Energy storage properties of all-organic polymers with hydrogen- bonded cross-links

Energy storage properties of all-organic polymers with hydrogen- bonded cross-links | Research Square window.SnipcartSettings = { analytics: { enabled: false } }; (function() { var accessVector = localStorage.getItem('access_vector') || ''; window.dataLayer = window.dataLayer || []; if (accessVector) { window.dataLayer.push({ user: { profile: { profileInfo: { snid: accessVector } } } }); } })(); (function(w,d,s,l,i){w[l]=w[l]||[];w[l].push({'gtm.start':new Date().getTime(),event:'gtm.js'});var f=d.getElementsByTagName(s)[0],j=d.createElement(s),dl=l!='dataLayer'?'&l='+l:'';j.async=true;j.src='https://www.googletagmanager.com/gtm.js?id='+i+dl;f.parentNode.insertBefore(j,f);})(window,document,'script','dataLayer','GTM-K279D39R'); Browse Preprints In Review Journals COVID-19 Preprints AJE Video Bytes Research Tools Research Promotion AJE Professional Editing AJE Rubriq About Preprint Platform In Review Editorial Policies Our Team Advisory Board Help Center Sign In Submit a Preprint Cite Share Download PDF Research Article Energy storage properties of all-organic polymers with hydrogen- bonded cross-links Fumin He, Hongwei Lu, Shijia Yang, Haiyang Mao, Linsheng Yang, and 1 more This is a preprint; it has not been peer reviewed by a journal. https://doi.org/ 10.21203/rs.3.rs-6495817/v1 This work is licensed under a CC BY 4.0 License Status: Under Review Version 1 posted 12 You are reading this latest preprint version Abstract Polyvinylidene fluoride (PVDF) has become the first choice for research due to its high polarization, high breakdown, and good processability. The amorphous polymer Polymethyl Methacrylate (PMMA) is interspersed in the PVDF molecular chain, which disrupts the orderly arrangement of the PVDF molecular chain, reduces the crystallinity of PVDF, and decreases the grain size. In addition, PMMA has low loss and high breakdown characteristics, which can further enhance the performance of composite materials. It was found that Glucose (GLC) is rich in hydroxyl groups and forms intermolecular hydrogen bonds with PVDF molecular chains, which reduces the size of polymer grains; the formation of a physically crosslinked network of hydrogen bonding can serve as a capture site for charge carriers and inhibit conduction loss. In this experiment, PMMA/GLC/PVDF all-organic composite films were prepared by casting method. Through the ternary composite synergy, the energy storage density of PMMA/GLC/PVDF all-organic composite film reaches a maximum value of 8.03 J/cm3, which is 1.5 times higher than that of 3 wt% GLC/PVDF composite, and 2 times higher than that of PVDF. nanodielectrics all-organic materials energy storage density dielectric properties Full Text Additional Declarations No competing interests reported. Cite Share Download PDF Status: Under Review Version 1 posted Editorial decision: Revision requested 10 Dec, 2025 Reviews received at journal 03 Dec, 2025 Reviews received at journal 26 Nov, 2025 Reviewers agreed at journal 21 Nov, 2025 Reviewers agreed at journal 21 Nov, 2025 Reviews received at journal 04 Oct, 2025 Reviewers agreed at journal 25 Sep, 2025 Reviewers agreed at journal 23 Sep, 2025 Reviewers invited by journal 23 Sep, 2025 Editor assigned by journal 23 Apr, 2025 Submission checks completed at journal 22 Apr, 2025 First submitted to journal 21 Apr, 2025 You are reading this latest preprint version Research Square lets you share your work early, gain feedback from the community, and start making changes to your manuscript prior to peer review in a journal. As a division of Research Square Company, we’re committed to making research communication faster, fairer, and more useful. We do this by developing innovative software and high quality services for the global research community. Our growing team is made up of researchers and industry professionals working together to solve the most critical problems facing scientific publishing. Also discoverable on Platform About Our Team In Review Editorial Policies Advisory Board Help Center Resources Author Services Accessibility API Access RSS feed Manage Cookie Preferences © Research Square 2026 | ISSN 2693-5015 (online) Privacy Policy Terms of Service Do Not Sell My Personal Information {"props":{"pageProps":{"initialData":{"identity":"rs-6495817","acceptedTermsAndConditions":true,"allowDirectSubmit":false,"archivedVersions":[],"articleType":"Research Article","associatedPublications":[],"authors":[{"id":524773275,"identity":"b497b0ad-5155-4f97-a3b5-d7b9eb257fb5","order_by":0,"name":"Fumin He","email":"","orcid":"","institution":"Hangzhou Dianzi University","correspondingAuthor":false,"prefix":"","firstName":"Fumin","middleName":"","lastName":"He","suffix":""},{"id":524773277,"identity":"4b6b2b7a-522a-4ad9-9c5b-d406dc9d0298","order_by":1,"name":"Hongwei Lu","email":"data:image/png;base64,iVBORw0KGgoAAAANSUhEUgAAAZAAAAAyAQMAAABI0h/eAAAABlBMVEX///8AAABVwtN+AAAACXBIWXMAAA7EAAAOxAGVKw4bAAAA00lEQVRIiWNgGAWjYBACPgYeCIONvYdBAkgzNhDSwgbXwnOGVC0MEjnEapHIPfi44NdhOT7Jtwdv8zDYyG44wPzsAX4tecnGM/sOG7NJ5yVb8zCkGW84wGZugF9Ljpk0b8/txDZpIIOH4XDihgM8bBLEaKlvkzwD0vKfSC08P24nsEnwgLQcIEILzxtjY96G/4ZtPDnGlnMMgB47zGaGVws/e47hY54/afLy7WcMb7ypsJPtO978DK8WMGBsg7FAQcVMUD0I/CFK1SgYBaNgFIxUAAB/bD4FbNk0IAAAAABJRU5ErkJggg==","orcid":"","institution":"Hangzhou Dianzi University","correspondingAuthor":true,"prefix":"","firstName":"Hongwei","middleName":"","lastName":"Lu","suffix":""},{"id":524773279,"identity":"48a16194-5506-4053-960e-5f4ea45fb19b","order_by":2,"name":"Shijia Yang","email":"","orcid":"","institution":"Hangzhou Dianzi University","correspondingAuthor":false,"prefix":"","firstName":"Shijia","middleName":"","lastName":"Yang","suffix":""},{"id":524773280,"identity":"6da55fdc-c8bc-4414-8dfb-1c6cd44d1724","order_by":3,"name":"Haiyang Mao","email":"","orcid":"","institution":"Hangzhou Dianzi University","correspondingAuthor":false,"prefix":"","firstName":"Haiyang","middleName":"","lastName":"Mao","suffix":""},{"id":524773281,"identity":"7653915f-0cd1-4edf-bc27-473e0a95d4a8","order_by":4,"name":"Linsheng Yang","email":"","orcid":"","institution":"Hangzhou Dianzi University","correspondingAuthor":false,"prefix":"","firstName":"Linsheng","middleName":"","lastName":"Yang","suffix":""},{"id":524773282,"identity":"44101583-31a8-420f-88d4-3fb723f2a366","order_by":5,"name":"Weitao Su","email":"","orcid":"","institution":"Hangzhou Dianzi University","correspondingAuthor":false,"prefix":"","firstName":"Weitao","middleName":"","lastName":"Su","suffix":""}],"badges":[],"createdAt":"2025-04-21 11:53:28","currentVersionCode":1,"declarations":"","doi":"10.21203/rs.3.rs-6495817/v1","doiUrl":"https://doi.org/10.21203/rs.3.rs-6495817/v1","draftVersion":[],"editorialEvents":[],"editorialNote":"","failedWorkflow":false,"files":[{"id":92832254,"identity":"effe3a7c-a374-41f6-b541-efa913449a71","added_by":"auto","created_at":"2025-10-06 06:41:59","extension":"pdf","order_by":1,"title":"","display":"","copyAsset":false,"role":"manuscript-pdf","size":1369832,"visible":true,"origin":"","legend":"","description":"","filename":"Energystoragepropertiesofallorganicpolymerswithhydrogenbondedcrosslinks.pdf","url":"https://assets-eu.researchsquare.com/files/rs-6495817/v1_covered_30537c9e-4880-43ea-b494-db1776c6b29f.pdf"}],"financialInterests":"No competing interests reported.","formattedTitle":"Energy storage properties of all-organic polymers with hydrogen- bonded cross-links","fulltext":[],"fulltextSource":"","fullText":"","funders":[],"hasAdminPriorityOnWorkflow":false,"hasManuscriptDocX":false,"hasOptedInToPreprint":true,"hasPassedJournalQc":"","hasAnyPriority":false,"hideJournal":false,"highlight":"","institution":"","isAcceptedByJournal":false,"isAuthorSuppliedPdf":true,"isDeskRejected":"","isHiddenFromSearch":false,"isInQc":false,"isInWorkflow":false,"isPdf":true,"isPdfUpToDate":true,"isWithdrawnOrRetracted":false,"journal":{"display":true,"email":"[email protected]","identity":"polymer-bulletin","isNatureJournal":false,"hasQc":true,"allowDirectSubmit":false,"externalIdentity":"pobu","sideBox":"Learn more about [Polymer Bulletin](http://link.springer.com/journal/289)","snPcode":"289","submissionUrl":"https://submission.nature.com/new-submission/289/3","title":"Polymer Bulletin","twitterHandle":"","acdcEnabled":true,"dfaEnabled":true,"editorialSystem":"stoa","reportingPortfolio":"Springer Hybrid","inReviewEnabled":true,"inReviewRevisionsEnabled":false},"keywords":"nanodielectrics, all-organic materials, energy storage density, dielectric properties","lastPublishedDoi":"10.21203/rs.3.rs-6495817/v1","lastPublishedDoiUrl":"https://doi.org/10.21203/rs.3.rs-6495817/v1","license":{"name":"CC