Configurable Writing of Ferroelectric Nanostructure for the Nonvolatile Memory and Encryption

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Abstract

Traditional nonvolatile memory technology’s reliance on single-dimension encryption poses significant security vulnerabilities. Herein, we demonstrate a template-free electron beam lithography (EBL) technique for ferroelectric nanostructures with dose-controllable ferroelectric domain, and use them for the nonvolatile memory and encryption. The obtained ferroelectric nanostructure could function simultaneously as an electron-beam read-only-memory (EB-ROM) by electron beam irradiation and a ferroelectric random-access-memory (FeRAM) by external electric field. By using properly irradiated electron beam, stable metastable phases consisted of ferroelectric phase and relaxor ferroelectric phase are formed in the irradiated P(VDF-TrFE) nanostructure, which possesses outstanding memory characteristics, such as, 2-fold reduction of power consuming, and 2000-fold enhancement of domain switching rate. Meanwhile, the effect of the defects induced by electron-beam irradiation on ferroelectric domain is well revealed by dynamic Monte Carlo (MC) simulations. Our systematic study provides a new avenue for developing next-generation memory devices in the flexible electronic fields.
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Abstract

Traditional nonvolatile memory technology’s reliance on single-dimension encryption poses significant security vulnerabilities. Herein, we demonstrate a template-free electron beam lithography (EBL) technique for ferroelectric nanostructures with dose-controllable ferroelectric domain, and use them for the nonvolatile memory and encryption. The obtained ferroelectric nanostructure could function simultaneously as an electron-beam read-only-memory (EB-ROM) by electron beam irradiation and a ferroelectric random-access-memory (FeRAM) by external electric field. By using properly irradiated electron beam, stable metastable phases consisted of ferroelectric phase and relaxor ferroelectric phase are formed in the irradiated P(VDF-TrFE) nanostructure, which possesses outstanding memory characteristics, such as, 2-fold reduction of power consuming, and 2000-fold enhancement of domain switching rate. Meanwhile, the effect of the defects induced by electron-beam irradiation on ferroelectric domain is well revealed by dynamic Monte Carlo (MC) simulations. Our systematic study provides a new avenue for developing next-generation memory devices in the flexible electronic fields. Supplementary Material File (yxchen-final version-0921.docx) - Download - 5.52 MB Information & Authors Information Version history Copyright This work is licensed under a Non Exclusive No Reuse License.

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Authors Metrics & Citations Metrics Article Usage 143views 75downloads Citations Download citation Yingxin Chen, Yijing Nie, Huigui Fang, et al. Configurable Writing of Ferroelectric Nanostructure for the Nonvolatile Memory and Encryption. Authorea. 22 September 2025. DOI: https://doi.org/10.22541/au.175851374.49487619/v1 DOI: https://doi.org/10.22541/au.175851374.49487619/v1 If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download. For more information or tips please see 'Downloading to a citation manager' in the Help menu.

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