Abstract
Silicon is a promising candidate anode material for high-energy lithium-ion batteries (LIBs) due to its high theoretical capacity. However, its practical utilization is limited by its low intrinsic electrical conductivity and significant volume expansion during lithiation. To address these challenges, substantial efforts have been dedicated to developing silicon/carbon composites. Herein, we report a solvent-free approach for encapsulating nano Si in nitrogen-doped carbon (Si@NC). The nitrogen-doped carbon coating significantly improves the electrical conductivity and effectively accommodates the volume fluctuation of nano Si. The resulting Si@NC composite manifests an impressive reversible capacity of 915 mAh g –1 with decent cyclability. This scalable, cost-effective, and environment-benign synthesis, which is solvent-free and flammable gas-free, offers a viable approach for the construction of high-performance silicon/carbon anodes.
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Solvent-Free Encapsulation of Nano Si in Carbon Enables Stable Lithium Storage | Authorea try { document.documentElement.classList.add('js'); } catch (e) { } var _gaq = _gaq || []; _gaq.push(['_setAccount', 'G-8VDV14Y67G']); _gaq.push(['_trackPageview']); (function() { var ga = document.createElement('script'); ga.type = 'text/javascript'; ga.async = true; ga.src = ('https:' == document.location.protocol ? 'https://ssl' : 'http://www') + '.google-analytics.com/ga.js'; var s = document.getElementsByTagName('script')[0]; s.parentNode.insertBefore(ga, s); })(); Skip to main content Preprints Collections Wiley Open Research IET Open Research Ecological Society of Japan All Collections About About Authorea FAQs Contact Us Quick Search anywhere Search for preprint articles, keywords, etc. Search Search ADVANCED SEARCH SCROLL Chinese Journal of Chemistry This is a preprint and has not been peer reviewed. Data may be preliminary. 8 January 2026 V1 Latest version Share on Solvent-Free Encapsulation of Nano Si in Carbon Enables Stable Lithium Storage Authors : Luxuan Yang , Jie Xu , Xiaofa Liang , Shanlin Liu , Lin Wang , Shidong Li , and Liang Zhou 0000-0001-6756-3578 [email protected] Authors Info & Affiliations https://doi.org/10.22541/au.176786488.82306995/v1 Published Chinese Journal of Chemistry Version of record Peer review timeline 151 views 66 downloads Contents Abstract Supplementary Material Information & Authors Metrics & Citations View Options References Figures Tables Media Share Abstract Silicon is a promising candidate anode material for high-energy lithium-ion batteries (LIBs) due to its high theoretical capacity. However, its practical utilization is limited by its low intrinsic electrical conductivity and significant volume expansion during lithiation. To address these challenges, substantial efforts have been dedicated to developing silicon/carbon composites. Herein, we report a solvent-free approach for encapsulating nano Si in nitrogen-doped carbon (Si@NC). The nitrogen-doped carbon coating significantly improves the electrical conductivity and effectively accommodates the volume fluctuation of nano Si. The resulting Si@NC composite manifests an impressive reversible capacity of 915 mAh g –1 with decent cyclability. This scalable, cost-effective, and environment-benign synthesis, which is solvent-free and flammable gas-free, offers a viable approach for the construction of high-performance silicon/carbon anodes. Supplementary Material File (manuscript.docx) Download 3.75 MB Information & Authors Information Version history V1 Version 1 08 January 2026 Peer review timeline Published Chinese Journal of Chemistry Version of Record 6 Apr 2026 Published Copyright This work is licensed under a Non Exclusive No Reuse License. Collection Chinese Journal of Chemistry Keywords conformal carbon coating lithium-ion batteries nitrogen-doping silicon solvent-free synthesis Authors Affiliations Luxuan Yang Hubei Longzhong Laboratory View all articles by this author Jie Xu Hubei Longzhong Laboratory View all articles by this author Xiaofa Liang State Key Laboratory of Advanced Technology for Materials Synthesis Processing View all articles by this author Shanlin Liu State Key Laboratory of Advanced Technology for Materials Synthesis Processing View all articles by this author Lin Wang State Key Laboratory of Advanced Technology for Materials Synthesis Processing View all articles by this author Shidong Li Hubei Longzhong Laboratory View all articles by this author Liang Zhou 0000-0001-6756-3578 [email protected] Hubei Longzhong Laboratory View all articles by this author Metrics & Citations Metrics Article Usage 151 views 66 downloads .FvxKWukQNSOunydq8rnd { width: 100px; } Citations Download citation Luxuan Yang, Jie Xu, Xiaofa Liang, et al. Solvent-Free Encapsulation of Nano Si in Carbon Enables Stable Lithium Storage. Authorea . 08 January 2026. DOI: https://doi.org/10.22541/au.176786488.82306995/v1 If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download. For more information or tips please see 'Downloading to a citation manager' in the Help menu . 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