Luminescent Nanoparticles of Gd2O3:Eu3+ Encapsulated Within SiO2-PMMA Gel-Polymer Hybrid Matrix: Synthesis and Optical Properties

Luminescent gadolinium oxide nanoparticles doped with europium were synthesized through a precipitation reaction using gadolinium and europium nitrates as precursors. The europium- doped gadolinium oxide nanoparticles were incorporated first: into a Gel matrix of silicon dioxide; and second: mixing with Polymethyl Methacrylate. Both processes are synthesized by the simultaneous hydrolysis of tetraethyl orthosilicate and polymerization of 3-(Trimethoxysilyl) propyl methacrylate. The solid samples obtained are round in shape with a size of about 2.5 cm, which makes it easy to handle to test different applications. The inclusion of Gd2O3:Eu3+ nanoparticles increases the level of absorbance in the ultraviolet region, which allows for improved emission of the material at a wavelength of around 609 nm. Furthermore, it enables easy doping of the material and the fabrication of thin films and monoliths with potential optical applications.