Transition Metal Chloride Catalyzed the Synthesis of Dipropyl Carbonate from Urea Alcoholysis: Influence of Initial Decomposition Temperature of Ammine Transition Metal Chloride

Transition Metal Chloride Catalyzed the Synthesis of Dipropyl Carbonate from Urea Alcoholysis: Influence of Initial Decomposition Temperature of Ammine Transition Metal Chloride | Research Square window.SnipcartSettings = { analytics: { enabled: false } }; (function() { var accessVector = localStorage.getItem('access_vector') || ''; window.dataLayer = window.dataLayer || []; if (accessVector) { window.dataLayer.push({ user: { profile: { profileInfo: { snid: accessVector } } } }); } })(); (function(w,d,s,l,i){w[l]=w[l]||[];w[l].push({'gtm.start':new Date().getTime(),event:'gtm.js'});var f=d.getElementsByTagName(s)[0],j=d.createElement(s),dl=l!='dataLayer'?'&l='+l:'';j.async=true;j.src='https://www.googletagmanager.com/gtm.js?id='+i+dl;f.parentNode.insertBefore(j,f);})(window,document,'script','dataLayer','GTM-K279D39R'); Browse Preprints In Review Journals COVID-19 Preprints AJE Video Bytes Research Tools Research Promotion AJE Professional Editing AJE Rubriq About Preprint Platform In Review Editorial Policies Our Team Advisory Board Help Center Sign In Submit a Preprint Cite Share Download PDF Research Article Transition Metal Chloride Catalyzed the Synthesis of Dipropyl Carbonate from Urea Alcoholysis: Influence of Initial Decomposition Temperature of Ammine Transition Metal Chloride Liangchun He, Dongxia Wang, Zhiyong Xu, Songyi Y. Ji, Rong Zhang, and 1 more This is a preprint; it has not been peer reviewed by a journal. https://doi.org/ 10.21203/rs.3.rs-7334198/v1 This work is licensed under a CC BY 4.0 License Status: Posted Version 1 posted You are reading this latest preprint version Abstract Herein, dipropyl carbonate was synthesized using a series of transition metal chloride (TMC) as catalysts. The catalytic activity of different TMCs was compared and the optimal catalytic conditions were systematically investigated. The catalytic activity order is CoCl 2 > ZnCl 2 > MnCl 2 > CdCl 2 > NiCl 2 . Thermal decomposition behavior of ammine TMC complexes revealed that Co(NH 3 ) 2 Cl 2 exhibited the lowest decomposition temperature, whereas Ni(NH 3 ) 2 Cl 2 showed the highest; these decomposition temperatures were negatively correlated with the catalytic activities of the respective ammine TMC complexes. Notably, although the catalytic activity of ammine TMC complexes lower than their parent TMCs but with consistent activity order with the parent salts. These findings highlight the crucial role of the catalyst’s ammonia-binding and -release capacity in DPC synthesis. The weaker the metal-ammonia interaction (evidenced by lower decomposition temperatures), the higher the catalytic activity, presumably due to more facile ammonia desorption, which facilitates active site regeneration and urea activation. dipropyl carbonate decomposition temperature transition metal chloride salts catalysis Figures Figure 1 Figure 2 Figure 3 Figure 4 Figure 5 1. Introduction Dipropyl carbonate (DPC) is a versatile organic carbonate with significant industrial value, renowned for its excellent solubility, low toxicity and biodegradability. These attributes have driven its widespread application in energy 1 , motor vehicles 2 , electronics 3 medicine and other high-value sectors 4 . In addition to its current applications, DPC, with its multi-functionality and environmentally friendly features, also stands out in the field of sustainable organic synthesis of future-oriented green chemicals, becoming a highly promising choice 5 . Numerous methods for DPC synthesis have been reported, including phosgene-mediated carbonylation 6 , oxidative carbonylation of alcohols 7 , transesterification of carbonates 8 direct carboxylation of alcohols using carbon dioxide 9 , and lipolytic enzyme-catalyzed method 10 . However, these methods have inherent limitations, the pathway based on oxidative carbonylation relies on highly toxic reagents, and the process involves explosive reactants such as carbon monoxide; Ester exchange reactions often have relatively low conversion efficiency and the direct utilization of CO₂ is subject to thermodynamic constraints. Enzymatic methods require complex preparation and maintenance of biocatalysts. The production of DPC using urea alcoholysis is a highly attractive route due to its low cost and facile product separation 11 . In this process, the intermediate propyl carbamate (PC) is first formed, followed by the sequential esterification of PC with additional n-propanol to yield DPC 12 . From a thermodynamic perspective, the initial step (urea alcoholysis to PC) in the reaction is more straightforward 13 . However, the subsequent transformation of PC to DPC is kinetically more challenging and serves as the rate-determining step for the overall urea alcoholysis process. This kinetic limitation necessitates the use of catalysts to accelerate the reaction and improve DPC yield. Numerous studies have explored the use of diverse catalysts, including organotin compounds, rare earth metal salts, metal powders, and mixed metal oxides to facilitate the synthesis of organic carbonates via urea alcoholysis. For instance, Li et al 14 . used different metal oxides as catalysts for vinyl carbonate production, additionally investigating how the acid-base sites of these metal oxides influence on the catalytic properties. Among the metal oxides, zinc oxide has the best catalytic properties. Notably, Fakhrnasova et al 15 . found that while although acidic sites significantly promote the formation of vinyl carbonate, when the acidity of the catalyst is too high, the surface sites are blocked, and the catalytic activity drops beyond the critical acidity threshold, indicating that the presence of a catalyst requires an optimal acid-base site balance. In a separate study, Gao et al 12 demonstrated that both MgCl 2 and ZnCl 2 are effective catalysts for propylene carbonate synthesis via urea alcoholysis. Similarly, Du et al 16 . prepared and investigated MgTiO 3 catalysts for the same reaction, revealing that strong basic active sites on the catalyst surface are the key factor governing urea alcoholysis performance. Focusing on zinc salts, Zhao et al 17 . investigated their catalytic behavior in the synthesis of dimethyl carbonate from methyl carbamate and methanol. The highest catalytic activity of ZnCl 2 was attributed to its ability to activate methyl carbamate by complexation with the -NH 2 based nitrogen proton, resulting in a significant enhancement in the yield of dimethyl carbonate. While urea alcoholysis has been extensively utilized for the synthesis of various organic carbonates, its application in DPC production remains limited, highlighting a gap in current research. Transition metal cations, prototypical Lewis acids, readily form ammonia complexes via coordination with ammonia 18 . In the synthesis reaction, transition metal cations can form coordination compounds with ammonia generated in situ through coordination 19 . This process can change the reaction equilibrium and thereby increase the yield of the product 20 . Therefore, transition metal cation is a benign reaction coupling agent for urea alcoholysis, where ammonia removal is critical to driving the reaction forward. Both transition metal oxides 21 , 22 and metal salts 23 , contain cations; however, only metal salts are soluble in n-propanol and dissociate into free ions. This solubility allows each transition metal cation to function as a discrete active site, maximizing catalytic accessibility. A key advantage of metal salts, particularly chlorides, is that their transition metal cations are readily regenerated via thermal decomposition of their ammonia complexes, ensuring long-term catalytic stability. This study evaluated the catalytic activity of a series of representative transition metal chlorides (e.g., CoCl 2 , ZnCl 2 , MnCl 2 ) for the synthesis of DPC from urea and n-propanol in a batch reactor. The transition metal chlorides and ammonia-transition metal chloride coupling agents was employed for catalysis under different reaction conditions. The effects of TMC and ammonia TMC on the catalytic activity of DPC synthesis using urea and n-propanol as raw materials were investigated. Through a series of studies, we have clarified the enhancing effect of transition metal ions on TMC and the mechanism of the ammonia TMC system in the catalytic process. These results provide new insights and theoretical basis for the development of efficient, economical and stable transition metal chloride catalysts. 2. Experimental sections 2.1 Evaluation of catalytic activity The reaction is carried out in a 100 mL stainless steel batch reactor equipped with a magnetic stirrer and immersed in a thermostatic oil bath. For catalytic screening with different TMCs, urea, n-propanol, and the respective TMC were loaded into the reactor at a fixed molar ratio of 1:10:2 (urea:n-propanol:TMC). The reactor was then sealed, heated to a specified temperature in the oil bath, and maintained for 8 h under continuous magnetic stirring to ensure homogeneous mixing. To optimize the reaction conditions, the TMC exhibiting the highest initial catalytic activity was selected as a model system. Key parameters, including reaction temperature, time and molar ratio of catalyst, were systematically studied to evaluate their impact on DPC yield and selectivity. After the reaction, the reactor was cooled to room temperature, and the product mixture was collected via centrifugal separation and weighed. The supernatant was analyzed by gas chromatography. The analysis conditions were as follows: chromatographic column temperature 110 ℃, vaporization chamber temperature 180 ℃, FID1 temperature 180 ℃, and injection volume 0.1 mL. The gas chromatography system is equipped with a SE-30 chromatographic column and a flame ionization detector (FID) for production inspection. Quantitative analysis of DPC and its intermediate products was conducted using butyl carbamate as the internal standard. 2.2 Preparation of ammonia chloride salts All reagents used in the experiment were commercially available analytical grade and used without further purification. The preparation process of ammonia TMC complexes was conducted as follows: 5 g of anhydrous TMC was dissolved in 100 mL of ethanol, and the solution was then filtered to remove insoluble salt. The filtrate was transferred to a Mason jar, into which a mixture of 20% ammonia and nitrogen gas was injected. Over time, different colored precipitates were formed in the solution. The precipitates were collected via centrifugation and subsequently dried in a nitrogen atmosphere at 65 ℃ for 5 h to obtain the pure ammine TMC complexes. 2.3 Characterization The prepared materials were characterized by X-ray diffraction (XRD, Anton Paar) with Cu Kα radiation. During the tests, the diffraction angle range was set between 5° and 70° with a scanning speed of 5 °/min. Thermogravimetric analysis (TGA) was performed by a NETZSCH TG209F1, under a high-purity N 2 atmosphere. Samples were heated from 30 to 500°C at a heating rate of 10°C min⁻¹, with continuous monitoring of mass change as a function of temperature. 3. Results and Discussion 3.1 Analysis of TMC catalytic activity Figure 1 shows the XRD patterns of TMC catalysts. It was established that the purchased CoCl 2 , ZnCl 2 , MnCl 2 , CdCl 2 and NiCl 2 corresponded to anhydrous TMC standard cards, ensuring that all TMC used during the experiment was anhydrous. Catalytic activity of TMCs were evaluated, in the absence of the TMC catalyst, although the yield of the intermediate product PC was 12.89%, but no detectable DPC. With the addition of TMC catalysts, DPC yields followed the order: CoCl 2 (5.88%) > ZnCl 2 (5.20%) > MnCl 2 (4.45%) > CdCl 2 (2.66%) > NiCl 2 (2.05%) (Table 1 ). Conversely, PC yields exhibited an inverse trend, with corresponding yields of 7.34%, 9.22%, 9.91%, 10.20% and 17.18%, respectively. This result suggests that TMCs primarily promotes the conversion of the intermediate PC to DPC. Table 1 Activity evaluation of TMC and their diamine complex Type of catalyst Yield of PC Yield of DPC catalyst-free 12.89 0 CoCl 2 7.34 5.88 ZnCl 2 9.22 5.20 MnCl 2 9.91 4.45 CdCl 2 10.20 2.66 NiCl 2 17.18 2.05 Co(NH 3 ) 6 Cl 2 8.53 2.64 Zn(NH 3 ) 2 Cl 2 15.49 1.93 Mn(NH 3 ) 2 Cl 2 9.74 1.59 Cd(NH 3 ) 2 Cl 2 9.59 1.36 Ni(NH 3 ) 6 Cl 2 9.22 1.18 3.2 Analysis of optimal catalytic conditions To determine optimal catalytic conditions for the catalyst, CoCl 2 was selected as an example owing to it has the best catalytic activity. Table 2 shows the effect of different reaction times on the catalytic efficiency. As time progressed, the yield of PC underwent a gradual decline, while the yield of DPC demonstrated an initial increase followed by a subsequent decrease as the reaction duration increased. As can be seen from Table 2 , at the beginning of the reaction, urea and n-propanol react to form the intermediate n-propyl carbamate. Crucially, extending the reaction beyond 8 h does reduced the yield of DPC, attributable to competing side reactions occur at this period. Therefore, the optimal time for catalysis was finally found to be 8 h. Table 2 Activity evaluation at different reaction times Reaction time (h) Yield of PC (%) Yield of DPC (%) 4 12.22 3.65 6 10.12 4.16 8 7.34 5.91 10 2.89 4.58 12 2.34 3.90 The influence of reaction temperature on catalytic performance is summarized in Table 3 . The yield of PC decreased monotonically from 11.42% at 170°C to 2.17% at 210°C, while DPC yield exhibited a distinct maximum of 5.91% at 190°C. This phenomenon can be attributed to the fact that, at temperatures below 190°C, the reaction progresses in a favourable direction as the temperature rises, resulting in the conversion of PC to DPC. Above 190°C, however, thermodynamic limitations dominate as competing decomposition pathways become significant, including urea pyrolysis and DPC decarboxylation to dipropyl ether. The temperature-dependent yield profile confirms 190°C as optimal temperature for maximizing DPC production. Table 3 Activity evaluation at different reaction temperature Reaction temperature (℃) Yield of PC (%) Yield of DPC (%) 170 11.42 1.91 180 9.43 2.87 190 7.34 5.91 200 2.86 3.02 210 2.17 2.66 Table 4 shows the effect of molar ratio of urea to n-propanol on the catalytic activity. The yield of dipropyl carbonate increased with increasing amount of n-propanol up to a molar ratio of 1:10 mol/mol. Relevant reaction mechanism studies have shown that during the reaction between urea and n-propanol to form DPC, a -NH 2 in urea first reacts with -OH in n-propanol to form PC intermediate. The intermediate then undergoes the next step of the reaction to produce DPC. While urea contains two -NH 2 , n-propanol contains only one -OH, so excess n-propanol can increase the formation of PC and thus speed up the reaction and improve the yield of DPC. However, as the molar amount of n-propanol increases, the yield of dipropyl carbonate decreases. This is due to the fact that when the n-propanol dosage becomes too high, the urea conversion reaches its maximum and the reaction cannot be accelerated even if the n-propanol dosage is increased further. Table 4 Activity evaluation of different raw material ratios Urea : n-propanol (mol/mol) Yield of PC (%) Yield of DPC (%) 1:5 12.19 4.63 1:7.5 16.76 4.92 1:10 7.34 5.91 1:12.5 13.63 4.52 1:15 10.53 2.40 The effect of the amount of catalyst on the synthesis of DPC is summarized in Table 5 . It can be seen that the yield of DPC increases gradually as the catalyst dosage is increased, reaching a maximum of 6.23% at a 1:3 urea: CoCl 2 ratio. This is because during reaction the catalysts interact with the NH 3 , a by-product of the reaction, to drive the reaction. When the molar ratio of catalyst to urea was increased from 1 mol/mol to 2 mol/mol, the yield of DPC increased significantly. And as the molar ratio increased further, the yield of DPC increased more slowly, although it increased to 6.23% when the ratio is reached 3 mol/mol. This is attributed to the conversion of urea is close to the conversion limit during the reaction, and even if the amount of catalyst is increased, the yield of DPC increases very little. Therefore, a molar ratio of 1:2 mol/mol was chosen as the optimum urea/ catalyst ratio, taking into account the principle of economy. Table 5 Activity evaluation of different coupling ratio Urea : CoCl 2 (mol/mol) Yield of PC (%) Yield of DPC (%) 1:1 17.58 1.74 1:1.5 9.38 2.45 1:2 7.34 5.91 1:2.5 8.45 6.02 1:3 9.43 6.23 3.3 Analysis of post-catalysis solid products To further determine the catalysis mechanism of TMC, the solid products recovered post-reaction were qualitatively analyzed. Figure 2 shows the XRD pattern of the solid product after TMC catalysis. In comparison with standard cards, it was established that TMC underwent a catalytic conversion to ammonia TMC complex, where CoCl 2 , ZnCl 2 , MnCl 2 and NiCl 2 was converted to Co(NH 3 ) 2 Cl 2 , Zn(NH 3 ) 2 Cl 2 , Mn(NH 3 ) 2 Cl 2 and Ni(NH 3 ) 2 Cl 2 , respectively. Notably, the CdCl 2 -derived solid product exhibited a distinct crystalline phase inconsistent with Cd(NH 3 ) 2 Cl 2 references, suggesting either variable ammonia coordination or the specific ammonia coordination number could not be determined. 3.4 Analysis of precipitates produced by the reaction of TMC ethanol solutions with ammonia Analysis of the post-catalytic solid products of TMC revealed that they were all converted to their respective ammonia complexes. This observation prompted the hypothesis that ammonia binding capacity plays a key role in the catalytic mechanism. Theoretical studies confirmed that TMCs, acting as Lewis acids, can coordinate with ammonia (a Lewis base) to form ammine complexes. To investigate this, ammonia TMC complexes were synthesized and evaluated as catalysts for comparative assessment of their activity relative to TMCs. Synthesized ammine complexes were characterized by XRD and the results are displayed in Fig. 3 . These results indicate that CdCl 2 , ZnCl 2 and MnCl 2 in ethanol can react with ammonia to form the diamine complexes Cd(NH 3 ) 2 Cl 2 , Zn(NH 3 ) 2 Cl 2 and Mn(NH 3 ) 2 Cl 2 . However, it has been demonstrated that ethanol solutions of CoCl 2 and NiCl 2 react with ammonia to form hexa-ammonia complexes, Co(NH 3 ) 6 Cl 2 and Ni(NH 3 ) 6 Cl 2 . TG-DSC analysis further corroborates these observations. For Cd(NH 3 ) 2 Cl 2 , the loss of the first ammonia molecule occurs at 200°C (Figure. 3i and Table 2 ) with a weight loss of 8.39%. Subsequently the loss of the second ammonia molecule take place at 260°C with a weight loss of 8.02%. These observations are in agreement with the theoretical value of 7.83%. Mn(NH 3 ) 2 Cl 2 exhibits a complete and abrupt loss of coordinated ammonia molecules at 300°C (Figure. 3h), with a weight loss of 21.03%, which is in close agreement with the theoretical value of 21.30% (Table 2 ). The precipitation of CoCl 2 ethanol solution exhibited a weight loss of 29.00% at 160°C, consistent with the theoretical value of 29.36%. This corresponds to the loss of four ammonia molecule. At 220°C and 280°C, ammonia losses were observed, with weight losses of 7.20% and 7.36%, respectively. These actual ammonia weight losses are in good line with the theoretical weight loss value of 7.34% (Figure. 3f, Table 2 ). Ni(NH 3 ) 6 Cl 2 has been observed to undergo a complete loss of coordination ammonia at 310°C (Fig. 3 j). At 200°C, four ammonia molecules are lost, corresponding to a weight loss of 29.10%, while one ammonia molecule is lost at 310°C, resulting in a weight loss of 14.23%. These experimental values agree well with the theoretical predictions of 29.39% and 14.96%, respectively (Table 6 ). Notably, the TG curve of Zn(NH 3 ) 2 Cl 2 is distinct from the other compounds presented (Figure. 