively (Table\u0026nbsp;\u003cspan refid=\"Tab1\" class=\"InternalRef\"\u003e1\u003c/span\u003e).\u003c/p\u003e\u003cp\u003e\u003cdiv class=\"gridtable\"\u003e\u003ctable float=\"Yes\" id=\"Tab1\" border=\"1\"\u003e\u003ccaption language=\"En\"\u003e\u003cdiv class=\"CaptionNumber\"\u003eTable 1\u003c/div\u003e\u003cdiv class=\"CaptionContent\"\u003e\u003cp\u003eCalibration curves, linear ranges, LOD, and LOQ of the analytes.\u003c/p\u003e\u003c/div\u003e\u003c/caption\u003e\u003ccolgroup cols=\"4\"\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c1\" colnum=\"1\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c2\" colnum=\"2\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c3\" colnum=\"3\"\u003e\u003c/div\u003e\u003cdiv align=\"char\" char=\".\" class=\"colspec\" colname=\"c4\" colnum=\"4\"\u003e\u003c/div\u003e\u003cthead\u003e\u003ctr\u003e\u003cth align=\"left\" colname=\"c1\"\u003e\u003cp\u003eAnalytes\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c2\"\u003e\u003cp\u003eCalibration curves\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c3\"\u003e\u003cp\u003eR\u003csup\u003e2\u003c/sup\u003e\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c4\"\u003e\u003cp\u003eLinear range (mg/mL)\u003c/p\u003e\u003c/th\u003e\u003c/tr\u003e\u003c/thead\u003e\u003ctbody\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eNotoginsenoside R1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003ey\u0026thinsp;=\u0026thinsp;1482.2x\u0026thinsp;+\u0026thinsp;3.2034\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e0.9998\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c4\"\u003e\u003cp\u003e0.07\u0026thinsp;~\u0026thinsp;0.45\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eGinsenoside Rg1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003ey\u0026thinsp;=\u0026thinsp;1639x\u0026thinsp;+\u0026thinsp;21.444\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e0.9991\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c4\"\u003e\u003cp\u003e0.018\u0026thinsp;~\u0026thinsp;1.71\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eGinsenoside Re\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003ey\u0026thinsp;=\u0026thinsp;1226x\u0026thinsp;+\u0026thinsp;8.0829\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e0.9992\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c4\"\u003e\u003cp\u003e0.01\u0026thinsp;~\u0026thinsp;0.92\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eGinsenoside Rb1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003ey\u0026thinsp;=\u0026thinsp;1167.9x\u0026thinsp;+\u0026thinsp;62.751\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e0.9998\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c4\"\u003e\u003cp\u003e0.03\u0026thinsp;~\u0026thinsp;1.94\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eGinsenoside Ro\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003ey\u0026thinsp;=\u0026thinsp;1691.9x\u0026thinsp;+\u0026thinsp;92.014\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c4\"\u003e\u003cp\u003e0.01\u0026thinsp;~\u0026thinsp;0.43\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eGinsenoside Rc\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003ey\u0026thinsp;=\u0026thinsp;825.47x\u0026thinsp;+\u0026thinsp;2.5608\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e0.9996\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c4\"\u003e\u003cp\u003e0.09\u0026thinsp;~\u0026thinsp;2.8\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eGinsenoside Rb2\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003ey\u0026thinsp;=\u0026thinsp;917.53x\u0026thinsp;+\u0026thinsp;2.3707\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e0.9996\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c4\"\u003e\u003cp\u003e0.003\u0026thinsp;~\u0026thinsp;0.22\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eGinsenoside Rb3\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003ey\u0026thinsp;=\u0026thinsp;883.95x\u0026thinsp;+\u0026thinsp;1.4466\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e0.9995\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c4\"\u003e\u003cp\u003e0.006\u0026thinsp;~\u0026thinsp;0.18\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eChikusetsusaponin IV\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003ey\u0026thinsp;=\u0026thinsp;1735.5x\u0026thinsp;+\u0026thinsp;20.492\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e0.9991\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c4\"\u003e\u003cp\u003e0.02\u0026thinsp;~\u0026thinsp;1.68\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eGinsenoside Rd\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003ey\u0026thinsp;=\u0026thinsp;1491x\u0026thinsp;+\u0026thinsp;3.5923\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e0.9999\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c4\"\u003e\u003cp\u003e0.01\u0026thinsp;~\u0026thinsp;0.45\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eChikusetsusaponin IVa\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003ey\u0026thinsp;=\u0026thinsp;1741.4x\u0026thinsp;+\u0026thinsp;11.189\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e0.9991\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c4\"\u003e\u003cp\u003e0.01\u0026thinsp;~\u0026thinsp;0.82\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003ePanaxydol\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003ey\u0026thinsp;=\u0026thinsp;5183.6x\u0026thinsp;+\u0026thinsp;6.8628\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e0.9996\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c4\"\u003e\u003cp\u003e0.1125\u0026thinsp;~\u0026thinsp;0.16\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003ePanaxynol\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003ey\u0026thinsp;=\u0026thinsp;12488x\u0026thinsp;+\u0026thinsp;229.58\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e0.9996\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c4\"\u003e\u003cp\u003e0.002\u0026thinsp;~\u0026thinsp;0.12\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003c/tbody\u003e\u003c/colgroup\u003e\u003c/table\u003e\u003c/div\u003e\u003c/p\u003e\u003cp\u003eThis study employed standard curves for content determination. The significant differences in chemical composition among the four medicinal materials were evident from their respective content chromatograms (Fig.\u0026nbsp;\u003cspan refid=\"Fig3\" class=\"InternalRef\"\u003e3\u003c/span\u003e). SQ was uniquely characterized by a high level of notoginsenoside R1 (6.33\u0026ndash;9.30 mg/g), which serves as a specific chemical marker for its identification. BSQ exhibited a distinct chemical profile dominated by exceptionally high concentrations of ginsenoside Ro (68.17\u0026ndash;128.57 mg/g) along with significant amounts of chikusetsusaponin IV and IVa, clearly distinguishing it from other species. Although XYS and RS share a similar set of ginsenosides (e.g., Rc, Rb2, Rb3), they can be effectively differentiated by their characteristic ginsenoside Re/Rb1 ratio. XYS showed notably higher levels of ginsenoside Re (7.64\u0026ndash;23.44 mg/g), while RS displayed a more balanced distribution of protopanaxadiol- and protopanaxatriol-type ginsenosides.\u003c/p\u003e\u003cp\u003e\u003c/p\u003e\u003c/div\u003e\u003cdiv id=\"Sec12\" class=\"Section2\"\u003e\u003ch2\u003e3.3 LC\u0026ndash;MS Analysis\u003c/h2\u003e\u003cp\u003eThe total ion chromatograms (TICs) of the four materials obtained by LC\u0026ndash;Orbitrap-MS are presented in Fig.\u0026nbsp;\u003cspan refid=\"Fig4\" class=\"InternalRef\"\u003e4\u003c/span\u003e. Data processing, including blank subtraction, deconvolution, peak extraction, and database searching against spectral libraries (mzCloud, mzVault) and a self-built database, was performed using Compound Discoverer. Compounds were initially filtered using thresholds of an mzCloud Best Match score\u0026thinsp;\u0026ge;\u0026thinsp;80 and mzCloud Best Match confidence\u0026thinsp;\u0026ge;\u0026thinsp;80, or an mzVault Best Match score\u0026thinsp;\u0026ge;\u0026thinsp;80. To minimize false positives, constituents with low spectral reliability, such as those exhibiting poor fragmentation or low intensity in MS\u0026sup2; spectra, were excluded. The identification accuracy was further improved by requiring a minimum number of matched product ions. A targeted screening approach was enhanced by incorporating literature-derived MS\u0026sup1; and MS\u0026sup2; data on known compounds in these four Panax species. A total of 129 compounds were identified across the four species. Specifically, 81, 78, 83, and 85 compounds were detected in BSQ, RS, SQ, and XYS, respectively. These included 34 protopanaxadiol-type saponins, 26 protopanaxatriol-type saponins, 17 C-17 side-chain varied saponins, 14 oleanane-type saponins, 8 ocotillol-type saponins, and 64 other compounds, as summarized in Table\u0026nbsp;\u003cspan refid=\"Tab2\" class=\"InternalRef\"\u003e2\u003c/span\u003e. Representative MS\u0026sup2; spectra of selected compounds are provided in Fig. S6.\u003c/p\u003e\u003cp\u003e\u003c/p\u003e\u003cp\u003e\u003cdiv class=\"gridtable\"\u003e\u003ctable float=\"Yes\" id=\"Tab2\" border=\"1\"\u003e\u003ccaption language=\"En\"\u003e\u003cdiv class=\"CaptionNumber\"\u003eTable 2\u003c/div\u003e\u003cdiv class=\"CaptionContent\"\u003e\u003cp\u003eThe compounds identified by LC-MS.\u003c/p\u003e\u003c/div\u003e\u003c/caption\u003e\u003ccolgroup cols=\"12\"\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c1\" colnum=\"1\"\u003e\u003c/div\u003e\u003cdiv align=\"char\" char=\".\" class=\"colspec\" colname=\"c2\" colnum=\"2\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c3\" colnum=\"3\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c4\" colnum=\"4\"\u003e\u003c/div\u003e\u003cdiv align=\"char\" char=\".\" class=\"colspec\" colname=\"c5\" colnum=\"5\"\u003e\u003c/div\u003e\u003cdiv align=\"char\" char=\".\" class=\"colspec\" colname=\"c6\" colnum=\"6\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c7\" colnum=\"7\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c8\" colnum=\"8\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c9\" colnum=\"9\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c10\" colnum=\"10\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c11\" colnum=\"11\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c12\" colnum=\"12\"\u003e\u003c/div\u003e\u003cthead\u003e\u003ctr\u003e\u003cth align=\"left\" colname=\"c1\"\u003e\u003cp\u003eNO.