Analyzing the torquoselectivity through Fermi-Dirac's entropy: revealing the origin of the stereoselectivity

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Abstract

This work analyzed the electrocyclic ring-opening reaction of the 3-cyanclobutene (3-CN-cyclobutene) through Fermi-Dirac's entropy. This chemical reaction is linked to an important concept called torquoselectivity, our results show that beyond the bond-breaking process in this reaction, a specific atom is responsible for the stereoselectivity observed in this reaction.

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europepmc
last seen: 2026-05-19T01:45:01.086888+00:00