Total Synthesis of Putative Xestocyclamine A
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This study reports the first total synthesis of putative xestocyclamine A, an important intermediate in polycyclic alkaloid biosynthesis, but the synthetic compound's spectral data deviate from previously reported data.
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Abstract
The first total synthesis of putative xestocyclamine A (-)- 1 is reported, a compound taking center stage on the the pathway explaining the biosynthesis of a prominent family of polycyclic alkaloids (Baldwin-Whitehead pathway). The identity of the synthetic sample is unambiguous but the recorded spectral data deviate from those of xestocyclamine A reported in the literature.
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- europepmc
- last seen: 2026-05-19T01:45:01.086888+00:00