3g). It is hypothesized that, under certain conditions, the compound may gradually lose two ammonia molecules over a temperature ranging from 180 to 400°C, resulting in a total weight loss of 20.15%. This process is believed to occur prior to the residue gasifying at higher temperatures. Table 6. Thermal decomposition process of Co(NH 3 ) 6 Cl 2 , Mn(NH 3 ) 2 Cl 2 , Cd(NH 3 ) 2 Cl 2 and Ni(NH 3 ) 6 Cl 2 under nitrogen atmosphere 3.5 Analysis of precipitates produced by the catalytic reaction of ammonia TMC As can be seen from Figure. 4, a part of Co(NH 3 ) 6 Cl 2 and Ni(NH 3 ) 6 Cl 2 loses four ammonia coordinations to form Co(NH 3 ) 2 Cl 2 and Ni(NH 3 ) 2 Cl 2 at high temperatures, while Mn(NH 3 ) 2 Cl 2 , Cd(NH 3 ) 2 Cl 2 and Zn(NH 3 ) 2 Cl 2 remain unchanged in structure under the same high temperature conditions. As can be seen from the XRD pattern in Figure. 2, all TMCs are converted to diammonia coordination complexes at low concentrations. XRD data from Figure. 3 show that TMCs with strong coupling tendencies, such as CoCl 2 and NiCl 2 , will be converted to hexammonia coordination complexes: Co(NH 3 ) 6 Cl 2 and Ni(NH 3 ) 6 Cl 2 at high concentrations. TG analysis (Figure. 3) showed that under high temperature conditions, some Co(NH 3 ) 6 Cl 2 and Ni(NH 3 ) 6 Cl 2 degraded, each losing 4 ammonia molecules to form Co(NH 3 ) 2 Cl 2 and Ni(NH 3 ) 2 Cl 2 , while Mn(NH 3 ) 2 Cl 2 , Cd(NH 3 ) 2 Cl 2 and Zn(NH 3 ) 2 Cl 2 did not change their structure until 190°C. This shift to stable low-coordination species is further confirmed by the XRD maps in Figure. 4, which confirms the persistence of these reductive coordination complexes at high temperatures. 3.6 Activity analysis of ammonia TMC The catalytic activity of ammonia TMC complexes is summarized in Table 1 . The catalysts of Co(NH 3 ) 6 Cl 2 , Zn(NH 3 ) 2 Cl 2 , Mn(NH 3 ) 2 Cl 2 , Cd(NH 3 ) 2 Cl 2 and Ni(NH 3 ) 6 Cl 2 were subjected to a reaction at 190°C for 8 hours, and the DPC yields obtained were 2.64%, 1.93%, 1.59%, 1.36%, and 1.18%, respectively. It was observed that the catalytic activity of these ammonia TMC complexes were lower than those of the corresponding TMC, yet the sequence patterns remained unchanged. This observation suggests that the coordination of NH 3 to TMC during the reaction plays a critical role in modulating catalytic activity. 3.7 Thermal decomposition analysis and catalytic activity comparison of ammonia TMC Figures. 3f-j show the initial decomposition temperatures of the post-catalyst products for the ammonia TMC complexes. Regionalize a tangent to the flat baseline before the first weightless step in the thermogravimetric curve, draw a tangent at the steepest part of the weightless step, and the intersection of the two tangents is the extrapolated starting temperature. Therefore the initial decomposition temperatures of ammonia TMC complexes were found follow the order: Co(NH 3 ) 2 Cl 2 (190.1°C) < Mn(NH 3 ) 2 Cl 2 (219.4°C) < Cd(NH 3 )Cl 2 (223.2°C) < Ni(NH 3 ) 2 Cl 2 (246.4°C), respectively. Notably, this sequence exhibits a negative correlation with the catalytic activity of the corresponding parent TMC precursors. Specifically, a lower initial decomposition temperature of the ammonia-TMC complex correlates with higher catalytic activity for diphenyl carbonate (DPC) synthesis. This relationship arises from the critical role of ammonia cyclin i.e., the absorption of NH 3 by TMC and its subsequent desorption from the ammonia-TMC complex during catalysis. The overall cycling rate is dominated by the desorption rate of ammonia from the ammonia-TMC complex, which is directly governed by the complex’s initial decomposition temperature. For Co(NH 3 ) 2 Cl 2 , the lowest initial decomposition temperature facilitates the fastest cycles of NH 3 absorption by CoCl 2 and desorption from Co(NH 3 ) 2 Cl 2 . This enhanced ammonia turnover explains why CoCl 2 exhibits the highest catalytic activity for DPC synthesis among the tested TMC. 3.8 Catalytic mechanism. According to the principle of coordination chemistry 24 , the proposed reaction mechanism for transition metal cations in DPC synthesis is illustrated in Fig. 4 . First, urea reacts with n-propanol to form the intermediate PC. The process begins with the nucleophilic attack of the oxygen atom in n-propanol on the carbonyl carbon of urea, forming an amphiphilic intermediate that undergoes deamination to PC. Secondly, the PC intermediate subsequently undergoes further deamination to generate DPC. The propanol molecule coordinates with the transition metal cation to form the complex Me(n-propanol) 2 Cl 2 (Me represents the metal salt). This complex undergoes intramolecular rearrangement, facilitating the transfer of a hydroxyl H atom to a N atom, which form NH 3 and complex with TMC to form Me(NH 3 )(n-propanol)Cl 2 . The oxygen atom of the coordinated n-propanol in Me(NH 3 )(n-propanol)Cl 2 then attacks the carbonyl C of the PC intermediate, leading to the formation of Me(NH 3 ) 2 Cl 2 and DPC. Since Me(NH 3 ) 2 Cl 2 is unstable at the reaction temperature of 190 ℃, one ammonia of Me(NH 3 ) 2 Cl 2 is replaced by n-propanol molecules to obtain Me(NH 3 )(n-propanol)Cl 2 again, completing the catalytic cycle. As shown in Figure. 4, the initial decomposition temperature is higher than the reaction temperature, and Me(NH 3 ) 2 Cl 2 does not lose ammonia molecules in the reaction. 4. Conclusion In this study, the optimum reaction conditions for the synthesis of DPC via urea alcoholysis reaction were determined using TMC as catalyst, and the catalytic activity of various TMC was evaluated. The results showed that the order of catalytic activity was CoCl 2 > ZnCl 2 > MnCl 2 > CdCl 2 > ZnCl 2 . Subsequently, the initial decomposition temperatures of the corresponding ammonia-TMC complexes were investigated, yielding the sequence: Co(NH 3 ) 2 Cl 2 < Mn(NH 3 ) 2 Cl 2 < Cd(NH 3 )Cl 2 < Ni(NH 3 ) 2 Cl 2 . A critical relationship between the catalytic performance of TMC and the thermal stability of their ammonia-TMC complexes was established: a lower initial decomposition temperature of the ammonia-TMC complex correlated with higher catalytic activity of the parent TMC. This negative correlation underscores the role of ammonia turnover (absorption by TMC and desorption from the ammonia-TMC complex) in driving the catalytic cycle, where faster desorption (facilitated by lower decomposition temperatures) enhances DPC synthesis efficiency. Declarations CRediT authorship contribution statement Liangchun He, Dongxia Wang and Zhiyong Xu have made equal contributions to this work. Liangchun He: Conceptualization, Methodology, Data Management and Writing - Original Manuscript. Dongxia Wang: Conceptualization, Methodology, Data Management and Writing - Original Manuscript. Zhiyong Xu: Conceptualization, Methodology, Data Management and Writing - Original Manuscript. Songyi Ji: Supervision and project management. Rong Zhang:Supervision and Project Management. Wenbo Zhao: Supervision and Project Management. Declaration of Competing Interest The authors declare no competing financial interest. Acknowledgments This work is supported by the National Natural Science Foundation of China (Grant No. 22278198, 22068016, 21666011), Yunnan province high level talents special support plan (YNWR-QNBJ-2018-369), Yunnan Major Scientific and Technological Projects (Grant NO.202302AG050002). Yunnan Fundamental Research Projects (grant NO. 202501CF070138). Ethics declarations Ethics approval, Consent to participate, and Consent to publish: Not applicable. References Marshall, M. A. P. L. Review of Dimethyl Carbonate (DMC) Manufacture and Its Characteristics as a Fuel Additive. Energy & Fuels. 1997 . 11 , 2-29 Moumouzias, G.; Ritzoulis, G.; Siapkas, D.; Terzidis, D. Comparative study of LiBF4, LiAsF 6 , LiPF 6 , and LiClO 4 as electrolytes in propylene carbonate–diethyl carbonate solutions for Li/LiMn 2 O 4 cells. J. Power Sources . 2003 , 122 (1), 57-66 Herstedt, M.; Stjerndahl, M.; Gustafsson, T.; Edström, K. Anion receptor for enhanced thermal stability of the graphite anode interface in a Li-ion battery. Electrochem. Commun. 2003 , 5 (6), 467-472. Giardi, C.; Lapinte, V.; Nielloud, F.; Devoisselle, J. M.; Robin, J. J. Synthesis of polyoxazolines using glycerol carbonate derivative and end chains functionalization via carbonate and isocyanate routes. J. Polym. Sci., Part A: Polym. Chem. 2010 , 48 (18), 4027-4035. Chai, X.; Huang, S.; Huang, Z.; Wu, C.; Lu, P.; Ye, C.; Qiu, T. Aminolysis of Toluene Diisocyanate Tar Residue Based on Polyamines: Efficient Conversion and Mechanism Exploration. Ind. Eng. Chem. Res. 2025, 64 (29), 14319-14328. Bhadauria, S.; Saxena, S.; Prasad, R.; Sharma, P.; Prasad, R.; Dwivedi, R. Synthesis of ethylene carbonate from cyclocondensation of ethylene glycol and urea over ZnO•Cr 2 O 3 catalyst system controlled by co-precipitation method. Chem. Eur. J. 2012 , 3 (2), 235-240. Wang, X.; Fu, T.; Zheng, H.; Zhang, G.; Li, Z. The influence of the pore structure in ordered mesoporous carbon over the formation of Cu species and their catalytic activity towards the methanol oxidative carbonylation. J. Mater. Sci. 2016 , 51 (11), 5514-5528. Mahloujifar, M.; Mansournia, M. A comparative study on the catalytic performances of alkali metals-loaded KAlSiO4 for biodiesel production from sesame oil. Fuel. 2021 , 291 , 120145. Hu, L.; Chen, L.; Peng, X.; Zhang, J.; Mo, X.; Liu, Y.; Yan, Z. Bifunctional metal-doped ZIF-8: A highly efficient catalyst for the synthesis of cyclic carbonates from CO 2 cycloaddition. Microporous Mesoporous Mater. 2020 , 299 , 110123. M.A.P.J. Hacking, F. v. R., R.A. Sheldon). Lipase catalyzed reactions of aliphatic and arylaliphatic carbonic acid esters. J. Mol. Catal. B: Enzym. 2000, 9, 201–208. Xiao, Y.; Xiang, C.; Lei, H.; Jin, S.; Yin, X.; Ding, Y.; Du, Z. Effect of change of Ca, P and Mg on the surface of catalyst prepared from phosphate tailing on urea alcoholysis. Catal. Commun. 2019 , 128 , 105712 Gao, Z. W.; Wang, S. F.; Xia, C. G. Synthesis of propylene carbonate from urea and 1,2-propanediol. Chin. Chem. Lett. 2009 , 20 (2), 131-135. Wu, C.; Zhao, X.; Wang, Y. Effect of reduction treatment on catalytic performance of Zn-based catalyst for the alcoholysis of urea to dimethyl carbonate. Catal. Commun. 2005 , 6 (10), 694-698. Li, Q.; Zhang, W.; Zhao, N.; Wei, W.; Sun, Y. Synthesis of cyclic carbonates from urea and diols over metal oxides. Catal. Today. 2006 , 115 (1-4), 111-116. Fu-Yu Zhong, H.-L. P., Duan-Jian Tao, Ping-Keng Wu, Jie-Ping Fan; Huang, a. K. Phenol-Based Ternary Deep Eutectic Solvents for Highly Efficient and Reversible Absorption of NH 3 . ACS Sustain. Chem. Eng. 2019 , 5 , 6284−6295. Du, Z.; Chen, F.; Lin, Z.; Li, X.; Yuan, H.; Wu, Y. Effect of MgO on the catalytic performance of MgTiO 3 in urea alcoholysis to propylene carbonate. Chem. Eng. J. 2015 , 278 , 79-84. Zhao, X.; Jia, Z.; Wang, Y. Clean synthesis of propylene carbonate from urea and 1,2‐propylene glycol over zinc–iron double oxide catalyst. J. Chem. Technol. Biotechnol. 2006 , 81 (5), 794-798. Weil, K. S. The synthesis of transition metal nitrides via thermolysis of metal–ammine complexes, Part I: Chromium nitride. J. Solid State Chem. 2008 , 181 (1), 199-210. Zhang, Z.; Zhong, H.; Xu, Y.; Zhang, M.; Zhang, H.; Wang, J.; Yang, Y. Impacts of Heat Treatment and Long-Term Storage on Methylaluminoxane Composition, Catalytic Activity, and Polyethylene Properties. Ind. Eng. Chem. Res. 2025, 64 (26), 12968-12977. Yu, Y.; Wang, Y.; Yang, F.; Feng, D.; Yang, M.; Xie, P. F.; Zhu, Y.; Shao, M.; Mei, Y.; Li, J. C. Meso/Microporous Single-Atom Catalysts Featuring Curved Fe-N 4 Sites Boost the Oxygen Reduction Reaction Activity. Angew. Chem. Int. Ed. 2025, 64 (3), e202415691. Das, R.; Alagarsamy, P.; Choudhary, R. N. P. Studies of Structural, Electrical, and Magnetic Characteristics of Double Perovskite Ceramic: La 2 FeMnO 6 . Phys. Status Solidi B. 2021 , 258 (12), 2100299. Ding, Z.; Xu, W.; Zhang, X.; Liu, Z.; Shen, J.; Liang, J.; Jiang, M.; Ren, X. Controllable Acid/Base Propriety of Sulfate Modified Mixed Metal Oxide Derived from Hydrotalcite for Synthesis of Propylene Carbonate. Catalysts. 2019 , 9 (5), 470. Schroder, K. W.; Dylla, A. G.; Harris, S. J.; Webb, L. J.; Stevenson, K. J. Role of surface oxides in the formation of solid-electrolyte interphases at silicon electrodes for lithium-ion batteries. ACS Appl. Mater. Interfaces. 2014 , 6 (23), 21510-21524. Zhao, W.; Feng, D.; Nong, J.; Cao, G.; Liu, X.; Tang, Z.; Chen, Y. Catalysis effect and conversion process of transition metal chlorides in the synthesis of diethyl carbonate from ethyl carbamate and ethanol. React. Kinet. Mech. Catal. 2015 , 117 (2), 639-654. Additional Declarations No competing interests reported. Cite Share Download PDF Status: Posted Version 1 posted You are reading this latest preprint version Research Square lets you share your work early, gain feedback from the community, and start making changes to your manuscript prior to peer review in a journal. As a division of Research Square Company, we’re committed to making research communication faster, fairer, and more useful. We do this by developing innovative software and high quality services for the global research community. Our growing team is made up of researchers and industry professionals working together to solve the most critical problems facing scientific publishing. Also discoverable on Platform About Our Team In Review Editorial Policies Advisory Board Help Center Resources Author Services Accessibility API Access RSS feed Manage Cookie Preferences © Research Square 2026 | ISSN 2693-5015 (online) Privacy Policy Terms of Service Do Not Sell My Personal Information {"props":{"pageProps":{"initialData":{"identity":"rs-7334198","acceptedTermsAndConditions":true,"allowDirectSubmit":true,"archivedVersions":[],"articleType":"Research Article","associatedPublications":[],"authors":[{"id":506628233,"identity":"8217b8b8-2185-4088-9e54-0b18e988ef6e","order_by":0,"name":"Liangchun He","email":"","orcid":"","institution":"Kunming University of Science and Technology","correspondingAuthor":false,"prefix":"","firstName":"Liangchun","middleName":"","lastName":"He","suffix":""},{"id":506628234,"identity":"3b539db8-56c4-44e6-a635-fa57bc9f850d","order_by":1,"name":"Dongxia Wang","email":"","orcid":"","institution":"Kunming University of Science and Technology","correspondingAuthor":false,"prefix":"","firstName":"Dongxia","middleName":"","lastName":"Wang","suffix":""},{"id":506628239,"identity":"47b4acaa-6139-473d-a035-b989c310372b","order_by":2,"name":"Zhiyong Xu","email":"","orcid":"","institution":"Kunming University of Science and Technology","correspondingAuthor":false,"prefix":"","firstName":"Zhiyong","middleName":"","lastName":"Xu","suffix":""},{"id":506628240,"identity":"10fb1099-b535-4421-a888-9e3763dbd12e","order_by":3,"name":"Songyi Y. Ji","email":"","orcid":"","institution":"Kunming University of Science and Technology","correspondingAuthor":false,"prefix":"","firstName":"Songyi","middleName":"Y.","lastName":"Ji","suffix":""},{"id":506628241,"identity":"fe739a6c-5e0d-499c-8592-baee2d471ebe","order_by":4,"name":"Rong Zhang","email":"","orcid":"","institution":"Kunming University of Science and Technology","correspondingAuthor":false,"prefix":"","firstName":"Rong","middleName":"","lastName":"Zhang","suffix":""},{"id":506628242,"identity":"0e7840e0-97ae-4985-b9a1-546d6582a185","order_by":5,"name":"Wenbo B. Zhao","email":"data:image/png;base64,iVBORw0KGgoAAAANSUhEUgAAAZAAAAAyAQMAAABI0h/eAAAABlBMVEX///8AAABVwtN+AAAACXBIWXMAAA7EAAAOxAGVKw4bAAAA2UlEQVRIiWNgGAWjYJACZgYGCQY2BgbGBwkVNqRpYTZ4cCaNaC1gwCb5sO0QYeUGx3sPfy5ss0jsk26/VpHAdoCBv707Ab+WM+fSpGe2SRizyZwpu5HAc4dB4szZDXi1mN3IMWPmbZOQY5PISbuRIPGMwUAil4CW+2+MPwO18IC0FCQYHCZCyw0eA2mILenHGBISiNBifybHTJrnHNAvEjnMEgkH0ngI+kWy/YzxZ56yusT5M9Iffvz5z0aOv70XvxYkwGMAJolVDgLsD0hRPQpGwSgYBSMIAACp7UPqt+AiRQAAAABJRU5ErkJggg==","orcid":"","institution":"Kunming University of Science and Technology","correspondingAuthor":true,"prefix":"","firstName":"Wenbo","middleName":"B.","lastName":"Zhao","suffix":""}],"badges":[],"createdAt":"2025-08-09 13:38:10","currentVersionCode":1,"declarations":"","doi":"10.21203/rs.3.rs-7334198/v1","doiUrl":"https://doi.org/10.21203/rs.3.rs-7334198/v1","draftVersion":[],"editorialEvents":[],"editorialNote":"","failedWorkflow":false,"files":[{"id":90176175,"identity":"41927984-bb3a-40d0-95d5-541255b7285e","added_by":"auto","created_at":"2025-08-29 12:31:11","extension":"png","order_by":1,"title":"Figure 1","display":"","copyAsset":false,"role":"figure","size":51180,"visible":true,"origin":"","legend":"\u003cp\u003eXRD patterns of different transition metals chlorine, (a) CoCl\u003csub\u003e2\u003c/sub\u003e, (b) ZnCl\u003csub\u003e2\u003c/sub\u003e, (c) MnCl\u003csub\u003e2\u003c/sub\u003e, (d) CdCl\u003csub\u003e2\u003c/sub\u003e, (e) NiCl\u003csub\u003e2\u003c/sub\u003e.\u003c/p\u003e","description":"","filename":"1.png","url":"https://assets-eu.researchsquare.com/files/rs-7334198/v1/d21ee0e76ccd155c955cfd00.png"},{"id":90177432,"identity":"a56c55f5-2e5e-465f-a0be-64bfcf3ee30a","added_by":"auto","created_at":"2025-08-29 12:47:12","extension":"png","order_by":2,"title":"Figure 2","display":"","copyAsset":false,"role":"figure","size":61628,"visible":true,"origin":"","legend":"\u003cp\u003eXRD patterns of solid products catalyzed by chlorine salts of different transition metals, (a) Co(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e, (b) Zn(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e, (c) Mn(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e, (d) Cd(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e and (e) Ni(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e.\u003c/p\u003e","description":"","filename":"2.png","url":"https://assets-eu.researchsquare.com/files/rs-7334198/v1/794b5cc35f0a1534c488e57a.png"},{"id":90176945,"identity":"68e0d7fb-b3a9-47eb-81db-5238db59b3fb","added_by":"auto","created_at":"2025-08-29 12:39:12","extension":"png","order_by":3,"title":"Figure 3","display":"","copyAsset":false,"role":"figure","size":138536,"visible":true,"origin":"","legend":"\u003cp\u003eXRD patterns and TG spectra of ammonia complexes with different transition metal chlorides, (a) Co(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e, (b) Zn(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e, (c) Mn(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e, (d) Cd(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e and (e) Ni(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e.\u003c/p\u003e","description":"","filename":"3.png","url":"https://assets-eu.researchsquare.com/files/rs-7334198/v1/b658b17deccb164a6e8b7e06.png"},{"id":90176176,"identity":"c47e58d2-3f66-45a1-89d1-fcc489d93cb7","added_by":"auto","created_at":"2025-08-29 12:31:11","extension":"png","order_by":4,"title":"Figure 4","display":"","copyAsset":false,"role":"figure","size":72030,"visible":true,"origin":"","legend":"\u003cp\u003e\u003cstrong\u003eXRD \u003c/strong\u003epatterns of solid products after catalysis with different ammonia TMCS, (a) Co(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e, (b) Zn(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e, (c) Mn(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e, (d) Cd(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e and (e) Ni(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e.