\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c2\"\u003e\u003cp\u003eRT [min]\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c3\"\u003e\u003cp\u003eIdentification\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c4\"\u003e\u003cp\u003eFormula\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c5\"\u003e\u003cp\u003eDiff. [ppm]\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c6\"\u003e\u003cp\u003em/z\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c7\"\u003e\u003cp\u003eReference Ion\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c8\"\u003e\u003cp\u003eFragments Ions (m/z)\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c9\"\u003e\u003cp\u003eBSQ\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c10\"\u003e\u003cp\u003eRS\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c11\"\u003e\u003cp\u003eSQ\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c12\"\u003e\u003cp\u003eXYS\u003c/p\u003e\u003c/th\u003e\u003c/tr\u003e\u003c/thead\u003e\u003ctbody\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e1.25\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eVinaginsenoside R4\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e47\u003c/sub\u003eH\u003csub\u003e80\u003c/sub\u003eO\u003csub\u003e19\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-1.58\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e993.5292\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e947.5223,785.4705,767.4596,\u003c/p\u003e\u003cp\u003e635.4165\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e2\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e1.34\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eFloralquinquenoside D\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e72\u003c/sub\u003eO\u003csub\u003e15\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-1.03\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e861.4862\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e653.4216, 491.3742, 391.2861\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e3\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e1.61\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eYesanchinoside B\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e48\u003c/sub\u003eH\u003csub\u003e82\u003c/sub\u003eO\u003csub\u003e20\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.12\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1023.5393\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e977.5334,815.4803,653.4267,\u003c/p\u003e\u003cp\u003e491.3742\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e4\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e2.17\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Re5 isomer/\u003c/p\u003e\u003cp\u003eGinsenjilinol isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e72\u003c/sub\u003eO\u003csub\u003e15\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-1.38\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e861.4865\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e815.4778,653.4274,491.3739\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e5\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e2.35\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eVinaginsenoside R4/\u003c/p\u003e\u003cp\u003eMajonoside F5\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e48\u003c/sub\u003eH\u003csub\u003e82\u003c/sub\u003eO\u003csub\u003e19\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.15\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1007.5444\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e961.5388, 815.4813,799.4864, 653.4271, 491.3731\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e6\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e2.58\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Re5 isomer/\u003c/p\u003e\u003cp\u003eGinsenjilinol isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e72\u003c/sub\u003eO\u003csub\u003e15\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e3.08\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e861.4879\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e815.4824,653.4316,491.3760\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e7\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e2.95\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eFloralginsenoside P isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e53\u003c/sub\u003eH\u003csub\u003e90\u003c/sub\u003eO\u003csub\u003e23\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.12\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1093.5804\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e961.5385,799.4838,637.4329,\u003c/p\u003e\u003cp\u003e475.3789\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e8\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e3.72\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eMajonoside R1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e72\u003c/sub\u003eO\u003csub\u003e15\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e0.79\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e861.4861\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e815.4807,653.4271,591.3742,\u003c/p\u003e\u003cp\u003e391.2851\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e9\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e3.76\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Re1/Re2/Re3\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e48\u003c/sub\u003eH\u003csub\u003e82\u003c/sub\u003eO\u003csub\u003e19\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.21\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1007.5445\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e961.5393, 799.4906,637.4330, 475.3797\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e10\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e5.17\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eYesanchinoside E\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e54\u003c/sub\u003eH\u003csub\u003e92\u003c/sub\u003eO\u003csub\u003e23\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e0.76\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1153.6023\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e1107.5961,961.5403,783.4889,\u003c/p\u003e\u003cp\u003e637.4313,475.3794\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e11\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e5.63\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eQuinquenoside F6\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e47\u003c/sub\u003eH\u003csub\u003e80\u003c/sub\u003eO\u003csub\u003e18\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.30\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e977.5340\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e931.5258,799.4898,637.4323,\u003c/p\u003e\u003cp\u003e475.3809\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e12\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e6.83\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Re4\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e47\u003c/sub\u003eH\u003csub\u003e80\u003c/sub\u003eO\u003csub\u003e18\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-1.58\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e977.5342\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e931.5295,799.4946,637.4330,\u003c/p\u003e\u003cp\u003e475.3756\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e13\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e7.07\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Rg1 isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e72\u003c/sub\u003eO\u003csub\u003e14\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-1.35\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e845.4916\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e799.4857,653.4272,491.3740,\u003c/p\u003e\u003cp\u003e391.2848\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e14\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e7.27\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eNotoginsenoside N/M\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e48\u003c/sub\u003eH\u003csub\u003e82\u003c/sub\u003eO\u003csub\u003e19\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.17\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e961.5375\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e799.4866, 637.4327, 475.3786\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e15\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e7.39\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eNotoginsenoside R1\u003csup\u003ea\u003c/sup\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e47\u003c/sub\u003eH\u003csub\u003e80\u003c/sub\u003eO\u003csub\u003e18\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-0.99\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e977.5336\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e931.5287, 799.4870,769.4736, 637.4327, 475.3797\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e16\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e8.74\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Re isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e48\u003c/sub\u003eH\u003csub\u003e82\u003c/sub\u003eO\u003csub\u003e18\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-2.00\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e991.5503\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e945.5449,783.4927,637.4338,\u003c/p\u003e\u003cp\u003e475.3811\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e17\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e9.11\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eNotoginsenoside ST5\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e47\u003c/sub\u003eH\u003csub\u003e80\u003c/sub\u003eO\u003csub\u003e18\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.58\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e977.5342\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e931.5308,799.4885,637.4332,\u003c/p\u003e\u003cp\u003e475.3801\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e18\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e9.72\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eQuinquenoside IV\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e54\u003c/sub\u003eH\u003csub\u003e90\u003c/sub\u003eO\u003csub\u003e24\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.27\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1167.5821\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e1121.5747,959.5238,797.4669,\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e19\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e10.57\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Rg1 isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e72\u003c/sub\u003eO\u003csub\u003e14\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e0.02\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e845.4904\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e815.0154, 799.4916,637.4333, 475.3786\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e20\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e10.57\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Rg1\u003csup\u003ea\u003c/sup\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e72\u003c/sub\u003eO\u003csub\u003e14\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-0.77\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e845.4911\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e799.4871, 637.4330,475.3794,\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e21\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e11.59\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Re\u003csup\u003ea\u003c/sup\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e48\u003c/sub\u003eH\u003csub\u003e82\u003c/sub\u003eO\u003csub\u003e18\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-1.09\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e991.5494\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e945.5438, 783.4899,637.4331, 475.3796\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e22\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e13.86\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Rg1 isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e72\u003c/sub\u003eO\u003csub\u003e14\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-1.41\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e845.4916\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e799.4854,653.4271,491.3740\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e23\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e17.37\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eMalonylginsenoside Rg1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e45\u003c/sub\u003eH\u003csub\u003e74\u003c/sub\u003eO\u003csub\u003e17\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.42\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e885.4866\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e637.4338,619.4233,475.3789\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e24\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e17.58\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eVinaginsenoside R13\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e48\u003c/sub\u003eH\u003csub\u003e84\u003c/sub\u003eO\u003csub\u003e20\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.53\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e979.5468\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e817.4965, 799.4860,655.4434, 