Structural, Optical and Electrical Characterizations of Cr-doped CuO Thin Films

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Cr-doped CuO thin films were synthesized and characterized, revealing monoclinic structure and altered optical and electrical properties, with 1% Cr doping yielding the highest light sensitivity in Cr:CuO/p-Si diodes.

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The study investigated polycrystalline Cr-doped CuO thin films prepared by spin coating onto soda lime glass and onto p-type Si (100) wafers, followed by characterization of structure (XRD), optics (UV–vis transmittance and energy band gap), and electrical behavior (I–V and C–V) of Cr:CuO/p-Si diodes. XRD showed monoclinic polycrystalline CuO with two main peaks (002) and (111), and UV–vis results indicated that both transmittance and energy band gap varied with increasing Cr doping ratio. Electrical measurements linked diode I–V and C–V characteristics to the Cr:CuO layer, with 1% Cr doping producing the highest light sensitivity among tested concentrations. The paper is described as a preprint and notes it was not peer reviewed prior to journal publication, which is the main caveat stated in the provided text. The paper does not explicitly discuss endometriosis or adenomyosis; it was included in the corpus via a keyword match in the upstream search index.

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Abstract

Abstract The polycrystalline copper oxide (CuO) thin films have been produced using method of spin coating onto the soda lime glass (SLG) as well as substrate of p-type Si (1 0 0) wafers at 500 ºC in furnace. The obtained undoped and Cr doped thin films of CuO have been comprehensively characterized via X-ray diffraction (XRD), ultraviolet–vis (UV–vis) spectroscopy, the current–voltage ( I – V ) and capacitance–voltage ( C – V ) characteristics for providing information on quality of the crystalline nature, change in energy band gap and electrical properties, respectively. Structural analysis results which obtained from XRD data demonstrate that CuO films conjunction with Cr doping indicated that all thin films have monoclinic polycrystalline nature, with two main peaks (002) and (111) with d hkl about 2.52 and 2.32 Å, respectively. The transmittance and energy band gap value of undoped and Cr doped thin films of CuO ranging in varying concentration ratio have been determined in the wavelength region of 300 to 1100 nm. UV–vis spectrum analysis results indicate that both transmittance value and energy band gap of the CuO films is changed with increasing Cr doping ratio in CuO solution at room temperature. The I–V and C–V characteristic of Cr:CuO/p-Si diodes were associated with the CuO/p-Si diodes. It is seen that doping of Cr had a significant change onv the obtained devices’ performance. Thus, the Cr:CuO/p-Si diodes generated by 1% Cr doping using spin coating method had the highest light sensitivity compared with those of the other diodes.
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Structural, Optical and Electrical Characterizations of Cr-doped CuO Thin Films | Research Square window.SnipcartSettings = { analytics: { enabled: false } }; (function() { var accessVector = localStorage.getItem('access_vector') || ''; window.dataLayer = window.dataLayer || []; if (accessVector) { window.dataLayer.push({ user: { profile: { profileInfo: { snid: accessVector } } } }); } })(); (function(w,d,s,l,i){w[l]=w[l]||[];w[l].push({'gtm.start':new Date().getTime(),event:'gtm.js'});var f=d.getElementsByTagName(s)[0],j=d.createElement(s),dl=l!='dataLayer'?'