\u003c/p\u003e","description":"","filename":"4.png","url":"https://assets-eu.researchsquare.com/files/rs-7334198/v1/47d817ca01da90d45fb1dd82.png"},{"id":90176947,"identity":"42666d14-4f00-4da8-90c4-a53d25329b86","added_by":"auto","created_at":"2025-08-29 12:39:12","extension":"png","order_by":5,"title":"Figure 5","display":"","copyAsset":false,"role":"figure","size":62635,"visible":true,"origin":"","legend":"\u003cp\u003ePossible reaction mechanism\u003c/p\u003e","description":"","filename":"5.png","url":"https://assets-eu.researchsquare.com/files/rs-7334198/v1/53bac9407566213057d79ea3.png"},{"id":91881352,"identity":"c6b2035e-783d-43eb-b585-c02d0ebed95c","added_by":"auto","created_at":"2025-09-22 14:56:08","extension":"pdf","order_by":0,"title":"","display":"","copyAsset":false,"role":"manuscript-pdf","size":1459359,"visible":true,"origin":"","legend":"","description":"","filename":"manuscript.pdf","url":"https://assets-eu.researchsquare.com/files/rs-7334198/v1/e3141df4-4ed4-4944-8304-991b5a9487d7.pdf"}],"financialInterests":"No competing interests reported.","formattedTitle":"Transition Metal Chloride Catalyzed the Synthesis of Dipropyl Carbonate from Urea Alcoholysis: Influence of Initial Decomposition Temperature of Ammine Transition Metal Chloride","fulltext":[{"header":"1. Introduction","content":"\u003cp\u003eDipropyl carbonate (DPC) is a versatile organic carbonate with significant industrial value, renowned for its excellent solubility, low toxicity and biodegradability. These attributes have driven its widespread application in energy\u003csup\u003e\u003cspan citationid=\"CR1\" class=\"CitationRef\"\u003e1\u003c/span\u003e\u003c/sup\u003e, motor vehicles\u003csup\u003e\u003cspan citationid=\"CR2\" class=\"CitationRef\"\u003e2\u003c/span\u003e\u003c/sup\u003e, electronics\u003csup\u003e\u003cspan citationid=\"CR3\" class=\"CitationRef\"\u003e3\u003c/span\u003e\u003c/sup\u003e medicine and other high-value sectors\u003csup\u003e\u003cspan citationid=\"CR4\" class=\"CitationRef\"\u003e4\u003c/span\u003e\u003c/sup\u003e. In addition to its current applications, DPC, with its multi-functionality and environmentally friendly features, also stands out in the field of sustainable organic synthesis of future-oriented green chemicals, becoming a highly promising choice\u003csup\u003e\u003cspan citationid=\"CR5\" class=\"CitationRef\"\u003e5\u003c/span\u003e\u003c/sup\u003e. Numerous methods for DPC synthesis have been reported, including phosgene-mediated carbonylation\u003csup\u003e\u003cspan citationid=\"CR6\" class=\"CitationRef\"\u003e6\u003c/span\u003e\u003c/sup\u003e, oxidative carbonylation of alcohols\u003csup\u003e\u003cspan citationid=\"CR7\" class=\"CitationRef\"\u003e7\u003c/span\u003e\u003c/sup\u003e, transesterification of carbonates\u003csup\u003e\u003cspan citationid=\"CR8\" class=\"CitationRef\"\u003e8\u003c/span\u003e\u003c/sup\u003e direct carboxylation of alcohols using carbon dioxide\u003csup\u003e\u003cspan citationid=\"CR9\" class=\"CitationRef\"\u003e9\u003c/span\u003e\u003c/sup\u003e, and lipolytic enzyme-catalyzed method\u003csup\u003e\u003cspan citationid=\"CR10\" class=\"CitationRef\"\u003e10\u003c/span\u003e\u003c/sup\u003e. However, these methods have inherent limitations, the pathway based on oxidative carbonylation relies on highly toxic reagents, and the process involves explosive reactants such as carbon monoxide; Ester exchange reactions often have relatively low conversion efficiency and the direct utilization of CO₂ is subject to thermodynamic constraints. Enzymatic methods require complex preparation and maintenance of biocatalysts.\u003c/p\u003e\u003cp\u003eThe production of DPC using urea alcoholysis is a highly attractive route due to its low cost and facile product separation\u003csup\u003e\u003cspan citationid=\"CR11\" class=\"CitationRef\"\u003e11\u003c/span\u003e\u003c/sup\u003e. In this process, the intermediate propyl carbamate (PC) is first formed, followed by the sequential esterification of PC with additional n-propanol to yield DPC\u003csup\u003e\u003cspan citationid=\"CR12\" class=\"CitationRef\"\u003e12\u003c/span\u003e\u003c/sup\u003e. From a thermodynamic perspective, the initial step (urea alcoholysis to PC) in the reaction is more straightforward\u003csup\u003e\u003cspan citationid=\"CR13\" class=\"CitationRef\"\u003e13\u003c/span\u003e\u003c/sup\u003e. However, the subsequent transformation of PC to DPC is kinetically more challenging and serves as the rate-determining step for the overall urea alcoholysis process. This kinetic limitation necessitates the use of catalysts to accelerate the reaction and improve DPC yield.\u003c/p\u003e\u003cp\u003eNumerous studies have explored the use of diverse catalysts, including organotin compounds, rare earth metal salts, metal powders, and mixed metal oxides to facilitate the synthesis of organic carbonates via urea alcoholysis. For instance, Li et al\u003csup\u003e\u003cspan citationid=\"CR14\" class=\"CitationRef\"\u003e14\u003c/span\u003e\u003c/sup\u003e. used different metal oxides as catalysts for vinyl carbonate production, additionally investigating how the acid-base sites of these metal oxides influence on the catalytic properties. Among the metal oxides, zinc oxide has the best catalytic properties. Notably, Fakhrnasova et al\u003csup\u003e\u003cspan citationid=\"CR15\" class=\"CitationRef\"\u003e15\u003c/span\u003e\u003c/sup\u003e. found that while although acidic sites significantly promote the formation of vinyl carbonate, when the acidity of the catalyst is too high, the surface sites are blocked, and the catalytic activity drops beyond the critical acidity threshold, indicating that the presence of a catalyst requires an optimal acid-base site balance. In a separate study, Gao et al\u003csup\u003e\u003cspan citationid=\"CR12\" class=\"CitationRef\"\u003e12\u003c/span\u003e\u003c/sup\u003e demonstrated that both MgCl\u003csub\u003e2\u003c/sub\u003e and ZnCl\u003csub\u003e2\u003c/sub\u003e are effective catalysts for propylene carbonate synthesis via urea alcoholysis. Similarly, Du et al\u003csup\u003e\u003cspan citationid=\"CR16\" class=\"CitationRef\"\u003e16\u003c/span\u003e\u003c/sup\u003e. prepared and investigated MgTiO\u003csub\u003e3\u003c/sub\u003e catalysts for the same reaction, revealing that strong basic active sites on the catalyst surface are the key factor governing urea alcoholysis performance. Focusing on zinc salts, Zhao et al\u003csup\u003e\u003cspan citationid=\"CR17\" class=\"CitationRef\"\u003e17\u003c/span\u003e\u003c/sup\u003e. investigated their catalytic behavior in the synthesis of dimethyl carbonate from methyl carbamate and methanol. The highest catalytic activity of ZnCl\u003csub\u003e2\u003c/sub\u003e was attributed to its ability to activate methyl carbamate by complexation with the -NH\u003csub\u003e2\u003c/sub\u003e based nitrogen proton, resulting in a significant enhancement in the yield of dimethyl carbonate. While urea alcoholysis has been extensively utilized for the synthesis of various organic carbonates, its application in DPC production remains limited, highlighting a gap in current research.\u003c/p\u003e\u003cp\u003eTransition metal cations, prototypical Lewis acids, readily form ammonia complexes via coordination with ammonia\u003csup\u003e\u003cspan citationid=\"CR18\" class=\"CitationRef\"\u003e18\u003c/span\u003e\u003c/sup\u003e. In the synthesis reaction, transition metal cations can form coordination compounds with ammonia generated in situ through coordination\u003csup\u003e\u003cspan citationid=\"CR19\" class=\"CitationRef\"\u003e19\u003c/span\u003e\u003c/sup\u003e. This process can change the reaction equilibrium and thereby increase the yield of the product\u003csup\u003e\u003cspan citationid=\"CR20\" class=\"CitationRef\"\u003e20\u003c/span\u003e\u003c/sup\u003e. Therefore, transition metal cation is a benign reaction coupling agent for urea alcoholysis, where ammonia removal is critical to driving the reaction forward. Both transition metal oxides\u003csup\u003e\u003cspan citationid=\"CR21\" class=\"CitationRef\"\u003e21\u003c/span\u003e,\u003cspan citationid=\"CR22\" class=\"CitationRef\"\u003e22\u003c/span\u003e\u003c/sup\u003e and metal salts\u003csup\u003e\u003cspan citationid=\"CR23\" class=\"CitationRef\"\u003e23\u003c/span\u003e\u003c/sup\u003e, contain cations; however, only metal salts are soluble in n-propanol and dissociate into free ions. This solubility allows each transition metal cation to function as a discrete active site, maximizing catalytic accessibility. A key advantage of metal salts, particularly chlorides, is that their transition metal cations are readily regenerated via thermal decomposition of their ammonia complexes, ensuring long-term catalytic stability.\u003c/p\u003e\u003cp\u003eThis study evaluated the catalytic activity of a series of representative transition metal chlorides (e.g., CoCl\u003csub\u003e2\u003c/sub\u003e, ZnCl\u003csub\u003e2\u003c/sub\u003e, MnCl\u003csub\u003e2\u003c/sub\u003e) for the synthesis of DPC from urea and n-propanol in a batch reactor. The transition metal chlorides and ammonia-transition metal chloride coupling agents was employed for catalysis under different reaction conditions. The effects of TMC and ammonia TMC on the catalytic activity of DPC synthesis using urea and n-propanol as raw materials were investigated. Through a series of studies, we have clarified the enhancing effect of transition metal ions on TMC and the mechanism of the ammonia TMC system in the catalytic process. These results provide new insights and theoretical basis for the development of efficient, economical and stable transition metal chloride catalysts.\u003c/p\u003e"},{"header":"2. Experimental sections","content":"\u003cdiv id=\"Sec3\" class=\"Section2\"\u003e\u003ch2\u003e2.1 Evaluation of catalytic activity\u003c/h2\u003e\u003cp\u003eThe reaction is carried out in a 100 mL stainless steel batch reactor equipped with a magnetic stirrer and immersed in a thermostatic oil bath. For catalytic screening with different TMCs, urea, n-propanol, and the respective TMC were loaded into the reactor at a fixed molar ratio of 1:10:2 (urea:n-propanol:TMC). The reactor was then sealed, heated to a specified temperature in the oil bath, and maintained for 8 h under continuous magnetic stirring to ensure homogeneous mixing. To optimize the reaction conditions, the TMC exhibiting the highest initial catalytic activity was selected as a model system. Key parameters, including reaction temperature, time and molar ratio of catalyst, were systematically studied to evaluate their impact on DPC yield and selectivity. After the reaction, the reactor was cooled to room temperature, and the product mixture was collected via centrifugal separation and weighed. The supernatant was analyzed by gas chromatography. The analysis conditions were as follows: chromatographic column temperature 110 ℃, vaporization chamber temperature 180 ℃, FID1 temperature 180 ℃, and injection volume 0.1 mL. The gas chromatography system is equipped with a SE-30 chromatographic column and a flame ionization detector (FID) for production inspection. Quantitative analysis of DPC and its intermediate products was conducted using butyl carbamate as the internal standard.\u003c/p\u003e\u003c/div\u003e\u003cdiv id=\"Sec4\" class=\"Section2\"\u003e\u003ch2\u003e2.2 Preparation of ammonia chloride salts\u003c/h2\u003e\u003cp\u003eAll reagents used in the experiment were commercially available analytical grade and used without further purification. The preparation process of ammonia TMC complexes was conducted as follows: 5 g of anhydrous TMC was dissolved in 100 mL of ethanol, and the solution was then filtered to remove insoluble salt. The filtrate was transferred to a Mason jar, into which a mixture of 20% ammonia and nitrogen gas was injected. Over time, different colored precipitates were formed in the solution. The precipitates were collected via centrifugation and subsequently dried in a nitrogen atmosphere at 65 ℃ for 5 h to obtain the pure ammine TMC complexes.\u003c/p\u003e\u003c/div\u003e\u003cdiv id=\"Sec5\" class=\"Section2\"\u003e\u003ch2\u003e2.3 Characterization\u003c/h2\u003e\u003cp\u003eThe prepared materials were characterized by X-ray diffraction (XRD, Anton Paar) with Cu Kα radiation. During the tests, the diffraction angle range was set between 5\u0026deg; and 70\u0026deg; with a scanning speed of 5 \u0026deg;/min. Thermogravimetric analysis (TGA) was performed by a NETZSCH TG209F1, under a high-purity N\u003csub\u003e2\u003c/sub\u003e atmosphere. Samples were heated from 30 to 500\u0026deg;C at a heating rate of 10\u0026deg;C min⁻\u0026sup1;, with continuous monitoring of mass change as a function of temperature.\u003c/p\u003e\u003c/div\u003e"},{"header":"3. Results and Discussion","content":"\u003cdiv id=\"Sec7\" class=\"Section2\"\u003e\n \u003ch2\u003e3.1 Analysis of TMC catalytic activity\u003c/h2\u003e\n \u003cp\u003eFigure \u003cspan class=\"InternalRef\"\u003e1\u003c/span\u003e shows the XRD patterns of TMC catalysts. It was established that the purchased CoCl\u003csub\u003e2\u003c/sub\u003e, ZnCl\u003csub\u003e2\u003c/sub\u003e, MnCl\u003csub\u003e2\u003c/sub\u003e, CdCl\u003csub\u003e2\u003c/sub\u003e and NiCl\u003csub\u003e2\u003c/sub\u003e corresponded to anhydrous TMC standard cards, ensuring that all TMC used during the experiment was anhydrous. Catalytic activity of TMCs were evaluated, in the absence of the TMC catalyst, although the yield of the intermediate product PC was 12.89%, but no detectable DPC. With the addition of TMC catalysts, DPC yields followed the order: CoCl\u003csub\u003e2\u003c/sub\u003e (5.88%)\u0026thinsp;\u0026gt;\u0026thinsp;ZnCl\u003csub\u003e2\u003c/sub\u003e (5.20%)\u0026thinsp;\u0026gt;\u0026thinsp;MnCl\u003csub\u003e2\u003c/sub\u003e (4.45%)\u0026thinsp;\u0026gt;\u0026thinsp;CdCl\u003csub\u003e2\u003c/sub\u003e (2.66%)\u0026thinsp;\u0026gt;\u0026thinsp;NiCl\u003csub\u003e2\u003c/sub\u003e (2.05%) (Table\u0026nbsp;\u003cspan class=\"InternalRef\"\u003e1\u003c/span\u003e). Conversely, PC yields exhibited an inverse trend, with corresponding yields of 7.34%, 9.22%, 9.91%, 10.20% and 17.18%, respectively. This result suggests that TMCs primarily promotes the conversion of the intermediate PC to DPC.\u003c/p\u003e\n \u003cdiv class=\"gridtable\"\u003e\n \u003ctable id=\"Tab1\" border=\"1\"\u003e\n \u003ccaption language=\"En\"\u003e\n \u003cdiv class=\"CaptionNumber\"\u003eTable 1\u003c/div\u003e\n \u003cdiv class=\"CaptionContent\"\u003e\n \u003cp\u003eActivity evaluation of TMC and their diamine complex\u003c/p\u003e\n \u003c/div\u003e\n \u003c/caption\u003e\n \u003cthead\u003e\n \u003ctr\u003e\n \u003cth align=\"left\"\u003e\n \u003cp\u003eType of catalyst\u003c/p\u003e\n \u003c/th\u003e\n \u003cth align=\"left\"\u003e\n \u003cp\u003eYield of PC\u003c/p\u003e\n \u003c/th\u003e\n \u003cth align=\"left\"\u003e\n \u003cp\u003eYield of DPC\u003c/p\u003e\n \u003c/th\u003e\n \u003c/tr\u003e\n \u003c/thead\u003e\n \u003ctbody\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003ecatalyst-free\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e12.89\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e0\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003eCoCl\u003csub\u003e2\u003c/sub\u003e\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e7.34\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e5.88\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003eZnCl\u003csub\u003e2\u003c/sub\u003e\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e9.22\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e5.20\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003eMnCl\u003csub\u003e2\u003c/sub\u003e\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e9.91\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e4.45\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003eCdCl\u003csub\u003e2\u003c/sub\u003e\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e10.20\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e2.66\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003eNiCl\u003csub\u003e2\u003c/sub\u003e\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e17.18\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e2.05\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003eCo(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e6\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e8.53\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e2.64\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003eZn(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e15.49\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e1.93\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003eMn(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e9.74\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e1.59\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003eCd(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e9.59\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e1.36\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003eNi(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e6\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e9.22\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e1.18\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003c/tbody\u003e\n \u003c/table\u003e\n \u003c/div\u003e\n\u003c/div\u003e\n\u003cdiv id=\"Sec8\" class=\"Section2\"\u003e\n \u003ch2\u003e3.2 Analysis of optimal catalytic conditions\u003c/h2\u003e\n \u003cp\u003eTo determine optimal catalytic conditions for the catalyst, CoCl\u003csub\u003e2\u003c/sub\u003e was selected as an example owing to it has the best catalytic activity. Table \u003cspan class=\"InternalRef\"\u003e2\u003c/span\u003e shows the effect of different reaction times on the catalytic efficiency. As time progressed, the yield of PC underwent a gradual decline, while the yield of DPC demonstrated an initial increase followed by a subsequent decrease as the reaction duration increased. As can be seen from Table\u0026nbsp;\u003cspan class=\"InternalRef\"\u003e2\u003c/span\u003e, at the beginning of the reaction, urea and n-propanol react to form the intermediate n-propyl carbamate. Crucially, extending the reaction beyond 8 h does reduced the yield of DPC, attributable to competing side reactions occur at this period. Therefore, the optimal time for catalysis was finally found to be 8 h.\u003c/p\u003e\n \u003cdiv class=\"gridtable\"\u003e\n \u003ctable id=\"Tab2\" border=\"1\"\u003e\n \u003ccaption language=\"En\"\u003e\n \u003cdiv class=\"CaptionNumber\"\u003eTable 2\u003c/div\u003e\n \u003cdiv class=\"CaptionContent\"\u003e\n \u003cp\u003eActivity evaluation at different reaction times\u003c/p\u003e\n \u003c/div\u003e\n \u003c/caption\u003e\n \u003cthead\u003e\n \u003ctr\u003e\n \u003cth align=\"left\"\u003e\n \u003cp\u003eReaction time\u003c/p\u003e\n \u003cp\u003e(h)\u003c/p\u003e\n \u003c/th\u003e\n \u003cth align=\"left\"\u003e\n \u003cp\u003eYield of PC\u003c/p\u003e\n \u003cp\u003e(%)\u003c/p\u003e\n \u003c/th\u003e\n \u003cth align=\"left\"\u003e\n \u003cp\u003eYield of DPC\u003c/p\u003e\n \u003cp\u003e(%)\u003c/p\u003e\n \u003c/th\u003e\n \u003c/tr\u003e\n \u003c/thead\u003e\n \u003ctbody\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e4\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e12.22\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e3.65\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e6\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e10.12\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e4.16\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e8\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e7.34\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e5.91\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e10\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e2.89\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e4.58\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e12\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e2.34\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e3.90\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003c/tbody\u003e\n \u003c/table\u003e\n \u003c/div\u003e\n \u003cp\u003eThe influence of reaction temperature on catalytic performance is summarized in Table\u0026nbsp;\u003cspan class=\"InternalRef\"\u003e3\u003c/span\u003e. The yield of PC decreased monotonically from 11.42% at 170\u0026deg;C to 2.17% at 210\u0026deg;C, while DPC yield exhibited a distinct maximum of 5.91% at 190\u0026deg;C. This phenomenon can be attributed to the fact that, at temperatures below 190\u0026deg;C, the reaction progresses in a favourable direction as the temperature rises, resulting in the conversion of PC to DPC. Above 190\u0026deg;C, however, thermodynamic limitations dominate as competing decomposition pathways become significant, including urea pyrolysis and DPC decarboxylation to dipropyl ether. The temperature-dependent yield profile confirms 190\u0026deg;C as optimal temperature for maximizing DPC production.