637.4316\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e25\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e18.09\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eMalonylginsenoside Rf\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e45\u003c/sub\u003eH\u003csub\u003e74\u003c/sub\u003eO\u003csub\u003e17\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.52\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e885.4867\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e799.4896,637.4344,619.4215,\u003c/p\u003e\u003cp\u003e475.3811\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e26\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e19.34\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eMalonylginsenoside Re\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e51\u003c/sub\u003eH\u003csub\u003e84\u003c/sub\u003eO\u003csub\u003e21\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e0.86\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1031.5441\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e945.5436, 783.4910,637.4319, 475.3790\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e27\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e19.34\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eAcetyl ginsenoside Re\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e50\u003c/sub\u003eH\u003csub\u003e84\u003c/sub\u003eO\u003csub\u003e19\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e0.49\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e987.5539\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e945.5434,783.4904,637.4319,\u003c/p\u003e\u003cp\u003e475.3792\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e28\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e19.74\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eAcetyl notoginsenoside R1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e50\u003c/sub\u003eH\u003csub\u003e84\u003c/sub\u003eO\u003csub\u003e21\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e2.00\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1019.5453\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e931.5303,799.4892,637.4332,\u003c/p\u003e\u003cp\u003e619.4190,475.3795\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e29\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e22.16\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eB1-20-Glc-Glc-6-Glc-Glc\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e54\u003c/sub\u003eH\u003csub\u003e94\u003c/sub\u003eO\u003csub\u003e24\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.77\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1171.6138\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e1125.6068,963.5540,801.5015,\u003c/p\u003e\u003cp\u003e783.4926\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e30\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e22.49\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003ePseudoginsenoside Rt2\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e41\u003c/sub\u003eH\u003csub\u003e70\u003c/sub\u003eO\u003csub\u003e14\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-1.81\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e831.4763\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e785.4711,653.4276,491.3740\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e31\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e22.64\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003ePseudoginsenosideRC1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e50\u003c/sub\u003eH\u003csub\u003e84\u003c/sub\u003eO\u003csub\u003e19\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.47\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1033.5604\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e945.5449,783.4912,637.4331,\u003c/p\u003e\u003cp\u003e475.3793\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e32\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e23.11\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eMajonoside R2\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e41\u003c/sub\u003eH\u003csub\u003e70\u003c/sub\u003eO\u003csub\u003e14\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.03\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e831.4757\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e785.4705,653.4280,491.3750\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e33\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e23.27\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003ePseudoginsenoside Rt\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e36\u003c/sub\u003eH\u003csub\u003e62\u003c/sub\u003eO\u003csub\u003e10\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-1.07\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e699.4333\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e653.4262,491.3764\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e34\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e23.94\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Rf isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e72\u003c/sub\u003eO\u003csub\u003e14\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-1.62\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e845.4918\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e799.4851,637.4342,619.4222,\u003c/p\u003e\u003cp\u003e475.3797\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e35\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e24.36\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eQuinquenoside L11\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e72\u003c/sub\u003eO\u003csub\u003e14\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-0.90\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e845.4912\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e799.4858, 653.4275,491.3739,\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e36\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e24.36\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003ePseudoginsenoside F11\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e72\u003c/sub\u003eO\u003csub\u003e14\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-6.97\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e799.4794\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e653.4275,491.3746,415.3222\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e37\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e25.23\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e24(R)-pseudoginsenoside F11\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e72\u003c/sub\u003eO\u003csub\u003e14\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e0.31\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e799.4832\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e637.4327, 475.3780\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e38\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e25.77\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eQuinquenoside L6\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e48\u003c/sub\u003eH\u003csub\u003e80\u003c/sub\u003eO\u003csub\u003e18\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.48\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e989.5342\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e943.5281781.4752,619.4212\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e39\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e25.84\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Rf isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e72\u003c/sub\u003eO\u003csub\u003e14\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-1.61\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e845.4918\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e799.4862, 637.4318, 475.3782\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e40\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e26.42\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Rf\u003csup\u003ea\u003c/sup\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e72\u003c/sub\u003eO\u003csub\u003e14\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.19\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e845.4914\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e799.4896, 637.4313, 475.3786\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e41\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e26.43\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Rf isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e72\u003c/sub\u003eO\u003csub\u003e14\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-1.21\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e845.4914\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e799.4861,637.4318,475.3787\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e42\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e27.01\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside F5\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e41\u003c/sub\u003eH\u003csub\u003e70\u003c/sub\u003eO\u003csub\u003e13\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e0.73\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e815.4806\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e769.4750, 637.4322, 475.3793\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e43\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e27.87\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Rf isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e72\u003c/sub\u003eO\u003csub\u003e14\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-1.53\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e845.4917\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e799.4960,637.4305,475.3822\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e44\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e28.55\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Rg2 isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e72\u003c/sub\u003eO\u003csub\u003e13\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.04\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e829.4965\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e783.4905,637.4332,475.3794\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e45\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e28.59\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside F3\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e41\u003c/sub\u003eH\u003csub\u003e70\u003c/sub\u003eO\u003csub\u003e13\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-1.42\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e815.4810\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e637.4305,475.3792\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e46\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e28.74\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e20(S)-Ginsenoside Rh1\u003csup\u003ea\u003c/sup\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e36\u003c/sub\u003eH\u003csub\u003e62\u003c/sub\u003eO\u003csub\u003e9\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-0.48\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e683.4379\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e637.4282,475.3793\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e47\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e29.24\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Rg2\u003csup\u003ea\u003c/sup\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e72\u003c/sub\u003eO\u003csub\u003e13\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-1.00\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e829.4963\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e783.4911, 637.4327, 