Alteration in Molecular Structure of Alkali Activated Slag with Various Water To Binder Ratios Under Accelerated Carbonation

Carbonation of alkali activated materials is one of the main deteriorations affecting their durability. However, current understanding in structural alteration of these materials exposed to an environment inducing carbonation at nano/micro scale remains limited. This study examined the evolution of phase assemblages of alkali activated slag mortars subjected to accelerated carbonation (1% CO 2 , 60% relative humidity, up to 28 day carbonation) using XRD, FTIR and 29 Si, 27 Al, 23 Na MAS NMR. Samples with three water to binder (w/b) ratios (0.35, 0.45, and 0.55) were investigated. The results show that the phase assemblages mainly consisted of C-A-S-H, disordered remnant aluminosilicate binder, and a minor hydrotalcite as a secondary product. Upon carbonation, calcium carbonate is mainly formed as the vaterite polymorph, while no sodium carbonate is found after carbonation as commonly reported. The sodium acts primarily as a charge balancing ion without producing sodium carbonate as a final carbonation product in 28-day carbonated materials. The C-A-S-H structure becomes more cross-linked due to the decalcification of this phase evidenced by the appearance of Q 4 groups, which replace the Q 1 and Q 2 ones as observed in the 29 Si MAS NMR spectra, and the dominance of Al (IV) in 27 Al MAS NMR. Especially, unlike cementitious materials, the influence of w/b ratio on the crystalline phase formation and structure of C-A-S-H in the alkali activated mortars before and after carbonation is limited.