\u003c/p\u003e\n \u003cdiv class=\"gridtable\"\u003e\n \u003ctable id=\"Tab3\" border=\"1\"\u003e\n \u003ccaption language=\"En\"\u003e\n \u003cdiv class=\"CaptionNumber\"\u003eTable 3\u003c/div\u003e\n \u003cdiv class=\"CaptionContent\"\u003e\n \u003cp\u003eActivity evaluation at different reaction temperature\u003c/p\u003e\n \u003c/div\u003e\n \u003c/caption\u003e\n \u003cthead\u003e\n \u003ctr\u003e\n \u003cth align=\"left\"\u003e\n \u003cp\u003eReaction temperature\u003c/p\u003e\n \u003cp\u003e(℃)\u003c/p\u003e\n \u003c/th\u003e\n \u003cth align=\"left\"\u003e\n \u003cp\u003eYield of PC\u003c/p\u003e\n \u003cp\u003e(%)\u003c/p\u003e\n \u003c/th\u003e\n \u003cth align=\"left\"\u003e\n \u003cp\u003eYield of DPC\u003c/p\u003e\n \u003cp\u003e(%)\u003c/p\u003e\n \u003c/th\u003e\n \u003c/tr\u003e\n \u003c/thead\u003e\n \u003ctbody\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e170\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e11.42\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e1.91\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e180\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e9.43\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e2.87\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e190\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e7.34\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e5.91\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e200\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e2.86\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e3.02\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e210\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e2.17\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e2.66\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003c/tbody\u003e\n \u003c/table\u003e\n \u003c/div\u003e\n \u003cp\u003eTable \u003cspan class=\"InternalRef\"\u003e4\u003c/span\u003e shows the effect of molar ratio of urea to n-propanol on the catalytic activity. The yield of dipropyl carbonate increased with increasing amount of n-propanol up to a molar ratio of 1:10 mol/mol. Relevant reaction mechanism studies have shown that during the reaction between urea and n-propanol to form DPC, a -NH\u003csub\u003e2\u003c/sub\u003e in urea first reacts with -OH in n-propanol to form PC intermediate. The intermediate then undergoes the next step of the reaction to produce DPC. While urea contains two -NH\u003csub\u003e2\u003c/sub\u003e, n-propanol contains only one -OH, so excess n-propanol can increase the formation of PC and thus speed up the reaction and improve the yield of DPC. However, as the molar amount of n-propanol increases, the yield of dipropyl carbonate decreases. This is due to the fact that when the n-propanol dosage becomes too high, the urea conversion reaches its maximum and the reaction cannot be accelerated even if the n-propanol dosage is increased further.\u003c/p\u003e\n \u003cdiv class=\"gridtable\"\u003e\n \u003ctable id=\"Tab4\" border=\"1\"\u003e\n \u003ccaption language=\"En\"\u003e\n \u003cdiv class=\"CaptionNumber\"\u003eTable 4\u003c/div\u003e\n \u003cdiv class=\"CaptionContent\"\u003e\n \u003cp\u003eActivity evaluation of different raw material ratios\u003c/p\u003e\n \u003c/div\u003e\n \u003c/caption\u003e\n \u003cthead\u003e\n \u003ctr\u003e\n \u003cth align=\"left\"\u003e\n \u003cp\u003eUrea : n-propanol\u003c/p\u003e\n \u003cp\u003e(mol/mol)\u003c/p\u003e\n \u003c/th\u003e\n \u003cth align=\"left\"\u003e\n \u003cp\u003eYield of PC\u003c/p\u003e\n \u003cp\u003e(%)\u003c/p\u003e\n \u003c/th\u003e\n \u003cth align=\"left\"\u003e\n \u003cp\u003eYield of DPC\u003c/p\u003e\n \u003cp\u003e(%)\u003c/p\u003e\n \u003c/th\u003e\n \u003c/tr\u003e\n \u003c/thead\u003e\n \u003ctbody\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e1:5\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e12.19\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e4.63\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e1:7.5\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e16.76\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e4.92\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e1:10\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e7.34\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e5.91\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e1:12.5\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e13.63\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e4.52\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e1:15\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e10.53\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e2.40\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003c/tbody\u003e\n \u003c/table\u003e\n \u003c/div\u003e\n \u003cp\u003eThe effect of the amount of catalyst on the synthesis of DPC is summarized in Table \u003cspan class=\"InternalRef\"\u003e5\u003c/span\u003e. It can be seen that the yield of DPC increases gradually as the catalyst dosage is increased, reaching a maximum of 6.23% at a 1:3 urea: CoCl\u003csub\u003e2\u003c/sub\u003e ratio. This is because during reaction the catalysts interact with the NH\u003csub\u003e3\u003c/sub\u003e, a by-product of the reaction, to drive the reaction. When the molar ratio of catalyst to urea was increased from 1 mol/mol to 2 mol/mol, the yield of DPC increased significantly. And as the molar ratio increased further, the yield of DPC increased more slowly, although it increased to 6.23% when the ratio is reached 3 mol/mol. This is attributed to the conversion of urea is close to the conversion limit during the reaction, and even if the amount of catalyst is increased, the yield of DPC increases very little. Therefore, a molar ratio of 1:2 mol/mol was chosen as the optimum urea/ catalyst ratio, taking into account the principle of economy.\u003c/p\u003e\n \u003cdiv class=\"gridtable\"\u003e\n \u003ctable id=\"Tab5\" border=\"1\"\u003e\n \u003ccaption language=\"En\"\u003e\n \u003cdiv class=\"CaptionNumber\"\u003eTable 5\u003c/div\u003e\n \u003cdiv class=\"CaptionContent\"\u003e\n \u003cp\u003eActivity evaluation of different coupling ratio\u003c/p\u003e\n \u003c/div\u003e\n \u003c/caption\u003e\n \u003cthead\u003e\n \u003ctr\u003e\n \u003cth align=\"left\"\u003e\n \u003cp\u003eUrea : CoCl\u003csub\u003e2\u003c/sub\u003e\u003c/p\u003e\n \u003cp\u003e(mol/mol)\u003c/p\u003e\n \u003c/th\u003e\n \u003cth align=\"left\"\u003e\n \u003cp\u003eYield of PC\u003c/p\u003e\n \u003cp\u003e(%)\u003c/p\u003e\n \u003c/th\u003e\n \u003cth align=\"left\"\u003e\n \u003cp\u003eYield of DPC\u003c/p\u003e\n \u003cp\u003e(%)\u003c/p\u003e\n \u003c/th\u003e\n \u003c/tr\u003e\n \u003c/thead\u003e\n \u003ctbody\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e1:1\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e17.58\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e1.74\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e1:1.5\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e9.38\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e2.45\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e1:2\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e7.34\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e5.91\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e1:2.5\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e8.45\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e6.02\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003ctr\u003e\n \u003ctd align=\"left\"\u003e\n \u003cp\u003e1:3\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e9.43\u003c/p\u003e\n \u003c/td\u003e\n \u003ctd align=\"char\"\u003e\n \u003cp\u003e6.23\u003c/p\u003e\n \u003c/td\u003e\n \u003c/tr\u003e\n \u003c/tbody\u003e\n \u003c/table\u003e\n \u003c/div\u003e\n\u003c/div\u003e\n\u003cdiv id=\"Sec9\" class=\"Section2\"\u003e\n \u003ch2\u003e3.3 Analysis of post-catalysis solid products\u003c/h2\u003e\n \u003cp\u003eTo further determine the catalysis mechanism of TMC, the solid products recovered post-reaction were qualitatively analyzed. Figure \u003cspan class=\"InternalRef\"\u003e2\u003c/span\u003e shows the XRD pattern of the solid product after TMC catalysis. In comparison with standard cards, it was established that TMC underwent a catalytic conversion to ammonia TMC complex, where CoCl\u003csub\u003e2\u003c/sub\u003e, ZnCl\u003csub\u003e2\u003c/sub\u003e, MnCl\u003csub\u003e2\u003c/sub\u003e and NiCl\u003csub\u003e2\u003c/sub\u003ewas converted to Co(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e, Zn(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e, Mn(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e and Ni(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e, respectively. Notably, the CdCl\u003csub\u003e2\u003c/sub\u003e-derived solid product exhibited a distinct crystalline phase inconsistent with Cd(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e references, suggesting either variable ammonia coordination or the specific ammonia coordination number could not be determined.\u003c/p\u003e\n\u003c/div\u003e\n\u003cdiv id=\"Sec10\" class=\"Section2\"\u003e\n \u003ch2\u003e\u003cstrong\u003e3.4 Analysis of precipitates produced by the reaction of TMC ethanol solutions with ammonia\u003c/strong\u003e\u003c/h2\u003e\n \u003cp\u003eAnalysis of the post-catalytic solid products of TMC revealed that they were all converted to their respective ammonia complexes. This observation prompted the hypothesis that ammonia binding capacity plays a key role in the catalytic mechanism. Theoretical studies confirmed that TMCs, acting as Lewis acids, can coordinate with ammonia (a Lewis base) to form ammine complexes. To investigate this, ammonia TMC complexes were synthesized and evaluated as catalysts for comparative assessment of their activity relative to TMCs. Synthesized ammine complexes were characterized by XRD and the results are displayed in Fig.\u0026nbsp;\u003cspan class=\"InternalRef\"\u003e3\u003c/span\u003e. These results indicate that CdCl\u003csub\u003e2\u003c/sub\u003e, ZnCl\u003csub\u003e2\u003c/sub\u003e and MnCl\u003csub\u003e2\u003c/sub\u003e in ethanol can react with ammonia to form the diamine complexes Cd(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e, Zn(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e and Mn(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e. However, it has been demonstrated that ethanol solutions of CoCl\u003csub\u003e2\u003c/sub\u003e and NiCl\u003csub\u003e2\u003c/sub\u003e react with ammonia to form hexa-ammonia complexes, Co(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e6\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e and Ni(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e6\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e.\u003c/p\u003e\n \u003cp\u003eTG-DSC analysis further corroborates these observations. For Cd(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e, the loss of the first ammonia molecule occurs at 200\u0026deg;C (Figure. 3i and Table\u0026nbsp;\u003cspan class=\"InternalRef\"\u003e2\u003c/span\u003e) with a weight loss of 8.39%. Subsequently the loss of the second ammonia molecule take place at 260\u0026deg;C with a weight loss of 8.02%. These observations are in agreement with the theoretical value of 7.83%. Mn(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e exhibits a complete and abrupt loss of coordinated ammonia molecules at 300\u0026deg;C (Figure. 3h), with a weight loss of 21.03%, which is in close agreement with the theoretical value of 21.30% (Table\u0026nbsp;\u003cspan class=\"InternalRef\"\u003e2\u003c/span\u003e). The precipitation of CoCl\u003csub\u003e2\u003c/sub\u003e ethanol solution exhibited a weight loss of 29.00% at 160\u0026deg;C, consistent with the theoretical value of 29.36%. This corresponds to the loss of four ammonia molecule. At 220\u0026deg;C and 280\u0026deg;C, ammonia losses were observed, with weight losses of 7.20% and 7.36%, respectively. These actual ammonia weight losses are in good line with the theoretical weight loss value of 7.34% (Figure. 3f, Table\u0026nbsp;\u003cspan class=\"InternalRef\"\u003e2\u003c/span\u003e). Ni(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e6\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e has been observed to undergo a complete loss of coordination ammonia at 310\u0026deg;C (Fig.\u0026nbsp;\u003cspan class=\"InternalRef\"\u003e3\u003c/span\u003ej). At 200\u0026deg;C, four ammonia molecules are lost, corresponding to a weight loss of 29.10%, while one ammonia molecule is lost at 310\u0026deg;C, resulting in a weight loss of 14.23%. These experimental values agree well with the theoretical predictions of 29.39% and 14.96%, respectively (Table\u0026nbsp;\u003cspan class=\"InternalRef\"\u003e6\u003c/span\u003e). Notably, the TG curve of Zn(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e is distinct from the other compounds presented (Figure. 3g). It is hypothesized that, under certain conditions, the compound may gradually lose two ammonia molecules over a temperature ranging from 180 to 400\u0026deg;C, resulting in a total weight loss of 20.15%. This process is believed to occur prior to the residue gasifying at higher temperatures.\u003c/p\u003e\n \u003cp\u003e\u003cstrong\u003eTable 6.\u003c/strong\u003e Thermal decomposition process of Co(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e6\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e, Mn(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e, Cd(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u0026nbsp;\u003c/sub\u003eand Ni(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e6\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e under nitrogen atmosphere\u003c/p\u003e\n \u003cp\u003e\u003cimg src=\"data:image/png;base64,iVBORw0KGgoAAAANSUhEUgAAAmIAAAK/CAYAAADK9qEXAAAQAElEQVR4AeydCbwW0xvHn8mWvSzJEiUqQvEPkShCZAmhLJUoZU1IKi2yZ0nWZKlEochW0h4itFFC1E2pLCVL9uV/v6fObe7be9fuMu87vz6dOzNnP78z75zfPM9zninzn/4JASEgBISAEBACQkAIlAoCZUz/hIAQEAJCQAiUGAJqSAgIgTACImJhNHQuBISAEBACQkAICIESREBErATBVlPxRECjFgJCQAgIASGQEwIiYjkho3ghIASEgBAQAkJACBQzAsVAxIq5x6peCAgBISAEhIAQEAJpgoCIWJpMpIYhBISAEIgtAhq4EEhhBETEUnjy1HUhIASEgBAQAkIgtREoViK2dOlSW7RokYIw0D1QtPeA8BSeugd0D5TIPfDvv/+mNstJgd4XKxF76KGHrE+fPgrCQPeA7gHdA7oHdA+k4D3w559/pgCVSe0uFisRu/322+3JJ5/c+KA6hKHuAd0Dugd0D+geKPF7oGzZsqnNclKg98VKxFJg/OqiEBACQkAICIENEFCEECgpBETESgpptSMEhIAQEAJCQAgIgQQERMQSANGlEIgnAhq1EBACQkAIlAYCImKlgbraFAJCQAgIASEgBIRAJgKxJWKZY9d/ISAEhIAQEAJCQAiUKgIiYqUKvxoXAkJACAiBmCCgYQqBpAiIiCWFRZFCQAgIASEgBISAECh+BETEih9jtSAE4omARi0EhIAQEAJ5IiAilidEyiAEhIAQEAJCQAgIgeJBQESs6HBVTUJACAgBISAEhIAQKBACImIFgkuZhYAQEAJCQAhEBQH1Ix0QEBFLh1nUGISAEBACQkAICIGUREBELCWnTZ0WAvFEQKMWAkJACKQbAiJi6TajGo8QEAJCQAgIASGQMgiIiEV6qtQ5ISAEhIAQEAJCIJ0REBFL59nV2ISAEBACQkAIFAQB5S1xBETEShxyNSgEhIAQEAJCQAgIgbUIiIitxUF/hYAQiCcCGrUQEAJCoFQREBErVfjVuBAQAkJACAgBIRBnBETE4jb7Gq8QEAJCQAgIASEQGQRExCIzFeqIEBACQkAICIH0Q0Ajyh0BEbHc8Yll6o8//mhffvlljmHZsmUpjctff/1lf//9d0qPQZ0XAkJACAiB9EBARCw95rHIRvHff//Z888/b5deeqndeuutLtSsWdMuueQSu/322+3GG2+0K664osjaK42K3nzzTVu6dGlpNK02Y4GABikEhIAQyD8CImL5xyoWOSFi22+/vT355JP2+OOP28CBA22bbbaxtm3bumvizjjjDPvzzz9TEo/333/fHnzwwZTsuzotBISAEBAC6YeAiFj6zelGjahMmTJ2yimn2J577mmcJ1a23Xbb2TnnnGObbbaZS3rkkUdsv/32s0MPPdRee+01F/fFF19Yly5dnDRt4sSJLq1Zs2b21Vdf2QcffOCu69evb5AiCnz88cfWqVMne/bZZ61v37524IEH2kUXXWRff/01yS7MmDHDTjrpJNcvJHLffvut/fLLL65My5YtbcSIEVavXj0bMmSIoVq94447DEke4+D8t99+szlz5tjpp59uEyZMsCOPPNKaNGlilStXtrp169p7771nn3/+ue2zzz5Z1999953dc889bry+/rffftv++ecfQ6pGHdR/2223GfW7jpbyn9WrV9vTTz9tnTt3toULF5ZybzZs/uqrr7brrrtuw4QCxHz66ad2/fXX28MPP2x//PFHAUqmf1Z+U5dddpn169cv/QdbAiOcNWuWex5Wq1bNbrjhBvv+++9LoNX8NbF8+XL3PHvnnXfyV0C5IouAiFhkp6b0OrbVVlvl2vgWW2xh//77r0FAVqxYYW+99Za1atXKOnTo4MjWmjVrjMXyjTfeMIjb66+/7uq75pprDJIGOdt///1t0KBBhgQO8vDRRx/ZM888YzVq1DBI3PTp0x0pI/2TTz5xBOvOO+80HjozZ860u+66y1atWuUCxIoHZIMGDRwhgiRNmjTJxowZY6NGjbJHH33UuK5Vq5aNHDnSeKhOmzbN6NfYsWMNmzcWdOKJ4/r33383wvz58x1hhHwddthhrv6pU6faq6++6sjfyy+/7MaBpBBM3ECL6c9LL73kiChkEQLJPO2www6OPHINEf3555+d/Rs4YQtnpfxv8ODB2Xqw6aab2iabbJItrjAXzBFEnfujMOWLogz3PvdWEATWuHHjHBdpiDFjrlChglPvF0XbOdWB9HrKlCn2008/5ZQlkvE//PCDM3+oVKmSu593220323zzzbPu91133dX95kuy87wgYooxdOhQpw3gOiMjoyS7kK0ttBA823gWkRAEgfF7SvbCTHqah7QanohYWk1nyQ0GY36IDhIhyAgEgEURMgUpgCAgkapTp46xACHl2mmnnaxFixa27bbbGg/aDz/80Ph30EEHOckURAppXPPmzR2pQwoFueHh88033zhpGud77LGHISHjgXTwwQcbqlTKYtOGbdvuu+/u2iEdggZhoTxtJYbq1atniwpfsygwBsZCv+677z47/vjjDUJEvxg/pHCXXXZxBJHFJFtlxXDx1FNPOTILkUQKedVVV7nr2bNn2wUXXGA77rijkzhaBP4tWLDAkEaGu4KEEUIdjivoOffXXnvtVdBiRZ6/YsWK1r59eyc55vcA2ee+CDfE/ffCCy+4e5T7B6lKOL2oz3nB4b4t6nqLuz5IRqNGjYz7mpc17nPmmRcl7qMXX3zRkLwn4luc/UKCTv3lypWzo48+2kaPHm08z4gr6cDmIp43SO55ztI+9x8vlkcccQSXCimMgIhYCk9eaXYd1SCSMd5aCZAjjPmPO+64QneL+iiM9AACxNse1xjWQ7Zoh3Dqqac61RQEiXTybbnllpy6ADnjGtUVD3WImEso5B/UsFtvvXVWaRZdHs70hdCuXTu3uWFj28lqIIcTFgEIZ7Jk+nPWWWdZ2bJls5IhAf3793f2fePHj8+KR9LHhgzs/lAJ+wWHDEgzkWKxOePaa681JJPEI10jX7du3QzJwN13321PPPGEsxVERYJ0FBUxZOPXX391alHygj/x2Byimkb9jN0hdfoA4b788svdJhAWYuJpD2KDKhM1NXZ9qIpJi1pg3nmZgCwkSqIgFKjyubeZI6QXvCCwoKJeBRt+N8yVHxcvM8R3yVTvs/gT/2smpqjd27Rp4+795557juh8BRbxYcOGuXu0Y8eOTq3uCzJXkGUw7t69u5P+ksZLxQMPPGCtW7e2Xr16OXU+8cUV+H1BxJKRyCAI7JBDDjHMGZYsWWJI0pEyggFqbkwUeDEDL3Cjvzyf6Ou8efOcZB0pIdJuiDP3rjcl4Ih0vXXmOLt27eqIIOWYN6Sd3OvUOXz4cKKN9nv27OlwueWWW2zRokUunnnnN0VgbvntcP/yu2Oe+e2gLqZ97nHMJx566CFngkEZV0nmH/qNuQdtXnnllfbuu+8axIsXPsbFvUFfGQ+aAl5qkNpnFnX/kRLffPPNrn8c+f2RwG9+8uTJdv/995ufW/pCPdRPHoXSQ0BErPSwT/mWIUhIii688ELzgYdiUQyMBSsIAlcVD5Hy5cs7KZdvhzd/FjSXIeEPEggWdxaXiy++2JDEJWTZqEtIAsTT9+W8886zypUrF7u9EosUJDWnziN5BDfSV65caTy8zz77bKtataqxqKLOI41FmYUB8oMkggf74sWLSXKkjYc3CzaSPsgdqmTmAHUz5JaFgwVs7ty5BjlCKgcRAevHHnvMbrrpJgMf7PEgxJC0k08+2VavXu3sulhcXGOZf1gEWVwgGKjVsCWkn/SPReaEE05wixUEDnVwSUpEMruXr//0G0nvuHHjnMsXXygjI8NdH3vssT7KHVmEWfR52cCeC4I1YMAAl4adJYHFGwyxUSIB9T/ziUQNUoKkiPj8BHBEVQ3pRjLNfYu6jbIQZ36z9If7GrtCMEalz9xCOiBJlCd/cQUwzO136oks2EGkkARxn3APoiKG+PAb5J7mXkHyyj3K74AxQNx4EahSpYpxDZ6MhfsZEsw9ywsX0jfimzZt6mxD9913X2eCgX0qpAvzCyTRzAOkDJMMTCQgN5BmXjgwswBTyCE2sZAfJPm8QJYrV85OO+00Z4YBsTz88MONFznuFdqF3EGYmCs0B9h6QqSZN/rA3CP5596hr9w7vAhRlt8w9rPkRaUKqWudSTDRBjC3/I7BAeKPNA3yCAnnGUB5hdJDQESs9LBPiZZ5oPBg5mEQfnNChcfCz1sbb2E88BCdQxTIR6Acg+RIeR4GXJNGID5MpnjIkufvv/92akgWsCAI7KijjjIWOWyzeODxAOJNNQgCJ5GhbogCdRN4+PFQpo/URyAdO7AgCJx9G3Fck59+sOgwVh6IXPMQ50ge+kh58hJQUyD94EFLf1gMePiyYJEehcBDHPywrYEs81Dmwcs47r33XmOhYfGDrCLhw54PWzsWeEjAAQccYCxq2M2xGCBpq127tlPDMR8sXCzikAbUzDVq1DBUwrQFCWaRRIoZBIEjZTz4IWuVMwmrx4d5ZMFkMfzf//5n9Im6wB7MqRO7PBZP1FKQBObNl4/KMQgCt/mjbt26bpcx9w0BlT1j4jeR2FfwYGws9JTj/iEPvwEWa0g3JA2siQcTyAhSYMgxc0N8XgGMWWyRfvJ7gCxjz4ZUkgWc+xfCx30CuQBnfpvcJ7S18847G7adkIC82iqJdO4h7jNIG/3ivuWeQiWPig48ue8hrbwE8FtlLNhPQqIYI1hC3ugvLweYV/Asoz6k6cTz4sf4ue/Bh98T9zXn3OPgBOnhuYf0DFX53nvvbUhHkSZDrJHWEce9fOKJJ7oXIswHaJN5ZSwckUJ7okteiBrj4DcBueJeYiz0gWeMHz/pxNFf8rzyyivupRPCx1xz//BMo3/koz3G07t3b+MF7cwzz3R2sJSlDoXSQ0BErPSwj3zLqKVYlHlQII3wb5F0nAc0aiNE/0gteINjx9YxxxzjxOkQJQIPSkT0lEUSglE7xIW6IXConKiPgO0VkhsWZqQyLBpIeHiY1q5d2xnzsqCQziLPIoIajTdT6uXNlnp4SELGkLTQDkSNI4SDBY6HGg9VFikWHd5weWtFJYCYnwcTOyh5M2XcPAxZuCAy1I/UBpUkkgUedryVQhp4oyY9CoH+obL1fcGGj3lE0gTuSK6QlKB+QaIHMQAjNlcQKMdDn52lkFQwII7AIsiRgGoDqQ11EVhkeMiTllf47LPPHJGGBJAXQoLdIBI81LAsdEg3UYHOnj2bLJENEEgkgNzDkABIDvcRi2Vip1nkkWqgwuKeY058HqQkkH8kI5B9NpiQxiLKfUw85JeFn/i8Ags8v6HwnOF+BgLBfYAkjzmErPH7hXiTH5LI/NBPfr/c33m1VVLpQRA4u1PfHvc5aj/uEfAEf5/GMQgCR5A494HnFueQWnZCIyUCK+494hMDvx+eDcydT4PsySFe/wAAEABJREFUgCvSLh/HczEI1kryfVxBjuwap07UlhB5/8zJqw5+26gqeS4Gwdr2IXNItXnB8uV5+QqCtenEgQPkj3OF0kOgTOk1rZajjgAPOEgQCyGLDG9T4T7z5sbbVo8ePQwDe6RjpPMmiWqLt3YIAT9+3hKxGaIO4s4//3xnu8FDhzIE7MsgSpACSB6LAfFcY++AvRMSBurCdQSSBoznefjyZskCQn5sciCGPBQhWRAEyiBZ4Y0WSQ4ifhazIAgMVQd95Y2aN1feZmmHhxpEi/wsRL5+HnAQRhZFFjXK8lCm7agGFhLsgegf84N6BnJJYBHzhAEy6/ORl/li3LmRTEgy9fiArRFkl/L5CUjPwvkgdpB4VJoQ5XPPPdewHwrnieI5EgbuKSQOEEokLWCd2FdIGhJFpBXcq0hYfB7KILFs0KCBMw5nnkhDssLvBxUvtk7ce8wVaXkFMOSlxedjTvnt8Ptm3rm/UWcNGjTI+Q8MgsCQDDGPzC2/L+6R8H3h64rCESkiqjheGJgDQn77xfh4roADKnvu4dzK0oZP5zkGjryw+LiNOaIiZC54geTZB0mGSBWkTu4J5psy/GaZY6R0XCtEFwERsejOTan3jIcTonQfeDiEO8UPnQcZCyWqC7/oYPfgy6AmCF8TD2nh6IOvExKGNIXFCRswHiKkQQQQx7NgUQb7CNJY9CB0xEEUffuQO0gifUK6g6QFoubJAeQSwoW4nvp5C4ZIkoe2EO1TN+P39UP4IJTk5+HLwsgDn75yTnwqBBZY3p5ZdHjw02ekj0gAmcsgCAz7IOIJkAVPYLlODA0bNnSuPMJSHWx0PNaJ+cPX1Ms9hDTGxyNRYm6pD/KItI58YO7zRPWIegxbJdS74MtLQLJ+MzbsKyHxSKDC40HaxTWEi5cZ7I4gpqhlIazct3369DGkM0h9yZtb4B5GwkY9Ph9zyksKpA+JIy86/O641yECSEhQu9N34iFh5ENC5uuI0hEJO/aL/B6Rhhekb6NGjXLSNeYCA3kkxb48Kk2kkFzzrOA5AY7YhBFHOqpynktcb2yA5DH/PIsg4mHpW15182zCrQ3SOcgY+X3/uJe4VoguAiJi0Z2b2PQMEsBDniOLTWwGXsiBQqBQF2E8zA4s1IYsCFTHwxdVE7ZuLOCQLtQPHMnP4orNFyoQ1DIQByRPkFXUyhBaFmMMe2kD9RhEiQUJ1Q9toxpGCkF7EFHsa5AgInVk4YYIQ4BZSHgbZ7GjDyyYqE84p38QahZ/dqRRDhsd1EpIZ1hYWFwhBLSLhAwywk457N1II2CATT9KI6CGxXYRzFFrITHipQRiDp4QHfoKMUXFxDi4RtLKoouqHnUw9mEQMwgcc4lKFpLFmMGW+sCNOWNOIXLgQ/2J4wZbSBpYo3oEY3BlHiERqENR4yO95sUFtVyvXr3cxg7wRNJMncwDkjnqIQ9kGPUracUdMDXgngEj+gHOvk36CBaYPDBO1L/gCb6YP4AbZcAZswKkh0iIuJ+Joyx1gTeECjyQ/FGG+iCupHN/UobxI91kbrlHkYwjbSeOeUWtjp0lUk6eX/SbPlAHLxLUSfvcu4wH9S/XzDvX/Ca5pl/8thgLGymoi74xLupk3pkv+sO8Up5nJmPAdhZyzW8Q205+3/SP3wq/QQz2+f1z3xBPoF7GyL3L2CHr9FmhdBAQESsd3NVqCAHe4njA8TBgR14oqQhP06cqFpTJkycb0hEkd9h5+cUKIsuCz1swtiHYxbGFnjd+FioWFHZpYSRPWRYSFlwIEyoW6sIOD4kOJINFG0kobbII8raOaouHOYiycECksOfDmBzpJOSMNOy8MI4mL3WzsLDQYe8EWSQPNkgQQcgbklJ27xGP1BJix2LKQoWqGikp9ogsdEifWJhYpMhfGgGSSPsQWiR5YE0/UHUhVeWcDSwsskj2WPgYNxigzoaIIYFFrYZaHpU30mOkZOAOQWM+wBhpDHOFmpB5ZbGFZNFGOGD7CEaUYb4h6EjQMFQHSwgZalEIN+W4h/jdoY7HiJ35CILAfZWCvqGCZ94hgQVVk1F/YQJjgPhji8l9Dnnx9YA3fQZD7gPIC/cFtqyQFa5R4SIN5x4hD/cmhI25QLLHNfc7LzHgThrjh9SgVqYtsOOeZR5JYw79vEBIUWHyMsLvKAgCAyOkwEjiSaMOyvC7pD3ufZ5zzCk7hCFUkEniIXIQKcgccwPJhjQzTkwjkBAjyaZuxsUcQsKpg5cniBkEnHsEiR6/a/oA0cMsg98lv182KPAcwK4WUgaR48WBnZSk02eF0kFARKx0cFerIQR4cPLgIPD2HkrSaRIEsHMDKx8wNEbVRFakJz6eI6SHow+oWFhg2GjARgl2dqGaoiyBNIga+SFISKeIR22MvRLxGBKzgBFPQFqCVIF4v8ATzwKAeg17psqVK7vNFpQnsO2fPCyIEC4IBn6NWMyIZzyQLzZRYLuHjRht0FeID3UQICTkL40ABoyZfmBn6LGCCLEo0ifGSboPSFXAhQUWySPqS8gXNpDMHeQVm0vys4j6OlG5IZlkoaUtylB/YvBzRHlIM22h/qUfYIy7EHYQ+nIQdu4f8tMu8wwBQ01Pe8TTN0iIL1PcR54BtOsDePo28RXm41El8lJAf3l5QIXK2NjgQN+R7vXKlPb5/GAQxgeVIiYH3OfkgYQxB7TF74M4H3gZIZ508kPO6Cd4EY+K3uflSBxzRJ+4pj9If/019zVtQHxJ55r+0n/mmN8Ncw4x436nPog4/addzvl9UJaABJY8/M4g3vSP3zbXxPMbJZ8PbArx5xz9OMirUIQI5LMqEbF8AqVsQkAICAEhIASEgBAoagRExIoaUdUnBISAEIgnAhq1EBAChUBARKwQoKmIEBACQkAICAEhIASKAgERsaJAUXXEEwGNWggIASEgBITARiIQCyK2KGOJXXp5N2t4wnlJQ9Nm7WzqW9M3EkoVFwJCQAgIASEgBIRAwRAoCBErWM0Ryv333//Y4YfVtlEvDLA3Xx9ipzU5zqruvZe9MOwhGzf6abvwvDMsKBMLKCI0K+qKEBACQkAICAEhEAv2sf1229rxxx1l22+/7QYzvummm9ixDY+0bbbZ2l59fYKNeHGMvfHmVFu58geXl2vCrDmf2Nx5n9vrYybZihXf2Zixk+210RNtydLlLh9//vjjT3vv/VmujjfHvWUrV60mWkEICAEhIAQKhYAKCYH0RyAWRKxChR2t0h675jib5ctvb7vtWsE+nPGx9bmtv83JJF34pqHATz//YsOff9WWLFmWeXzFbr71fhs34W2b89F8e/DhwdarTz/74Ycf7fff/7Cnn33J3ps+y/7+628b+dIYe+iRIVShIASEgBAQAkJACAiBpAiUSRobw8hdKuxkN1zX3varsY/99fffBjkDhm232cqannaCNT7hGKfO/O8/s0bH1bOrr7jIOl97qc2Y+bGNHTfVScsyMpZau4tb2DlnN7FTM9WfEya9Yx/P+4xqFIRAvhBQJiEgBISAEIgXAiJiofneaquyjkjNmj3PPp77mZNyTZg0zY5vdJRtvvlmtllmQFK2a8UKtuWWZZ1KE7Xnim++s88XLLR3pn1ozZpfZqc0vdgeHjDUtt5qK/t66YpQCzoVAkJACAgBISAEhMB6BEqZiK3vSFTOjqh7iKGmfOudD5w9WLV99zakZTn1b7fddslKOrh2TRv9ylNZ4aUXBljtWvtnpetECAgBISAEhIAQEAJhBETEwmhknvNttpNPauikWyNeHG3NzzklMzb5/++/X2VLv15hVfbaw3beeUf7ZP4Ce/+D2VmZJ099z9b8+mvWtU6EgBAQAkKglBFQ80IgYgjEjohh/zX3k8/drsg///xrg+koUyYwJFvbbru1IQ3bbdddsuX5448/7NnhL9v3K3+wQU+PdNKzkxo3sDr/O9BQWV5z/S3Wvdc9zuh/VqaKs0rlStnK60IICAEhIASEgBAQAh6B2BGxZud2sOXLvzUI1SWX3uB2Snow/LFCpnRrv+pV7fRTG/mobMfZH823lhd1sp9++sUeefBW23zzza18ue3tlpuvs2OPOcLmzJlvf/31j7W9uIVhU5atsC6EQMkioNaEgBAQAkIgwgjEjoiFbbg4R5KVOD8Qte2338722nP3xCRDdXnXbV2cHdjNPa+xHcpvn5Vn9912sT69r7VXX3rcSNtxh3JZaToRAkJACAgBISAEhEAiAulHxBJHWIBrnLQOGPiMjX5jklWosJOVK7ddttLLln1j//37r/Mbli1BF0JACAgBISAEhIAQKAQCImIh0GbNmmdPDHrBNttsM6t3xP9sk002yUp98JEh9twLr9maX3+zy6/u4dxbZCXqRAgIASEgBGKLgAYuBDYGARGxEHpdu1xu778zylq3bLbB55Cu6NDSZrz3qs2dNdaeHXK/HXhA9VBJnQoBISAEhIAQEAJCoOAIiIgVHDOVEAKxQeCXX36xDz74wKZOnWq///77unEXz2HZsmX23XffFbjyv/76y7788kv77bffClw2igV+/fVXy8jIsD///LPA3Zs3b579/PPPBS6nAkJACJQeAiJipYe9WhYCkUdg5cqVNmLECHv44YeLbYH/999/7f3337fZs2dbEAT2999/27hx4+zSSy+1Pn362Jo1a7LhBEGBGEJWfMLSpUttwoQJbje0j0vF4/Lly+2JJ56wTTfd1GExduxYa9eund122222YsWGX+l48skn7fvvv88aKqT0scceKxShzapEJ0JACJQoAiJi+YBbWYRAXBHYY489bP/99y9WaRhSsFdffdUOOugg22mnneybb76x/v3728knn2wQkZEjR2aDf/78+fbJJ5/Y7ruv3dWMTeeRRx5pCxYssDFjxmTLm0oXSMKuuuoqO+200wzcGedNN91kLVu2tK+++spGjRpl//zzT9aQIKvly5c3go8Ew+OPP9569+5dbMTZt6WjEBACRYOAiFjR4KhahECRIYCEaNWqVfb11187ArRkyRJbtGiRkwwh8eD6iy++sB9//NH+++8/1y5+8ZAKQUZ8XpeQ+QeJEqq7hQsXugU9M8r9R4VFPYRvv/3WqNslhP6wYQWiE4pybf7www9OHUhZpGb02eehrs8//9wWL15s5CMeAoFEh/4hyWJ8xBMGDRpk2223nSMflvnvnXfecW0cccQRdsEFF9g999yTGbv2P/UhMYKchPvF+RlnnGFdu3Y1cFibO3X+gt/w4cMd6d1rr71cx9966y3bYYcd7KijjrJGjRrZ5MmT3ZyTCIaoco855phsm4rwW1itWjXbdttt7fXXX3c4kl/BnKSV+4ffAmpsMOQ3we8DfPgNcY9yb3JPQ36RvpKG1JFy5CedOB+4t5Fkcm9Thnp8Gup82iGNFwzyksZvjfuU3wlHTAB8/Lr87vdDeeIV0hsBEbH0nt+UGR2kAoKxsR3+9NNPLfFBubF1liDYH0wAABAASURBVHR5FoF7773XzjrrLLf4Pv3003bxxRcbcSzGqKNQV91xxx3OjojF4rnnnnMkpG/fvnbJJZc4VSISFvp+55132q233mq33367kzIRx4I0YMAAu+WWW5z0hHQWANLyCnPnzjXavvvuu61Hjx7Wvn17e/fdd520hgWne/furr0uXboYfaW+jz76yLVF/7p16+bGQjxkAiJWr149LpMGxkcCBA8Sdu2119pWW21FVLZQuXJl23XXXY1xZUtIgQsW6Zdeesnq1q2bY29R2ULYfvrpJ6eGPfjggx1RSyyAg+mqVavaG2+8kUXcEvPE8RqM+/XrZ7Vr13bY9OrVyxo3bux+NxAhSBG/He7tgQMHWtu2bY04bCT5nfBCANEn/uOPP3YQcm8OGzbMqdBRH5933nlOmksiv7EhQ4a4ex3JZocOHey9994jydlc9uzZ0/1OOnXq5PpDAmYAxPM74Tf+4YcfEq2Q5giIiKX5BKfC8HgLnThxYpZ9D6oqyAMPIghGeAw8MHnwXXHFFXb++ecbi/6bb77pHmyUQzLyyiuvZJP8hMunwvk222xjW265pVtE99xzT7vhhhuMBzw2UKihuIaYsXBDtnijBz9UUo8++qhbQEaPHp1lU8TD/eabb3aSJaRGYMCbO8QXMvXQQw/ZSSed5OySSMsrsCihFmRRe+CBB5yT4/vuu8+pFCGK22+/vWGnhH3Xzjvv7KqbNWuWk3jRFgsNKjQSJk2aZMzpbrvtxqUL++67ryHpg3i9/fbbhtqRPMxzgwYNnHsZMCBA5FyhdX9YZBlvqkkSkB5mZGRY5UwyuW4ots8++7iXChZ0Fn4kZRBQ7v8qVao4MgoGV155pX322We+mPuax26ZeFIm1V9KsgZVBCflypWzcpmB3wy/K+7Pzp07G/cwKvBKlSoZL0Fgxu8E9e7WW29tF110kf3vf/8z7nfIGNIv0nh55L7mBYfnEXaUhxxyiCNedBc1OXl4yXnwwQedCpnfJ2SaF5cTTjjB/U7oQ9myZSliQ4cONerid3L55Zeb//24RP1JWwRExNJ2alNnYM8//7zxgNx7771dpwcPHmy77LKLXXPNNcZCDOEggcXq8MMPdw8riAlvjTwwUcHcddddTnWHJIBFHikSD1TKpVqAhLEAcGTBQD2I7RQP6+rVqxtHyNrq1auNhzrEh0UCm6oXXnjBSb54U0f9wdhZtHlbh8wgjSJuxx13NIgYiwTxqL5oi7TcAgvPtGnTjHngKxPUA2GeMWOGoabEnuy1114z5hTp1DnnnOOqw+YJCQ3EGqLFvJEAgUSCwyLINaFGjRpWv359O/XUU10fIW60ifoSooUEoUKFCm6R4pwyPjD/4IJa18elwpH+orZizn1/jz32WAMnMEWS0qpVKydR4X448MADnYQRrCDg1113nSPCtu4f9wT3P3O7Lir2B35TPFeCIDAIE/ccmIIVkqdymSSNe5p7iN9Z3UzpJPc7O1F5AeA+5QUEiezs2bMNGz7ude5z5oi54/dEGdT+qJYhacwRzyR+E2wy4SWD3/NTTz1ltAvJYw6ZoEMPPdQRMeab3zO/FeIV0hsBEbHSmV+1ug4BFvCXX37ZsAfCvoVoCAIL+H777efeViFjSD5at25tPDRZzJGS8NbPQwwVA9cswJTHRgYpAm+5PPSIS+fAGOfMmeOMurEP4609PF5sj1h0mjVr5t7AsY+BGKF+qVixorEI8MbO4hEul+wccgfJow6fzuIGiYAUomJEIgXpYg6ZX/Lx9g9ZfPHFF+24444zFilUbdQVBEE2OycWNNSajGXKlClOOoZtDvZQkAukaJw3yJSOQeSQnNm6f5AUTukPx1QJvr9BEGR1GenujTfeaEhgwBOSgJoM9RlxqNrAGywgXKiFfeEgCBxu3Bs+Tsf1CATBWpzBuE6dOu6Fxqf6e4hrb++VeL+DK/c79y/3MXkJ2ObxcoJElnheCCHZPL/4fSG5pH6kbEi+kIa1adPGvXBQnmcZAZU/qkzue+IV0hsBEbH0nt9Ij46HGG/yLNJIeXxnOUd1xsMMEsaDjTfPmTNnOtsnpEE+L0fUdc2bNzfIBtek8yYJwfMLHPHpGiAikBwM23mwQ67CY2URYEF/5JFHDNUIqi2IKnnI/+yzzxqEBskiiwvxOQUkUSww2Il5bJlHjMqRKEAGUKmhmkSihQoVlTEqH1RrEDEWHiSYLEqexKHCSdYm/aRfSIcg4ZBtCDv3CMSEc+J8WYhiEAROXerjUuGIyhFc6X+y/kK6+C20aNHCJUMQIAMs6kEQOLUyKjeXmPmHucEFBumZl/qfAwJghiTXPzsSs3G/E+dfKDhnjpgvpFoEpFrUQRqB+5X7mfuVHb+exDFn/sUCcoZ92qhRo5w2AMkuRA3iRTxaANrgd81cUu/GB9UQVQTKRLVj6lf6I8BuIUT1kKbwaLFXwn0BKi/IVNOmTQ17F1QLqGTCef05ak0Im79GWsYDkgeij0uVIwsyEg4e4Cy2kCMICYsxD2vGwWJAPnZzQYSQFPHAptz06dOdc1PUeaShjkS6hP0RCwukCKI7aNAg9yYOQWJBoW7ao/5wwIYPOzT6Qx3MBwsMqhnaw/UEUhnmcfLkyYZqmT4j0aROFiD6AuGjPwcccICTgEG0kcaRzsIUbpNz0ukjaiSknMTRPv1FXYQKiHPiSCNABFEVJZJR0qIcIALc38xzYj+Za2yKatasmeWygzFCRplXCC15UEH7shj083vgpcTH6bgWAe5xXuy4d1HlQ1bPPvtsZ5PJPcdLCfc6uVHBo7ZHegxJYn6Qcp1yyinGfcfLBi8DV199tSF5xt6M3xYvI0h+UTHyHEOKjx2lrxcChs0nZK1WrVpudzG/Z8pDuLkXUJHyu6O/9EUhfREQEUvfuY38yJBw8ZAJLyB0GvsgDMKxAUNEjxqNxRpyRXp+AosQD0j8TeUnf5TyoNpjswKkAgLCYoG9HGSUnXLYmrBzi0UB1wYQpYYNGxrSLYzvIUA81HnogwH1QJQoCwnCCJjFBzUXCw12V0gVsUciPowFRKhXr15uMwQuI5A+sasMctSkSRNna0MbkD0WD6RU7FqElHXs2NFJMJk3+gO5Zq5Ry2DjxwKEpAtyCCkPt8s5JBzifdhhh3HpAnY61MOihkEzCxdxLjHzD4TvwgsvdBKxzMuU+Q8uzFtYsuI7z7xDuFGh+fkBU6Qo7MYDT4z2eRmhDIQcVwuo7fkdEKewHgGeObwsQJYgZBjVow7nWcMzafz48c5tCiUgsvweIUX8hlCHc0+CO/cdtmTcp7wkId3nN4nqmLIQODYTcU9iV8a8HH300c5RLy8okDdeJNgJjOQLiTLPOX5nzCXqaPIg2aQ+hfRFQEQsfec28iNjcaaTiQ8aFhtUXaitsLlgceeahySqBMrkFSAHQRA430F55Y1aOmpWHtTggy3QueeeaxAgrnngY3vFA58HO2o/yBRkCRUkuyOxl8NdxGWXXeZUVtiP8ZbOGz22YKg8IGS8wVN/RkaG21EJ3olYtG7d2pCusEAg7WKxYCcXdmhsnmB7P/ZckCnKsoigxoEcIrE6/fTT3S4+SB6SGyRfxLPjlXnHRuf66693RuiMjzp8YNwsZsylj+MIMUPSgOSPc+IISOhYUFF9cp1KgY0IkFOkuEi3wn2H9EK8wcvHgwmLOpIy1MRIkfndkI5UB3V106ZNnT8x4hTWIwB2vNxwj3LkpQH877//fucOhvsQia8vgdQKiRi2q/yWeCniN0R6EATGSxDzxssEZM6ncW8zp5Bi0nhZ4TlGOTag4GqH3x/2kpDmIAjciwtSTtpi5zMvSeRXSG8ERMTSZn5TbyBIYeg1ajWOOQWIGFIy1DFIQVBvhfOiBuOhihjfx0NSiPcPRR+vY/QQQM3DQgiBY84K00OIK6QE2zPqKkwdpV0GNS2EFju6RDJWkL7hEJcdsPxmClIuDnmRLDLO/L7QkVdBCBQ3AiJixY2w6s8RASQ5QRAYkpocM61L4K0T0T+qN1wxoMKBbGHnwcKDmi28iPPA5Y2Ut911VegQUQQgTjivRbqHxKyg3YSYYzPG1n/UdwUtH5X8vHCwUw4V7+zZs5N+6SCvviIl5L5H4oh0MK/8cUpH+sWGFZ4TqHWR5sZp/MUyVlVaJAiIiBUJjKqkMAig5kKVhcoqr/JItrBtwj4KFRSqGGzHzjzzTEfksJXCnsPXg7oNlxgs8j5Ox2giEASB2/HK7lmkngXtJcQD+zeM2cPqu4LWE4X83K/c2/idKsxYsLtDZQmZi8J4otQHdiNiiA/Zx5krxvZR6p/6El8ERMTiO/eRGDk2TdgM5aWepLMYx2LczQ4kDNCxr8DbOk4ZUXMGwVrfQOyUJA1bqsIsZrSlUPIIML+Fma8gCJxxPrY/xdzrEqkeWy+kY0Gw9n4uSKPspKR8QcrEJS/2phB9AnaO3G9xGbvGGW0EykS7e+pduiPAtv327dsbhIpdfkUxXtRUGKPj7LIo6lMdQkAICAEhIASKCwERseJCNh3qLaExYKTMjj1UjhvbJLuasB3DADysqtzYelVeCAgBISAEhEBxICAiVhyoqs4CIQBhwq4FKVaBCibJzHfdsA3D/ixJsqKEgBAQAkIgwgjEsWsiYnGc9QiOGbuWorDZwLamMHZGEYREXRICQkAICIEYICAiFoNJ1hCFgBCIKgLqlxAQAnFHQEQs7neAxi8EhIAQEAJCQAiUGgIiYqUGfTwb1qiFgBAQAkJACAiB9QiIiK3HQmdCQAgIASEgBIRAeiEQ+dGIiEV+itRBISAEhIAQEAJCIF0REBFL15nVuISAEIgnAhq1EBACKYWAiFhKTZc6KwSEgBAQAkJACKQTAiJi6TSb8RyLRi0EhIAQEAJCIGUREBFL2alTx4WAEBACQkAICIGSR6BoWxQRK1o8VZsQEAJCQAgIASEgBPKNgIhYvqFSRiEgBIRAPBHQqIWAECg+BETEig9b1SwEhIAQEAJCQAgIgVwREBHLFR4lxhMBjVoICAEhIASEQMkgICJWMjirFSEgBISAEBACQkAIbICAI2IbxCpCCAgBISAEhIAQEAJCoNgRKFYidtJJJ9n++++vIAx0D+ge0D2geyB8D+g8Re6HNWvWFDsRiXsDxUrExowZY5988omCMNA9oHtA94DuAd0DKXgPbL311nHnScU+/mIlYsXeezUgBFIFAfVTCAgBISAEhEASBETEkoCiKCEgBISAEBACQkAIlAQCxUXESqLvakMICAEhIASEgBAQAimNgIhYSk+fOi8EhIAQEAJrEdBfIZCaCIiIpea8qddCQAgIASEgBIRAGiAgIpYGk6ghxBMBjVoICAEhIARSHwERsdSfQ41ACAgBISAEhIAQSFEEUoiIpSjC6rYQEAJCQAgIASEgBHJAQEQsB2AULQSEgBAQAjFHQMMXAiWAgIhYCYCsJoSAEBACQkAICAEhkAyVMiPFAAAQAElEQVQBEbFkqChOCMQTAY1aCAgBISAEShgBEbESBlzNCQEhIASEgBAQAkLAIxBvIuZR0FEICAEhIASEgBAQAqWAgIhYKYCuJoWAEBACQiCeCGjUQiARARGxRER0LQSEgBAQAkJACAiBEkJARKyEgFYzQiCeCGjUQkAICAEhkBsCImK5oaM0ISAEhIAQSEsEVq9ebW+//XaJj+25556zH374ocja/eWXX+z111+3Bx54wL799tsiq1cVlRwCImJFjLWqEwJCQAgIgeJD4N1337VmzZpZpUqVbO+997YuXbrYe++9Z++8806+G/3uu+/spZdest12280qVKjgwkEHHbRBHb1793Zp5Dn88MPtlltuybomjvDvv//a/PnzjXSuCXXq1LHp06cn7U+9evXsvvvuKxBpevzxx61u3bqu7UMPPdSGDx9uEydOtIULF9qff/5pn3/+uY0aNcogZUkbVWSkERARi/T0qHNCQAgIASEAAj///LPdeOON1qJFC7vwwgtt3rx5jog0btzYkbGpU6faf//9R9ZcA3mef/55K1eunCNy33zzjXXv3t1WrFhhPXv2zEaQuH7rrbesSpUqTupEPkjPzjvvbA0aNHB9KFOmjO233342evRoq1q1qu20007uHGKWrCN77LGHnXDCCdavXz9DKpcsD3EQvAULFtj//vc/e+211+yxxx6zZcuW2fjx4+2nn36ym266yVauXGk77LCDHXnkkUZ+yimkHgIiYqk3Z+qxEBACQiBWCPzxxx+GVGjYsGH24osv2umnn27bbbedwwBCdP/99zsJ2a+//urilixZYuR96KGH7M0337Qff/zRxfMHIvXKK6/YUUcdxaUFQWBNmza1Vq1a2ddff511dImZf6pXr25bbbWVI1iW+Q8Ct8022xhh8803z4xZ+3/HHXd0+ZDUIRVbG5v8L3XSJyR5yXOY60unTp1cnQMHDjQkdptuuqltv/321rp1a2vfvr2F28+pHsVHHwERsejPkXooBIRAGAGdxw4BJEGQJ9RyhxxyyAbj33///Q3JGMRk+fLlTrIF0dlss83s9ttvt9tuuy2LjN1888221157GVKtcEW1a9e2vn372uzZs52E7Pvvvw8nF+l5+fLlnSQL9WhOkizs11DDXnbZZRv0lXE2adLE9tlnnyLtlyorHQRExEoHd7UqBISAEBAC+UQA43akXMccc0zSEhAuVIIcIVMcL7nkEiNg5zV06FBDdUnhF154wVAPch4OqBiRkmFMjyoQO641a9aEs2Q7R+IGEUL65QNqzHAmyFTFihWd6vCTTz7JSkKyRfyHH36YTaV466232i677GIjRoywxYsX26pVq+zUU0/NKhc+2WGHHWzrrbcOR2Wd33vvvc6erFGjRoY0MStBJ5FEQEQsktOSrVO6EAJCQAgIgUwEcpIeZSZl/UdNic0WZMeTK9R5SLo++ugj++eff6xatWpZ+cMnQRDY0UcfbQ8++KA9/fTTNnLkSJc/nMefY6v2xRdfOJsydisS6tev75PdzkiM+JHQXXrppa6urMTME1SZkC1s1pDeXXPNNfbVV185OzA2I9i6f/R33Wm+DqhXy5Ur5/oFqUMimK+CylRqCIiIlRr0algICAEhIATyg8C2227rJDzvv/9+ntkhNpCicEbKQ8zCcbmdn3zyydahQwen0hw7dmxuWXNM22KLLQxbriAIXN8x0M8p8+TJk23RokXO6B9XFORDYoYd3IQJE7jMd9h9992tTZs2Lv8ZZ5xhv//+uzsv2B/lLkkERMRKEm21JQSEgBAQAgVGAAP4448/3iZNmmTTpk3boDy7D2fNmmW//fabHXHEETZjxgwL23htueWWbocktmEQtYyMjA3qCEdA3DCGp80rr7wynJTvcwz8UZGee+65bocjLjPChVEZQrSIQ6WJlA7yhU0Y10jmDjjgALvrrrsMqRr5wgFVJ+4rwnGJ50jcLrjggsRoXUcMARGxiE2IuiMEhEDJI6AWo41A2bJlrWPHjobqD2lVv379zBObjz/+2DkzReJFPogLJAUbLsjO4MGDDenUscce63YcNmjQwKkAwyPG/xaG8RA6H49BPXWxW9HHccReDfcRED2/S5N4+oNNGZItXGEQR2DnJmQMVWdYUscGBFSoqE8p27x5cyNfu3bt7IMPPnAuMx555BEnKTvrrLPsjTfecESTOrFjg5RiJ8Y1hIy6cfHBNQHXF2xioA2uFaKLgIhYdOdGPRMCQkAICIF1CECMcGExYMAA50sLYlW3bl3DEB97rQMPPNC5osCn1pNPPul8eeFYFTst8vhdktdee61zgIojVKpGegYBgticcsopRGUFJGlPPfWUNWzY0MWNGTPG2ZBB+iBcqBuxW4P0oIaEiEH6OJ85c6YrwyaC0047zWrVqmWbbLKJi4MwIeXCDQdEbNdddzXIWxAEzkEr0rQgCIwxUQ87QnEme9hhh9lJJ51kEEYkXeXKlXO7PNkVSj3EQT4hZag79913XyPvX3/95drVn2giICIWzXkp5l6peiEgBIRA6iGA7y5IE7sakYThh+vOO+/M5sYhCAJDpQhpIg9SLU/CGDFEBikXEjCucZhKPh+ICwfITo8ePVwUZX0+f4QAQXiw7fJxSK/w2g8BxPAf1xu0iYE+FWFQj/qTfgZB4JzDjho1ym0SQJ0Y3imJzRftswOT+hkXxv9sQKAu3G4Q7wO7SyFtEDH60adPH4MgklchmgiIiEVzXtQrISAEhIAQKAYEIE4YsyNpQgpVDE24KrEPQxqG3Rf+z8LSNggkZGvPPfd0eXHL0bJlSyMvLiwgXy6hEH/KZqpxsS/DUJ/6UGtCJgtRVdEWUW05IiAiliM0ShACQkAICIF0RADbqTPPPNMZ9RfX+JB+oVLEFQV2ab4dbMUgXqgZvaoSFSg+zMjryZnPX9AjPtKoxwfs6gpah/KXLAIiYiWLt1oTAkIgHgholBFGAKkYOyjxTl/S3bzwwgudIT59KOm21V40ERARi+a8qFdCQAgIASEgBIRADBAQEYvBJJfIEHNoZNy4ccZ2bHYRYcyamO2dd95x6VdccYXhBygxPdk1277ZEv7pp59ukDx+/HjDkJX2Xn31VcNnUDgTBrqkX3755U4tkZgezpuu53///bdh+Nu+fXs7++yzrX///m7Hlh8vu8CYi+uuu87OOecc5xpg5cqVPnmDI3Y2fFaGnWu9evUyDJE3yJQZ8fnnn7tv+Z1//vmW7F7IzBKL/7g94PM54MUcJDopJf2OO+4w0rt3724YX+cGDPnJB67PP//8BlnZDdi2bVvn/gG3DhtkUETaIiBnrqkxtSJiqTFPKdlLnBLyfTf8/kB4WrVqZRkZGVljwWP1eeedZxipYjPBYsGikpUhyQk+fCZOnGhPPPGELV26NFsOSB1t0h5ifwxy+QSJzwQpZLFii/dxxx1nLILffPONT47Nkd1VGARjwMvOq86dO1vXrl2zPooMruy6Yss++fgw8U033ZSVnggU2/sxCsZtAD6bILnhPHyihW/ngTu2MDfccIPheiCcJ07n4A3RRTXGPYlR9ZQpU7Ig4B7F4JqPU0NqMfLOiYzhzwr1Gq4dOnXqZP369bOBAwdm1cVuPTzEX3zxxXbwwQc7crd69eqsdJ2kNwLsGOW3na7PuXSZvTLpMhCNI3oIbL755sbW6aZNm1q3bt2MhQf/NvSUBwOLO9IpjFSRzOyzzz6WuIiTNxxYcDB8rVChwgbSLtrr2bOn4ZuHh8/ee++d5fSRdpHWXHTRRc4pJIa6ODq86qqrwtXH4nzVqlU2aNAgQ+qCXya+RTd9+nTzpJU0SBo+ktiWj7Rr9OjR9uGHH26Aj/eFhN0LHsgh0xC5cEYIN76f2MaP13C28UPIwnnico70kN/DkCFDHP5IcHEm+sILLzgIOLKbDxzBHmkl3x8EP5ch4Q/+o5AQ81KBG4Ybb7zRrr/+eucElHjOScPfFi9C+KuCsCVUo8s0RQCHs7j3wEM/v3ek0t5/WpoOOSWHJSKWktOWGp0+/PDDXUchXWzXZvdOzZo1XRxSGeJxdOgiMv/Uq1fPWIhyU4NlZsvxP1vEkYRRL+3xqRPf3rx589xnQpAu+ApIf/HFF7N9CsWnpfMRaSAfA/ZjPPHEEw0JDESWOKSYOKVk+z3XbKVnJxZOK1FbEucDCzs70FCB8FHljIwMw2GmT8fjNySce2HOnDkG8WMufHrcjkgOw/d8lSpVDJKEZBIsUBkHQWBbb701l4avKSReYLtmzRoX5//8+OOPBsnlnvb5wRmHnhMmTHDEGekXO/d8mYYNG9rIkSMNMu7jdEx/BNA0QNLZSYm0Gye23CfpP/LUGKGIWGrMU0r3ElsXHBKysPuFHLKEJAApmB8cTheDIMjRxsjny+tIe9jMQMp8XiRieLOuWrWqjzJ8/ATBxreXVWGKniDBQsroscFpJipg1F4MCRzx9E0cakbiwoE37GeeecaQuEAAIBs+na36SGaqV6/uyAXp2APKVmktQjja5HeARJgYCBUYo5LkmgBJg+iSl2sfeGFhjpCc+TgkxZQHcwLfXkQy7NMh4PwG+f35OB1TEwG+GMBvCXKVU8BJLGYhfoS8AKOlaN26tbPXhKj7NB1LDwERsdLDPjYtY8+FfRCLcr9+/bKN20thskWuuyjsgc+bQAqGDx9uGEWH6ymO9sL1p+I5nrpRCUO26D9EFqkYXrlZ1LFj+uyzz5z3csg0ecKBOMqgAoHEoW5mkSAP9mVI1Jo3b+7sk5iPuXPnGt/KIz3uAYks2KOuBQtw5IWB3wlHNpegvsRLOy8q5EkMfG4nMS58rXs+jEb6nEPAkW6hts4pIO0OgmCDQaMp4AsF22233QZpiih5BETESh7z2LWI+oUHBkbJ2LwAAKovFhBsGLgm8NbP2xvfRUO9hdqLgONDVI3kyU+oXLmy9e7d23hLfPjhh12RnNojEbUcx7gFpCXsXrz66qstLDXB4zcG9ffee69BoLArQZJSo0aNpBAFQWCQOFRgkDcIxLRp01xepD3VqlUzyFoQBAahwDYP2zKXIaZ/ILiobZEesmEFqSNQ8G1Bdvtij8f9ywYUsEI9GQTZF1QIFriGf0PMaRAETtXMfY3D0GTp/B5oTyF1EeD5iS0njmNzCt4Wk/uL3zD2iR999JHxkgqRIz51ESiWnpdKpSJipQJ7PBtlVx0LDaOvVauWsQhhBM61d6mAUSnSAXY8IkEjQAhYzMlXkIDtDXVRhnYhARAFrmkPsgApQG1GXJwCZAlbLXCBuIbHDqliEwPkFykXD252tuZnDiDO7M7jSJ28kbMRADUa14QgCCyxTeLjElANYoCPjRefokkcN5jhcoJ7nw0UqC3ZCZyYD7s9DPSRaKIeJh0bMwga9fICw+YWJJqk8YJDvcx5mHiTppC+CCCR5nnKJpxhw4YZ85++o03NkYmIpea8Rb7X2LOgJgwLZAAAEABJREFUksRGAduiL7/80ni7Z+cinWchZoFBVYU9DIs1BslIzHjLR3TeqFEjI7CrcocddqCYCywo1M+WfiRoRHKNGwVUYRgiL1q0yPnKwlCcdD4bQnvs3MMm6oMPPjB2p9E+6XEKSKnYFIHaC6Nd5ohdfCzSEFSIAhgxf6jNMO6HiHkpCnkhaNgnYXMCUUYVCbnjI8fYmrERAkxRU5YtW9YeeeQR9+FhVJ5IaJgL0uMY2LQwePBgAzNIFOpJbOy4n8EDux0klfhxg0ixqxWjfdK4r3Fv4X2PsQMSsobtHXZfjz32mJFeu3Ztp0pG/fTAAw8Y9mK4dkEtzC5Y6nJBf9IaAaTbEHqec0is+S2m9YBTdHAiYik6cVHvdhAExkOfRQHpFw9/3sogVfQdssXW+pNOOsntGuvYsaPhzoI3edJzC4cccoghrUFq4xf0IAgMA3AIA+2xeHGOfzLqoj0WLVQ8kARcLaB+a9CgAcmxCuCMkS/jx3aPOWJzAwQXdQdkmd11EOO7777b+VsL25IsXrzYZs+ebey6CoLAcK6L9BGpDaoxfBdBIACVt2/IGSQPMgwpgISEN2mQLy4BKSz3HK4EcFEB9rj+gIzxsgEhQ/IIRqgsmSsM8D0+kLTJkycbR+L4LfACgs8xdh0j4cW+jAUXyVivXr2MnZRIx5hjFmTuf8oqpD8CzDXPQGw303+0qTtCEbHUnbtI9xz1Fg99JFWoYR599FFjMQjbJCBhYTclkgAkVPj/CqfnNEAkbJAGJDs4CiUf7UH2kMpQH5IByEG4vs0339z5MyMdGxx8iWFDQ/k4BeYFqRSB+SEwR/gNAwcWdVxVQJqQTELOiPcBcoCKA+NxVMlIO1GzIXGBXHi7FPIHQWCoz5DYoJ5EEoe7iyDIbu9E3jgE1PNghT0kuPuASwl2TELM2OGLh3wkGNzXYVxQ+yJB9nMVBIFxjnQTyRhzBwnzZfiN4ZQXCSckELVnEMQTe49JnI7h51+cxp1qYxURS7UZU3+FgBAQAkJACAiBFEEg726KiOWNkXIIASEgBISAEBACQqBYEBARKxZYVakQEAJCIJ4IaNRCQAgUDAERsYLhpdxCQAgIASGQBgiwQ9hveijJ4bC7FRvXomoTn3R8wgjbV+/GpKjqVj0lg4CIWMngrFbSFgENTAgIgZJEgM0KuFzBWTObgKZMmeLccxCf336wUQUXILgSwWUOgS9ysKkhXAcud0gj4LaFDQ9sYuHaB1zosBGFdB+Hzy5choTr8uf4envzzTeNPvi4vI70EzcU1M+OWlyfsHsZIsnmD9LYRZ7Y/7zqVXo0EBARi8Y8qBdCQAgIASGQBwIvv/yy4XIF/3XlypUznJWyW5QvcfBFgjyKZyVDhtgZzE5uHOOy6/Saa64xXH9kZco84TufSM4gQOxG5ZqAixZ2Dnv/brjHIR2ShuscdqsSMqvY4D++vSBPfOYrLwkW7mD4WHfv3r0Nv304SsYVBY6pcT8DGeOar15AyjZoTBEpgUCBiVhKjEqdFAJCQAgIgbRCAOe3HTt2NPyude7c2X27FFLDNZ/iwp0Nvu3yGjQOi5Gm4V8NVyu4scHtx7HHHmsDBw403H34OnDPwifAIGt8cgp3LrTHVzogP3y2LQgCw88e6ZUqVTLK4EiXzw75esJH/LvhTxFnyki2wmnhc1yc4JAax8q4+cE5Mn4T6S/f0sVnHFI16sMHXbiszlMLARGx1Jov9VYICAEhEDcE7LvvvjMc1+60006GY2ikTUGw1h8aRAQSxRcgsL2CjKGqww8bPuvOOuss44sOSLYAjq9rcA6R4ppAfU2bNjUITp8+fQzHutRFGr4GgyAw75MrCAILgvXB1v0jPQgCl49zy+UfPviQoqGiRLWZLCtSOlSwqBz5UoL35xcEgUG8IGQ4SU5WVnGphYCIWGrNl3orBISAEIgdAitWrHBfzuBLHMkGj4oQZ7eo6VBf4hD38ccfN8gMX3FAqsWXPih7zz33GHk5DwcIHRKodu3aGV8kQALnyVg4nz/nSx4DBgww1JY+YDDv0zlis4W6EmKIQT1xBCRxSNn41i4SOpz44oSaeihDHuzCsHtD0sZ1YuCrFahmE+O5xkE2dQ0fPtww5idOIboIiIhFd27Us7gioHELASGQDQEIEfZSqASzJSS5wKaKr2pAdLDn6tKli2GThVE/NlWQpcqVK1uyf9h5IRHjU2g9e/a0jz76KFk2F8eXEOgP7fhAeZeY+YevJkC0IEuzZ882/xWQzCT3H6kY9m0QsVdeecWpN/nCBTZwZEDtiA1ZlSpVuMx3gNTxJQv6hKqVrzbku7AylgoCImKlArsaFQJCQAgIgfwigFoO9SFEKq8yixYtcqpDnw8yhioPY3cIWRAEBony6YlH8l933XW21157GZ/sWrVqVWIWd006NmqoCH2AXLnEzD+QKG/ThV0Z/c+MzvqPBA5ySQSftsKu7LbbbnNSPCSAkDrGjeSNPPkNqG+xpaNPqHH59Fh+yypf6SAQBSJWOiNXq0JACAgBIZASCCB54pulqAshU4mdxubr559/dmo4iBQ7IpGi+XyQoPLlyxsqQWyyMIT3acmOSJMgRZChDh06JMuSZxztEdjhic0ZpC1cCEkYRIs4+hUEgRFXsWJFI9SpU8eQhuEWA7s38oUDEjdP5MLx2KeVLVvWRTHWZGpYl6g/kUFARCwyU6GOCAEhIASEQDIEkPIg3SENNxN8tB/VHdcY8qOKw6YK8oVqcvr06YYkCPsobMP4eHq9evVs3333NQzc58yZQ9GsQDn8foUJD4b+kLFZs2Zl5eMEEkc+SBDliCPQH64hipAk4gjseqRvd9xxRzbfYUjaIFpBEJDNhcmTJxv5uTj00EPtkksuMezLHnnkEVu4cKFBOEljtyUuLOgz17iuoH2kcFwTfvjhB2MnKdI4rhWii4CIWHTnRj0TAkJACAiBdQgcffTRzjAelR5kC7Uf9lQPPfSQIfk56KCDDEkQ6kQM3PHnxY5J7KQw1setBFW1b9/ekRrOCaj+iMOlRcuWLYnKCg0aNDBIEBI5IvE/RruQosmZpIn8tI1tF7sbIX2EK664wiBLlME3Wa9evYzdl0jtiIPIoWZt2LCh22VJHHWjPmUHKNdIyS6//HLr27ev4ViWPjKuyy67zLA9q1q1qlOffvrpp9a9e3fXHvkhY5DESZMmGWTOS92oUyGaCIiIRXNe1CshUKQIqDIhkOoIQGTq169v999/vzN8R1LEjkTsuY4//nhn7M4YUQdCTF544QXDWz6E7OSTTzbcRZAOKYOsQKa4rlatmuFclZ2Gzz77LFHZAsSIHY1E4gAWz/YZGRk2b948Gzp0qLNHwyCf3ZgY30PK7rvvPid9o4wPEEhvQ4YEC2kdLjNQJVIfKkxPzHCxQTls2XCpgad++sh4kNJBxmrVqmWQLHaFjh071qiDMTNOxoJEDLcXfH1g+fLlVKcQUQRExCI6MeqWEBACQkAIZEcgCALD3gs7MAzwIV24rICkhXNCevC8Tx7SITs+HUkTEit8eCGZgsyQzwefzx+DYL1xP/X6fP5IPtr3fSKetiFq2IVBhpDKsRvT94NdlBBAyBTlcZmBKwwIJflPOOEEol2gDISMsfq6GUMQrFVpJvZ//PjxhnQOkopdHWpRPPK7yvQnkgiUiWSvNrpTqkAICAEhIASEQHIEUHOiboSkJM+x8bGQLD67BOnCGa2vEdUltl7nnXeeI5XEQwrJ5wMkjfjCBMicr4cjErHC1KMyJYeAiFjJYa2WhIAQEAJCIAII4AAWqROfJCqy7uSzIiR0fAWAzyLls4iypTkCImJpPsEanhAQAkJACGyIAIb9paGyw5ksbW/YI8XEFQERsbjOvMYtBDYOAZUWAkJACAiBIkBARKwIQFQVQkAICAEhIASEgBAoDAIiYvlFTfmEgBAQAkJACAgBIVDECIiIFTGgqk4ICAEhIASEQFEgoDrigYCIWDzmWaMUAkJACAgBISAEIoiAiFgEJ0VdEgLxRECjFgJCQAjEDwERsfjNuUYsBISAEBACQkAIRAQBEbFSnAg1LQSEgBAQAkJACMQbARGxeM+/Ri8EhIAQEALxQUAjjSACImIRnBR1SQgIASEgBISAEIgHAiJi8ZhnjVIIxBMBjVoICAEhEHEERMQiPkHqnhAQAkJACAgBIZC+CIiIpdfcajRCQAgIASEgBIRACiEgIpZCk6WuCgEhIASEgBCIFgLqzcYiICK2sQiqvBAQAkJACAgBISAEComAiFghgVMxISAE4omARi0EhIAQKEoERMSKEk3VJQSEgBAQAkJACAiBAiAgIlYAsOKZVaMWAkJACAgBISAEigsBEbHiQlb1CgEhIASEgBAQAgVHIGYlRMRiNuEarhAQAkJACAgBIRAdBETEojMX6okQEALxRECjFgJCIMYIiIjFePI1dCEgBISAEBACQqB0ERARK13849m6Ri0EhIAQEAJCQAg4BETEHAz6IwSEgBAQAkJACKQrAlEel4hYlGdHfRMCQkAICAEhIATSGgERsbSeXg1OCAiBeCKgUQsBIZAqCIiIpcpMqZ9CQAgIASEgBIRA2iEgIpZ2UxrPAWnUQkAICAEhIARSEQERsVScNfVZCAgBISAEhIAQKE0EiqxtEbEig1IVCQEhIASEQKogsGbNGvv0009LvLvTpk2zX375pcja/f33323mzJk2ZswY+/HHH4usXlVUcgiIiJUc1mpJCAgBIZC6CESk5/PmzbMePXpYs2bNrHnz5jZgwAD75JNPbO7cufnu4erVq238+PH2xx9/2Omnn+7CRRddZB9//HG2OgYNGuTSyHPppZfakCFDsq6JI/z333+2ePFia9++fVZa27ZtXZ+yVbbuYrPNNrOnn37afvjhh3UxeR9ee+0169Chg6u/Xbt2NmHCBEe+li1bZr/++qtNmTLF+vfvbytXrsy7MuWIHAIiYpGbEnVICAgBISAEkiEA2TjyyCNtzz33tPvuu88GDhxou+yyi5133nn2+uuvW37+QZzeeOMNJ5U68MADHbk64IAD7LnnnrM+ffpkqwKid8MNN9iSJUuM47nnnmv333+/zZ8/3+W79957LQgCq1SpknXu3Nm+/vprR+Y4r169usuT+KdOnTpWtWpVe/DBB+23335LTM52/fPPP9vxxx9vt956q9H2k08+aTfddJN9+OGHBtlbvny5lS9f3g4//HBDMpatsC5SBgERsZSZKnW0hBFQc0JACEQEgX/++ccGDx5sd911l40YMcIuueQSR3623XZba9q0qT388MO2/fbbZxGbn376yUmkUNktWrTISb78UJAaIek6+uijrUyZMq4c0q7zzz/fpk6d6uqGAJG/bNmyBvGj7r333tu22GILq1y5siM/O+64o+20005kc/WQTr59993XCJtssolLS/wTBIEddNBBtmLFCpsxY0Zictb1qlWrnFLBhlEAABAASURBVJTtq6++sueff94aNGhgtAnpu/rqq61NmzYGqQyCwHJqy/QvJRAQEUuJaVInhYAQEALxRQDSAhnZf//9nYQoEYmDDz7YTjzxRCedQuV3zz33GNIj1JaXXXaZDRo0yKnwKHfHHXfYDjvs4Igc1z5AzLp3724jR440ynsy5tOL8kj7kMhXX33V/v3336RVv/322zZp0iTr2LHjBn2FIJ5yyikG+UtaWJEphcB6IpZS3VZnhYAQEAJCIC4IfP/99/bll19ao0aNkg55yy23tCpVqhgE5YknnrAvvvjCqfBQI6LSu/vuu+399993ZSFo1apVc+fhP5tuuqm1aNHC+vbta48//riTwOWm7sPGjPzYifnw0Ucfhat0akokdpDBjIyMrLTNN9/cdt11VyeBg4gxNiRy1OPt1D7//HP79ttvrWnTplnlwid77bWXI5ThOH8OaaWuTp062V9//eWjdYwoAiJiEZ0YdUsICAEhkO4I5Hd8qCYhFNttt12eRZBqHXrooU7lCDGD4KCCZLcihv7sLExGxKgYMobR/o033mi33HKLUYb4ZAEJ2mOPPeYM7zG+JyCx83lXr15t2KINypTG0R6qVZ/GsUKFCo5col5E3Xr77bfbmWeeafXq1SPZ/vzzT2PcSM9cRD7/LF682CB99Adbtn79+uWzpLKVFgIiYqWFvNoVAkJACAiBfCEAocL+KlHilKwwBAYS5NOwn6IshAdiQzzEjGOyQH4kXezKRJLlJVSJeZFqoV6EHPoAkfP5qOeqq66ycuXKOWP6//3vfz7JHYMgyFJLshGADQitWrVy9mzfffeds0ND0vfOO++4/Pn9g6SMzQL06eKLLzZ2Vua3rPKVDgIiYqWDu1qNJQIatBAQAoVBAAP1+vXr27hx4wyVXWId+ATDKB8ShvQJ8hS28YLI7bbbbrbzzjs7A3eITmId4WukUJAjjOrbt28fTsr3OSQN434kUqg7UUWGC//9998G0QrHsZEAiRj9ZJNAjRo13O7KMLH0+ZcuXWrffPONv0x6ZJwnn3xy0jRFRgcBEbHozIV6IgSEgBAQAkkQgNQgncIO7IILLrAXXnjBPDlZuHChDRs2zPnQQtJ188032+zZsw3fWxCzsWPHOtuxY445xtll1a5d2xYsWJCtFdxIoLYMO1qF/GHYT53hzBA8fHeh4gzbkNEf6sGlBDsefRlcVUDCHnnkkaw+kwaJYndluP4333zTHn30UZINNWfPnj0No31svbBxw+8ZiRMnTnR+0LAv45o2aZ9+cU2AqEEoGzZsyKVChBEoViIW4XGra0JACAgBIZBCCCDpwu4JtWHv3r2dL7Hdd9/d+f5C7XfIIYcYqsGzzjrLIGMEJEvPPvusIzeQOIaL6wdspzgnYAeGby+kVkigiPOBXYnDhw937iiIY0clbeJA9pVXXnHxkCGuGzRo4DYEQOiwH3v33XcpYqeeeqqhoqR9T6QgTNhyIa3yRAw7sW222cbVSUEcv1IW0kUe7McYT61atYy6TzrpJKtYsaJNnz7d+VFDbVu3bl3nTwxCCamDzIEJ9SlEFwERsejOjXomBISAEBAC6xAIgsA5b73mmmucF318heFA9amnnjLcV0BWzMz51MJAH7KF1AryBqEKgsDVdOGFFzoCM2vWLHeNChApFySJo4sM/YF4YZRPFCSPdrE1Y/MA57QL4UEKh7qRNLz8o9bkiK8w0pBO4XyWetgNWbZsWYOIBUHgPk+Ek1Ykf/g+8+1RN85m2cWJhIv25syZY926dXNYBEHg7M8gdrQLAUMqN3ToUMvIyHAG/7169TJUlLSrEE0ERMSiOS/qlRAQAkJACBQDApAbPheEyg91XjE04aqE/OAnDLUp57TpEjL/fPDBB3bUUUdlSb+4hsShTiU/PsIysxXqPw5gcd8BOaMu1KJI0gpVmQqVCAIiYiUCsxoRAsWEgKoVAkKgwAigykSNh/SpwIXzWaBy5cqGGwx8mF1xxRVZpbBZQ02JA1rUjyTw7Uzy+cDGAuILE1Bd+no48tWAwtSjMiWHgIhYyWGtloSAEBACQiACCLCbEbswbLlKujvHHnusQQTpQ0m1jcqypNpSOwVHINWIWL5HiJ4c+4B8FyiCjNgMoPtHV18E1bkqsFtYsmSJYQtRlPW6yvVHCAgBIRBTBIIgcMb9JT18pGBBsNZeraTaxtC/T58+xkYC1pSSalft5A+ByBExjBuHDBnivvU1cOBAw6ASh3Rsz83fkMx9FgIneOjd+WYY4bnnnrPEtwLfDukvv/yyoc/n3Af067SJvt3HcUxWF/nQydPu5MmTDX0/cXkF/N+Qny3L1E2b6PjxiUMa57feeqvde++9Wd9Ky6vO0k5nazj2F4mGr2wlJ/6BBx4wPkNCvsS+gh/p7FSC1CamJ17jLwjDVj5lwidHmAOfB/xGjx7t7iXaY2cTTh19Okd8ElEeY1i2wSemkyfdAy8s/Na4/8KB314yPHiQT5gwwZgncMOIOCeMwB9VTE7pijfj9x/GnXN2+vHNxGT4oE7jedG/f3/3iZywCwXy87zkfudD2J9++ilRChuFQOoXxj8Z6s/mzZtbr1693O7OxPsm9UeZuiOIDBHjprjtttsMfynsDEGHzicg2JrLdmMIWn5gZpF4/fXX3ZsO25l32mkn508GHzRsNw7XgQfizz77zFgoyIdRI1t9r7vuOmMHC9fkZ0sxW5TxKTNmzBjbcccdXf2khQPemxE7s4146tSp4aSk5zww8aQMIdx6662N7dl4Y/aLIjiwPZmdNkj4klYSsUjIDp/1gBglLiQQJXDFQPaZZ54x5jW80ENwuQfAkZ1BvMGBe05DhGjjQRrCMGrUKLv88ssd6SI/pI8+vPjii47MP/TQQ8ZOqjD5oy8Y0AZB4Pz7UFfY/w/1xCHMnj3bmA9+YwQWel5MVqxYkXT4EAd2gvFw79evn9uaz72amJnfATvc+O5dYpqu1yPAwgieYE9466237KWXXjI8t6/PtfaMFxU+4cOc8Xtp166dcW+vTTUnOW/ZsqW7n4nr2LGj8YzjXEEIcH+xjrVu3dpY53iRDT+DhVDpIBAJIsaiyVvggw8+aCzELI6IUk877TSDqOCQLtmDPhlkiF6RbB122GHug6g8lG666SbncwYPyZMmTcoqhoM/tiPjyZiAzQCLNRkOP/xwa9CgAacGGaI/5cqVsyZNmthxxx3nHAS6xIQ/kAjKQvpyk+iwyNEWkr4777zTkQR8xvBZjTZt2rg2wQWCxpbmhGYie1m9enXbb7/9shYC31HIF9u3IUsYsEJ6IG3+IcBWc761xthx2IhxK0QL3zq+jsQjc81i5AkXjhohb2CKdItt6Uht+Mgv0gHIPlIE6kEKRD8wbOUzICxYxLMocoxT4IUAnAcMGGAEJLBHHHGEcygZBBuqUFDBQ7AgBHfddZdBItgVFsYMQstvDZV6OF7n2RGAWGFQjQsGsCfwfGnUqJHx28+e29xLBc5MuY95xuyxxx7GwuqfNfirQhrPSw5G2rhV4NuJifXoOn0Q4DfI54xyC7zYhkfM8xapKhsW8I0WTtN5ySMQCSLGgszDBWICGUIqBBRBELhPQOBrBV8qxKHuQpXUuHFjw08Lzv1Qd/HwwYaKxZxtwVtttRXZLQgC92bJws4uFdrg4eclLWxlJrjMmX/8eRBkX4CCIHB1kR4EQWbOnP/jkTkjIyPHN1HahkAgkYGAsrWYeqmRI9JAnPUlexCTJ8qBuSMk9hESy48e+wjUhyzcZ5xxhsOUvEhhiGvatKmBAb572HWExIX0ZKF169bGwwfJQfny5Q1STf3cCzhmbNCggbt/SKdtJKBITKmLBxFqX4gv7SEJhYzj/TpVpI+MoygCvyEkwuBEQC0OTjnt3GJrPZjxcoRakhelcF5eIJCaIZFmfoqij+laB/cczzwMt8GecfIs5CWR88TAc4znAnmRzPM8Yy6457/88ktjwT3vvPOcxJ7fIXOD1AOpcWJduk4PBHip5beYW+CFMzxa7h20N5AwhAzhNJ2XPAJlSr7JDVtEeoH4HHK1YaoZCzKSFtJ4SPGmzZfsUf8hreKbYNj6sCigFmMRJm84QHaQihx44IFOJIvaBEJkFs61/pyFBJLkAzYXiao2PjlBOtIEFi5fmsUHKRY+YXwcR5zs8SaLR2UejOSBIJCWGNhVw+KYGE+fUVvQLh6XE9Ojfo2EBJE4OCDBCoK1pJZFhIdDEKy9ZhzM+3vvvcdpvgJEjoUJIpxYAALPd93atm3rkiBhSG3C9wrlWNS4l1ymmP7h3odsQWpzggApGFIXpDHnnHOOW/h9XkguxACCAZ4+Xse8EeCZgpQrfF/mVgrpL0QaIszLHy85/llJOeriBZU0rhXijQBrCkQdTQHrFmuufqOlf09EgohBYlAb8dDICxIe/KhNsJtCysJiwMOIBxiqLN4CvW1XYl2QMewpOKLC+v777xOzZF2TB5stH5BS8RbqM0Ae0bcTz4doad+nYVOGhAayRRy2NHxugzz77LOPk/gwZogG6QUJ2I9ACBk7n/lg0StI+dLOCxliyzj2f4jUmTPfp7Jly/rTAh+ZS4gYmCQrDHE44YQT3LbxcLqXnIbj4nyOiot7DPV6bjjw+0Oaw2/N39vkZw4wDUASw1wTp5B/BFCjoyrPTwnMG3gW4GU9nB/pWvha5xFEoIS7xHMOAoY9Mmsg5B2BQQl3Q83lgEAkiBgEh4dHfiQRuHLwdkWMCULCDcUOOUSzQbBWnUlasgARwmYMo20kM8nyEFezZk33jTDstgiIcVEJkEagTXagYMfGW0WYREAGkSawSxMJFrYcqLuwf0PNCkljzIUhUSx+2M1ddNFFhnQPOyn6kyoBOzGkViw4EFbsu/LqOzZMqCyRIBIg4ki0fDmkL6hfqBdi4OP9ESKMXRMPH+bGx+u4IQK8VNSvX9/AecPU9TGoeTEUZ/fkN99844zLSb3lllvcd+94keFaIf8IcJ+jFm7YsGGehVD/os7HVk9Y5wlX7DNAwLBDZK1izYw9IBEDIBJEDFE6Omx2uEFYEjEiDtUSBIzFGzUWC6vPx5s3RvKwfvIgXfNpyY6HHnqo+1AsKhiMY5PlySsOES952NWJXUZYlUAfIGCQLR6YU6ZMcd9GQ8pw/fXXGyQNMoHKAFUrR+rygfIYt1PWx/kjtkyQCcTJnCOx82mpcgyCwH0njQUflQr9RhXLQsQ8c83YwRayy9yy65U3OQJG9v5hAgmDjCJh23fffSmaLWCUTzrfovNlyIDNIXZofBiXa+YLNShEkXuRuLgFMIcgs2EiP2PnHuQFBIILtkiJkfqyoYUNGwRI2siRI40NOKiC81NvXPPwPOJlAlxzw4B54sWD56b//ZAfm1meS2GThWnTpjmjf8wAyKMQTwTQ3LAeBcF60494IhHNUUeCiEEm2OHDA6Rv376G7xseNkCG5AqXEdg4QFACmM/9AAAQAElEQVTYFYRxPosmBIYHEm+ELOQs7CzMEDXKEiiDZIpF3tdJPMbw+FWBJHHtA1I1zilDXZwTkLhxjerF14NaAD07/cbokf6QFzsNCACLPWVYoNhEgLQBuzE2J2AgyUO3S5cuxvZ+FizIAGVR1+HqgTbpP30inrqon4BvM4yhefhyHaVAv+kz6lffL7DCTQhzC7FG+kk+FnHyMH+MBwkZY2VewBmpJZJI1IrsgCUghUQiSXn8jSEZoAy4cW9wpE5wx88V+ZA0EI9rE+aQBxPG/NgaIjHDRpHNE6i+KRvHgPoWlSPSrvD4kdzi1woixbzi2oL542WIexn8jj/+eIPYMh/4DvMBuz/Sevbs6TZWhOvV+XoEuEdxScELw/pYM35D2LbyvCOeFxV8DTInzAf3NKpkbF55DvJ74oUWW0yeeUjjkZ5zv1NeQQgIgeghEAkiBlNHf33fffcZDxikH6effrrxAIGkYETN2x9vihA2SBRuBliQIUAdO3Z0H09lIWBxDautWECwoWCLOKTHTwFtouLDVoy3euJ54LHQc44Yl00AnL/77rvujR5bNES8Xbt2NRYf2sNoHpsO0jxRWr16tUE8WIAojyqShyRvr6hGeegiwcG2BuNxHqyMn/HQJosbhs5IGZCYPf30087XGcSR+rANgXCwC5TrKAXmg34ihbrkkkuMsdA/xsyGB8gn7inIx7lfeNh0wZxCiNj9CP64uvDp1BEO1MfcXXvttQZ5Zy4J3DPYOUHQuS9whEse0gjYpaEGR4oK1hCPCy+80JhT8D/33HPDzcTqnI0uYJQ4aAgCkjLueYgBGy24X1FNQrg4534FV0gci74PSG0hzcwv54l163otArxo8pwAv7Uxa//y0sIzht87JJh7loCZA3NF4HeCjSQleHbyfOQ5yTmSdyTIpCkIASEQTQQiQcSABjKEO4NBgwY5D/cQEPyKIRHhIQ9xIh8Epnfv3sabHi4g8MGFTYV/yEO6eEP06smzzz7bkK6wmOAfiTp8QEUIEWLBJg5CxcLCWyf5sXchHlUmixSSFIgFBAAVFmlIrJBkIdVjISIO6RYLEb7M6DdpkDneUHmgYudFPsgZqkrIJlIGpAkQBYgKhvxBEBiSM0gFkkHSkLqhToOYggXlqSsqAXs6drNCFpE+0U/6BmmFxDIXHCFHHgfSCZAuFnzmHtKGWjIIkovSUUMjZUH6iTrMBzZING7c2PnAAk+InU/jiHQVYkB72JMhgaM9HJqy8QOCRlocA2TUvzyEx89vCAP8qlWrGqovpLqTJ092jkSRULP5AnV5uIw/B39ecPy1jskRQI3Lsw4JYjgHanl+/9yb2O1BypCGcy/7wLOlQYMGrhj5+V3wbOSextcbBM8l6k9aI6DBpS4CkSFiQBgEgUFmUEVhC8aR6yDIvhhDukgjT2I66i0M4vEVBmmBCJGPkGyRZQGBkNE+dZHPB5+f9nwcR+JxIcHDDzKBJAwpDnUgMYDE4ZCRhZ72eWuFYCDlQ1JEm+QlcA4JpV4CddMeaQTKE08gDeLJ1mMWQIhe7dq1yRaZEO4vfWZ8dC4IAucElzjmjnxBkH1eg2Dt/JOHsSIBpWyyEASB8xFG3sRAmwTIWmIaceH6mHv6QzxlwmlxO+f+T4Y596OfjyBYjzuYJZvHMG5gS73hOJ1viAC4cy8GwYa/CXD2acxD4j0NxpT3tTJfxBE49/E6CgEhEE0EykSzW4XvFQ99RPPYaGEjVPiaci+JpAqpALYbSNXIjV0Zb6+VK1e2sGQBWzEkeNhzoJ4kb2EDUgvq8QH1XmHrUjkhkLoIqOdCQAgIgfRAoEx6DCP7KFCDQYS8+jB7avFd8fZJ26hqeIMtvpZUsxAQAkJACAgBIZAOCKQlEWNisKdItLcgvjgDKkbUkRCyom5H9QkBISAEhIAQEALph0DaErH0myqNSAgIASEgBDwC2OayWx1zEFzPYH/LbnXMUtht6vPldcT1Df7W2MiD70Lq8u5ZfFlc6RBHGoE2w9fEsRmL/Gys4toHNi4RnxgwL2FzGDvAE9PYBMamMTZmUA+bkPAGwCY0NoNhi0x/+a4yn/xLLF9E16qmhBAQESshoNWMEBACQkAIFA0CkBd2O/fq1ctwdcMuUVzi4OqH3afsps5PSxAadqJC4NiFjl9Bdn6zgx9yxo546oGs4duRHe3Y6bJzmGucH7Ornh3tkDPysmucr7fg15Id9uy0Jz4xsNGK+nGxg31xOJ0y7PLv16+fsfubwHjZ5U0f2VjEDmbIGqQtXFbnqYeAiFjqzZl6LASEQHEgoDpTAgGIB645Hn30UWNjFmQMX4L4V8M2GAkUUrH8DIZNVBkZGYZPRpxKsysd90j4ZYNMeUKHT0d8s1E/n5XCNxvXxx13nAVBYJ07d3Z10CZukHCJBLGjT3wej/jEgB0xrnZoC7dNPp3+sCse8kc9jA2H4Pg7ZActEjHMXzCDYRetL6dj6iIgIpa6c6eeCwEhIARihwAOm3HOfeSRRxquirxfQHbM44+Nz9bxiTiAwQkuRA2HwnwCjS9tEE9ACoYTcZx4Q2yIw7Z4//33N5wVQ4SQfhFPQAoFESKPv8Z9C+e0zdEH8kG0OPq4ZEfabd26tUHEIFjk6dSpk6HmbN++veEAPAgCwz0JxA4nvRAw07+0QkBELK2ms0CDUWYhIASEQMohgKNoCBAqQY6JA8BFUJMmTQw7MQgVeXAs/NBDDxkqRAJlcD3Ep6COOeYYLrOFmjVrGlIoPh2FdApCly1DwsXcuXMNmy8f+JRbOAsqyCVLlrg8ixcvDicZjqyR4uGInDyoPfmaDIQwW8bMC8ggqtfM0w3+o65FPUofqG+DDIqILAIiYpGdGnVMCAgBISAEEhFAcoQULC/JEE69IVKo9/jiAF9g4TNm2G2hDsSoHqe3ifX76wYNGhjqSezOsCOD6Pi0xCNfO8GGy4dEA3qkeKhTSeeTYHylJVwHO/zxe+lVqvieDKfndc5mAsaLLRlSP8gabeZVruTT1WIyBETEkqGiOCEgBISAEIgkAqj7kHahWsytg0i7MMYnP/lQFdaqVctQObLbkm+nejUj6YmB/HxmDRLGJ9fYFEC7ifm4Rp2IpM2HDh06EJ0VkMo1bdrUSeT++usv95WRrMTME2y9kLp5FSc7JDOj8/0f1eWBBx5ofOIPdSt2dBDNfFegjKWKgIhYqcKvxoWAEEhnBDS2okcAg3mkYnxKDhcWubUAWVu1alVWFlR7XHhyxnluwdtwQXAwmse9BSQntzLJ0nAuXr16dWNH5R133GE5EUBswvbee2/DNUZByBj9RELIuAh77LGH5SbtS9ZHxZUeAiJipYe9WhYCQkAICIECIlCjRg3Dbuvll182VIBenQcpQ+VI3Ntvv23sgtxrr70MNxBIslDfYZ+FirJq1aqGDdaiRYuMcuEukBc1JHZdxCNtQjKGWhNVJ3EE0n1ZJG/E+cA1aRx9HOpL1KJ8hxibMh/PEfcVEKkgCJw7DvqAqwrIGPVA/ujT/Pnz7cEHH6SI6zffUyavi1j3B/uw8uXLG+4x1kXpEHEERMQiPkGp1T31VggIASFQvAhAjHAXgWQMUnLttdca0qpHHnnERowYYRAuHJ0igUJliFF+9+7dDRXj0qVLs4gMasqdd97ZIGO+x9hY4RYDX11sCvBECmKDKwrIGHnx30VeCB8kiY0A2GiRhj+zgQMHGjZaDz/8sCFFIx4XGePGjTPqGDt2LFEuYC8GmTrkkEPc9RFHHGH4D8N1Bm4ybrnlFkPdiI0ZbbRq1cogbrjewLgfm7CJEye6slyTj92VLkJ/UgIBEbGUmCZ1UggIASEgBDwCuHKAGCHtwvkq0i1spPDLBeEhHzZeLVq0MNxZ4MvrsMMOM4gNEjXSkYrh/gLv9lwTKleubDhppW6kaV6VSRrqPtSK7KhEFYgasUePHsYux2bNmhmkjnx77rmn4RIDw/xzzjnHcLxKvA+77LKL2ynprydPnmz16tXLJsFiDP3793duNNgdSpv0n/pQa9I+hA3btUsuucRwz4E08NVXXzUc0kLs3n33Xd9Eeh/TYHQiYmkwiRqCEBACQiBuCEBI2F2IqwoCuxwhUmEcICw+D85XIVM+HaKGPzIkW6jziK9bt65RF+Gggw4yyhPvQ5UqVQx7L4zrIUbk86FatWouG8TJx3GE8CEh22abbYxw9tlnG30lM5I1CBcqS+okjkC7EDpca1AHxKx27drGblHSy5Yta+F26FPbtm0NZ7NI1g4//HDzYyK/QrQREBGL9vyod0JACAiBMAI6L0IEcBuBGpIdkUiUUDMWYfVZVUGSUCcSsBFDvcruTdSfqBaRvmVlLsQJErGXXnrJUKXSBt75kRQWoioVKQUERMRKAXQ1KQSEgBAQAtFAAEkWnyVCOoUBfkn1ih2d3patpNpUO9FEQEQsmvOiXnkEdBQCQkAIFDMC2JyhdgzbhBVzk7b77rtbWFVa3O2p/ugiICIW3blRz4SAEBACQkAICIESRqCkmxMRK2nE1Z4QEAJCQAgIASEgBNYhICK2DggdhIAQEALxRECjFgJCoDQREBErTfTVthAQAkJACAgBIRBrBETEYj398Ry8Ri0EhIAQEAJCICoIiIhFZSbUDyEgBISAEBACQiAdEch1TCJiucKjRCEgBISAEBACQkAIFB8CImLFh61qFgJCQAjEEwGNWggIgXwjICKWb6iUUQgIASEgBISAEBACRYuAiFjR4qna4omARi0EhIAQEAJCoFAIiIgVCjYVEgJCQAgIASEgBITAxiNQOCK28e2qBiEgBISAEBACQkAIxB4BEbHY3wICQAgIASEQfQTUQyGQrgiIiKXrzGpcQkAICAEhIASEQOQREBGL/BSpg/FEQKMWAkJACAiBOCAgIhaHWdYYhYAQEAJCQAgIgUgiEBkiFkl01CkhIASEgBAQAkJACBQjAiJixQiuqhYCQkAICIHIIqCOCYFIICAiFolpUCeEgBAQAkJACAiBOCIgIhbHWdeY44mARi0EhIAQEAKRQ0BELHJTog4JASEgBISAEBACcUEgnYlYXOZQ4xQCQkAICAEhIARSFAERsRSdOHVbCAgBISAEooaA+iMECo6AiFjBMVMJISAEhIAQEAJCQAgUCQIiYkUCoyoRAvFEQKMWAkJACAiBjUNARGzj8FNpISAEhIAQEAJCQAgUGgERsQJBp8xCQAgIASEgBISAECg6BETEig5L1SQEhIAQEAJCoGgRUG1pj4CIWNpPsQYoBISAEBACQkAIRBUBEbGozoz6JQTiiYBGLQRKHIHffvvNfvzxR/v3339LrO2ffvrJfv7550K1Rz9Xr15tn3zyiVFPoSpRocggICIWmalQR4SAEBACQiC/CPz+++82bdo0GzBggN1xxx325JNP2qeffmpffvmlfffdd/mtxr755hsbO3asTZo0ye69915X17Bhw2zNmjVZL3KHGwAAEABJREFUdUB2nnvuOZdGW48++qiFr4l76623XP4XXnghKx/x7733notP/LNixQp7+eWXXfuJaRCtxYsX24gRI+zOO+90/XrzzTdt1apV9v7779tff/1l7777rrVq1co+/PDDxOK6TjEERMRKe8LUvhAQAkJACBQIgR9++MFuvfVW69evn5UtW9YOPvhgq1ChgkGCmjdvnpTcJGvg119/tSuuuMKqVq1qhx12mJUvX94Rus6dO9trr71m//zzjyu2+eab2x577GFjxoyx5cuXW82aNa1SpUo2efJku/HGGy0IAtt1111dXuqCCNI/6t9ll11cfOIf8tWqVcuuvPJKW7lyZbZk6iX+448/NvLst99+BnG7/PLLbeLEibbZZptZ5cqVS1SCl62DuihSBETEihROVSYEhIAQEALFiQDSIiRX48aNsz59+ljLli3txBNPtCZNmjhS9L///c++//77fHVh4MCBtu+++9qBBx5ou+22m7Vp08ZJ2Gjj+uuvt48++sjVA9mrV6+eHX744XbWWWdZ/fr17cgjj7SDDjrIkbCTTjrJ9tlnH5f3kEMOsdNPP90RwzPOOMOqVKni4hP/bLLJJq7dOnXqOKmXT4d8tW7d2o466ig3nsaNGxv1X3DBBXbxxRfb119/bWXKlLFtt93WETIrxD8ViRYCImLRmg/1RggIASEgBHJBYMGCBda/f3879dRTHfkJgsDlDoLANt10U6cWRGJEJETqhhtusGOOOcYgUt26dcuSPi1dutQGDRpkzTMlaOQlBEHgyM3VV19tEKrrrrvOli1bRpILQRA4EmTr/gXB+rbXRblDEASOoAVB4K5z+3PmmWfa6NGj7YsvvrA///zTLrvsMitXrpzrFwTQl4V8NWrUyBFAH6djeiAgIpYe86hRCAEhkCMCSkgnBCZMmGDbbbedI0pIlRLHBomBdKEeRMUIoUKl+MADDxh2VsRRBtsqbK6QanEdDnvuuaf17NnTsENDCoW9Vjg98fzxxx+322+/PSsMHTo0W5a///7b6Dd53njjjWxpSNJ++eUXmz59ukEOOVavXt3oQ7aM6y5atGix7iz7AcL42GOPuT7kZJeWvYSuooKAiFhUZkL9EAJCQAgIgTwRYHfjlltu6aRGuWV+++23bcmSJYbEaauttnK2Vpw/88wzlpGRYRj2YxOWUx0QtPvuu8/mzJljXbt2NezScsqLDReEz4dq1aply0o/5s+f78hjhw4dbNGiRdnSd9xxR1u4cKFhU0YC9mcc8xvY9Qmx3GGHHWz33Xd3Kk3qy2955StdBETEShf/YmldlQoBISAE0hUBpGG4fWC3Y25jZKcjkiavpkR6ttdee7kdh5SHvGyxxRY5VkF+DPhfeeUVQ4p12223GfUlK4AEDjs1HygXzlexYkWnaiS9Ro0ahqF9OJ0+/vHHHwZhJB7SxjG/AWJ6yimnOPu1Cy+80NmuQf7yW175ShcBEbHSxV+tCwEhIASEQAEQgHD8999/hruIsIsJXwVxSK8gJ5CtMKnBCB+7KyRHHFE9+nI5HTGmx6j/1VdfdTsWaTunvDnF0xfScLWBIT/uJ7j2gX5h37b33nvbcccd51xwzJw50xLbYhdnTgQLG7IgCJxtGgSTzQe+/hI4qomNQEBEbCPAU1EhIASEgBAoWQRQ2910002OiGET5VVwkCqM83E7gbTs0EMPdW4munfv7vyKodLEB1fr1q2d+g4XFNiRQdbCIyAOeyvsunz8CSecYG3btrVvv/3WRxnplIUs4Vw1KyHzBCJIWjie3Y6UxwXF1KlTM3Ot/08+pHXE3H///c4+DPcXkE3UlRA13Fdg6wZBIx/xGPcn7hBljLjzYDco+RSij4CIWPTnSD0UAkIgagioP6WGAJIfyFTHjh1txowZds4551jjxo0dUYK44L4C9R/G7jhUhcQ0bdrULrroIkNF2Lt3b9d3yAo+vj777DN3zR9cVkDc2JXZr1+/LKeu22yzjau/devWTuIEWWMH5osvvkgxY5flkCFD3DkkkTTyXHPNNc7xKwn4AyMNv2PYnRFHwF6MMUEcuca+DNs03F7QVySAuMF48MEH3Y5NxorfsYceesjYQdqrVy/DwSxlcX0BycMWjmuF1EBARCw15km9FAJCQAgIgXUIbL311sbuQdxPvPPOO85D/RNPPGHt27d3Li3Iho0Xfr9w8ooT1OHDhxuuLHbaaSeSnUPW888/3zyZIhI7MCROkDOIHu0QT8A27a677nLuI6jjlltucSpEJHF4uT/vvPPIZj169HDe7rFDY/dis2bNXLz/AwlD/eiv6Rt+wpDQ+Tj8muFRHwkY4fnnnzcIF/lQO6Javfvuu52/tFmzZtkll1zi/Ithz4aDWqRneO339ekYbQRExKI9P1HpnfohBISAEIgUAkEQOL9hEBMC3u8hX4mdxPYqp3R2MCJVYschkjOM5slLoFxiXdSP9CoIAudvjHw++PzhOkijDGQPg37CzTffbLVr13ZVIw2DiCFBC4LAxfk/lGNM1EGg/iBYmycIsrePahMnt/gjg+Sh/ixXrpyvSseIIyAiFvEJUveEgBAQAkKgeBBA4gWB4ePZGRkZxfbJIFSFSO4IqEQZDVKrefPmWd++fQ0JG3GFDZS/5557jPoJ2MnhxLaw9UWjXHx6ISIWn7nWSIWAEBACQiABAb4RyWeL8CkWBGslTglZiuUSVxVHH320+7RSsTSgSlMGARGxlJkqdVQICIF0RkBjKz0EkIyVNBHD5oxQeqNWy1FBQEQsKjORBv3Ax81XX33lPtXBFmq2a4eHxVbrzz//3KZNm2YYxLKrKJzOuS8/d+7crB1LxOcWEPFTpw/4EfL52eKNMSv9IZ+P90d2H2EfQn/Ycu7j43TE2JjdZx4/f1y+fPkGfozAhW37uAzgUyyUw3Em8ckC9jd8Qy9ZmuLWIoCdkMfcH9n9xryszZH9L/ZA3K8YgmdkqtOyp669wt4JFw4YhjNPuFJYm6K/QkAIRA0BEbGozUgK92fSpEnGdmt2DbFVnJ08kCCGhANDdi3xrTW2b7dq1crY3cNiQToB2wbS2CHE9vFHHnkkKREgbzjgd4ct54Q+ffoYu5VIZ8HCCBZnjHzWhH6FF64vv/zS7aJ69tlnjR1X4bKUj0tg0cdoGfwIXbp0cbuwmA98JCXiwJyyVZ9v97HrjN1jEN7EfGCNl2/mPDFN1+sRwMUBmIM9gWt+B+EXCp+bbyNyv/JtQ76ZyG+MHX4+nSMvRGPHjjV2AD755JOGV/icPMKTXyE+CPAcjs9oU2ekImKpM1eR7ikPejw+s1sHnzaQI9708ctDx5F0sQOIxeOpp55yBIi3fxYU0hcvXuw+ssunQXBkCEl76aWXDHJHek5hypQphiNEFhwCpAtfQeSHKLD1m23fLEp4t8bfD2n0F+LFZ0V69+5t7GTi23MPP/wwybEKECbmC/wIbIvHgSV+j9ghlggGkk4IAL6OwBPijKPKcD6kZOPGjTOMkcPxOs+OACT43HPPNX4TYE84++yzrUGDBsb3B7PnNiM/u+K4X/EjxW+M30A4Hy8d1IOrA4gdH6/eeeedw1l0HlMEBg0aZDzjIPSxhCCigxYRi+jEpFq3cHjYqlUrO+SQQwxHhCwWOCJEhcJY+HQHC85+++1nnCNJ2WeffdzCQjoqLtSRl112mZUtW9bwo8PiASkgPadAfnYLDR482JXbY489XFaIAVKBCy64wCpUqGDYgBx//PEGMcP7NuoyVJL0edttt3WLXv369Q2Hi66CGP3BUPmII46wypUru4BaCyKFQ8xkMJx22mkGzswPn1FhPtm15fMikZkyZYrLA7Y+XscNETjggAPcNwirVq3qsK+cOQe4IGjYsKEl+8c9Wr16dbfLDuxxlcDc+byzZ892zkUhX3zXkDnyaToKAUwK8I/GSxaSVamso3FPiIhFYx7Sohdh6QkqLcTgnTp1cmMLgsB5pHYXmX+wF0NCdvHFF2demUHCkADgO4eIIAgM79ioVbhOFrDvQvXINu3nnnvOedfGboa8PHCwQfP+eoiDIAZBYBAxbNVQix500EEkueA/CYJdjYuIyZ/wvDFknFPiiRzfRVwnBvKDL1IZFnwkmEgbfT6km3xO5qijjnKewH28jhsiEATZfxf8Dvhd4B1+w9zm8MRGD2edbdq0cSQOT+zk5Td17bXXuhedoUOH4njUIGlIliHH5FEQArxoLV261HgZhqzz7ETKzX0ldEoHARGx0sE97VtlMUYKhcQq2WB5c+ftvlGjRlnJ5M+6yMcJxA1v1nxvjsUGUnXppZdm2YhRRV51atcSKK0PEChUingkXx+74Rnft+N7fKh2kVrOnz/fZaI8PowoL2mYg6RAf5DsovbNrRCkCvtGFk7sLrFvJD9SXlSV/KbwIP/6668bvwlszlA/k0chfRGAXGEWghlGToGXLIiYR4FPQjVv3twg9cOGDcv3BilfXseiQUBErGhwVC0hBBB38+BHLcinOEJJ7hQjenYotmzZMpuUzCUm+cOi37VrV+PtjdC+fXtDmuWzIqFBXdOjRw+DEPBA8mk6FgwBvlOHyphv8OVWEls+VMIQgQ8++CDrMzEDBgxw6mkvXcytDqVlR4D7HFU+3xLMnpL9CkkltnlgzcsM31Pk90BgpyX2fbhi4LeH1APJMPaP2WvRVbohgHkIqu46depYTqFixYpJn7mQM6/qTjdcUmE8ImKpMEsp1kfUK7vvvrvtv//+SXvOYoONQtgGibwY9KPS9IWwG+PtHlUNDxgMmAk8ZLCN8fn8EQIRBIH77AlqSCRmXlVJHkgaDxzqgihgO8YbImkEVJKkI0XgOo4BQ152UOZn7EgbmUcWeyRjqHuRjmHfxJwRkJphIMxHiyEE+ak3rnm4V08//XRjQc0LA1T42OnxUuJ3CXM/Q9LwEu/Le6kkn8fxcTqmJwLlypUzzAEg4jkFnotBEGQBwLPw7bffNkxAjj32WOM3m5Wok3whUBSZRMSKAkXV4RDAhQG2K0i7WKSxO0CF4nfocET1wkID4SGdrfeUwyYGcoRtC7ZluEjAYPy6664z1IeoINnST0B1w9s+ki8WHaQAEAF2YUIiqAeJDg8W+oMEDlcAEyZMMDYRYDdGHjYEjBw50pDg4TMLyU6vXr2SvjG6Aab5Hwg088KGivBQIVDY1YETOCNdwT4PFRlpzB+SmUqVKhm7XCHQbIQgYCzOpg2kZywU4Xp1vh4B7LuQRrLZZX2sGepHfOBxrxOPpBn1I/PAfc9cIEHjfsfg/9BDD7Wnn37a8JlHWfy4+XjKKwgBnqcQNnbWQv75/iXEPgjWEzShVLIIiIiVLN5p2xoki8UWdxV8uw0jfALSEtxasIDgx4s8HEkjXHXVVQbh4k2Nsnwct3fv3oYbCqQD7HTMCTSIFQQNg3F2AGEjg08rn//KK680pGSke1cVbPknHTLI1n76BvlCvXetijwAABAASURBVIN6k/6QHsfAWzFzkjj28ePHG7iAFSSbXVdgi3sQVJNIECG9GOzXrFnT2SURR0ByyY5KdlZynli3rtcigE0l9yQvCGtj1v7FzQruLLi/iYFk4ZuN3wiSRl50+vXrR5LbNcz9z2+JF5g777zT2L2KCpMXF5dpo/+oglRGAJOCu+66y7CpxdcjL8ypPJ506buIWLrMZCmPA5cTqBEhOuzc8gECxOLMW1jz5s0NIubTOLLzDrsFun/yyScbiwfqR6ReLPZBkPNbGm4U8H+FGB6J2plnnplNrYOUgPRmzZoZddMXCAFtERDL4zgWiQKuNSCI9JO0OIZTTz3V7TxNHDuqRnyGoQpD3QuOPMRRETdp0sRwAZKTSgMDYOY5sU5dZ0eAexUcwTecAjkDQ347xJOHFwt+a3Xr1nWuKihLGoEdlNzT7dq1c2oqsGfnJGkKQoDfK89WXo6ERnQQEBGLzlykdE/4gC0PfCRYiQH7FN7IEYcnprG7zg+cfLisYJFBRePtW3x64hGDZFxXoG5E+sKilZiHhQ21GR/XxW4tCLITO5zBQjSOPPJI50sssXycrpEIJiOiEOWDDz7YmGOkWqi/mEfmE2LLvOWEE9hj/5dTuuLXIgDu3IuJWHLNventKTmCPRJIVOzbb7/92gpCfyFm3O/8NpifUJJOY45ATi9MMYel1IcvIlbqU6AOCAEhIASEgBAQAnFFIIGIxRUGjVsICAEhIASEgBAQAiWPgIhYyWOuFoWAEBACQsAjoKMQiDkCImIxvwE0fCEgBISAECgZBHCRw67Xzp07l0yDaiUlEBARS4lpUifTCAENRQgIgQghgN/CiRMnWqdOnYyNO2xC4ZM/uAxhV3d+u4prF77byK5Edn6zoQK3L6NHj7Zbb73VVcPmIXzy4YPPReiPEMhEQEQsEwT9FwJCQAgIgfghgGNc/KzhKJqd1yNGjDA8zfft29dwsjt9+vR8gQIJwz/XkCFDDInXq6++apA7JF843eULHjjgZRcrbmDyVakyxQaB4idisYFSAxUCQkAICIFUQgCHt926dTN8EuIcGokV/efINT4GuSZ8++23dttttxnuQ/Cjx5cQ+HoBaWPHjjWkYVdccYXhNsS73oF04Q8RcsbXKMirIAQSERARS0RE10JACAgBIZDSCOS383ydgK8X4Mw40ccW1xAr6uLLIXyJg890jRkzxvClx1co3nrrLZLt+eefN6RdyXzm4XvvnHPOMfwYusz6IwQSEBARSwBEl0JACAgBIRAPBPjeLSNFLckxMQTBWgfQM2fONL6rimd6nOzy2Sm+5vHMM8/Yf//9Z9TDt1Yhaol1cB0Ea+vhPBwyMjIMezJP7GgjnK7zeCAgIhaPedYo0xoBDU4ICIHCIIDUi3LYeHHMKcyfP98lbbHFFu6I6nLfffc1DO+JoJ5ff/3V2ZVxnd+wYMECZ0v2+uuvu7Jz587Nb1HlSyMERMTSaDI1FCEgBISAEMg/AnyvE4kWxvR5lfrxxx8Ng3vylSlTxpCMbbnllsY/PsmGUX5BJVrYm1EXn7iqWrWqcU59CvFCICWJWLymSKMVAkJACAiB4kCgffv2hjrx3nvvtW+++WaDJp588knDyJ5vrc6ZM8c++eQTlweXF7/99pvxTU8iWrVq5fINHz7cqSqJC4dRo0bZV199FY7Kdo6dGt96rVatWrZ4XcQDARGxeMyzRikEhIAQEAIJCGBAj4sKJF3t2rWzxx9/3LmvYEck5Az1I2rImjVrGjslH330UUONiJsL1JnsrAyCwLAxIz8+w1q2bOl2UE6bNs3efPNN69Wrl7F7cs899zTa+vjjj23GjBnG0e+6RMWJjdmuu+6a0ENdxgEBEbE4zLLGKASEgBAQAkkRgGzhvJWdjRjd44oCyddxxx1nRxxxhCtTvnx5w9dYs2bN7L333rPvv//eOYBFikUG1JRnnHGG4UesXr16hq3XuHHjbNmyZda6dWurU6eO8Y96kZ7Vr1/fPv/8c4OI4fZi4cKFLg+EDFUpeRXig4CIWHzmWiMVAvlHQDmFQIwQQFp1/vnnW8+ePa1Pnz6GyrJWrVrODszDgGQMaRfp+AaDhIVtunBTgfsKypKHulpnkrDKlSv7KpxUjTTCWWed5drDRQYEDp9ls2bNysqrk/ggICIWn7nWSIWAEBACQiBCCOAgdvny5W7n5Pjx4w2iFwTJXV1EqNvqShEjICK2FlD9FQJCQAgIASFQoghssskmTuqGapMQBEGJtq/GooGAiFg05