475.3796\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e48\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e29.38\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Ra3\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e59\u003c/sub\u003eH\u003csub\u003e100\u003c/sub\u003eO\u003csub\u003e27\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e0.47\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1285.6428\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e1107.5964,945.5447,783.4913,\u003c/p\u003e\u003cp\u003e621.4388\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e49\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e29.38\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eNotoginsenoside R4\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e59\u003c/sub\u003eH\u003csub\u003e100\u003c/sub\u003eO\u003csub\u003e27\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-0.58\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1285.6430\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e1239.6398,1107.5957,1077.5864,945.5438,783.4894\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e50\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e29.68\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003enotoginsenoside R2\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e41\u003c/sub\u003eH\u003csub\u003e70\u003c/sub\u003eO\u003csub\u003e13\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-1.75\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e815.4813\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e769.4719, 637.4291, 475.3798\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e51\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e29.70\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e20(R)-Ginsenoside Rh1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e36\u003c/sub\u003eH\u003csub\u003e62\u003c/sub\u003eO\u003csub\u003e9\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-1.27\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e683.4385\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e637.4349, 475.3799\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e52\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e30.64\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eNotoginsenoside Fa\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e59\u003c/sub\u003eH\u003csub\u003e100\u003c/sub\u003eO\u003csub\u003e27\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e0.04\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1285.6434\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e1107.5964,945.5482,783.4912,\u003c/p\u003e\u003cp\u003e621.4382, 459.3853\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e53\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e30.65\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Ro isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e48\u003c/sub\u003eH\u003csub\u003e76\u003c/sub\u003eO\u003csub\u003e19\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.25\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e955.4920\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e793.4400,731.4383,631.3849,\u003c/p\u003e\u003cp\u003e567.3701\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e54\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e30.79\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eMalony notoginoside R4\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e62\u003c/sub\u003eH\u003csub\u003e102\u003c/sub\u003eO\u003csub\u003e30\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-0.26\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1325.6380\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e1239.6392,1107.5951,945.5432,783.4902,621.4391\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e55\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e31.02\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Ro isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e48\u003c/sub\u003eH\u003csub\u003e76\u003c/sub\u003eO\u003csub\u003e19\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.22\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e955.4920\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e793.4360, 631.3850, 455.3521\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e56\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e31.19\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Rh7\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e36\u003c/sub\u003eH\u003csub\u003e60\u003c/sub\u003eO\u003csub\u003e9\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-0.89\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e681.4225\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e635.4201,473.3641\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e57\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e31.25\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eNotoginsenoside I\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e54\u003c/sub\u003eH\u003csub\u003e92\u003c/sub\u003eO\u003csub\u003e22\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e0.95\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1091.6011\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e1091.6027, 929.5491,767.4955, 605.4443\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e58\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e31.42\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Ro isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e48\u003c/sub\u003eH\u003csub\u003e76\u003c/sub\u003eO\u003csub\u003e19\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.12\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e955.4919\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e793.4396, 731.4379, 613.3751, 569.3850\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e59\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e31.99\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e5,6-Dihydroginsenoside Rb1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e54\u003c/sub\u003eH\u003csub\u003e90\u003c/sub\u003eO\u003csub\u003e23\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.19\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1105.5802\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e943.5283, 781.4746, 619.4221, 457.3685\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e60\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e32.03\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Ro isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e48\u003c/sub\u003eH\u003csub\u003e76\u003c/sub\u003eO\u003csub\u003e19\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.38\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e955.4921\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e793.4406, 731.4396, 631.3869, 569.3854, 523.3801\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e61\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e32.23\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Rh8\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e36\u003c/sub\u003eH\u003csub\u003e60\u003c/sub\u003eO\u003csub\u003e9\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-1.21\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e681.4228\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e626.2918,473.3637\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e62\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e32.38\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Rb1\u003csup\u003ea\u003c/sup\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e54\u003c/sub\u003eH\u003csub\u003e92\u003c/sub\u003eO\u003csub\u003e23\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-0.36\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1153.6016\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e1107.5963,945.5442,783.4905,\u003c/p\u003e\u003cp\u003e621.4370\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e63\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e32.54\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eYesanchinoside D/\u003c/p\u003e\u003cp\u003eVinaginsenoside R1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e44\u003c/sub\u003eH\u003csub\u003e74\u003c/sub\u003eO\u003csub\u003e15\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-0.88\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e887.5018\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e841.4966,799.4870,653.4386,\u003c/p\u003e\u003cp\u003e587.3959,491.3762\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e64\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e32.58\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eMalonynotoginoside R4\u003c/p\u003e\u003cp\u003eisomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e62\u003c/sub\u003eH\u003csub\u003e102\u003c/sub\u003eO\u003csub\u003e30\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-0.12\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1325.6382\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e1239.6395,1107.5956,1089.5851, 945.5433, 783.4905\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e65\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e33.18\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside F1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e36\u003c/sub\u003eH\u003csub\u003e62\u003c/sub\u003eO\u003csub\u003e9\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-0.33\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e683.4378\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e637.4292,475.3796\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e66\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e33.51\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Ro isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e48\u003c/sub\u003eH\u003csub\u003e76\u003c/sub\u003eO\u003csub\u003e19\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.59\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e955.4923\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e793.4389,731.4380,\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e67\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e33.59\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Rc\u003csup\u003ea\u003c/sup\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e53\u003c/sub\u003eH\u003csub\u003e90\u003c/sub\u003eO\u003csub\u003e22\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.01\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1123.5919\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e945.5450, 783.4906, 621.4368, 459.3876\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e68\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e33.59\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside V\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e54\u003c/sub\u003eH\u003csub\u003e92\u003c/sub\u003eO\u003csub\u003e24\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e0.23\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1123.5908\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e1077.5855,945.5249,783.4904,\u003c/p\u003e\u003cp\u003e621.4374,459.3857\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e69\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e33.73\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eMalonynotoginosideR4 isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e62\u003c/sub\u003eH\u003csub\u003e102\u003c/sub\u003eO\u003csub\u003e30\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-0.41\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1325.6378\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e1239.6381,1107.5946,945.5421, 783.4898\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e70\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e33.84\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eMalony ginsenoside Rb1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e57\u003c/sub\u003eH\u003csub\u003e94\u003c/sub\u003eO\u003csub\u003e26\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e0.89\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1193.5971\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e1107.5958, 945.5427,783.4899, 