&l='+l:'';j.async=true;j.src='https://www.googletagmanager.com/gtm.js?id='+i+dl;f.parentNode.insertBefore(j,f);})(window,document,'script','dataLayer','GTM-K279D39R'); Browse Preprints In Review Journals COVID-19 Preprints AJE Video Bytes Research Tools Research Promotion AJE Professional Editing AJE Rubriq About Preprint Platform In Review Editorial Policies Our Team Advisory Board Help Center Sign In Submit a Preprint Cite Share Download PDF Research Article Structural, Optical and Electrical Characterizations of Cr-doped CuO Thin Films Silan BATURAY, ilhan CANDAN, Cihat OZAYDIN This is a preprint; it has not been peer reviewed by a journal. https://doi.org/ 10.21203/rs.3.rs-1118403/v1 This work is licensed under a CC BY 4.0 License Status: Published Journal Publication published 16 Feb, 2022 Read the published version in Journal of Materials Science: Materials in Electronics → Version 1 posted You are reading this latest preprint version Abstract The polycrystalline copper oxide (CuO) thin films have been produced using method of spin coating onto the soda lime glass (SLG) as well as substrate of p-type Si (1 0 0) wafers at 500 ºC in furnace. The obtained undoped and Cr doped thin films of CuO have been comprehensively characterized via X-ray diffraction (XRD), ultraviolet–vis (UV–vis) spectroscopy, the current–voltage ( I – V ) and capacitance–voltage ( C – V ) characteristics for providing information on quality of the crystalline nature, change in energy band gap and electrical properties, respectively. Structural analysis results which obtained from XRD data demonstrate that CuO films conjunction with Cr doping indicated that all thin films have monoclinic polycrystalline nature, with two main peaks (002) and (111) with d hkl about 2.52 and 2.32 Å, respectively. The transmittance and energy band gap value of undoped and Cr doped thin films of CuO ranging in varying concentration ratio have been determined in the wavelength region of 300 to 1100 nm. UV–vis spectrum analysis results indicate that both transmittance value and energy band gap of the CuO films is changed with increasing Cr doping ratio in CuO solution at room temperature. The I–V and C–V characteristic of Cr:CuO/p-Si diodes were associated with the CuO/p-Si diodes. It is seen that doping of Cr had a significant change onv the obtained devices’ performance. Thus, the Cr:CuO/p-Si diodes generated by 1% Cr doping using spin coating method had the highest light sensitivity compared with those of the other diodes. Chemical Engineering Biomedical Engineering Cr CuO thin films spin coating Cr:CuO/p-Si diodes Full Text Cite Share Download PDF Status: Published Journal Publication published 16 Feb, 2022 Read the published version in Journal of Materials Science: Materials in Electronics → Version 1 posted You are reading this latest preprint version Research Square lets you share your work early, gain feedback from the community, and start making changes to your manuscript prior to peer review in a journal. As a division of Research Square Company, we’re committed to making research communication faster, fairer, and more useful. We do this by developing innovative software and high quality services for the global research community. Our growing team is made up of researchers and industry professionals working together to solve the most critical problems facing scientific publishing. Also discoverable on Platform About Our Team In Review Editorial Policies Advisory Board Help Center Resources Author Services Accessibility API Access RSS feed Manage Cookie Preferences © Research Square 2026 | ISSN 2693-5015 (online) Privacy Policy Terms of Service Do Not Sell My Personal Information {"props":{"pageProps":{"initialData":{"identity":"rs-1118403","acceptedTermsAndConditions":true,"allowDirectSubmit":true,"archivedVersions":[],"articleType":"Research Article","associatedPublications":[],"authors":[{"id":68042122,"identity":"61666308-b54f-470e-b3f4-556f091fa683","order_by":0,"name":"Silan BATURAY","email":"","orcid":"","institution":"Dicle University: Dicle Universitesi","correspondingAuthor":false,"prefix":"","firstName":"Silan","middleName":"","lastName":"BATURAY","suffix":""},{"id":68042123,"identity":"21a9b81c-aa03-47e5-9a60-20a429cfc778","order_by":1,"name":"ilhan CANDAN","email":"data:image/png;base64,iVBORw0KGgoAAAANSUhEUgAAAZAAAAAyAQMAAABI0h/eAAAABlBMVEX///8AAABVwtN+AAAACXBIWXMAAA7EAAAOxAGVKw4bAAABAUlEQVRIiWNgGAWjYBACNnYeGDOBgeEDmwQDH4jNg1MDUAszkhbGGUAtbFAtEjj1IGth5gGqJ6iFj5n34OcCBjt5c/bkZ49tyizk2dgbGB+8bWOoM2/A5TC+ZOkZDMmGO3uemRvnnJMwbOM5wGw4t41BQuYATr8YSPMwHGDccCPBTDq3TSKBDYikeYFacLkMqMX4N1CL/YYb6d+kLUFa5B+w/yagxQxkS+KGGzlm0oxgW4CChLRY8xgkJ28486ZMsgfsl8RmyTnnJCRn4NAi395jfJunws52w/H0bRI/yurk+dkPH/zwpsyGH3fEgIABCo+xgQFfTI6CUTAKRsEoIAwAa6BDeWgnUxAAAAAASUVORK5CYII=","orcid":"https://orcid.org/0000-0001-9489-5324","institution":"Dicle University: Dicle Universitesi","correspondingAuthor":true,"prefix":"","firstName":"ilhan","middleName":"","lastName":"CANDAN","suffix":""},{"id":68042124,"identity":"b3dfdda3-f5bb-4b33-9cac-ea0d5c21bced","order_by":2,"name":"Cihat OZAYDIN","email":"","orcid":"","institution":"Batman University: Batman Universitesi","correspondingAuthor":false,"prefix":"","firstName":"Cihat","middleName":"","lastName":"OZAYDIN","suffix":""}],"badges":[],"createdAt":"2021-11-26 23:21:27","currentVersionCode":1,"declarations":"","doi":"10.21203/rs.3.rs-1118403/v1","doiUrl":"https://doi.org/10.21203/rs.3.rs-1118403/v1","draftVersion":[],"editorialEvents":[{"content":"https://doi.org/10.1007/s10854-022-07918-2","type":"published","date":"2022-02-16T05:31:26+00:00"}],"editorialNote":"","failedWorkflow":false,"files":[],"financialInterests":"","formattedTitle":"Structural, Optical and Electrical Characterizations of Cr-doped CuO Thin Films","fulltext":[{"header":"Full Text","content":"This preprint is available for \u003ca href='/article/rs-1118403/latest.pdf' target='_blank'\u003edownload as a PDF\u003c/a\u003e."}],"fulltextSource":"","fullText":"","funders":[],"hasAdminPriorityOnWorkflow":false,"hasManuscriptDocX":false,"hasOptedInToPreprint":true,"hasPassedJournalQc":"","hasAnyPriority":false,"hideJournal":true,"highlight":"","institution":"","isAcceptedByJournal":true,"isAuthorSuppliedPdf":true,"isDeskRejected":"","isHiddenFromSearch":false,"isInQc":false,"isInWorkflow":false,"isPdf":false,"isPdfUpToDate":true,"isWithdrawnOrRetracted":false,"journal":{"display":true,"email":"[email protected]","identity":"researchsquare","isNatureJournal":false,"hasQc":true,"allowDirectSubmit":true,"externalIdentity":"","sideBox":"","snPcode":"","submissionUrl":"/submission","title":"Research Square","twitterHandle":"researchsquare","acdcEnabled":true,"dfaEnabled":false,"editorialSystem":"","reportingPortfolio":"","inReviewEnabled":false,"inReviewRevisionsEnabled":true},"keywords":"Cr, CuO, thin films, spin coating, Cr:CuO/p-Si diodes","lastPublishedDoi":"10.21203/rs.3.rs-1118403/v1","lastPublishedDoiUrl":"https://doi.org/10.21203/rs.3.rs-1118403/v1","license":{"name":"CC BY 4.0","url":"https://creativecommons.org/licenses/by/4.0/"},"manuscriptAbstract":"The polycrystalline copper oxide (CuO) thin films have been produced using method of spin coating onto the soda lime glass (SLG) as well as substrate of p-type Si (1 0 0) wafers at 500 ºC in furnace. 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