kG9EAJCQAgIgVghoMEKgbUIiIitxUF/hYAQEAJCQAgIASFQ4giIiJU45GpQCMQTAY1aCAgBISAENkRARGxDTBQjBISAEBACQkAICIESQUBErNhgVsVCQAgIASEgBISAEMgdARGx3PFRqhAQAkJACAiB1EBAvUxJBETEUnLa1GkhIASEgBAQAkIgHRAQEUuHWdQYhEA8EdCohYAQEAIpj4CIWMpPoQYgBISAEBACQkAIpCoCImKpNHPqqxAQAkJACAgBIZBWCIiIpdV0ajBCQAgIASEgBIoOAdVU/AiIiBU/xmpBCAgBISAEhIAQEAJJERARSwqLIoWAEIgnAhq1EBACQqBkERARK1m81ZoQEAJCQAgIASEgBLIQEBHLgiKeJxq1EBACQkAICAEhUHoIiIiVHvZqWQgIASEgBIRA3BDQeBMQEBFLAESXQkAICAEhIASEgBAoKQRExEoKabUjBIRAPBHQqIWAEBACuSAgIpYLOEoSAkJACAgBISAEhEBxIiAiVpzoxrNujVoICAEhIASEgBDIJwIiYvkEStmEgBAQAkJACAiBKCKQ2n0SEUvt+VPvhYAQEAJCQAgIgRRGQEQshSdPXRcCQiCeCGjUQkAIpA8CImLpM5caiRAQAkJACAgBIZBiCIiIpdiExbO7GrUQEAJCQAgIgfREQEQsPedVoxICQkAICAEhIAQKi0AJlhMRK0Gw1ZQQEAJCQAgIASEgBMIIiIiF0dC5EBACQiCeCGjUQkAIlBICImKlBLyaFQJCQAgIASEgBISAiJjugXgioFELASEgBISAEIgAAiJiEZgEdUEICAEhIASEgBBIbwRyGp2IWE7IKF4ICAEhIARKFYG///7bvv32W3v//fdt1qxZ9vvvvyftzy+//OLyTJkyxaZOnZo0T7LI1atX26RJk2zcuHFZ5adNm2a//fZbtuwLFiww6vYh8Xr27Nku/8KFC7Pl+/zzz1184p/ly5fbc889Z19//XViUo7Xv/76q3322WdufG+99ZZ98sknxrgzMjIMnMDntNNOs9tvvz3HOpQQTQRExKI5L+qVEBACQiDFEdj47v/zzz+2bNky69atm0EyZsyYsUGl//33nyNSjRs3tq5du9rkyZM3yJMs4scff7QhQ4bY5ptvbgceeKC98cYbdvnll1ujRo3s+eeft7/++iurGKSnT58+dtNNN9nEiRMdCbrjjjvsxBNPtP79+zuSSOYvv/zShg8f7uro0aOHzZ071+gfaeGwyy672L777muDBw+2lStXhpOSnn/11VdGe4888oi99tprrg9vvvmmPfDAA0a/ypQpY7vvvrsxpn///TdpHYqMLgIiYtGdG/VMCAgBIRBrBLbYYgtHkvbff38npRo6dOgGeEA8XnnlFdt5553trLPOMgjQBpmSREBo1qxZY/Xq1bOKFSta586dHdkpX768IzejR4/OKgUJbNGihV1wwQXWu3dvRwrPPfdc22qrraxDhw520UUXubzHH3+89e3b17beems777zzrGnTphYEgSX+gzjVrl3bypUr5+pLTA9f//TTT3bNNdfYF198Ye3atbNbb73VjfHiiy+2WrVqGVI36qtQoYJrN1xW56mBgIhYasyTepkCCKiLQkAIFA8CSHsaNmxogwYNskWLFmVr5J133rEddtjB9thjDytbtqxL++abbxyxQpKGyu7QQw91EijUjmQg/cUXX3QkjGsCZffaay+7+uqrrWbNmnbLLbc4kkNaEAQGKYRg+evNNtvMkSwkasT5sM022xjEaMstt3RHH594JA9SPKRckKzEdH89cOBAmz59urVu3dogpL7dbbfd1k4++WQ744wzfFYdUxSBMinab3VbCAgBISAEYoQA0iWICBIhVJYMHRupO++800nCuPYBKdn333/vVIZTpkxxKjzUjyNGjHBZIHPYaUHgXETCn379+hmSsRtuuMHZqCUkZ7ucPXu2TZ48OVvIliHzAvXq5Mw82HhlXmb933vvvZ1U7dlnn3Vx9Iv+YhPH2Ih86KGHbKeddrKDDjqIyw1Cp06dNogj4o8//rCZM2e6fs2bN48ohYgiUKbw/VJJISAEhIAQEAIlg0DVqlXtnHPOcfZbc+bMcY1iZF+/fn3bbbfd3LX/s+uuuzqbKeI7duxodevWtQMOOMAwpidPRkYGB0Nq5U4S/iAZQ8W5ePFiu+yyy2zVqlUJOdZfQsQgT+GwPnXt2VNPPeVs0Lp06WIQxLWxa/8ifYMwLV261OWBsN11111unNipQeJQgaI+XVsif3+RBKJ+pV9XXXWVzZ8/P38FlavEERARK3HI1aAQEAJCQAgUBoF27drZdtttZ6jzIDRvv/22s9HKqa5EtSFSMIzn2YmJai8x3deD2vDII480pG0YxbMJICcyhsqwZ8+eFg6+Ho602bx5c6fqhCCiAiXeB6RyjIVxQTSp59JLLzXIJjslUXWyWzQ/Rv2+To4QV2zLqO+II45wu0KJV4geAiJi0ZsT9UgICAEhIASSIIC6kN2DSHnuueceO+qoo2z77bdPknPjoyBjGN/jKgLV4dNPP51tJ2V+W4B8QYo++OADa9myZY4G9RCxHXfc0VXLkWuIIkb/kMCCqhfZvADZpEIkfNTHuUL0EBARi96cqEdCwCOgoxCIPQJIsH7++Wf7888/HRZIlyAYECRvN4XEyAcyYUNGfspxTR3E4W8rCAI7+OCDDVXgDz/8QHJWoI7Vq1c7v1w+kp2JqAqx32IHI/HUh9qQI1Ir4nzAtgsbNXyRcSQe2zDcTGCc79WixBO4rlGjBqdZYcWKFUZeVKc33nij4e7iwQcftNmzZ7vdo2Skftxl4MKC3Z/0h/HRPuk+0GfSjzvuOB+lY8QQEBGL2ISoO0JACAgBIbAWAXY33nzzzfbSSy/Zww8/bB9++KFtsskm1qZNGzvhhBPcTkmIDCpEbKBGjhxp5Gcn5fjx452zVq7fffddZ7SOPy6usR3bc889s0gNrWGbdd9999kLL7zg2sInF/GE888/36688kqnFuX61VdfdQ5ZIWEQJGzAiKdN3GBAfIYNG2Yvv/yyQdaqV69u7NLE5QQ+yshLgAjifqJJkyZcujBmzBjD0B63GkQgUXv00UedJI2+Y2fGjs7HHnvM+U/DZQc7KcEIwocrj8cff5yizuErZU899dSsvrsE/YkUAtEiYpGCRp0RAkJlHd7TAAAQAElEQVRACAiB0kQAdxHHHnusQXbat2/vjPKDIHA+uvCphUuJcuXKWatWrRzRYUflMcccY+xGRHWJ3zGuIV2kQbK4rlSpkjPgx1GrH1/lypWdny7cRUCCqNunIYG74oorzBMmJFjsqMQJ7HXXXeckbOSlXey82ETQq1cv5wYjCAKSnGsNJGRHH320u+YPEq5DDjnEUIFyDRmELHLNzkk2CxCPVA7/ZDiUPfPMM406GjRoYPgyg1RCTmvXru0cxLLLkjopd//99xuSMNSU7733nnkJIWkK0UFARCw6c6GeCAEhIASEQAgBDNUbZBIOHyAdJGMr5ncRQsR8OkeIFj7FOCcku8b2CoN4JFjUR6icScTIT/jf//7niBPxPmC3BaHhulq1akY+HyBBxEPEfBxH8vEpoyAInM8xCFLdunXJ6qRxeOHH9oxxct6sWTODcEL8+FSRJ4PYq+HCApUq44GIQc7AgcogYrTVYB1WeO1nt2f37t2tTp06hrNX7Oqol/wK0UJARCxa86HeCAEhIASEQAkgAJG79tprnad67MKKq0mkVqgnCRdeeKEjZNivIaFCxbrPPvu4prF9Y/ck+QioGumjSyzgHwgXqlzqIWD7hgSvgNUoewkhICJWQkCrGSEQDQTUCyEgBDwCSKguueQSw1bLx5XEESKGupT2gyAoiSbVRoQREBGL8OSoa0JACAgBIVC8CLAjsUqVKsXbSELtqCJxaYGRfUKSLmOIQCSIGKJTQm74k+5DbvkS00aPHu0+8+DLckzMQ1xuwedPzOPjw0eMMdmxgz6ercThtLzOc6qfnTnsvsHBoP9WWl51RSndjyunPuWVnqycL8MxMZ04HxLTuM4tjfS4BI8Dx5zGnFtauAz5fAjH+3OfxtHHxfkIDj7khAPpOaUlxpOXkBjPNfE+cK0gBIRAtBAoVSKGd+NnnnnGGRKyEySZ52DIDDs/MFrEZwzbdvMDIaJmdsnwpoNflcMOO8zQm/PxV3yv+DogOWwpZosw3yJjazCiaoxCMZDEKHLIkCEuO7t0MIjEtwt5IXkuIfSHMhh64nMG8hRKSnrKA3Lx4sXWv39/w36AHS6nnHKK88LMdme2U2OIyRsUvmWSVhLRSOaAuWMH0H777ec+povvG99d7CHwrcNOJD5eiz8cRPY+Pacj27+pD4NUwtixY11W7hV2K7FriQ8Ed+jQwZgHl5j5h/uLe8K3R9/YJp6ZFKv/OIe8++673a4xdo/hBgDcwA8guCexmcGJJfc7cbkF792c3ycevNnaH87Py8MFF1xgzEnbtm2dC4JwetzOJ02a5Hb9sfOO5xNG2fxWPA7ck1OnTnUfdMYdgY9PdmTOwBsXBuCLiwX8Y5EXv1k4EeV3wOd9eJHjkzekKRQrAqpcCBQIgVIlYuzkOOmkkwwRLVKk6dOnb9B5Fk8+McG3tvisBdt3N8iUEMFi/sQTT7gtzCzYkCl8q+ChGNIDmVuyZIkr5evFzwpEAH80+F05/fTTXToPObwhc8G2Zj4XwY6cfv36GQ73iE8MfMKC8rSJQWZieviahyYO+2bMmGEdO3a0iRMn2qhRo9w31XhgsyBCQsEIAhguG/VzvnUGYQU3xgix9AsLhAwniSzi+OCBiLK7CAPV3MbFgvXxxx8bPnQGDx7stmuzU4gyLPj4+2HXERiicoA8s2UbY1XIBwsc7bEdnrbwO0TZOAXmhXuUe525YTGHDPjfBEQM55BgzedZcsMGX0uUgwCw+4vfBuTal/n000+Nz6xAfiEBEAKuv/76a58lVkeca/Ibx4Cbexi3C/iG4oXUAwH2vCCCPec+PtmRutgd16lTJ+dri5c25oKXT3xw8fLGNb8tSPWAAQOSVaM4ISAEShGBUiVifty8GUI0IEg+zh9xbrf//vs7Z3RsH2aR+OKLLwxCBFEhnHHGGXb99ddnGVzyYVcc/2EI6etB4sXbOvlY/CF1PKxIh+hAyKifa/T2LFScszWaow9sISaNeKRfPj7xyLZiCCAPyMS08DUPYXzZ8FFWJGmk0T4OAEmjLeJSMYA/PoB460cSyRzzXTXGwhwhUWQRgTAh2cJ3T154sZBAsvgOG4s+ZZg/6oSYVa5c2djezfycffbZNmXKFBeQjHEvIZGhPfpCWZwvUjZOgW3v4ACB5UUIf0cQIyTU4MB9zTZ9pGWcE5dTAPtTMiW4NWvWNLbw8+JD8PkhZ0g+eTFBqgsx5vfrpZg+X1yO4IU/qqZNm7r7lJ1sYMf97DEAJ34zPJN8XE5HXih4VvBs45nDSyPSTV5qy5Ur55yeUj8EmOcseXOqS/HxQMCve/EYbWqMskwUugkBYtHEM/KECROyuoQ0COkUqjofiQ3WsmXLnEdh3ihxiMdDHjUgpIx0vCgj3qdeX84f69evb7z9s7U3P9IQiF9i8HX5o0/31/4IsUL6gBSGOJ+PI9csfnhAZsEjbxBk3z3DgxVJEnmTBeohJEuLQhwLAf1AKoj0BRUJO4WIY95440ddwjUBHzm8wX/00UdcJg2bbrqp7b777oYKmbJIEsmIVAZJGcSPPMSx+EAkuKeoE7wpQxoB4oDUILwIEp/ugZcJCIEfJ6SLb9Ghjvdx+T3yooDKH8n1vffe6+wxUfn68pBjiB+OOYmDXEC6+Y1yHbcA7rwI+HGDB9d11/mW8vH5OfIyw/cHIdRIwijDyw8aATQM1E17SNWQ9mOSgbsG8inEFwHWWtZATBTii0K0Rh4JIgYkqC6QfKGuQixPHEQr8cHBA4d8+Fdh0UXNAVFDBcaiipqFT0bwIVi/IFOXD0EQGFIAvCEjDcHTMrYUPj3xiM1WOHTp0iVblu+++85J47BBu+2227KlIbGBGKKegTyihsCOA5XmggULjLKMh4dntoJ5XDBG1LXY1SHV6datm3nMLIL/wBkp5KBBg9y30sJdTEaWw+mJ58wb3qwhcmAJCUe96/Mx7/482dFL5JKlxTUOlS5qe14ICoMBLz0jRoww1GszZ840PHvziRdfFy8U/lzH7AjwHIDM8lvOnpL/q+222y7XzNj6YefKCwkSZdT0uRZQYtoj0LVrV0OKig0y5iKQ97QfdIQHGBkixgKKmJ5FAZIBcUE6AsnKCb9EmylUHpAUFmYWXLwnJyvL2/nVV19tONDDLgvbFd4ak+XFBiMckOyE8yFlwbgfGwxu6HAakgeIGHkYC3ZlqA0gXqhmUEEi0UJ1Ey6X1zljRNXKwxU7JySJkM+8ypVWOmOGhGFzBCnLqx8s7NjXoTIjgBu2feFySFWYC4isl4qF03WePwS4d5CabAwRoDxeypFK82LEfHkpcP56Ec9c2IthTM8GkuIkq6gr+T1hBgARQ0IdT8RTedRF33fWDExB2CSGWRCagZzWwaJvXTWGEYgMEaNTJ554oqE65M2ahfu0006zRLJFvqIIqFOwM8O+jAchqqvC1FujRg0joCbA9iOnOiBfkEOIAzYbSOv4HAZqCRZDpGM5lU2M5w0aCSBjoE7sPqg3MV9UrlmomVd+8Pz46RcqSlSXqBO5JiAdgJhi5wVpg7wSsF2CnJEnHFBRgj0STTZ+EFAF+zzYhVEf+CDtYbGbO3euTzaIO+nYi2VFxugEvFH/s+MuL6lKfmBBAoytIzZi/uUCiW3ib4t7gDnOT53pmgc7HSTl/C64hwszTlTJSJTD+DKnPAt4tvg6gyAwXtwwDeDlkN+TT9MxvRDgpRcNDurqnALfsAyPmpcBXmoRTLCRiedpOF3nxY9ApIgYCzbkiLc3Fmi2w+cXAhZU8iJlYncQi3Be6jpIDDcgDzNsKihf0IDUDRUqLgCQsoXLs6MsCAKrWLFiVjQSMkgYPxJIJsa2kAfs1ZB0ZWXMPGGR7N27d+ZZzv8ZNw9eiFnOuUonhb6FW2Z+UUETh/0WJBQDeq6ZK+yGkKxgs4QaF/tAAipf5pR84TqRKBB48FA3RB7pJbiTlwcMeEPoUWezGCGJJI1dm0gGkGZiHE1cnAISRuy62ESBLVEY17xwIC/B5wufMw9ly5Y1Ty7YxQqZhiCQn0UgCAJnRM51TiGd4/md80LA/c8LAmMNY8h1bsHnBWdU86gc2RlMGUwAiMdlDNc+L+dBELjP62BGwbVC+iHAvHM/TJ482SbnEJLNP/dMixYtnJaI9ST9kIn2iEqViGGsjVoQdSR2PyzGLJi8obOolitXzjAwReXBwxw7FAgaIlQkUJ6w8WZJXbxpEzD6RsRKAH6OPPhYhNmuzznxBNSU99xzj5PEcQPyNsDDjDpJRzKXkZHBqbGw484CWzT6jcoRY3B2gqGWRM8OmXCZM/+wG5IbPGyIy24mCJhfqHiQIhbGaB+1HWNi0wGuHrC1QdUDaQAjjCvZMQjJzKzeuMYIF/Ey11EKkCGIKcSKPjOH4A6pop9Ipxg3Kl0koGyegKBiREp6sgAuSLfIi+qLuUQ9i1qb/PiDY9MDbYDfsGHDjPlDcsC9BKlFlTt06FBj1yxl6APHOAV2FOMGhnvn8ssvN+YI9RV4QRLAgnv7rbfeMu5p7k3U/cQTsC/hN4oUlzzYXOJ+hAWAnb6QLwgeeSHBBNriZeOOO+4w3Cn4dPLEKfByxaYGXji5T8GeHayYSPBMAwueV+z25ZnHbwODfOIJvLRxL/Mc4prfGN8qxDUL9q58OBrXPZA86sAwmzTOsQdi3uMujQQ3BTNemlhvkWLzbO7Ro4fzTiBsSh6BUiViPGggOTzIv/rqK/c1et7O2SmIIT4kh91wPHj4ijxvdzyUkIJg04JUhWsWBOrg4Q6BQpKGqoV4IOXBhvqPm47dYZwT7wOLO+pJJCYQMQgUu+tYuFmQ6Bt5eQjygGMhoW++ftJQkyG18W+4xLHg0S/a5fr11183SB7OS+kD6gnIX5s2bQxygToBI3QIH5I9HtKMA+NaFkhUC1yDGQ90yAaqH/qMmo02ohKYR+z7wAWSSr9YwD1p4po5hmyyyCOVwraIuSYtWWCXIwsPBJRFCzKArZjPS5sQM+YTAo+qGCN0n96gQQNDAsmcQoZZEJGG+vS4HPndsXiDE/NDANvDDz/cIMPgQB5U38wZakZsNokncP/ioJWXGF4ouMe5H7kHebFAmkk+HyBnderUMaRi3NNRfHHwfS3uIy8o/J753YI7gWcG16jraZ/nFfi3bt3amWbwTCOewDOK5xLmDVzzu0GdRD1IOXlO8mwkjedRo0aN3HOV5yQvt8wPaQrxRoDfO/cKxJ3nLvdgvBEp3dGXKhFDcgUL94FFEWKCms0/lBpkLp4+nSN6bOy6OCckXrM481AiDxIU4GWB5s2Q/ATOifeBNrHVQFWJqhEJF/kI7EjEHxh5w/GkcTOzyxO/VbSLaBc7GfKyeKGGYbHnzQOiRXnIE7v9kBIFQUBW97BFXAxxoF4kYziYxZ6DDEiPkFiQxo+HBZSNDTjO5MgDG2JC3qgEiCTqWvpMH1kAsOFK7B+El3ScsEJEoNpQqQAAEABJREFUE9PD1+CABAcMGHOyN3uIcps2bdxOVlSWQbAWY18P0knag9RiGxYE2dN9vnQ+QpCZl3Bgd3IYfySLPh1XIdyfHhN+Kyz2/K5QI0OOyQvJ4jfh8/kjv2vuX+qBDCAl9mlxO/IiCFaJga9BeBIMruF0ni0ep4oVKzrHz+G54pnDs4UdxcyNzwtp43eFFAxDfV5Ueb75dB3jiQD3CQSsc+fOxlobBPF7BkZt5kuViBUXGBAryBYSJ1RRxdUO9UKaEPtj6wR5Ig51DmpQFnxIIXE8CJHEoJpEKobUD4kCaQUNqNrY/cQbMG0jaYP0FLQe5RcCQkAICIF4IcALKi/zIuXRmfe0JGIeXqRZECGvWvTxxXlEfQpBQoLA7rHibEt1CwEhkG8ElFEICAEhEEkE0pqIgTiEyKs5uS7uEASBYbdEQDJX3O2pfiEgBISAEBACQiB1EUh7Ipa6U7ORPVdxISAEhIAQiCQC2A+zW5ENYJHsoDpVogiIiJUo3GpMCAgBISAEShMBzEdwfMomrCAInIukZP3BpAVH3EGwVsuRX1+T1I/tLp+yY1crmhF2Co8fP97w7UU6O+45Z1NXsrZTNU79LhwCImKFw02lhIAQEAJCIAURCILAcHzK7nV2qLJjOPHLHbgLYtc97pNwk4RbIVyM5DVcvgiCjzh2JrKLGMKFeyF2xeKqx38FoVatWsamq7zqU3o8EBARi8c8a5RCQAgUOQKqMNURwCceTrRxEB0eCzvc2XWPexY2fLHDHcfa7HrH6TT+4J599lnjHCfjlMX/G2QLJ9F9+/Y1XCjhr5A03OaQFxdJXCsIgTACImJhNHQuBISAEBACsUGA798imcLPY1gqxtdb8FsIEfNg8BkpXAXh442vvEDMcFvEFz3IgyoTd0k4Lz7qqKOIyhZwsIu6MgjktysbMLowETHdBPlGQBmFgBAQAumEAF/y4BNQSLX4Egpjw4Zr9OjRBpniCyrEEXBIzVdSUDXipxIChn9IylGGT98hKcPZsXfOSzkfqMs76fZx/kgd1I89GZ8K8/E6xgMBEbF4zLNGKQSEgBAQAkkQOPfccw2ChJRrzZo1zqAeh6e5uT3iU3PhqvhWI0QrCAJDchZOy885n4Hjs2wTJ040pGZh6Vx+yqdxnlgMTUQsFtOsQQoBISAEhEAyBIIgMD4vh3H+jBkz7LHHHrPzzz8/WdZc4/i8Grsk+apKQYkU7fFtVz6XB6Hj6yy5NqbEtEJARCytplODEQJCIKURUOdLBQFcWaAavPrqq+20004zzgvakUqVKhkqS3ZGjhw5coPi7KhE7Ygac4PEdRGLFi2ytm3bGqRsXZQOMUBARCwGk6whCgEhIASEwHoEfvrpJ1u+fLktWLDA/v33X0MNyTcY2R3ZokULgyyhLly5cqV98cUXBokiH3GkYczPtVdDcsS+q2vXrobbiiuvvNJuuukm+/bbbw2bMnZbsqOycuXKFgRr1ZfLli1zdVMPPaPe1157ze6//34uFWKEgIhYjCY7gkNVl4SAEBACJYoAxOfGG2+0hQsX2rBhw6xbt26u/SZNmhg7IrlAMnXrrbc6yRjkCS/4DzzwgOFPDMKGgT/XGPUfe+yxxq7LefPmUdSIf/LJJ23FihV23nnn2YknnujszjivWrWqywMpQ+qG5Oy5554zdmAOHTrUDj74YEM1yQ5Ml1F/YoGAiFgsplmDFAJCQAgIARCA6ECE8HRPwL8X8ThuPeGEEzi1vffe24YMGWKkE55++mlDbYl7imTXkCjKu8KZf04//XQbOHBgVvkbbrjB1ZmZ5P4/+OCDWWlI4Pr06WP4JcOnGQ5hZ86c6fLpT3EgEL06y0SvS+qREBACQkAICIH4INC0aVNDrXnqqac6r/94/o/P6DVSETHdA0JACAiBNEZAQ4s+AocddpjVr18/K2CrFv1eq4dFhYCIWFEhqXqEgBAQAkJACAgBIVBABETECgiYskcdAfVPCAgBISAEhEDqICAiljpzpZ4KASEgBISAEBACUUNgI/sjIraRAKq4EBACQkAICAEhIAQKi4CIWGGRUzkhIASEQDwR0KiFgBAoQgRExIoQTFUlBISAEBACQkAICIGCICAiVhC0lDeeCGjUQkAICAEhIASKCQERsWICVtUKASEgBISAEBACQiAvBJIRsbzKKF0ICAEhIASEgBAQAkKgCBAQESsCEFWFEBACQkAIbAwCKisE4ouAiFh8514jFwJCQAgIASEgBEoZARGxUp4ANR9PBDRqISAEhIAQEAIgICIGCgpCQAgIASEgBISAECgFBEqIiJXCyNSkEBACQkAICAEhIAQijoCIWMQnSN0TAkJACAiBQiCgIkIgRRAQEUuRiVI3hYAQEAJCQAgIgfRDQEQs/eZUI4onAhq1EBACQkAIpCACImIpOGnqshAQAkJACAgBIZAeCKQuEUsP/DUKISAEhIAQEAJCIMYIiIjFePI1dCEgBISAEMg/AsopBIoDARGx4kBVdQoBISAEhIAQEAJCIB8IiIjlAyRlEQLxRECjFgJCQAgIgeJGQESsuBFW/UJACAgBISAEhIAQyAEBEbEQMDoVAkJACAgBISAEhEBJIiAiVpJoqy0hIASEgBAQAusR0JkQMBEx3QRCQAgIASEgBISAECglBETESgl4NSsEYomABi0EhIAQEALZEBARywaHLoSAEBACQkAICAEhUHIIiIgVL9aqXQgIASEgBISAEBACOSIgIpYjNEoQAkJACAgBIZBqCKi/qYaAiFiqzZj6KwSEgBAQAkJACKQNAiJiaTOVGogQiCcCGnW8EPjvv//s77//tj///NOFf/75x4j7999/NwBi2bJl9uijj9rRRx9t06ZNy0onP2nDhw93dVDXX3/9ZYl1UDdpBNLD18QRqJT6SOeawDlxpCWGXr162ZIlS1yfE9NyuqZd6vR1008Cbaxatcruu+8+u+CCC2zhwoU5VaH4CCMgIhbhyVHXhIAQEAJCYD0CGRkZjnS0adPGTjvtNDvnnHOsT58+9thjj9krr7yyPuO6sy222MIqV65sy5cvXxez9jB//nwbPXq0HXfccXbqqafa/vvvb7vvvrs9/fTTazOs+/vUU09ZgwYNbOedd7ZWrVrZ4MGDrXHjxrbDDjvYnnvuaSeeeKIjVIsXL7bWrVtbhQoVrFy5co4UzZs3b10t2Q+dOnWyZ555xj788EODYGVPzX4F4Xz//fete/fu1rx5c2vSpInrx8CBA+2BBx6wTz/91DbbbDPX5tdff529sK5SBgERsZSZKt9RHYWAEBAC8UMA8tSxY0ebMWOGXX/99TZq1CgXzj//fPviiy/ss88+c5KyMDI77rijbbXVVuEoJ/WCYFWrVs0RrLFjx1q/fv1sjz32sLvuusvGjRuXlf+SSy5xbRxwwAEG+YEAvv7667bPPvs4EjdixAgLgsAqV67syOCBBx5o5H3iiSfcMaui0Ml2221nJ598siGNy408IQF78cUXHamD+EG83njjDaPuGjVq2AcffGA//fSTbbvtto5IhprQaYohICKWYhOm7goBISAE4obAzz//7IgOUqb+/fsbhKds2bIOhn333deuvvpqO+igg+y3335zcUiRIGjHH3+8k2K5yHV/xo8fb7NmzbLDDjtsXYy5shdeeKHtuuuuBtmC7PlEpFybb765bb311i5qyy23NCRthE033dTF8Yd08pUvX9622WYbonIMe+21l/3xxx/21ltvOYlasowQz7vvvtvq1atnV155pe222262ySabGO3Xr1/fWrZsaeXKlUtWtOjjVGOxIiAiVqzwqnIhIASEgBDYWASwqZo6dapTBSLlSqwPadZJJ53kpEPYfl111VV29tlnO+kR5C2cv2vXrlanTh3zRM6nVaxY0ZCUQaLatm1rixYt8klJj6gVIVPhgN1WODPXpGPbhT2XT9t+++0dsUIqRh7SyENersn3zjvv2Ny5c50qMrGvZcqUsRNOOMGqV69O1g2C7xt1bpCoiMghUCZyPVKHhIAQEAKli4BajxgCSLpWr16do7ov3N3LL7/cDj30UGvatKmz48I43qcjWZs5c6az5fJx4SNqw9dee82QbHXp0sWWLl0aTs52PmHCBGvRooWdfvrpWeGjjz7KyoNqEbs1+oEdGpK4rMTME+zOUKlCwt58801n73b44Yfbvffem5lq9sMPPzgJ3xFHHOGu8/sHrO68807XpwYNGjiVbX7LKl/pICAiVjq4q1UhIASEgBDIJwJIgFADskMwryKQmoMPPjgrW9hGDClXEAROGpWVIeGkatWqds8997gdiBCaX3/9NSHH2kskUthwYbflQ+3atdcmZv795ZdfDOkdmwI6duxoiZI5bLu+++47p5rkHOnYsGHDDIkdtl8Y4TPuFStWZNaW//9I1Y499lijT40aNbInn3wy/4WVs1QQEBErFdgj1qi6IwSEgBCIMAI77bSTValSxSZPnpxnL3///XcnTcozYy4ZsB+76aabDFJ3//3355Iz5yTIFfZdQRAY6lJs1nLKfeSRRzpV6X777eeM/1FFsiEA+zQ2B+RULlk8dmN169Z1SdjNoWp1F/oTWQRExCI7NeqYEBACQkAIgEClSpUMFd/06dPt2WefdW4fUOmRxpHdh2PGjHG7CDHeR22IRIp0b3NFPohJEATOWJ+0cCDdXyONwj3GFVdc4VxH+HiO5AsH4gjhOM6R4CHRwogfidiQIUOc9Iu8BCRtEK0gCLh04eOPP7bbb7/dqUYbNmzoNhTgugLDfT8OMmIDBilFzUpbPpDmA3HU17lzZx8VqaM6sx4BEbH1WOhMCAgBISAEIorARRddZNht3XbbbW6X5PPPP28QrlGjRtlLL73kXDhg4zVo0CBDnQcBYVciRv5BEFhGRoZBfthtSLofJrZYqPFQC7788ss+2h3ZrdijR4+sHZOUGzlypPNL9sknnzhfZBAeSB+2ZUi+MLCnHuqlkjVr1rhNA8R/++23RDkiuXjxYke0IGtE4usMoskOUK6RbOGMlh2S7dq1szvuuMP5SmNMjz/+uKHWrFGjhv34449u/DhzxRUHhA3/Y++9956hmoRUUp9CdBEQEYvu3KhnQkAIpA0CGsjGIoC7CJyhIlnCfQXEY86cOc6lw7nnnmu4hKANDN4HDBhgSMbIg6F8z549DXUdRvjUAelZuXIl2Q0SxTnqQSRrLjL0B0KHZIwobNQwsL/sssuchA4yRTwG8pAwnL5C3qifekkj4LMM1apXE0KeCGeccYZTRVIvEj36iIsKyBblcKcxePBg69atm/OHhp0ZhA5fZaeccoqLg+hB2jp06GBsaICILViwwNmkoerkiwLYnFGfQjQREBGL5ryoV0JACAgBIZCAAGTskEMOsUsvvdRuvPFGg1ShQmQHos8aBIHbNXnNNdc41w8Y7mOfhRE+6sKaNWs6r/xI0yiD2pO6fCAuHPDb1RR0TlgAABAASURBVLhxYxeFB/4uXbq4tn3+IAicY1jfJ+I9KcLzPwSvb9++dlGmRA81JRVB5nDSirQrCAK3+/KWW25xPszIj5SNfARIFu137NjRtUvd2J7RL9L5IgBt+oAEsFmzZoYEDWzwu4bNGXkVoomAiFg05yXle6UBCAEhIASiiEAQBM5VBNIsJEfF1UekdqhPkUjxSSMIH21h34XaEHUjZIw4VIpI73BES36+jUl8YQI7JpGcQfaoiz4gCSxMXSpTMgiIiJUMzmpFCAgBISAEIoIARvJ8vgiVZEl3iZ2YSOhwIFvSbad5eyk7PBGxlJ06dVwICAEhIAQKiwCfIsImq7DlC1uOLwDgX6yw5YuiHHZkOJwtirpUx8YjICK28RiqBiEgBITA/9k7E3ibqr+N/3aDlAZNSkloUKEIUUpooEEpDQoZmqRJoWgyplTkTaWQSANJA0kypzImiQwpoqJBKY0a/u/9LtZp33PPvS7dYZ9zHh/r7L3XWnsNzzrn7mf/piUEhEDSILB69WrDgeH999+3sD1a0kwgxQYqIpZiCxql6fDWhft1mTJlnDEr0arDP3rKn332WReoEe+esWPH5vhHgXunTp1qGNtidIvXEC7k4TnjrUTEawxcMeQlyrQvpz9iEJUrV87t0YbbO3m+PF2Pn376qVsD3Nx9At/HHnvMudnH44IHFtG/CbKJETCBL/EAox5rNHPmTGNbFtpq1qyZfffddxQpZYMAeLZu3drYfxCVWb9+/RLizu3gi3cdvxdCNfAdx+aIMhLn3bp1cx6EBx10kA0YMCDbtqivlJ4IEPQW2zH23MT4f9WqVfqeFOJXQUSsEMFP6q5zMfhp06a5aNEQHh4YBCokMCG3Ihbv37+/PfTQQzZlyhTDJZ0HCA9xyhOlBQsWGB5AnTp1Mh5WxPQhTg5vd9SnbVzXcSFftmyZc0vnjwxkjP4ef/xxw3uJPd8gZIznnXfe4da0TrjDQ5jAhITrf/PmzQ3vLVzp48Hh4U6MJAgcJAs7G9aReqzFBx984NaHtvDgAnPKlBIjQCgEQi/wEsGLBfGoCFmQqDbhGjAy5/cC5rzIjBw50lXlO85vgzXgt8Lvjt8Y2/QQV8pV0ocQiEOA3zuepXhd4kRAOIy4KrrMZwRExPIZ4HRuHnfxli1bWuXKla1Ro0ZOCuUf7Dwsnn76acPFnPg6bNILifLxehLhhvQF7yNIAvWIrUOARIgE9QcOHGi4dOO6fcABB9jVV19tPKjwRGLzXgI9ch8SsapVqzqpTbt27bg1rRPxlghaefHFFxuJdSDeUZkMSWYiYJYuXWpIY/DEoh5v1Zs2bYpVRbpDG7TFNi3FixePlekkKwKoh5CGgSdSRr6bvDxkrWkO9zZt2rjwDMTOwtaIe6kLMSbYKC8i2D+xTQ9rwBY9vLRQRyk9EGAPTIhVdomNxXmB8mgQf4wXJoLd8tKMB6cvi9IxVcciIpaqKxuBefGWzzBwpeYN/rLLLjPIGXm82fNwqFu3LpcuQcZ4k8ft2mXEfaCO2W233WK5EIggCIyH/ddff23z5s0z1JLEGqIS25kQtRrX8IULF7r93urUqUORSzzw2AIkP13YXUcR/yA2EmpEP0ywQv2bHYHi4f7SSy8ZRJr1QgIG6eV+1hzCzHo8/PDDjnzjpk+ZUmIEiKSOCn/UqFGG2hH1IvGnEtXmJQL1JKokpMONGzc2/xtCoobKCULn7+X3QGBR/7Li83VMbQQqV65s559/frbptNNOi+0WEEYCUw0IPC8E4Xyd5y8CImL5i69az0AAwoMahZg2/i2MSNSoUkqVKpVRY/N/HuBBELhtSDbn5PzJwwVbJaJWI5FBioBdjL/LEzJE7Tyg6I/gh76c/jhn2xOOSuZs9MaMGWPEMQqCICEkZ5xxht1+++3WtWtXFzATaZon2NyA2rJdu3auDsQCogt5oEwpKwJXXnmlC/ZJOAXILYE4kXSZZa1LDsQKaViPHj2cWt9Hg4c4Q8JQ74M3CUkH93hJNOdKqY8AhB2P0OzScccd58xGQIKXVb5v9957r82fP9/4PiLxpkypYBAQESsYnNO6F8jX8OHD3Y+8Q4cOW8UCexZIFvu/kaZPn2483MM3InFBAoBqM5yv8/+GABIuHvRIybJrCbswpDYQMR7+SGXmzp1rvE1zD2oxJKDY/rEXHhHFsWuiTCkrAhApHnzgiaTr8ssvN+wds9bcnLPHHnsYvwkIMy8f1OfFBokxW+agoofQYaM5dOhQp85EOrz5bn0Kgc0I8CLK94K/oWgoeKnle7i5VJ8FiYCIWEGinaZ9sa1HkyZNDINwvB6BgS1JyOfBwzWJvdp4iyfa9MSJE51hPuoXHirYeFGHtHHjRkPKgqoTIkAedjKch20bIGu0hxQMUTv2TGFCAJGjnP3caEPJDMLMG3FOWGBIzls0W7pAuCBtGIV7z0nuRdV58sknG/mQaNaWfKWsCOB1yne0Y8eONnjwYEN6i0MELyRZa2/O4SHKtjfYAPFbYK9C8mgLCSWSsDVr1hj2fNjsYTO5+U59CgEz/sZCwF544QXnwMT3T7gUHgIiYoWHfdr1zI/91FNPdfPmTYyHAxIvMnizR3WJUX/p0qWdqoaHEgmvL9SP1COheilfvrxxP9ck3uRom6jVqCLJ81Kac845x9gkF8KFvRhl9Ec7bAhMyADy0j1hs8ca1K9fP0coZs+ebZBe1F3YhGE8zr0Q5PgbiR6Oipg1jS/T9WYE3njjDfPfQX4XOKNgeI+Ua3ON7D9RxaPe9/fzgOUFBbs82uB7z6bV2begknREgBdhnDp4iQqCxCYIaYJLJKYpIhaJZUi9QSAFuemmm6xXr16G1IuHN275SLiYLQ9oHhDdunUzxOKvvPKKEXICV2qkLTzoeciQIFw8zHnrJxwFaplBgwYZ4SdoH2Nn7LzoD/XYo48+ajyE8BbD7gGVDW20b9/e3UN/qHUIFUBIC8ajZM7eCDUjnqdhPAhDQVwwpCvk4yWJxAb8kCryVo0KkjUlH4kanoCo3LBlwhAdssC9SlkRIAQL32N+J3xv8XzERg8VJJItvrt8j7mT3wzf8+XLl7vfC9Iv4kEhgUS6ywsGLxvgTlvEgkNazL1KQsAjEASBESvQX+tYuAiIiBUu/inbO96NeN7NmDHDcIcmXhcBXTEK9ZPG+44HBWQMlSVqLt7UfHn8kQc+DysMSmnXJyQ49MeDi7hVkAPiKWE7E7ZJg2T4/lB9PvXUUwZ5iO8nXa9RLWJjFD9/JJl4WfkHOob4hAghfAhqL6RiPXv2NAzF8daCPLCm/fr1MwzK2dIlvk1d/4sALw4QXQgWRAtvN86pAcE677zzDMkF17Vq1XJqeZwlIMh8n30ZUkleVPBoxfCflxokZNwXSzoRAkIgcgiIiEVuSVJjQEiwsCHCa46YNkijyiSIS8UDnXIeGgQVzGn2119/vXPvp81wOvvss2O3EZMMAkAoAIzEka7FCjNOLrzwQqM/DJqR7ASBxPIZsLj/PMQJBeIuQh+ofCFaqHbJxraPeGxIMVkHApJ6kgahQKKDxJG4RHjMco9S9gjw8oGtF5iBHapFL5UEa6S/niBD0sAc7CG7qOh9y6zPkCFDzNfnXl+moxAQAtFFQEQsumujkf13BNSCEBACQkAICIFIIyAiFunl0eCEgBAQAkJACAiB5EFg20cqIrbtmOkOISAEhIAQEAJCQAjkCQIiYnkCoxoRAkJACKQnAskwawIQE1cND1PiEsaP+ZtvvnFOEDnFbou/579eE/Nw1apV29UM48TLHFtXvGO3qxHdFBkERMQisxQaiBAQAkJACOQWgZ9++skgVXhDs5VP06ZNbfLkyUYsvHhyQlgbyAtepjjyhPsgFAh5eGM3aNDAaAvHIMLl+HoEh8aTlTISTj/ha/IgRdQnUCrXPuENTn58wssbpwsIVXwZxJG9c3FywgGG/URxflm9erXhLUs5RI6AyeEg1fHt6Do5EBARS4510igjg4AGIgSEQGEjwE4bV1xxhSHhwnt01qxZRnicSZMmWb169Yy4guExEgYEj2pirYXzIVt4ohJEl9hreFzjaf3ss886krdp0yZXnVhuBJYuU6aMEbIFz2uuCZhLjETiwBFEl8oPP/yw4YHMjgeEGWGc5McnvGUJMwKpg2D5ckgj/RN+57DDDrN3333XCHxNsF88xFeuXGl4pVeqVMnkGetRS+6jiFhyr59GLwSEgBBIKwTYAgqC8+effxqxACFDAEBMQII833///YYEizykYEi8iBtILEP2USWfxP3Ub9OmjduPkzzagmARBJpgz0isyCcRUoSYeT5uG9fERQyCwCBV1PGJTbfZcxXy5/MSHZGKsbUVgXkJxksdSB7XbFcFuYMYQryIl0gsReL9UU8pdRDYKhFLnalqJkJACAgBIZDsCKCyY1so1IiQr/j5EL/QEyAkSXfddZdBwgh0G97zFJXguHHjDNVmuI0gCAwpFpIqSB07eYTL8/qcLdgY38KFC41twgiUzN645MdHv0cKRiDsvB6D2itcBETEChd/9S4EhIAQEAKZEcjxClUgOwZASpAWxVdGUoVKb8WKFW5LM9R/kBt2LWCXCF9/0aJF9ssvv1ii7bdoH1svJFuoLSF//r5ER+zTvE0YR6Rs4XqoONlyjTIkbuEypGlBELit3tgWDNUjgZAZQ7ieP69evbo/zXRcvHixXXLJJc7GDdVmpkJdRBoBEbFIL48GJwSEgBAQAmEEIDU77rij21LLcvjHfqfYip155pmuLvvWhm2qlixZkuMWZ9THGWD33Xc3iBV2afE2Zr775557zrBT84n9VX0ZR0ghakzKUTtCAsn3iTI8KDHCJ48t2zjmNqFyZT4PPPCAjRgxwtgJY8GCBbm9XfUKGQERsUJeAHUvBEwQCAEhkGsEkFKtX7/e8IzMjhjRGLZkYeJF3ramPffc01BfFilSxDp06GBIrHLqM7v22TqsUaNGxrhRnWKLlqguhAwSBon67bffElVJmAdZZLs4nAlIqDWR9iWsrMzIISAiFrkl0YCEgBAQAkIgOwROO+00g2xg//Xdd99lqYYdGNIhCA1SJlKWShkZkJ5E92cUZfqPvRkemXg2TpkyJVNZbi8gckjFUI9Cxgi9Eb4XpwJUqti8YaBPXTxAvYTM18Wg/6233vKXOR6POOKIHMtVGB0ECoOIRWf2GokQEAJCQAgkFQIQKFRwGNu3a9fOZs6c6cYPuRkzZoyNHDnSSpYsaTVq1LBDDjnELrvsMic9g0hRB69DpGkVKlQwCBDXroEtH8Tnwt4KidqWLKtWrZp17tzZqTh9HqSIe5GQQf58PkfUmPSFBI1rEmMhPhnjwzOSPJ8IKOuJE/ZsDRs2dP0NHTrUNmzYYBAyyCV2ZpA17iMf1Ss2ZVz7RJwx5lyiRAmfpWPEEdgh4uPT8ISAEBACQkAIxBAIgsCQig3NICkYup++k9t/AAAQAElEQVR++ukuntbJJ59sECCM7IsXL26lS5c2jNapU6NGDXvkkUeMkBInnHCCBUFgxx9/vGG8/+GHH8baJkQEMcD69u1rtAOZopA4ZJAjQk1gn0Y/qAKHDx9uSN7wsMQui7oXXHCB4SCAahDjeaRp5EMg6ZMAr5Ao8kioISnDkJ/rvfbayyCa9E8IDcYIsaSds846y3BSWLt2rRHeAkJJYFnGBSGcOnWqC92BsT/kjfaUoo+AiFj010gjFAJCQAgIgTgEsLPq16+f83yE9BD+oW3btplq4T2JlAwV5EMPPWQQFQKuYmcGKYPsIEFCusWNEyZMiLU3YMCAWHwxykg33HCDnXTSSc7TcuzYsbG69E+YDOoQe4xrn4iOT/R7Qm6QkOARRJa6SOSof+WVVzriSB6J+GLk4XBAO0jMBg8e7EhYEARO4sd9lJEggYwd5wLs0Yg3xrxpSyn6CIiIRX+NNEIhsM0I6AYhIAS2jsB5551n