Synthesis, thermal, physical, structural, optical, and elastic characteristics of new class of glasses based on the Sb2O3-K2O-B2O3 system

Synthesis, thermal, physical, structural, optical, and elastic characteristics of new class of glasses based on the Sb2O3-K2O-B2O3 system | Research Square window.SnipcartSettings = { analytics: { enabled: false } }; (function() { var accessVector = localStorage.getItem('access_vector') || ''; window.dataLayer = window.dataLayer || []; if (accessVector) { window.dataLayer.push({ user: { profile: { profileInfo: { snid: accessVector } } } }); } })(); (function(w,d,s,l,i){w[l]=w[l]||[];w[l].push({'gtm.start':new Date().getTime(),event:'gtm.js'});var f=d.getElementsByTagName(s)[0],j=d.createElement(s),dl=l!='dataLayer'?'&l='+l:'';j.async=true;j.src='https://www.googletagmanager.com/gtm.js?id='+i+dl;f.parentNode.insertBefore(j,f);})(window,document,'script','dataLayer','GTM-K279D39R'); Browse Preprints In Review Journals COVID-19 Preprints AJE Video Bytes Research Tools Research Promotion AJE Professional Editing AJE Rubriq About Preprint Platform In Review Editorial Policies Our Team Advisory Board Help Center Sign In Submit a Preprint Cite Share Download PDF Research Article Synthesis, thermal, physical, structural, optical, and elastic characteristics of new class of glasses based on the Sb2O3-K2O-B2O3 system majda hamzaoui, lina Beghdadi, nesrine guesmia, Ronan Lebullenger, and 2 more This is a preprint; it has not been peer reviewed by a journal. https://doi.org/ 10.21203/rs.3.rs-4814244/v1 This work is licensed under a CC BY 4.0 License Status: Posted Version 1 posted You are reading this latest preprint version Abstract A new series of glasses based on the system (80-x) Sb 2 O 3 -20K 2 O-xB 2 O 3 where (0 ≤ x ≤ 40 mol. %) was prepared using melt-quenching process. XRD characterization is used to improve the non cristallinity nature of the glass samples. The different structural characteristics, including molar volume (V m ), density (ρ), d (B−B) distance between two boron atoms, oxygen content by oxygen molar volume (V O ), packing density (OPD) and the free volume (V f ) were obtained to properly verify the compactness of the SKB glass network characterized by more links. In addition to the thermal, optical, elastic, structural and physical factors, which were examined, the vitreous nature of SKB glasses was verified according to the DSC curves. Structural analysis were performed using ATR spectroscopy to determine the fraction of four coordinated boron atoms as well as the presence of several functional groups in the glass samples. All these changes support the modification of the glass structure from BO 3 to BO 4 . The study carried out using ultrasonic technology has been done to investigate the structural role of B 2 O 3 in SKB glasses. The different moduli of elasticity (E, K, G, L, and υ) as well as the Debye temperature and Makishima Mackenzie’s theory can be explained by the glass structure’s compactness. Borate glasses ATR spectroscopy DSC method and Makishima–Mackenzie's model Full Text Additional Declarations No competing interests reported. Cite Share Download PDF Status: Posted Version 1 posted You are reading this latest preprint version Research Square lets you share your work early, gain feedback from the community, and start making changes to your manuscript prior to peer review in a journal. As a division of Research Square Company, we’re committed to making research communication faster, fairer, and more useful. We do this by developing innovative software and high quality services for the global research community. Our growing team is made up of researchers and industry professionals working together to solve the most critical problems facing scientific publishing. Also discoverable on Platform About Our Team In Review Editorial Policies Advisory Board Help Center Resources Author Services Accessibility API Access RSS feed Manage Cookie Preferences © Research Square 2026 | ISSN 2693-5015 (online) Privacy Policy Terms of Service Do Not Sell My Personal Information {"props":{"pageProps":{"initialData":{"identity":"rs-4814244","acceptedTermsAndConditions":true,"allowDirectSubmit":true,"archivedVersions":[],"articleType":"Research Article","associatedPublications":[],"authors":[{"id":343443220,"identity":"a9fed1ac-c0ff-403e-be6a-0a5ae38e3935","order_by":0,"name":"majda 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XRD characterization is used to improve the non cristallinity nature of the glass samples. The different structural characteristics, including molar volume (V\u003csub\u003em\u003c/sub\u003e), density (ρ), d \u003csub\u003e(B\u0026minus;B)\u003c/sub\u003e distance between two boron atoms, oxygen content by oxygen molar volume (V\u003csub\u003eO\u003c/sub\u003e), packing density (OPD) and the free volume (V\u003csub\u003ef\u003c/sub\u003e) were obtained to properly verify the compactness of the SKB glass network characterized by more links. In addition to the thermal, optical, elastic, structural and physical factors, which were examined, the vitreous nature of SKB glasses was verified according to the DSC curves. Structural analysis were performed using ATR spectroscopy to determine the fraction of four coordinated boron atoms as well as the presence of several functional groups in the glass samples. 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