Estimation Ion Transport Parameters in PVFM Based Solid Polymer Electrolyte using Trukhan Model

Estimation Ion Transport Parameters in PVFM Based Solid Polymer Electrolyte using Trukhan Model | Research Square window.SnipcartSettings = { analytics: { enabled: false } }; (function() { var accessVector = localStorage.getItem('access_vector') || ''; window.dataLayer = window.dataLayer || []; if (accessVector) { window.dataLayer.push({ user: { profile: { profileInfo: { snid: accessVector } } } }); } })(); (function(w,d,s,l,i){w[l]=w[l]||[];w[l].push({'gtm.start':new Date().getTime(),event:'gtm.js'});var f=d.getElementsByTagName(s)[0],j=d.createElement(s),dl=l!='dataLayer'?'&l='+l:'';j.async=true;j.src='https://www.googletagmanager.com/gtm.js?id='+i+dl;f.parentNode.insertBefore(j,f);})(window,document,'script','dataLayer','GTM-K279D39R'); Browse Preprints In Review Journals COVID-19 Preprints AJE Video Bytes Research Tools Research Promotion AJE Professional Editing AJE Rubriq About Preprint Platform In Review Editorial Policies Our Team Advisory Board Help Center Sign In Submit a Preprint Cite Share Download PDF Research Article Estimation Ion Transport Parameters in PVFM Based Solid Polymer Electrolyte using Trukhan Model Kamlesh Pandey, Mrigank Mauli Dwivedi, Sharda S. Sanjay, Nidhi Asthana This is a preprint; it has not been peer reviewed by a journal. https://doi.org/ 10.21203/rs.3.rs-3855884/v1 This work is licensed under a CC BY 4.0 License Status: Published Journal Publication published 10 Apr, 2024 Read the published version in Ionics → Version 1 posted 9 You are reading this latest preprint version Abstract Biosynthetic route for the synthesis of nanoparticles involving fossil extract is a modest eco-friendly process, the study focused on a relatively new class of functional materials known as polymerized ionic liquids The synthesized nanoparticles were then characterized through UV-Visible, FTIR and X-ray diffractionspectroscopy.Nanoparticles incorporated in polymers providing an exciting base for newer technology for the development of cost effective electrochemical and devices. Poly (vinyl alcohol) (PVAM) is one of the eco-friendly semi-crystalline polymers which has inter- and intra-molecular hydrogen bonds, whose degree is greatly dependent on the texture of the polymer. We have fabricated a naturally plasticized nanopolymer electrolyte membrane with high ionic conductivity using nano MMT incorporated in PVAM. Randomly interwoven nano-fibrous structures are generally preferred for electrolyte systems due to their continuous structure. The use of nano-composites provided a better polymer interface as well as the high free volume size, through which molecules transport occurs in nano-composite membrane matrix. The advantage of a surface comprised of ultra-fine, continuous nano fibres naturally becomes highly porous. Nano composite membrane due to its high porosity becomes a major responsive factor to enhance the ionic conductivity. We have considered a comparative study of these fabricated nano-composites. The structural behaviour of the polymer nano-composite membrane was investigated by XRD, FTIR, optical microscopy and scanning electron microscopic technique. XRD curve revealed the amorphous nature of membrane, which is favourable for the better conduction and sensing behaviour, as the conductivity-frequency plots showed the Universal power law. The asymmetric shape of the Dielectric relaxation plots given a strong evidence of low frequency dispersion and deviation from the pure Debye behaviour. Figures Figure 1 Figure 2 Figure 3 Figure 4 Figure 5 Figure 6 Full Text Additional Declarations No competing interests reported. Cite Share Download PDF Status: Published Journal Publication published 10 Apr, 2024 Read the published version in Ionics → Version 1 posted Editorial decision: Revision requested 19 Feb, 2024 Reviews received at journal 11 Feb, 2024 Reviewers agreed at journal 05 Feb, 2024 Reviews received at journal 01 Feb, 2024 Reviewers agreed at journal 17 Jan, 2024 Reviewers invited by journal 16 Jan, 2024 Editor assigned by journal 16 Jan, 2024 Submission checks completed at journal 16 Jan, 2024 First submitted to journal 12 Jan, 2024 You are reading this latest preprint version Research Square lets you share your work early, gain feedback from the community, and start making changes to your manuscript prior to peer review in a journal. As a division of Research Square Company, we’re committed to making research communication faster, fairer, and more useful. We do this by developing innovative software and high quality services for the global research community. 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Also discoverable on Platform About Our Team In Review Editorial Policies Advisory Board Help Center Resources Author Services Accessibility API Access RSS feed Manage Cookie Preferences © Research Square 2026 | ISSN 2693-5015 (online) Privacy Policy Terms of Service Do Not Sell My Personal Information {"props":{"pageProps":{"initialData":{"identity":"rs-3855884","acceptedTermsAndConditions":true,"allowDirectSubmit":false,"archivedVersions":[],"articleType":"Research Article","associatedPublications":[],"authors":[{"id":267587119,"identity":"3c711459-f663-4d05-8b1e-64e64d838eb0","order_by":0,"name":"Kamlesh Pandey","email":"data:image/png;base64,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","orcid":"","institution":"University of Allahabad","correspondingAuthor":true,"prefix":"","firstName":"Kamlesh","middleName":"","lastName":"Pandey","suffix":""},{"id":267587120,"identity":"878b4d44-d546-45cd-b434-87235ebfd430","order_by":1,"name":"Mrigank Mauli Dwivedi","email":"","orcid":"","institution":"University of Allahabad","correspondingAuthor":false,"prefix":"","firstName":"Mrigank","middleName":"Mauli","lastName":"Dwivedi","suffix":""},{"id":267587121,"identity":"31d55bd3-1b42-418c-b54e-057c6a2649ea","order_by":2,"name":"Sharda S. 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