Analytics of Antimony in Natural Water of Nanoparticle Platinum Electrode by Application Square Wave Voltammetry

This study on the production of a modern natural water electrochemical antimony (II) test include the use of platinum platinum electrode electrodes. Antimony (II) was pre-concentrated on the modified electrode surface and adsorbed to the surface, oxidizing at E = -680 mV. Compared to the platinum electrode, the platinum nanoelectrode exhibited superior performance and, unexpectedly, received a higher electrochemical response. After 25 min of accumulation, time the best-defined anodic peak was obtained with 0.2 mol L-1 KNO3 pH 5.0. Using these parameters, the L-1 Sb 2 + calibration plot was linear over range 1 = 10−8 to 5x10−6 mol. The precision was tested by carrying out eight replicate measurements at a concentration of 2.5x10−5 mol. L-1; the variance coefficient was 2.9%. The method was applied to analyte determination in water samples from the river. Other metal ion attack on Sb's (II) voltammetric response has been studied. In the SEM image, the nanoparticle electrode was clearly observed and characterized by X-ray diffraction and cyclic voltammetry