621.4373\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e71\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e33.97\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Ro\u003csup\u003ea\u003c/sup\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e48\u003c/sub\u003eH\u003csub\u003e76\u003c/sub\u003eO\u003csub\u003e19\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.29\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e955.4920\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e793.4397, 613.3754, 569.3854, 455.3543\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e72\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e34.24\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eMalonyginsenoside Rb1 isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e57\u003c/sub\u003eH\u003csub\u003e94\u003c/sub\u003eO\u003csub\u003e26\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.09\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1193.5974\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e1107.5973,1089.5869,945.5444,783.4910,\u003c/p\u003e\u003cp\u003e621.4377,459.3876\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e73\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e34.44\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Rs1/\u003c/p\u003e\u003cp\u003eGinsenoside Rs2\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e55\u003c/sub\u003eH\u003csub\u003e92\u003c/sub\u003eO\u003csub\u003e23\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-2.26\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1119.5931\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e1077.5864,1059.5767,945.5444,783.4908, 765.4805\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e74\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e34.68\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eMalony ginsenoside Rb1 isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e57\u003c/sub\u003eH\u003csub\u003e94\u003c/sub\u003eO\u003csub\u003e26\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.38\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1193.5977\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e1107.5973,945.5436,783.4921,\u003c/p\u003e\u003cp\u003e621.4385\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e75\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e35.23\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eChikusetsusaponin Ⅱ\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e66\u003c/sub\u003eO\u003csub\u003e14\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.27\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e793.4390\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e631.3865, 569.3864, 455.3536\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e76\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e35.28\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Rb2\u003csup\u003ea\u003c/sup\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e53\u003c/sub\u003eH\u003csub\u003e90\u003c/sub\u003eO\u003csub\u003e22\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-1.26\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1123.5920\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e1077.5863, 945.5488,783.4912, 621.4350, 459.3821\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e77\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e35.46\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eMalonyl ginsenoside Ro\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e51\u003c/sub\u003eH\u003csub\u003e78\u003c/sub\u003eO\u003csub\u003e22\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e0.23\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1041.4931\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e997.5026,937.4821,835.4489,\u003c/p\u003e\u003cp\u003e775.4276,731.4383\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e78\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e35.56\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eMalony ginsenoside Rb1 isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e57\u003c/sub\u003eH\u003csub\u003e94\u003c/sub\u003eO\u003csub\u003e26\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e5.41\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1193.5896\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e1107.5968,1078.5889,945.5440,783.4877,621.4351\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e79\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e35.56\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eIsomeric Ginsenoside V\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e54\u003c/sub\u003eH\u003csub\u003e92\u003c/sub\u003eO\u003csub\u003e24\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-1.36\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1123.5921\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e1077.5857,945.5440,915.5322,\u003c/p\u003e\u003cp\u003e783.4895,621.4367\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e80\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e35.60\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eMalony ginsenoside Rb1 isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e57\u003c/sub\u003eH\u003csub\u003e94\u003c/sub\u003eO\u003csub\u003e26\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-7.04\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1193.5877\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e1107.5960,1078.5892,945.5432,783.4895,621.4338\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e81\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e35.64\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eMalonyl ginsenoside Ro isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e51\u003c/sub\u003eH\u003csub\u003e78\u003c/sub\u003eO\u003csub\u003e22\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.63\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1041.4929\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e997.50305,835.4504,773.4487,\u003c/p\u003e\u003cp\u003e613.3742,569.3854\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e82\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e35.75\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003ePseudoginsenoside RT1\u003csup\u003ea\u003c/sup\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e47\u003c/sub\u003eH\u003csub\u003e74\u003c/sub\u003eO\u003csub\u003e18\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.32\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e925.4815\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e763.4280, 613.3746, 569.3858\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e83\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e35.85\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Rb3\u003csup\u003ea\u003c/sup\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e53\u003c/sub\u003eH\u003csub\u003e90\u003c/sub\u003eO\u003csub\u003e22\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-0.69\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1123.5914\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e1077.5866, 945.5435,783.4907, 621.4376, 459.3900\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e84\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e36.03\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eChikusetsusaponin IV\u003csup\u003ea\u003c/sup\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e47\u003c/sub\u003eH\u003csub\u003e74\u003c/sub\u003eO\u003csub\u003e18\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e0.97\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e925.4811\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e793.4382, 613.3750, 569.3852, 455.3536\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e85\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e36.28\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003ePPT-Glc-Ace\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e38\u003c/sub\u003eH\u003csub\u003e64\u003c/sub\u003eO\u003csub\u003e10\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.19\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e725.4490\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e637.4321,475.3799\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e86\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e36.74\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eQuinquenoside R1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e56\u003c/sub\u003eH\u003csub\u003e94\u003c/sub\u003eO\u003csub\u003e24\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-0.96\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1195.6129\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e1107.5967,1089.5863,945.5443,783.4913, 621.4382, 459.3855\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e87\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e36.83\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eMalonyl ginsenoside Rb3\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e56\u003c/sub\u003eH\u003csub\u003e92\u003c/sub\u003eO\u003csub\u003e25\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.04\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1163.5867\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e1077.5864, 945.4912,765.4815, 621.4384, 459.3872\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e88\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e37.32\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eChikusetsu saponin IVa\u003csup\u003ea\u003c/sup\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e66\u003c/sub\u003eO\u003csub\u003e14\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.22\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e793.4390\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e631.3861, 569.3861, 455.3511\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e89\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e37.60\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eYesanchinoside F\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e56\u003c/sub\u003eH\u003csub\u003e94\u003c/sub\u003eO\u003csub\u003e24\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e0.35\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1195.6120\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e1107.5969,1089.5864,945.5446,783.4912,621.4384\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e90\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e37.85\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eMalonyl ginsenoside Rb2\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e56\u003c/sub\u003eH\u003csub\u003e92\u003c/sub\u003eO\u003csub\u003e25\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e0.27\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1163.5858\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e1077.5851, 945.5427, 783.4897\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e91\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e37.93\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Rg8/Rg9\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e70\u003c/sub\u003eO\u003csub\u003e13\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.41\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e827.4811\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e781.4754, 619.4219, 457.3698\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e92\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e38.01\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eChikusetsusaponin IVa isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e66\u003c/sub\u003eO\u003csub\u003e14\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.40\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e793.4391\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e631.3853, 569.3845, 455.3561\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e93\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e38.38\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eMalonyl ginsenoside