Rhodium(III) Complexes Featuring Coordinated CF3 Appendages
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Abstract
The synthesis and characterisation of complexes featuring intramolecular CF 3 ➞Rh(III) interactions is described. This bonding is evidenced in the solid state using X-ray diffraction, with Rh–F contacts of 2.36 – 2.45 Å, and in solution using NMR spectroscopy, through detection of time-averaged 1 J RhF and 2 J PF coupling.
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- last seen: 2026-05-19T01:45:01.086888+00:00