Co-Catalyzed Oxidative Alkylation between Styrenes and Cyclic Ethers via sp3 C−H Functionalization

2019 · doi:10.3762/bxiv.2019.119.v1
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Abstract

A new cobalt-catalyzed oxidative alkylation from readily available styrenes and ethers has been disclosed for a rapid and highly efficient construction of C−C bond via sp3 C−H bond functionalization. This methodology was demonstrated by good yields and functional group compatibility with simple operation, easily available starting materials, low catalyst loadings, and mild aerobic conditions.
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Materials

chemistry Medicinal and pharmaceutical chemistry Nano- and molecular-scale electronics Nano-biomaterials and bioscience Nanomagnetics Nanomaterials, thin films and nanointerfaces Nanomedicine Nanometrology and nanomechanics Nano-optics Nanopatterning, self-assembly and nanofabrication Nanostructures for energy and sensing applications Natural products chemistry Organo main group chemistry Other nanotechnology (unclassified) Other organic chemistry (unclassified) Photochemistry and photovoltaics Physical organic chemistry Supramolecular chemistry A new cobalt-catalyzed oxidative alkylation from readily available styrenes and ethers has been disclosed for a rapid and highly efficient construction of C−C bond via sp3 C−H bond functionalization. This methodology was demonstrated by good yields and functional group compatibility with simple operation, easily available starting materials, low catalyst loadings, and mild aerobic conditions.

Keywords

cobalt; oxidative alkylation; styrene; cyclic ether; sp3 C−H functionalization | Format: DOCX | Size: 2.5 MB | Download | When a peer-reviewed version of this preprint is available, this information will be updated in the information box above. If no peer-reviewed version is available, please cite this preprint using the following information: Chen, R.; Wang, K.-K.; Wang, Z.-Y.; Ma, X.; Wang, D.; Zhang, A.-a.; Liu, L. Beilstein Arch. 2019, 2019119. doi:10.3762/bxiv.2019.119.v1 Citation data can be downloaded as file using the "Download" button or used for copy/paste from the text window below. Citation data in RIS format can be imported by all major citation management software, including EndNote, ProCite, RefWorks, and Zotero. © 2019 Chen et al.; licensee Beilstein-Institut. This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0). Please note that the reuse, redistribution and reproduction in particular requires that the authors and source are credited. The license is subject to the Beilstein Archives terms and conditions: (https://www.beilstein-archives.org/xiv/terms)

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last seen: 2026-05-19T01:45:01.086888+00:00