Rc\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e56\u003c/sub\u003eH\u003csub\u003e92\u003c/sub\u003eO\u003csub\u003e25\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e2.40\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1163.5867\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e1077.5867,945.5447,783.4909,\u003c/p\u003e\u003cp\u003e621.4376\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e94\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e38.48\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eAcetyl ginsenoside Rd\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e50\u003c/sub\u003eH\u003csub\u003e84\u003c/sub\u003eO\u003csub\u003e19\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-2.68\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e987.5508\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e945.5446,783.4912,621.4378,\u003c/p\u003e\u003cp\u003e459.3848\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e95\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e38.48\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eMalonyl ginsenoside Rd isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e51\u003c/sub\u003eH\u003csub\u003e84\u003c/sub\u003eO\u003csub\u003e21\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.40\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1031.5447\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e987.5585,945.5449,783.4917,\u003c/p\u003e\u003cp\u003e621.4385,459.3840\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e96\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e39.17\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eNotoginsenoside K\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e48\u003c/sub\u003eH\u003csub\u003e82\u003c/sub\u003eO\u003csub\u003e18\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-1.73\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e991.5500\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e945.5437,783.4903,621.4375,\u003c/p\u003e\u003cp\u003e459.3861\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e97\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e39.24\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eAcetyl ginsenoside Rd isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e50\u003c/sub\u003eH\u003csub\u003e84\u003c/sub\u003eO\u003csub\u003e19\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e0.73\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e987.5552\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e945.5456,783.4921,765.4807,\u003c/p\u003e\u003cp\u003e621.4385\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e98\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e39.42\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eMalonyl ginsenoside Rd isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e51\u003c/sub\u003eH\u003csub\u003e84\u003c/sub\u003eO\u003csub\u003e21\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.45\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1031.5447\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e945.5434, 783.4896, 621.4358\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e99\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e39.53\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eAcetyl ginsenoside Fc\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e55\u003c/sub\u003eH\u003csub\u003e92\u003c/sub\u003eO\u003csub\u003e23\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e0.32\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1165.6015\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e1077.58451059.5743,945.5427, 783.4887, 765.4777\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e100\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e39.98\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Rd\u003csup\u003ea\u003c/sup\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e48\u003c/sub\u003eH\u003csub\u003e82\u003c/sub\u003eO\u003csub\u003e18\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-5.00\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e945.5381\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e783.4950, 621.4378, 459.3838\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e101\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e39.99\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGypenoside XVII\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e48\u003c/sub\u003eH\u003csub\u003e82\u003c/sub\u003eO\u003csub\u003e18\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.10\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e945.5401\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e945.5480, 783.4895, 621.4382, 459.3840\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e102\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e40.28\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eQuinquenoside Ⅲ\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e50\u003c/sub\u003eH\u003csub\u003e84\u003c/sub\u003eO\u003csub\u003e19\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-1.76\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1033.5607\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e987.5557,945.5457,783.4915,\u003c/p\u003e\u003cp\u003e621.4384,459.3849\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e103\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e40.29\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eAcetyl ginsenoside Re\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e50\u003c/sub\u003eH\u003csub\u003e84\u003c/sub\u003eO\u003csub\u003e19\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.30\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1033.5603\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e987.5538,945.5444,925.5031,\u003c/p\u003e\u003cp\u003e783.4903,621.4377\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e104\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e40.30\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003ePPD-Glc-(Glc-Glc)-2malonyl\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e54\u003c/sub\u003eH\u003csub\u003e86\u003c/sub\u003eO\u003csub\u003e24\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.28\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1117.5451\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e987.5561, 945.5461, 825.5042, 783.4879, 765.4809, 621.4365\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e105\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e40.48\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eAcetyl ginsenoside Rd isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e50\u003c/sub\u003eH\u003csub\u003e84\u003c/sub\u003eO\u003csub\u003e19\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.06\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e987.5543\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e945.5440,927.5318,783.4946,\u003c/p\u003e\u003cp\u003e621.4375\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e106\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e40.59\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eAcetyl ginsenoside Rd isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e50\u003c/sub\u003eH\u003csub\u003e84\u003c/sub\u003eO\u003csub\u003e19\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-0.75\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e987.5529\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e945.5447, 783.4916, 621.4379, 459.3849\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e107\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e41.00\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eNotoginsenoside Fe\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e47\u003c/sub\u003eH\u003csub\u003e80\u003c/sub\u003eO\u003csub\u003e17\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.81\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e961.5395\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e915.5329, 753.4825, 621.4378, 459.3850\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e108\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e41.00\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGypenoside XLVI\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e48\u003c/sub\u003eH\u003csub\u003e82\u003c/sub\u003eO\u003csub\u003e19\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.60\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e961.5393\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e915.5339, 753.4791, 621.4377, 459.3860\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e109\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e41.04\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eMalonyl ginsenoside Rd isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e51\u003c/sub\u003eH\u003csub\u003e84\u003c/sub\u003eO\u003csub\u003e21\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.56\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1031.5448\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e945.5442,783.4913,621.4382\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e110\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e41.91\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eMalonyl ginsenoside Rd isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e51\u003c/sub\u003eH\u003csub\u003e84\u003c/sub\u003eO\u003csub\u003e21\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.47\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1031.5448\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e945.5435,783.4941,621.4349\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e111\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e42.17\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eMalonyl ginsenoside Rd isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e51\u003c/sub\u003eH\u003csub\u003e84\u003c/sub\u003eO\u003csub\u003e21\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.50\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1031.5448\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e945.5446, 783.4896, 621.4393\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e112\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e42.45\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eVinaginsenoside R3\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e48\u003c/sub\u003eH\u003csub\u003e82\u003c/sub\u003eO\u003csub\u003e17\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-1.24\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e975.5546\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e929.5486,767.4965,605.4433\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e113\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e42.49\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eNotoginsenoside Ft1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e47\u003c/sub\u003eH\u003csub\u003e80\u003c/sub\u003eO\u003csub\u003e17\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.05\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e915.5293\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e783.4911, 621.4381, 459.3839\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e114\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e43.04\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGypenoside IX\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e47\u003c/sub\u003eH\u003csub\u003e80\u003c/sub\u003eO\u003csub\u003e17\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.79\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e961.5394\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e915.5339, 783.4954, 621.4392, 459.3845\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e115\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e43.65\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGypenoside XLVI isomer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e48\u003c/sub\u003eH\u003csub\u003e82\u003c/sub\u003eO\u003csub\u003e19\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.27\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e961.5390\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e915.5302, 783.4879, 621.4372, 