Construction of Angularly Fused Tricyclic Compounds via Photo-induced Radical Cascade Cyclization
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Abstract
A photo-triggered cascade cyclization of silyl enolate to prepare angularly fused tricyclic scaffold is developed. The reaction demonstrates good substrate scope and stereo-selectivity. The excellent stereo- and regio-selectivity for this cascade reaction is elucidated via conformational analysis and DFT calculation, respectively.
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- last seen: 2026-05-19T01:45:01.086888+00:00