Visualized high-Tc superconducting mechanism of polyhedral quantum wells confined electrons

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Abstract Despite decades of research, the origin of high-temperature superconductivity is still unclear, and its microscopic mechanism remains a subject of intense debate. The intrinsic Mott insulating properties of copper oxide parent compounds and the experimentally observed charge-ordered phases in real space suggest that high-temperature superconductivity may stem from localized electrons rather than itinerant electrons. In this work, we propose a unified microscopic mechanism where confined electrons within polyhedral quantum wells represent the Mott ground state, and symmetry-breaking of electron-hole pairs acts as the superconducting mechanism. A single parameter formula for the critical temperature (Tc) of unconventional superconductors is developed, allowing accurate determination of Tc based on lattice constants. The approach elucidates relationships between various charge-order phases and doping concentration, explores Fermi surface structures, investigates spin resonance peaks and parities, and examines pressure-induced dual superconducting phase transitions - all consistent with experimental observations. It is also estimated that the highest Tc of the newly discovered nickel-based superconductor will not exceed 100 K. This work offers critical insights into unconventional superconductivity’s fundamental mechanisms while introducing a new paradigm to reveal more intrinsic connections between superconductivity, conductivity, and magnetism.
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The intrinsic Mott insulating properties of copper oxide parent compounds and the experimentally observed charge-ordered phases in real space suggest that high-temperature superconductivity may stem from localized electrons rather than itinerant electrons. In this work, we propose a unified microscopic mechanism where confined electrons within polyhedral quantum wells represent the Mott ground state, and symmetry-breaking of electron-hole pairs acts as the superconducting mechanism. A single parameter formula for the critical temperature (Tc) of unconventional superconductors is developed, allowing accurate determination of Tc based on lattice constants. The approach elucidates relationships between various charge-order phases and doping concentration, explores Fermi surface structures, investigates spin resonance peaks and parities, and examines pressure-induced dual superconducting phase transitions - all consistent with experimental observations. It is also estimated that the highest Tc of the newly discovered nickel-based superconductor will not exceed 100 K. This work offers critical insights into unconventional superconductivity’s fundamental mechanisms while introducing a new paradigm to reveal more intrinsic connections between superconductivity, conductivity, and magnetism. Physical sciences/Physics/Condensed-matter physics/Electronic properties and materials Physical sciences/Materials science/Condensed-matter physics/Superconducting properties and materials Full Text Additional Declarations There is NO Competing Interest. Cite Share Download PDF Status: Posted Version 1 posted You are reading this latest preprint version Research Square lets you share your work early, gain feedback from the community, and start making changes to your manuscript prior to peer review in a journal. As a division of Research Square Company, we’re committed to making research communication faster, fairer, and more useful. We do this by developing innovative software and high quality services for the global research community. Our growing team is made up of researchers and industry professionals working together to solve the most critical problems facing scientific publishing. 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