459.3857\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e116\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e44.02\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eAcetyl pseudoginsenside RC1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e52\u003c/sub\u003eH\u003csub\u003e86\u003c/sub\u003eO\u003csub\u003e20\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.80\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e1029.5658\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e945.5441,927.5289,783.4958,\u003c/p\u003e\u003cp\u003e765.4800,621.4363\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e117\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e44.28\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside F4\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e70\u003c/sub\u003eO\u003csub\u003e12\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e2.23\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e811.4868\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e765.4805,619.4224,457.3719\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e118\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e46.67\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside F2\u003csup\u003ea\u003c/sup\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e72\u003c/sub\u003eO\u003csub\u003e13\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-0.95\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e829.4963\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e783.4917,621.4370,459.3877\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e119\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e47.16\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eChikusetsusaponin Ib\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e47\u003c/sub\u003eH\u003csub\u003e74\u003c/sub\u003eO\u003csub\u003e18\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e0.91\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e925.4811\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e793.4390, 731.4374, 569.3846,\u003c/p\u003e\u003cp\u003e455.3529\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e120\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e48.97\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e20(S)-Ginsenoside Rg3\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e72\u003c/sub\u003eO\u003csub\u003e13\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.52\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e829.4967\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e783.4905, 621.4426, 459.3846\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e121\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e48.98\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e20(R)-Ginsenoside Rg3\u003csup\u003ea\u003c/sup\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e72\u003c/sub\u003eO\u003csub\u003e13\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.52\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e829.4967\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e783.4902, 621.4388, 459.3860\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e122\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e49.56\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Rk1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e70\u003c/sub\u003eO\u003csub\u003e12\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.94\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e811.4867\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e765.4808,603.4275\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e123\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e49.83\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003ePseudoginsenoside Rp1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e41\u003c/sub\u003eH\u003csub\u003e64\u003c/sub\u003eO\u003csub\u003e13\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e0.79\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e763.4280\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e613.3749, 569.3851, 509.3635,\u003c/p\u003e\u003cp\u003e455.3528\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e124\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e49.92\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Rs5\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e44\u003c/sub\u003eH\u003csub\u003e72\u003c/sub\u003eO\u003csub\u003e13\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e0.62\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e807.4906\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e765.4796,603.4274\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e125\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e50.27\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Rs4\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e44\u003c/sub\u003eH\u003csub\u003e72\u003c/sub\u003eO\u003csub\u003e13\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.09\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e807.4909\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e765.4796,603.4257\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e126\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e51.70\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e20(S)-Ginsenoside Rh2\u003csup\u003ea\u003c/sup\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e36\u003c/sub\u003eH\u003csub\u003e62\u003c/sub\u003eO\u003csub\u003e8\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-1.06\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e667.4434\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e621.4500, 459.3846, 161.0460\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e127\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e51.92\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Rg5\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e70\u003c/sub\u003eO\u003csub\u003e12\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.52\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e765.4783\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e603.4280, 441.3755\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e128\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e52.14\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Rg6\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e42\u003c/sub\u003eH\u003csub\u003e70\u003c/sub\u003eO\u003csub\u003e12\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e1.33\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e765.4784\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M-H]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e603.4279, 441.3759\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e129\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e52.68\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eGinsenoside Rh4\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003eC\u003csub\u003e36\u003c/sub\u003eH\u003csub\u003e60\u003c/sub\u003eO\u003csub\u003e8\u003c/sub\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c5\"\u003e\u003cp\u003e-1.13\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c6\"\u003e\u003cp\u003e665.4278\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e[M\u0026thinsp;+\u0026thinsp;COOH]-\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c8\"\u003e\u003cp\u003e457.3695\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c9\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c10\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c11\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c12\"\u003e\u003cp\u003e\u0026radic;\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003c/tbody\u003e\u003c/colgroup\u003e\u003c/table\u003e\u003c/div\u003e\u003c/p\u003e\u003cp\u003e\u003cstrong\u003eNote:\u003c/strong\u003e The superscript letter \u0026quot;a\u0026quot; indicates that the compound was identified by comparison with an authentic reference standard. The check mark (\u0026radic;) indicates that the component was detected in the sample.\u003c/p\u003e\n\u003cp\u003eIn negative-ion mode, the MS1 spectra of protopanaxadiol-type ginsenosides were dominated by the formate adduct [M\u0026thinsp;+\u0026thinsp;HCOO]⁻ and the deprotonated ion [M\u0026ndash;H]⁻. High-energy collision-induced dissociation (CID) experiments revealed a stepwise loss of sugar substituents, ultimately affording the protopanaxadiol aglycone. Diagnostic fragments appeared at m/z 459.3900. Ginsenoside Rb3 (compound 83) was selected to exemplify the cleavage pattern. It eluted at a retention time (RT)\u0026thinsp;=\u0026thinsp;35.85 min and exhibited a precursor ion at m/z 1077.5866 ([M\u0026thinsp;+\u0026thinsp;HCOO]⁻, C₅₃H₉₀O₂₂). The MS\u0026sup2; spectrum displayed sequential losses of one xylose residue (\u0026ndash;C₅H₈O₄) at m/z 945.5435, one glucose residue (\u0026ndash;C₆H₁₀O₅) at m/z 783.4907, and two additional glucose units at m/z 621.4376 and 459.3900. These data, together with comparison to the reference standard and literature, unambiguously identified compound 83 as. Its fragmentation pathway is illustrated in Fig.\u0026nbsp;\u003cspan refid=\"Fig4\" class=\"InternalRef\"\u003e4\u003c/span\u003ea. Similarly, protopanaxatriol-type ginsenosides yield prominent [M\u0026thinsp;+\u0026thinsp;HCOO]⁻ and [M\u0026ndash;H]⁻ ions. Its MS\u0026sup2; showed sequential excision of glucose units, termina ginsenoside Rb3ting in the protopanaxatriol aglycone whose characteristic fragments occur at m/z 799.4871, 637.4330, and 475.3794. Ginsenoside Rg1 (compound 21) was eluted at 10.57 min with [M\u0026thinsp;+\u0026thinsp;HCOO]⁻ at m/z 845.4911 (C₄₂H₇₂O₁₄). The spectrum displayed successive losses of two glucose residues (\u0026ndash;C₆H₁₀O₅) to produce m/z 637.4330 and 475.3794, confirming compound 21 as ginsenoside Rg1 (Fig.\u0026nbsp;\u003cspan refid=\"Fig4\" class=\"InternalRef\"\u003e4\u003c/span\u003eb). Oleanane-type ginsenosides are also detected as [M\u0026thinsp;+\u0026thinsp;HCOO]⁻ and [M\u0026ndash;H]⁻ ions. Their sugar moiety is stripped stepwise, delivering the oleanolic acid aglycone (m/z 455). Ginsenoside Ro (compound 71) eluted at 33.97 min with [M\u0026ndash;H]⁻ at m/z 955.4920 (C₄₈H₇₆O₁₉). Sequential losses of two glucose units (\u0026ndash;C₆H₁₀O₅) and one glucuronic acid residue (\u0026ndash;C₆H₈O₆) generated fragments at m/z 793.4397, 631.4370, and 455.3543, identifying compound 71 as ginsenoside Ro (Fig.\u0026nbsp;\u003cspan refid=\"Fig4\" class=\"InternalRef\"\u003e4\u003c/span\u003ec). Ocotillol-type ginsenosides also produced abundant [M\u0026thinsp;+\u0026thinsp;HCOO]⁻ and [M\u0026ndash;H]⁻ ions. Their MS\u0026sup2; revealed progressive removal of glucose units, yielding the ocotillol aglycone (m/z 491). Majoroside R1 (compound 8) was eluted at 3.72 min ([M\u0026thinsp;+\u0026thinsp;HCOO]⁻, m/z 861.4861, C₄₂H₇₂O₁₅). Stepwise loss of two glucose residues afforded m/z 653.4271 and the diagnostic fragment at m/z 491.3742. Subsequent elimination of C₃H₆O and H₂O produced an additional ocotillol-type ion at m/z 415.3212. These data enabled the identification of compound 8 as majoroside R1 (Fig.\u0026nbsp;\u003cspan refid=\"Fig4\" class=\"InternalRef\"\u003e4\u003c/span\u003ed). The C-17 side-chain-modified ginsenosides were identified via their representative deprotonated ions ([M\u0026thinsp;+\u0026thinsp;HCOO]⁻ and [M\u0026ndash;H]⁻) and a characteristic fragment ion at m/z 455. Ginsenoside Rg5 (compound 128) eluted at 51.92 min ([M\u0026ndash;H]⁻, m/z 765.4783). Sequential losses of two glucose units (\u0026ndash;C₆H₁₀O₅) yielded fragments at m/z 603.4280 and 441.3755, confirming compound 128 as ginsenoside Rg5 (Fig.\u0026nbsp;\u003cspan refid=\"Fig4\" class=\"InternalRef\"\u003e4\u003c/span\u003ee).\u003c/p\u003e\u003cp\u003eThe peak area data of 129 compounds identified by mass spectrometry were imported into SIMCA 14.1 software for principal component analysis (PCA) and orthogonal partial least squares-discriminant analysis (OPLS-DA). The resulting score plots are shown in Fig.