Fixation of Dinitrogen at an Asymmetric Binuclear Titanium N2 Complex
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Abstract
We report the first example of a binuclear Ti–N 2 complex with triphenolamine that adopts trigonal bipyramidal and octahedral geometries on the Ti centers. The activated N 2 was reduced to ammonia with 154% yield (per Ti atom) in the presence of proton and electron sources.
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- europepmc
- last seen: 2026-05-19T01:45:01.086888+00:00