BY 4.0","url":"https://creativecommons.org/licenses/by/4.0/"},"manuscriptAbstract":"Polyvinylidene fluoride (PVDF) has become the first choice for research due to its high polarization, high breakdown, and good processability. The amorphous polymer Polymethyl Methacrylate (PMMA) is interspersed in the PVDF molecular chain, which disrupts the orderly arrangement of the PVDF molecular chain, reduces the crystallinity of PVDF, and decreases the grain size. In addition, PMMA has low loss and high breakdown characteristics, which can further enhance the performance of composite materials. It was found that Glucose (GLC) is rich in hydroxyl groups and forms intermolecular hydrogen bonds with PVDF molecular chains, which reduces the size of polymer grains; the formation of a physically crosslinked network of hydrogen bonding can serve as a capture site for charge carriers and inhibit conduction loss. In this experiment, PMMA/GLC/PVDF all-organic composite films were prepared by casting method. Through the ternary composite synergy, the energy storage density of PMMA/GLC/PVDF all-organic composite film reaches a maximum value of 8.03 J/cm3, which is 1.5 times higher than that of 3 wt% GLC/PVDF composite, and 2 times higher than that of PVDF.","manuscriptTitle":"Energy storage properties of all-organic polymers with hydrogen- bonded cross-links","msid":"","msnumber":"","nonDraftVersions":[{"code":1,"date":"2025-10-06 06:33:51","doi":"10.21203/rs.3.rs-6495817/v1","editorialEvents":[{"type":"communityComments","content":0},{"type":"decision","content":"Revision requested","date":"2025-12-10T20:10:28+00:00","index":"","fulltext":""},{"type":"editorInvitedReview","content":"","date":"2025-12-03T21:42:42+00:00","index":"hide","fulltext":""},{"type":"editorInvitedReview","content":"","date":"2025-11-26T13:38:32+00:00","index":"hide","fulltext":""},{"type":"reviewerAgreed","content":"197785460700262587418613270979285902302","date":"2025-11-21T21:16:15+00:00","index":"hide","fulltext":""},{"type":"reviewerAgreed","content":"43687150825784946230635092977588067151","date":"2025-11-21T08:04:35+00:00","index":"hide","fulltext":""},{"type":"editorInvitedReview","content":"","date":"2025-10-04T23:58:09+00:00","index":"hide","fulltext":""},{"type":"reviewerAgreed","content":"129899726050227326602772568537008267240","date":"2025-09-25T10:46:29+00:00","index":"hide","fulltext":""},{"type":"reviewerAgreed","content":"330995564733432337816895666615358613270","date":"2025-09-24T00:17:37+00:00","index":"hide","fulltext":""},{"type":"reviewersInvited","content":"","date":"2025-09-23T18:47:25+00:00","index":"","fulltext":""},{"type":"editorAssigned","content":"","date":"2025-04-23T12:38:11+00:00","index":"","fulltext":""},{"type":"checksComplete","content":"","date":"2025-04-22T04:22:58+00:00","index":"","fulltext":""},{"type":"submitted","content":"Polymer Bulletin","date":"2025-04-21T11:49:03+00:00","index":"","fulltext":""}],"status":"published","journal":{"display":true,"email":"[email protected]","identity":"polymer-bulletin","isNatureJournal":false,"hasQc":true,"allowDirectSubmit":false,"externalIdentity":"pobu","sideBox":"Learn more about [Polymer Bulletin](http://link.springer.com/journal/289)","snPcode":"289","submissionUrl":"https://submission.nature.com/new-submission/289/3","title":"Polymer Bulletin","twitterHandle":"","acdcEnabled":true,"dfaEnabled":true,"editorialSystem":"stoa","reportingPortfolio":"Springer Hybrid","inReviewEnabled":true,"inReviewRevisionsEnabled":false}}],"origin":"","ownerIdentity":"8c2fadd8-fe1f-4923-8858-455e655a5fd6","owner":[],"postedDate":"October 6th, 2025","published":true,"recentEditorialEvents":[],"rejectedJournal":[],"revision":"","amendment":"","status":"under-review","subjectAreas":[],"tags":[],"updatedAt":"2026-02-23T20:08:11+00:00","versionOfRecord":[],"versionCreatedAt":"2025-10-06 06:33:51","video":"","vorDoi":"","vorDoiUrl":"","workflowStages":[]},"version":"v1","identity":"rs-6495817","journalConfig":"researchsquare"},"__N_SSP":true},"page":"/article/[identity]/[[...version]]","query":{"redirect":"/article/rs-6495817","identity":"rs-6495817","version":["v1"]},"buildId":"8U1c8b4HqxoKbykW_rLl7","isFallback":false,"isExperimentalCompile":false,"dynamicIds":[84888],"gssp":true,"scriptLoader":[]}