\u0026nbsp;\u003cspan refid=\"Fig5\" class=\"InternalRef\"\u003e5\u003c/span\u003e. Both PCA and OPLS-DA facilitate the visualization of overall clustering trends among samples[\u003cspan citationid=\"CR17\" class=\"CitationRef\"\u003e17\u003c/span\u003e], where the dispersion of points reflects the similarities or differences in composition across samples. In the PCA score plot (Fig.\u0026nbsp;\u003cspan refid=\"Fig5\" class=\"InternalRef\"\u003e5\u003c/span\u003eA), Panax japonicus and Panax notoginseng were clearly distinguished from Panax ginseng and Panax quinquefolius; however, RS and Panax XYS were not effectively separated, a finding consistent with the chemical fingerprint similarity assessment. In contrast, the supervised OPLS-DA method effectively reduced errors associated with non-experimental factors, yielding more accurate classification results[\u003cspan citationid=\"CR18\" class=\"CitationRef\"\u003e18\u003c/span\u003e]. A 200-permutation test confirmed the model\u0026rsquo;s robustness, with parameters R\u0026sup2;Y\u0026thinsp;=\u0026thinsp;0.982, R\u0026sup2;X\u0026thinsp;=\u0026thinsp;0.806, Q\u0026sup2; = 0.964, and P\u0026thinsp;\u0026lt;\u0026thinsp;0.005, indicating high explanatory and predictive power without overfitting (Figs.\u0026nbsp;\u003cspan refid=\"Fig5\" class=\"InternalRef\"\u003e5\u003c/span\u003eC and \u003cspan refid=\"Fig5\" class=\"InternalRef\"\u003e5\u003c/span\u003eD)[\u003cspan citationid=\"CR19\" class=\"CitationRef\"\u003e19\u003c/span\u003e]. Based on a variable importance in projection (VIP) threshold greater than 1.0, 55 differential compounds with contributions were screened, while using a VIP threshold greater than 1.5, 15 significantly contributing differential compounds were identified. The relative abundances of these 15 marker compounds across the four Panax species are visualized in Fig.\u0026nbsp;\u003cspan refid=\"Fig6\" class=\"InternalRef\"\u003e6\u003c/span\u003e. As shown in Fig.\u0026nbsp;\u003cspan refid=\"Fig7\" class=\"InternalRef\"\u003e7\u003c/span\u003e, the heatmap visually illustrates the differential relative abundance of 55 ginsenosides across four Panax species. The results demonstrate distinct interspecies clustering, indicating that the accumulation patterns of characteristic ginsenosides were markedly species-specific. Specifically, BSQ was significantly enriched in oleanane-type saponins (e.g., chikusetsusaponin IV and IVa), while SQ was characterized by notoginsenoside R1 and Ft1 as its predominant markers. Although XYS and RS shared certain protopanaxadiol- and protopanaxatriol-type ginsenosides, the former exhibited significantly higher levels of malonylated ginsenosides, further delineating the chemical boundaries between the two species.\u003c/p\u003e\u003cp\u003e\u003c/p\u003e\u003cp\u003e\u003c/p\u003e\u003cp\u003e\u003c/p\u003e\u003c/div\u003e"},{"header":"4. Conclusion","content":"\u003cp\u003eIn this study, an integrated HPLC and UPLC\u0026ndash;Orbitrap\u0026ndash;MS strategy was successfully established for the comprehensive chemical characterization, quantitative evaluation, and species authentication of four medicinally important Panax medicines. The validated HPLC method permitted the reproducible quantification of 11 major ginsenosides and 2 polyacetylenes in 41 commercial batches. Similarity evaluation of the generated fingerprints revealed high intra-specific consistency and pronounced inter-specific divergence, underscoring the specificity of the approach. Multivariate modelling (PCA/OPLS-DA) delivered unambiguous species segregation; the final OPLS-DA model possessed excellent explanatory and predictive power and afforded clear chemical distinction even between the closely related RS and XYS[\u003cspan additionalcitationids=\"CR21\" citationid=\"CR20\" class=\"CitationRef\"\u003e20\u003c/span\u003e\u0026ndash;\u003cspan citationid=\"CR22\" class=\"CitationRef\"\u003e22\u003c/span\u003e]. Heat-map visualisation further demonstrated species-specific accumulation patterns of these markers, underscoring their utility as quality-control indicators. These findings offer a scientific basis for quality assessment, authentication, and standardization of Panax-derived products.\u003c/p\u003e\u003cp\u003eThe integrated approach enhanced the capability to detect adulteration and ensure product consistency and supported the development of a more robust quality control system for traditional herbal medicines. Future studies may focus on correlating these chemical markers with pharmacological activities to further validate their roles as quality markers.\u003c/p\u003e"},{"header":"Declarations","content":"\u003cp\u003e\u003cstrong\u003eAuthor contributions:\u003c/strong\u003e\u003c/p\u003e\n\u003cp\u003eConceptualization, X.L.; methodology, A.W. and L.C.; investigation, X.L. and J.L.; formal analysis, B.L. and J.C.; writing \u0026ndash; original draft preparation, S.W. and Y.Q.; writing \u0026ndash; review \u0026amp; editing, X.N. and X.B..; project administration, W.W.; supervision, H.Y.; Funding acquisition, C.P. All authors have read and agreed to the published version of the manuscript.\u003c/p\u003e\n\u003cp\u003e\u003cstrong\u003eFunding:\u003c/strong\u003e\u003c/p\u003e\n\u003cp\u003eThis work was supported by the Natural Science Foundation of Hunan Province [Grant No.2024JJ8237, 2023JJ60130, and 2025JJ80144] and National Natural Science Foundation of China (Grant No. 82405012).\u003c/p\u003e\n\u003cp\u003e\u003cstrong\u003eConflicts of Interest:\u003c/strong\u003e\u003c/p\u003e\n\u003cp\u003eThe authors declare that they have no competing interests.\u003c/p\u003e"},{"header":"References","content":"\u003col\u003e\n\u003cli\u003eYang, W.Z.; Hu, Y.; Wu, W.Y.; Ye, M.; Guo, D.A. Saponins in the genus Panax L. 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Characterization of Ginsenosides from the Root of Panax ginseng by Integrating Untargeted Metabolites Using UPLC-Triple TOF-MS. \u003cem\u003eMolecules \u003c/em\u003e\u003cstrong\u003e2023\u003c/strong\u003e, \u003cem\u003e28\u003c/em\u003e, doi:10.3390/molecules28052068.\u003c/li\u003e\n\u003c/ol\u003e"}],"fulltextSource":"","fullText":"","funders":[],"hasAdminPriorityOnWorkflow":false,"hasManuscriptDocX":true,"hasOptedInToPreprint":true,"hasPassedJournalQc":"","hasAnyPriority":false,"hideJournal":false,"highlight":"","institution":"","isAcceptedByJournal":true,"isAuthorSuppliedPdf":false,"isDeskRejected":"","isHiddenFromSearch":false,"isInQc":false,"isInWorkflow":false,"isPdf":false,"isPdfUpToDate":true,"isWithdrawnOrRetracted":false,"journal":{"display":true,"email":"[email protected]","identity":"chromatographia","isNatureJournal":false,"hasQc":true,"allowDirectSubmit":false,"externalIdentity":"chro","sideBox":"Learn more about [Chromatographia](https://www.springer.com/journal/10337)","snPcode":"10337","submissionUrl":"https://submission.nature.com/new-submission/10337/3","title":"Chromatographia","twitterHandle":"","acdcEnabled":true,"dfaEnabled":true,"editorialSystem":"em","reportingPortfolio":"Springer Hybrid","inReviewEnabled":true,"inReviewRevisionsEnabled":false},"keywords":"ginsenosides, Panax, HPLC, LC-Orbitrap-MS","lastPublishedDoi":"10.21203/rs.3.rs-7772424/v1","lastPublishedDoiUrl":"https://doi.org/10.21203/rs.3.rs-7772424/v1","license":{"name":"CC BY 4.0","url":"https://creativecommons.org/licenses/by/4.0/"},"manuscriptAbstract":"\u003cp\u003ePanax species are medicinal plants of high pharmaceutical and economic value. However, the high degree of similarity in their chemical compositions often leads to issues of adulteration and challenges in quality control. This study developed an integrated analytical strategy combining high-performance liquid chromatography (HPLC) and ultra-performance liquid chromatography\u0026ndash;Orbitrap mass spectrometry (UPLC\u0026ndash;Orbitrap\u0026ndash;MS) to systematically characterize and differentiate four major Panax species: Panax ginseng (RS), Panax quinquefolius (XYS), Panax notoginseng (SQ), and Panax japonicus (BSQ). The established HPLC method proved robust and reliable, enabling the simultaneous quantification of 13 bioactive compounds, including 11 saponins and 2 polyacetylenes, and demonstrated excellent precision, reproducibility, and accuracy. The approach clearly revealed content variations of major constituents among the different species. Chemical fingerprinting combined with similarity analysis indicated significant interspecies differences. A total of 129 compounds were identified using high-resolution mass spectrometry, covering structure types such as protopanaxadiol-type, protopanaxatriol-type, oleanane-type, ocotillol-type, and C-17 side-chain variant saponins. By elucidating the characteristic fragmentation patterns of representative ginsenosides, this work offered a theoretical foundation for reliable compound identification. The results provided a scientific foundation for quality assessment and species authentication, offering a comprehensive strategy for the standardization of Panax-derived medicinal products.\u003c/p\u003e","manuscriptTitle":"Application of HPLC Combined with UPLC–Orbitrap–MS in Chemical Characterization, Quantitative Detection, and Species Authentication of Four Panax-derived Products","msid":"","msnumber":"","nonDraftVersions":[{"code":1,"date":"2025-10-20 15:37:50","doi":"10.21203/rs.3.rs-7772424/v1","editorialEvents":[{"type":"communityComments","content":0},{"type":"decision","content":"Revision requested","date":"2025-11-18T09:06:03+00:00","index":"","fulltext":""},{"type":"editorInvitedReview","content":"","date":"2025-11-09T16:06:03+00:00","index":"hide","fulltext":""},{"type":"editorInvitedReview","content":"","date":"2025-10-21T10:25:50+00:00","index":"hide","fulltext":""},{"type":"reviewerAgreed","content":"85100150726562861398927014462254223629","date":"2025-10-10T13:28:25+00:00","index":"hide","fulltext":""},{"type":"reviewerAgreed","content":"333340293622356567122107730626923827827","date":"2025-10-09T01:19:06+00:00","index":"hide","fulltext":""},{"type":"reviewersInvited","content":"","date":"2025-10-08T07:57:36+00:00","index":"","fulltext":""},{"type":"editorAssigned","content":"","date":"2025-10-08T03:01:35+00:00","index":"","fulltext":""},{"type":"checksComplete","content":"","date":"2025-10-07T06:10:22+00:00","index":"","fulltext":""},{"type":"submitted","content":"Chromatographia","date":"2025-10-03T09:55:28+00:00","index":"","fulltext":""}],"status":"published","journal":{"display":true,"email":"[email protected]","identity":"chromatographia","isNatureJournal":false,"hasQc":true,"allowDirectSubmit":false,"externalIdentity":"chro","sideBox":"Learn more about [Chromatographia](https://www.springer.com/journal/10337)","snPcode":"10337","submissionUrl":"https://submission.nature.com/new-submission/10337/3","title":"Chromatographia","twitterHandle":"","acdcEnabled":true,"dfaEnabled":true,"editorialSystem":"em","reportingPortfolio":"Springer Hybrid","inReviewEnabled":true,"inReviewRevisionsEnabled":false}}],"origin":"","ownerIdentity":"108bef06-182e-423f-b722-8bd23af86509","owner":[],"postedDate":"October 20th, 2025","published":true,"recentEditorialEvents":[],"rejectedJournal":[],"revision":"","amendment":"","status":"published-in-journal","subjectAreas":[],"tags":[],"updatedAt":"2025-12-22T15:59:34+00:00","versionOfRecord":{"articleIdentity":"rs-7772424","link":"https://doi.org/10.1007/s10337-025-04468-7","journal":{"identity":"chromatographia","isVorOnly":false,"title":"Chromatographia"},"publishedOn":"2025-12-18 15:57:12","publishedOnDateReadable":"December 18th, 2025"},"versionCreatedAt":"2025-10-20 15:37:50","video":"","vorDoi":"10.1007/s10337-025-04468-7","vorDoiUrl":"https://doi.org/10.1007/s10337-025-04468-7","workflowStages":[]},"version":"v1","identity":"rs-7772424","journalConfig":"researchsquare"},"__N_SSP":true},"page":"/article/[identity]/[[...version]]","query":{"redirect":"/article/rs-7772424","identity":"rs-7772424","version":["v1"]},"buildId":"8U1c8b4HqxoKbykW_rLl7","isFallback":false,"isExperimentalCompile":false,"dynamicIds":[84888],"gssp":true,"scriptLoader":[]}