The Uptake Characteristics of Prussian-Blue Nanoparticles for Platinum-Group Metal and Molybdenum Ions in a Nitric Acid Solution Toward Application for the Recovery of Precious Metals from Nuclear and Electronic Wastes

We have examined the uptake mechanisms of platinum-group-metals (PGMs) and molybdenum (Mo) ions into PBNPs in a nitric acid solution for 24-h sorption test, using inductively coupled plasma atomic emission spectroscopy, powder XRD, and UV-Vis-NIR spectroscopy in combination with first-principles calculations, and revealed that the Ru 4+ and Pd 2+ ions are incorporated into PBNPs by substitution with Fe 3+ and Fe 2+ ions of the PB framework, respectively, whereas the Rh 3+ ion is incorporated into PBNPs by substitution mainly with Fe 3+ and minorly with Fe 2+ ion, and Mo 6+ ion is incorporated into PBNPs by substitution with both Fe 2+ and Fe 3+ ions, with maintaining the crystal structure before and after the sorption test. Assuming that the amount of Fe elusion is equal to that of PGMs/Mo substitution, the substitution efficiency is estimated to be 39.0% for Ru, 47.8% for Rh, 87% for Pd, and 17.1% for Mo 6+ . This implies that 0.13 g of Ru, 0.16 g of Rh, 0.30 g of Pd, and 0.107 g of Mo can be recovered by using 1g PBNPs with a chemical form of KFe(III)[Fe(II)(CN) 6 ].