2IBBagjwuvU7tq8GEfzxlCRhJ0aftEQoDhwKWrZsyeV2J8aO5yTkFBXmDz/8YJxvd4O6sUAREBErULjVmRAQAkJACEQFASLW33jjjUaoio8++sjZjOXH2KpUqWIQMBK2YvSBjRvqQ+zG8Hokb3sT96MqpX0SbXqbs+1tU/cVHAIpQsQKDjD1JASEgBAQAqmDADZetWvXdjZj8ZHs83OW5cuXN/pFIpaf/ajt6CMgIhb9NdIIhYAQEAJCIGoIaDxCII8QEBHLIyDVjBAQAkJACAgBISAEthUBEbFtRUz1hUB6IqBZCwEhIASEQD4gICKWD6CqSSEgBISAEBACQkAI5AYBEbHsUFK+EBACQkAICAEhIATyGQERsXwGWM0LASEgBISAEMgNAqqTngiIiKXnumvWQkAICAEhIASEQAQQSGoixt5aRBRmc9Z//vknE5xcEywvU2Y+X/jxcMyrrpjHpk2bjJSX7ebV+NSOENh+BHSnEBACQkAIRI6IsZnqjBkzbNy4cTZlyhRbtWqVsV1DeJNUv2xffvmlDRo0yNioNbxx648//mjs5zV58mTXDm1xDWHz93J8++23Y+Xz5s2z+fPnx66557333qOarVu3LlN+oraoyDYWI0eOtAULFhgEirytJfY4+/jjj23SpEmuD/pkX7Rvv/3WKGNT13bt2hn7mLGFxdbaU7kQEAJCQAgIASGQPAhEhogh8Rk2bJjbBmLixInGBq6k8ePHW5cuXRxJioeVXeoPOOAA27BhQ6wICdmbb75pkJYKFSrYrFmz7J577jF2wYfsxCpmnHz22Wc2cOBA6969u61cudLWrFnjCNG5555rbCYLCcqoZhs3bjTG0bRpU+vatauxNQWbtVIWTuygDymkHzZrDZdxHp8gXBCshx9+2I0TQjZ37lx7+umn7ZFHHjGIHW0yT+YTf7+uhYAQEAJCQAgIgeRGIBJEDPL01FNPOUIEYerYsaPdfvvtxh5gF1xwge2///6ZyJaHfI899rAiRYr4S3dcvny5jRkzxk444QQ7+OCD7e6777Y777zT2Ivrpptusjlz5rh6fLDR6pVXXmlnnnmmNW7c2M4//3zXL2UNGjSwZs2acWrs2cVY9ttvP7vwwgutefPmrj1XGPdBnapVq9ro0aMdkYorjl1CwhjPtGnTjCNzJl177bVWp04dQ60KLsWLFzfIWOxGnQgBISAEhIAQyB0CqpUECESCiEGekAJBfho1amQQrB122MF23HFHO/DAA+3SSy+1ww8/3MEJOXnppZcMaRdlffv2dfl8YEPFdcWKFW3vvfcmyxG1EiVK2M0332wlS5a0iy++2OjPFWZ87Lrrrq4O/WVcunOO7DkWBAGnLu28885GHfYlY1wuM8FHEAR22GGH2ZIlSwy1aoIqLguihvrzvvvus0qVKtkuu+zi8osWLWrVq1e3s846KzYWV6APISAEhIAQEAJCIOUQiAQR++STT2zx4sV29tlnJwT4yCOPtGOPPdaVYfc1ZMgQQ42J6nKfffZx+XysXbvWXnzxRUdsuA6ngw46yJUhYWrbtq2hloS4heuEz1ETQpR8mjp1qv3yyy/hKrZixQpn1zV79mwLqypRJSKBe+WVV4w+UHn6dmgANSP3QOhOP/10srKkU045xSCa8QXYnqG+pD0wiy/XtRBIawQ0eSEgBIRAkiEQCSL222+/2a+//hqTeuWEYc+ePQ2SUq1aNUPSdfnll8eqY2yP1Aq7sVhm6ARVJZI3SFOvXr2cE0CoONMpBvqQMZ8gXdix+Uo4CkAKP/roI3v88cct7CxQrFgxJ5HDaB8JHgb8tEOfEEjaYc5HHXWUby7XR9qcPn26vfvuu9ahQ4ccpW65blQVhYAQEAJCQAgIgUJBIBJEDLUfKSdVnkdn0aJFhoTMX4dtxL755hunPkS16cvjj5UrV7Y77rjDkCpBjOLL/XW9evUMmy2frr76akeufDmEr1GGGhUyhIE+Ho6+jLmgaly/fr2h4oQs0k63bt3ssccecypX6nhnAH9fbo5lypQx7MhwYChZsqTz0MzNfaojBISAEBACQkAIRA+BSBCxcuXKGdIhPBNRvcXDRB7G6+QjTfr88885zZIgR2RSn2OiRB2M8yFGQ4cOtREjRiSqttU87M28EwGEq0aNGpnuQSUZBIEjhqhFLeMfatSyZcsaqkvswn766SebNm2aU19mFGf6j9SONjJlZlzQBkQTorfnnns6u7eMbP0XAkJACAgBIVAACKiLvEZgh7xucHvaO+aYY5yH4qhRo5zt11dffRWzuUJFiArwgw8+cLG5Tj31VCM8BapCCBfeh5A07K5q1aplqAKXLl2aaRjEDyMWGeTGF1x00UXOgB+jeZ/HEZUhRyRctMs5yV9Dnnw7SPBatGjhxkw7jIe6qFkJeXH00Udz6RIEEvUlUjEyLrvsMmeQf8MNNxjxzIh9BvGiH2zmXnvtNWNu5DEm8sPjARdIXTwBpG0lISAEhIAQEAJCIDkQiAQRK1q0qF133XUudASEpn379nbrrbfavffea88//7yTGOEliTTrgQceMGywbrnlFnv00Udt9erV7pqYW6VLl7YqVaoYRvse/gkTJriYXNhx9e/f32cbfd52222OjHn1Jn137tzZ1cEz09dHHdqjRw8jyCrOAPQLIUOSR6iMK664wiBPkEBuhlQxnrAhPrHRsFFD8kedUqVKGR6etWvXtj59+hjzQc3Zr18/R8xQvxK2gqC2GP0T5PbJJ5/kVhcWg1hlhPpwGfoQAkIg3xBQw0JACAiB/EQgEkSMCaJua9OmjQ0YMMA6depkkJuGDRu6QKx169Y1wkxQj9AUkCqCsKJi5J7hw4cbdSBU2H9hyI4EivqoAAnoim0WISHI8wn1HmSsZcuWLgsHAGJ6YT9GH4TToADSBDGEFGHsTzt+PJSjLiRkBf1zja0aqssTTzyRS2ePxo4BOBkg2SNRUKZMGevdu7cjZEjGkJIRy4zYaZ54Ml+CzkJIKUPqxjgYE6rRhx56iKaUhIAQEAJCQAgIgSREIDJEDOwgMocccogdd9xxBikiZAWEA8N2yklBEDi7KCRfRx11lOEhifQIe6kgCBwhq1mzprFlEWo97LNoi0R92ggnpGu0Qd6hhx7q+qUuydcn5AXXPpUvX94gf7RNAFfCUzRp0sSCIHAqVTwbIV20R4gJDP+RduHlSYgOxk5/JAgoMdKOP/541zd9QuyQ/lEOofP9UtauXTtr1aqVQVKJlQaZpF7eJbUkBISAEBACQkAIFBQCkSJieTFpVI7nnHOO4ZGIFCov2kzURuvWrQ1bNmzPvDoTWzS2P4IUItXiPiRb2Iv5FFabUr6tia2PfFscifi/rW2ovhAQAkJACAiByCCQ5gNJOSLGeqImRH0YBP9Gxic/vxNG/EjvIIJI9/K7P7UvBISAEBACQkAIJDcCKUnEWBJUhqg1OS+oRDR91KQiYQWFuPoRAkmJgAYtBISAEIghkLJELDZDnQgBISAEhIAQEAJCIKIIiIhFdGFSaliajBAQAkJACAgBIZAQARGxhLAoUwgIASEgBISAEEhWBJJp3CJiybRaGqsQEAJCQAgIASGQUgiIiKXUcmoyQkAIpCcCmrUQEALJioCIWLKunMYtBISAEBACQkAIJD0CImJJv4TpOQHNWggIASEgBIRAKiAgIpYKq6g5CAEhIASEQLYIEGyb7ea6dOli7CccX3HVqlU2e/Zs++OPP+KL8u36/fffN/YdZiu+be2EvZTZU/naa6912/lt6/2qv10I5NtNImL5Bq0aFgJCQAgIgfxAAPLCFnPdunWzihUrGtvK1axZ00aMGGGjR4+2RYsWZeqW+vvss4+NHz/eVqxYESsjf+bMme6+lStXGruy7LTTTlanTh0Lb5HH+XnnnWfsnLLrrrvasccea+eff74RvDsIAitWrJjde++9rt3GjRsbdXbYYQfbbbfdrG/fvi4//uOYY45x46F/xhEu/+233+yNN96wRo0a2V577WUlS5a0m2++2T788EPr06ePUf/nn3+26dOn208//RS+VedJiICIWBIumoYsBISAEMh3BCLaASRk1qxZdtVVV9mPP/5or7/+uiMjkKxff/3VbrvtNkNiFB4+BAoyU7Ro0XC2ISXr3Lmzk5I1adLE3nnnHWvWrJktXLjQHnjgAVu/fr2rzy4to0aNcmWDBw925S+++KJdeeWVrnzChAl25513unOI4LBhw2z//fe3l19+2W699VaXH/8BWWvXrp117drV9evLIVaQOghX69atbcOGDbZ69Wpr3ry59ezZ0815l112sQoVKljx4sX9bTomMQIiYkm8eBq6EBACQiDdENi4caPdfvvttu+++9pdd91lZcqUcRDsvffeBnF5+OGH7dtvv3V5v//+u5Ms3XHHHfbQQw/ZN9984/L5gLRBtiB0SK7Ioy2u69WrZ5MmTbJBgwaR7RLkp0SJEnbooYfGrpHEBUHgpFYuc8sHpG+PPfawAw88cEtO4gP93njjjfbggw8a86LW448/bi+88IJ16NDBzj33XAuCwEniqlWr5qRrQRBQTSmFEBARS6HF1FT+EwK6WQgIgSRAYNq0aU6SBVmCfMUP+eyzzzbUlOQPGTLEkZfatWs7MoMEjXzSggULDDurRhnqP67DCQLUtm1bGzhwoD3zzDPhojw/P/30042xzJkzx7777jtHGPfbbz+rW7euod4Md3jIIYcY4wrn6Tz5ERARS/411AyEgBAQAmmDAOpEpGFHHXWUkxbFTxwbL+yqsKfq37+/oUps0KCBXXPNNTHpGfd88skn9vfff9vuu+/OZaZUNEOFidqR+1q1auVsuVCJZqoUujjxxBOdnRoSMhL3hYoN6VvHjh1dHdr9559/YsWoKLExW7p0qa1bt86pWWvVqmWMIVYpdHLAAQeErjafMjbUtVWqVHHzQbUZ7mNzLX1GD4HNIxIR24yDPoWACxjYeAAAEABJREFUEBACQiAJEIBo4QW5NQ/Hjz/+2BEf1I1MC8KDrRjnpM8++8wSkRrKSNRHnXnJJZdY+/btnfSMfimLTxjcY9vl05tvvpmpCipRJF+UY8uGzVe4AsRx7dq1tuOOO7psr6Z0F7n4QAXL2Oj3008/dcRx/vz5ubhTVaKAgIhYFFZBYxACQkAIpAECeTHFypUrOxXekiVLLCepDwb7pP/SJzZcjzzyiFWvXt3uueceW758ufNY3NY2MfY/9dRTnccmtl9lypRJ2MRBBx3kbN/w+vzhhx8S1kmUCWk8+eSTHbGEXKKaRdqXqK7yooeAiFj01kQjEgJCQAgIgWwQQG1HeuWVV+zLL7/MUmvZsmU2Y8YMJw1DErVgwYIsdcjA3ipeMkV+fML7EacAjPWnTJkSX5yra6R42LZddtll9uSTT8acCfzNEEZUmkjGevTo4QgfHpdIuXwdjr/88os98cQTnOaYIGGE2Mixkgojg4CIWGSWQgNJPQQ0IyEgBPIaAaRU/fr1c3ZXl156qYsbhspvzZo19tRTTxlhJk455RQjFthxxx1n9evXd8FavZRpw4YNLs4Ycbxoy3tYMk6Izrx581w4ie+//z4m/TriiCOsV69eVq5cOao5SRyhLVAnYp+F3ZpXlWIPRl+Uc/T52I3NnTvXuCfsAABpwjaMcBQ0jtcm9mSQP0gZKlSkY++9954RkPbCCy904yK2Gc4HqCBRTXIvbRG3jBAeSMnIU4o+AiJi0V8jjVAICAEhIARCCJQvX96effZZu+KKK5xXIzG2MFAnvAQEhqp4VELM2rRp4zwRseM666yzrEWLFoZXIhIjEtIz6pNoY+rUqQapo30Cq5JPwhCechwFIGmoLCFCBHol3ATxw6iHXRm2WnhqQgqJc0a+T5AppGz+mthlRx99tFN/+jyCtz799NNOBXvLLbcYcyDy/w033GDMEWJG7LIjjzzSSf8YK2Tstddec+E1kKxB+Hx7OkYbgTwlYtGeqkYnBISAEBACqYIAdlYQFMgHCZVdw4YNM02PeF7dunVzUrKrr77aBWllWyDie+Etib0WJAqJGjci9aItElshITEj3ydIF5I0iBztUs+nyy+/3FXDlszncSTSPmEyMPgnIUEjxAaVIU/Dhw93UfMhWOSRkGYhQXvssceMNkaOHGkQMuZMObsEQOgoI+FQMGDAABd1H2JJcFm8KKmrFH0ERMSiv0YaoRAQAkJACCRG4D/lYtSONA0SAyn6T43lcDOSq6ZNmxoJ8giRozoelJA7JHVcb2+CuNEO4TqQEhLYtm7dutvbnO4rYARExAoYcHUnBISAEBAC0UCAcBEQmAsuuMA++OADizeOz6tRooo8/vjjjYQkjnaJc0aUfqR44bAalG1r4n72yaR9UqVKlTJtf4TTwp9//ulsy7a1bdXPfwRExPIfY/UgBPIOAbUkBIRAniOAxIqgrHg35nnj2TSIIwGkKQiCbGrkXTZqU7aFQkWKQ0LetayW8gIBEbG8QFFtCAEhIASEgBCIKAIY97MHZ8uWLY29LSdPnuy8TiM63LQbVtSJWNotSDJP+OeffzaMS3Edxz4Br5/4+RAQEfdryokDFF/++OOPG/ezDQjxgOLLE12/9NJLVrVq1Vhi6xJfj3OMZevUqWPUiw8AOXHiRMM+A/XA22+/nZaie2IxnXPOOTH8PJYjRoxwW8B4LP0RTzK/ztTFvoY8X44rP3Y3lGG4vK1Rwn076XLENgnDbyQyeNphmJ3T3Kl/xx13GPV79uzptsTx9VFBYYAO9nzveeD6Mh2FAFH3+buMHRl/YwnVgfOAkClcBETEChf/lOmdHzOxfQh4yCa6uE9fd911hou3nyQPaGLl4L0E4erevbvhgk058W94aOPB9PzzzztXbu73MXiokyhh9/Dqq686N3b+uODeTcwf6hJ5G/d0DFcJonj//fe7rT8oY7wQwVatWtmDDz7oPJK4d+XKlRSnVcI2Zo899ohhePHFFxvhAfDQwoYmHgxiIOGRBX486KdPn+68tajHpsWsH0bJrAfrD76UKSVGoFOnTkYYhLfeesv4/t9333323HPPWaJ/2DARFBQyBv68rBCOgXwIL/spBkFgF110kRFn6swzzzTiTCVqS3nZIZBc+fy+ihcv7mzCimdzxB4tPKuvvvrKXnzxRSPaP4Fjw2U6L3gERMQKHvOU7BG7g7p167rgirhoDx061Lgmpg4ThlDhUo3bNhIo4uZAgki4jvNmhgSmT58+RsTrJk2aOGkM5I77s0s8tGiLoI14I9EedekPYnfGGWcY0h6IBWW4rtMfMXYeeOABR8AqVqxo9erVsxo1aljbtm25Pa0SEb1ZL2IXkXiI495ftmzZhDjgHg/ZhWzzh5/1hIBRmT/wSGtwvaetE044wYgaTplSYgSIM8V3sFixYnbwwQcb0tlwkNHwXRA14lxdf/31xhrxcsE1bSAN4zvNg7lz5842bNgwg0xzDLeh89RCgOCvGzZssA05JOzRwrPmbyyE/o033jAcFcJlOi94BHYo+C7VYyoigCcQ2474ufGAxnOHBzZ5K1ascPusoS7hmoT6hIjSSFcgYjywyaOM+4866qgct/OAUBF1GlUOtg88gJAKcD/5qCUbNWrEpUsYxvKwIkI10jlIAwTOFWZ8QMSQ8JCfcZk2/1GHFS1aNDZfooGzX513sY8VbDmB3I4ZM8bGjRtn4Lx06VIngaEYCSSEgocCEhtiI0GAKVNKjAAvHaiLpk2bZvwOUPFDbhPVRoqBpx0ecpRD3LgmgCh5GJ2TT+L3g6SzdOnSXCoJASOuWrt27WzQoEHubysSsR12EA0o7K+GVqCwVyBF+0d1AqEhEjVT5MFMHg8NrklIYoIgMLYCIRGxOgj+9SAiMvbnn39O1YSJ2DlIAJCkNWvWzEXYJsghlVH1YLcUfgj5/pDeYLzKViRhqQ/kLwiCLPvA0V46JWIbnXbaaZZILQkOvEGfe+65hhcWQS/B/qSTTqLIJQgy64D0EcKL2tkV6CMhAgTqZFNptrbhAYmEAwluosr8HiBc4TIIcyIJGrZ/PHixBQrX13n6IcDLEaYevEDxN5kXUF6e0w+JaM44DYlYNBcilUaF/RVv9rzVEzAxPLec3r6ye/BjYI/qE3JFQmJAHrFzkLgQ6Rr7LlSR2CTxAPJ9Ztdmbst9vXQ5YswLeapWrVq2UwZTCC7SRvbOY187VL3+BggvBHnw4MHOMwuJz9dff+2LdYxDoEiRIoYkC0kj9jqoG3kxiasWu8xNiAV+H9hrQup4wYjdrJO0RABJKna5/K7jdwtIS0AiNmkRsYgtSCoMB3UjhAupiZ8Pb2QQJ/Zo83moESFtqE94eCOh8mUckaIRCJG3fcTpSF1IeOSFH/zUJeGNCUngPv7Y8ICL74969MV4dtllFwuXQ/IYD+XUS8eEmndrqkQkkGCMxx5ep6iUcbxgPT1mYEugTLZvQR2MmtiX6ZgZAbbVQTqBQwk2YNjgEWoAMpW5prl9Bvk9hPMhbdjr+TzuA29eUE4++WSfrWNhIlDIfWNPWMhDUPc5ICAilgM4Ktp2BFBHrl692ngIhB8OvPGXK1fOMCr2rWKrhToSqRm2YagSsTminAf9Rx99ZHhYoqLEJR+jYxIEgPuoF07cTz/YzRx++OGGCgdjVF8HWzSkA7j9Y79GPe+1ifflzJkzDePysLrS35sOR9S14AWhzWm+qC4x9oVYYxPWo0cPw9uUNYu/D5yph4osvkzXmxEYMmSIk4hxdfrpp9utt95qeLnxfSYvnNhTcMGCBeYljHhGEhIGaZqvh7cwZgD8BnkZ8fk6CgEhEE0ERMSiuS5JOSrewu+66y57//333Ua1kCa8GonPhYQKWxhE5HPmzDEeFqNGjTLe/LFxwUYGV3sIF1IqYn7xAOceHibYzCBWJxECA+Pyp556yvAeW7NmjXswoQrjoQbZoj+89l599VWbPXu24eZP36jMkLJBwlq2bGl4dUIikELg5o9qMynBz4NBv/POO4YEBeIbbg7iRYgEcCIfkovkBtyxB2N9S5UqZWxEDMY9evRwjhmsI5JMvGXDtoG0ofQvApBZbMOwXYRg8YICgeU7jpQRez2+29yBmpfvP/WRNCJNI+4e0kfKJ02a5Iyw+c6zFvwGUdn7taOOkhAQAtFCQEQsWuuRtKPBtoiHNTYuhC+ABJF69+5tVapUcfPibR+CRT0Mvr2hN4U8dCBJPOSRaiE5gxQlknxRn0Q9vMUgcdgpoQrlnDIS4TO8qo0HFeEtUGtShgoT41USXoPEcqJ/PCspT8cEGeVBHz93VMbY6Pl8QiOULVvWkGRiK4aqDI9V1L2o2CAJqJAx4keCA+65sWvy7afbcejQoS5UCwSLFw0kufyG+I6iZoTsov4FF9TmfKeJ/UZIAlTAqIrBHuku32fUwfwe+P2RkKCxXtyvJASEQPQQEBHLizVRG04NyJs86qn4hA2YhwgVCtIwQh4Q9NPnc6QeEiokA0iykBSQn11CEgABxCaNN38eZPF1IX8ff/yxk4gRYBTbtXAdjPyR7CClo24Q/Ou1Ga6XDucQ0cqVK2eZKiFHIND+YY7KmXhvOEWw1pAwT5iJE4dqGmkNak6kOVkaVEYmBJDOIslFGsZ3EakwhJZKYI1DRDi+HfVHjx5t2EkiUfYSTDzhkEqzJuGEpxxtKQkBIRBNBETEorkuGpUQEAJCQAgIgWwRUEHqICAiljprqZkIASEgBISAEBACSYaAiFiSLZiGKwTSEwHNWggIASGQmgiIiKXmumpWQkAICAEhkE8I4KCCTey2eqMSIoZg12wjlk9DU7NJiICIWEQXTcMSAkJACAiBgkGAMCFjx441vFUJmdO/f3/n4PPuu+8mHAAOQITqYb/VcAUcKJ555hnDC5tdDdhDFOcjYhRSb9WqVUb75HOtJARAQEQMFJSEgBAQAkIgLRFASkVYGzapJ44e4XXwwGZLIOIgJgKFuHk+vIgvJw7fpZde6jbCJyYibRIjEY9X387RRx9thBzx90TsqOEUEgIiYoUEvLoVAkJACAiBwkWA7aEIscJOBOzxSfgVQrjUq1fPCERM8Gc/QmK6EVOP0CDEdePalxGSB0kXIXC6dOli3E/4nYYNG7oAu7RDgGPiJYqIedR09AiIiHkkdBQCQiC9ENBs0x4B4g8S8Paaa66xEiVKZMKD69atW7u8v/76y6ZMmeJ28mjVqpUR640t2FxhxgdBdVFvEqg6CIKMnH//s+ME9f/+++9/M3UmBEIIiIiFwNCpEBACQkAIpA8CbAkVBIGxu0aiWRM0mnxsuwYOHGjs3oEKE/svH0iXcnalqFixoh1wwAFcZkmoJJGKZSnIyGjfvr2zGyNoMnveZmTpf5ohICKWPguumQoBISAEhEAIAb91F7Zcoewsp+zdiVSMrbsoLFeunLG9F+ck2mFnkG1VO+IUwA4jqEfZmqVSvSYAABAASURBVGrhwoU0p5RmCIiIpdmCa7pCQAgIASGwGQEv1Vq+fPnmjGw+se9iu6ldd93V1QiCwIIgcOd8FC9e3NhqDfUk17lNN954o7G/LbZl7J1LP7m9NznqaZS5QUBELDcoqY4QEAJCQAikHAKXX3657bTTTvbyyy/bH3/8kWV+n3/+uWGYX6RIESNmGB6WWSplZGAbxv652Um0CGuBoX9G1YT/kbaxh+jWJHMJb1Zm0iMgIpb0S6gJCAEhEBUENI7kQuCcc86x2267zYjr9cQTTxjEixmgapw4caLNmjXL8I6sVKmSIe0aOXKkUQYhw+MSCRZxwho1auTszPC8fPHFF4082uGI7RcOARjr451JHvdB8KhDwhMTVWf58uW5VEozBETE0mzBNV0hIASEgBDYjECxYsVcENe7777beUVijE/4Crwlv/jiCxeGgpAT1apVs86dOzvJWY0aNQxyRSwxJGUQNYz07733XmvcuLE99thjhpE/9SB52I1xjQ0ZqsgPP/zQMPjv2rWrI3eM5MEHHzTUk7vtthuXSmmGgIhYmi143k5XrQkBISAEkhsB7L6aNWtmr732mhGSAukVki/CVHhPRwjXRRddZHPmzDG2J+revburTyR+wlwEQWAQs5tvvtmmT59uxBXDwH/IkCFGLLHdd9/dgTRo0CBDKoYErFevXs7OrH79+tamTRtDSkY4DSRnrrI+0gYBEbG0WWpNVAgIASEgBKKEQJ8+fQypHMFjb731VueJucMOeiznuEYpWKgVT8FF1ZSEgBAQAkIg+ggQhR9HAZ/q1q3rpGTRH7lGmJcIiIjlJZpqSwgIASGQtwioNSEgBFIcARGxFF9gTU8ICAEhIASEgBCILgIiYtFdm/QcmWYtBISAEBACQiCNEBARS6PF1lSFgBAQAkJACAiBzAgU9pWIWGGvgPoXAkJACAgBISAE0hYBEbG0XXpNXAgIgfREQLMWAkIgSgiIiEVpNTQWISAEhIAQEAJCIK0QEBFLq+VOz8lq1kJACAgBISAEooqAiFhUV0bjEgJCQAgIASEgBJIRgW0as4jYNsGlykJACAgBISAEhIAQyDsERMTyDku1JASEgBBITwQ0ayEgBLYbARGx7YZONwoBISAEhIAQEAJC4L8hICL23/DT3emJgGYtBISAEBACQiBPEBARyxMY1YgQEAJCQAgIASEgBLYdgdwRsW1vV3cIASEgBISAEBACQkAIbAUBEbGtAKRiISAEhIAQKHgE1KMQSBcERMTSZaU1TyEgBISAEBACQiByCIiIRW5JNKD0RECzFgJCQAgIgXREQEQsHVddcxYCQkAICAEhIAQigUChEbFIzF6DEAJCQAgIASEgBIRAISIgIlaI4KtrISAEhIAQKDAE1JEQiCQCImKRXBYNSggIASEgBISAEEgHBETE0mGVNcf0RECzFgJCQAgIgcgjICIW+SXSAIWAEBACQkAICIFURSCViFiqrpHmJQSEgBAQAkJACKQoAiJiKbqwmpYQEAJCQAjkNwJqXwj8dwRExP47hmpBCAgBISAEhIAQEALbhYCI2HbBppuEQHoioFkLASEgBIRA3iIgIpa3eKo1ISAEhIAQEAJCQAjkGgERsRyhUqEQEAJCQAgIASEgBPIPARGx/MNWLQsBISAEhIAQ2DYEVDvtEBARS7sl14SFgBAQAqmPwKZNm+zRRx+1yZMnZ5nsunXrbNmyZfbnn39mKcuvjDVr1tiSJUvsf//7X5518fnnn9uwYcPspZdeyrM21VDBIyAiVvCYq0chIAT+RUBnQiBXCPzf//2fVapUyY499ljr3r27/f7777H7IDhnnXVWrLxfv372119/2WuvvWbz58+P1eNk6dKl9uKLL9o333xj5557rrunUaNGtmLFCopd2rhxo91zzz2ujD6pd/3118euybv77ruNek8//XSm/Guvvda1Ef+x33772bx582z8+PHxRdleM6bbb7/datasaVWrVrV27drZ5xnki/Fbxr+ffvrJwOWdd97JuNL/ZEVARCxZV07jFgJCQAikEQI333yzk3CtX7/eBg0a5AjNP//84xA4+uijbejQoVakSBF74YUXHGHZbbfdbOLEidaxY0dXhw/I18UXX2ytWrWyU045xUmTatSo4drq27ev/fDDD1SzPfbYw5G9Jk2a2HHHHWevv/66PfbYY3b11VfbokWL7KqrrrIePXq4erQFGVq7dq21adPGnnjiCddG/Meuu+5qzZs3tyFDhjgpXU6Ssb///ttefvllg1yWLFnSXn31VXv//fetRYsWds011zjyxf0QwlKlSsV3peskQ0BErKAXTP0JASEgBITAdiFw6qmn2k033WRHHHGE3XvvvRaWBB1wwAEG+apQoYJB0L7//nubO3euLV++3PWFqvK+++4zJFYQLTIPPPBAGzhwoHHPm2++aY888ohRjzJSuXLlnASOc1KJEiUsCALjyLVP+++/v+29994GIQyCwGcnPPbs2dORvK+//jphOZlz5syxrl27urkyX8ZJfpUqVWz06NFWr149J9EjTyn5ERARS/411AyEgBAQAmmDwA477GAdOnSwww8/3O644w777LPPsswd269PPvnEbrvtNqeepALqS9SCjRs35jKWgiCwWrVqGSrA559/3kndLB//HXXUUc42berUqdn2MnLkSNtxxx0d4WK+4Yq77767tW3b1pHOcH5O5yqLNgIiYtFeH41OCAgBISAE4hAoXbq0denSxf744w+75JJL7IsvvshUY+edd3aSLMp9weLFi+23334zVH0+zx+RpF1xxRWuLSRRw4cP90UJj5A21II+XXjhhbZ69epMdZ988klnO4YELlNBxgX2YgsWLHB2bBmXTiWKChVJF7Zt2JJB2LwkjDrhxBy8VC+cz3m1atVcv926dctkR0eZUjQREBGL5rpoVEJACGw3AroxHRBADYjROqpHjNix78JuirkjRcImC6kS1ySM9LMjNpRTH7svbMhQe86YMcN8e5SHU+/eve2jjz6KJey5IIe+DtK3vfbay5W/++67Nm3aNF/kjth14bn5888/O3LYsGFDp9qcMmWK7bTTToaNGGMPgpzVnK6x0Aeq1/fee8/GjRvnHANmzZoVKtVpVBEQEYvqymhcQkAICAEhkCMCZcuWdYb0qCEhIXgR5nhDLgrxuKxcubKTuEG2cnFLliqoTfG0/PHHH+2iiy5yBv9ZKm3JuO6666xixYp25JFHOo9IssuUKePOsXPjOrepc+fOzmEBeznmELZ3y20bqlfwCIiIFTzmed6jGhQCQkAIpCsCeD8SSgKbq08//TRbGDCox2sy2wpbClD5YVBfrFgxGzFixJbcbTugGiXMRKdOnWzmzJn266+/ZmoAlekuu+ziDO4nTJhgqCEZPxI5pGF4a6LqRJKWSCqHWhPv0UyNhi5oHwndIYccEsrVaVQREBGL6spoXEJACAgBIZAFgY8//tiFkPAFQRAYqr2WLVsa5Mbnf/fdd07th5qQPDwj8abcsGEDl7GEypI6YWka3pL333+/YRgfq5hxQpsQI0hWxmXsP6QI6ReSOcopOPTQQ+2WW25xgWMJWUGeT5As+kA9ybgIi3HnnXcaY4GInX766da6dWvnGYqtF/W5F1u4Xr16GR6Xe+65p/3yyy/ONu3LL7/MZA/GHPfdd1/nXcp9+ZDUZB4iICKWh2CqKSEgBISAEMgfBIhMX7t2bWf/REgHVIi+JwgYxKVp06YuC1LkCQz2Ukiajj/+eENK9MEHH7g6fHTt2tUIiYEt1ZVXXmkQGvKxMYMgPf744847EZJGHDMCySJZI+YY1+QTXwyHAe5DMnfppZdy6kgc6sannnoqk0QMY/xvv/3W9UsYDOaFBI0YaCRuRhqHQwD9MzYM8JFuYQtXp04dq1+/vnEPY/7qq69s+vTpjvRBwJg747jgggtizgC0qRRdBETEors2GpkQEAJRQUDjKHQEICJvv/22U+ehYoSUhAeFsX3//v1dFobynFMP6RHEpHjx4nbrrbcaISp8VH6IGHVIo0aNsoMPPtjd7z9Qe95www2G9ImgrdTziWvyibjv8zjiQAC5oj0SY7788st9ky5QK2QKYohKEnKJKvS5556z888/3xnrU7lo0aIuoCvxzWiXNtnK6KSTTqLYJVSnlJEGDBjgnAOQplHnmWeeMcJgQPxcZX1EFgERscgujQYmBISAEBACeYnAOeec44K3QpCINZaXbYfbwkYLckRCSkeYC8rx8CTuGbZjSPHI69Onj2FcjyoRwoY0jvztSUjDUNFCvvDIPOGEE1w8su1pS/cUHAIiYgWHdTL1pLEKASEgBFIOAVR/bEN02GGH2Ycffphvqju8JpGUkVBPAiR2XqgR6f/AAw8kyyUvVWvWrJmh9nSZ2/mBpyZ9+kSIjyAItrM13VZQCIiIFRTS6kcICAEhIAQKHQFUfqjusLsiZldBDQj7NFSSxTNUpAXVZ3L1k76jFRFL37XXzIWAEBACQkAICIFCRkBErJAXINW7Z1Ne3LLZ8404OfHzff/9941yjGZxS48vT3SN8S1bkCSKGUQbeEhhyIshK+7q4Tbmz5/v+mN7lEWLFmUbOTt8T6qd4x7PFioYMGOIPGzYMMMt388TzMCRAJk33nijUY43li+PP+IBxsbJeJFhwMz6hOtgF/PAAw8YfWFAHB9TKVw3Hc6JAE84A76jrAEqsvC8KX/iiSeMcrzz1q5dGy7Ocs56sZ5jx4417ILiK+B1d8cddxi/ixUrVsQX6zoFEeA7kZ82cCkIWaFOSUSsUOFP7c5nz55tkyZNsvLly7tYN7iX4/njZz1t2jRr0aKFnXjiic6tHLuGrUWShhBMnz7dHn30UVu1apVvyh2Jgo1hLN5IZ511lquDu7krzPjAe6lVq1ZWs2ZNIyI3LvCQiIyitPoPySIWEa73PPQhUOC0ceNGhwN2LJAwMLrsssvs2WefNer7clcp9EF5EASGKz6eah06dIiVQiKIkUSk8EaNGtngwYON8nQmY7wE8FICIcZTjuCdBP30oLE3IUbXhEEgcCflrIkvjz8SjmH8+PFundhLMVz+1ltvOQKM9x/G4Hz/aTtcR+eph8DKlSuN8Bdz585Ny5fNZFtREbFkW7EkGi/ba3Tt2tXYTLd79+6GbQQBCZkCEhg8h9j+AwNTSBoPivbt21OcbaIN7Dv23ntv463PV+QcqQsEDM8o4uxgFItbOFIwAi4ieTvvvPNiwR/xVOrYsaNvIm2OkGFiHyG9ggjwB5s97pBcAQLEihhFF154oYE1++7hBo/UhfJwYj3r1atnkC3wJa4R5MHXeeihh5wBMnGWcKunLdz7ISK+TjodIVQnn3yyIdGFtEKUeKEgpAI4vPbaa8Za8FLCCwovHOCOxJHyRKlq1arOE9CHZPB18NiDZLN3Ir+Ltm3buu1vkI75OjqmJgL87eW7hNckv02Yb9tKAAAQAElEQVRevvh++GCzqTnr5J2ViFjyrl3kR85bOINEyoW0ij8K7KlGHteosJCScE3iAYUabHve2GkLtQvbk9AWiUCNbJzLpruLFy82pDMQMcpIkAyICFI2rtMlnX322VayZMnYdH3sIm+4DBHAoBkPMyoRv4n64AvhJc8nNi8+7rjjjD/8EDlIHg9/X466jJhO/prvBG1DLnxeOh0POuggg5T6OeNdBybEwCIPgkr4Ah/RHY86XlR4mYiXdlE/pwTGSDy539eDNPOdRxrq83RMbQQIKFurVi3jpRMtRCL1dcoikCQTExFLkoVK5mFec801zi4L12weMswFyQAPA+/aTR4u3UEQWPz2IZRtLUG4giAwyICv6wkA0bIhYRC8I444whfbf+kv1kgKnLDNCmQAl36mQ3wjsPJ/sCFoYIkaF3UadcIJW5SXX37ZUHtBJI455phYcdGiRQ1yRlwln4k0E2mNv07nI+SKhGQYHMAejHmx4JqE5JatbLJTDVMnUSJcAipgyJ4vJ2Ap7fOb8Hk6Jh8CkGmkptkl7AHROviZ8bKJdBWJNapvtmLyZToWPgIiYoW/Bik/Agz1GzRo4NQxGCGHJ8yDOny9veeoNXENHz16tE2ePNkgeWPGjHHqy8qVK8eazav+Yg2mwAmRu1HjeikMpAApIvZ9PLR5i+YPN3vjQcripwwJrlu3rvFQ4BwDf+pTD7UIqkokYzwMWBvUmUQUpzzd0+uvv+5U99g1ggXYQ4DZ2oYjziyQWySSfMepk0NKWAS5S1igzKRFwP/e+M0lSgSG5eUpfoKYHKAVgJDHl+m68BAQESs87NOmZ1SS7At32mmnGUbglvGPBzbSMaQpGZfuP9GgOeEtHg871Iwk9nx77733KMo20V7nzp2dYXLz5s2NP0QQDIgXBI3y7PpLRC6y7SiFCsAbsorEEoz91CAD5LEdzBlnnGGodfmjDnkKgsBXix3BFamNxxybJxwqqAApwykCA31fDuFDDU15uiZsdZD87rbbbs6+zn8Hq1evbtjQ8UKBah3iSiT2M888c5sjpNNmEAQW/xsLgmCb2zL9ixQCqLiRPGeXkG5Duhg0x0MPPdSw10RdjRMI3zvKlKKBgIhYNNYhLUaBfQoPcyaLlArV4BtvvMGlIXkh1AWeehgfY7yP+J0EiQurFN0NfMQlSBvefahdMNxH/cX+a/Rz7LHHun3kIGfcRn+QuzJlyjhDZ/LSKUF2CZuAzV5YdQUGxYoVMwy6IQAYlS9btszwnvRrR53sEjZjeKXiQenr3HXXXQY5Q8pDn0jJqlSp4ovT7ggJQyqIqpeXk3gAsNkjtAoSSVSUOJ+QF19va9c1atSwffbZxyZOnOiqQryRrrHeYZMAV6iPlEMAssVvkRdUvHJxhOJvZMpNNAUmJCKWAosYxSnwoOfNnocA9kbYq+BKzQOe8ZYtW9Z5L+K9h40Sxsi44ePJxxscqhpE6CSkMtiXcR+JBwrtY/fFQ408nyBh9Pvggw8aUgQIBGW8EWK0/OSTTxr9oS5D7cM+b5SnUwI7PKqYPypE1uiVV14x4k1BUDHIByNwvOWWWxxRveqqqwzpIjhRFxxRnUHSMAYmpht2TK+++qph3M8DgLok2sKGjJhZ2KIhaSM/XRMebC+88IIL6TJjxgybMGGCsR58n8EEtTqE6Z577nFOEMQSQyJJGfZ2rAmElmsSvwHsx3jxCNvi8fLC7wdzAMoIJ7Nw4ULr3bs3tymlMAL77befe5kibh+e66i2U3i6BTq1/OhMRCw/UFWbLnYNb2Hsn4Y9w8MPP2y81RNWAniwWyF8BdIv8rAjQx3JOeU5JYgZInbuQYXm6yJpgWzRL+fYTqCSpJz+UI+hJqUP3g4xWsWtn/J0SqiHURcSboLQIqwRISzwsEPNCDnlAQ5JYE3ADcmKxwiPV4gCRuY8+CG9hKaA9EK6MBT2EjHWiPVCVQnetIVq0reVbke+t3itIrm97rrrDOxZA8JXIImEsBK2AnILae3WrZshZfQ4YYBNoGJw9nlIGpF68CLDb82TNIgz9yMBY314IEOGkUz7e3VMTQQgYnjnQsaDIKs5QWrOOnlnJSKWvGsX6ZHzUIF8oVpB2sU5DwBPjBg8rvm8nfPg4MGObRd2LZTllJDiINXhYTRo0KBYVc55GKHKJDSFDwngK9AfD0D6wwCdYLJI33x5uhwhSqjFSKwPCW9TSGkQBM7Nfc6cOUacq9q1a8ckYR4fJDWQAaSUqHyXLl1qBJDE3gyjf/J9XVTEEDckndiFxa+Jr5cuR/Y3xDYMxwVw94k4bXw/id2GTR6x3HiQhgkwGKHSRXLGywTXJF448EImThS/DcKJkE8i7h4SNSRhSD5pM/wbpE7OSaXJiEAQBLIDtOT5JyKWPGulkQoBISAEhIAQEAIphoCIWIotqKbz3xDQ3UJACAgBISAEChIBEbGCRFt9CQEhIASEgBAQAkLgXwRMRCwEhk6FgBAQAkIgNRDAmxQHFOxJ42eE5zXbclEnviy/rn2fedk+MeLwSsdrNi/bVVsFi4CIWMHird6EgBAQAumNwHbOHqcPnBoIq4L3KaFWfFMQrnHjxpkvxzkBr16cEwiR4+txpC7OQeweQbgV7iG+IISGchIEB4cVykjEO8SLmHOfKKcezio+jyMewrQRnwg9Qjs4a8SXZXfNmAgrgzftSy+9ZIwZ0kW4GO4BE7yV8YblWik5ERARS85106iFgBAQAmmFAJItgjCzp2m7du3cjg8eAEgZsQo7duxokBNIWJEiRYwwLYRP8fXIh7QQ7JQAxXigEn4Fj21IFOFYqIukjLh4eK9SDiGCAEGGmjRpYhwppx7eqoyLINTsiEA92ohPxE6kT7y68TKOL4+/Jt4cIX7oi/oQSAL93n///YbnM/UJSM04OFdKXgRExJJ37TTy5EBAoxQCQiAPEGCnAMLPtG3b1oVL6d69uxG2g6aJm0XsQIIJs5MDdQmF07BhQ2MXD+qQCKRL+A5itRHklDiESMXII87alClTqGaQOGKysd0XMfWQOhH/jViIQRAYeZRTj/Yhh2zzxZFYhq6RBB8QsTp16hgx/CBwCaq4LKRnxPYjrh+x+G6++Wa3FRYx55DyQb4gh4Q38cF+3Y36SEoERMSSctk0aCEgBIRA+iFAfEKCBSPVYncM4tOhHgQJiBfEheDN5LGTAPubItGinN0FCH7btGlTox553MMG2JAsJGfsWsDWXpSRIFoExuWcRP3wkXMSRI5E31znlCBz7EjBzhbZ1WP3CuZHrEPm6/slDh9x4giMzA4M2d2v/ORCIO+JWHLNX6MVAkJACAiBJEMAiRYSMVSHBItmu63wFFAZ7rvvvrZkyZJYNsQMMsbuGrHMLScEIe7SpYuVK1fOCKpLgOMtRQkP2G2hyvSJbarix4BqkfJENmOMDTs1thODlFHvrbfeMk+uxo8fbxAuSGKiASDxQ/qXqAxVJu3F29Elqqu8aCAgIhaNddAohIAQEAJCIJcIIH1q1KiRoU4kDR482JCC+duRZLG1U3g7LQhPTmo8SBj2V0ifsM3C5sy3F3+EdH3//ffmE2pC7NR8PVSmEC3K2U4Ng35fxvGggw4y1I8Y3Y8dO9YgiE8//bRhlA+JxB4MtSO2bNTPbWJ3C3bMYIcFdrVgzrm9V/UKDwERscLDXj0LASEgBITAdiIASUF1x36aqB+RAhEiIrvmkDZxT3bl5LNl19ChQw1pFvZoECny4xN7d7JXqE/YbYVJHgQQ+zTKK1WqZPEqS8aBjRjbWmFXxp6u2KOtWrXKkJJRDhnDQSG+75yukRSyzRgqVqRpOZHJnNpRWcEiICJWsHirNyGQBwioCSEgBEAAyRcSJ4zY+/fvb2H7LsrDCSlaWGoVLgufV6xY0QYMGGATJ0503pHhstyeQ7Aw3ifkRc2aNS1ejYjUKwgCR9BQUwZBYNh/lSpVyoIgsPr16zuvUIhZoj7x7kw0F1SsQRC4fSaRukEITf8ij8AOkR+hBigEhIAQEAJCYAsCSIrCkioM75EooYpERbilmiFxQkK2YcMGlwXBQh1IIFeXseWDctoM5yNZwmuRcBFbqrkDbUKi4kNUQIy4P9w/9ml4aRJSg/hhroEtH6gPIWpIvsgirAaekHhUMp9LL73UDjvsMMMZgXhlqEKpx3H+/PmGPRkYoI4lj3vDxIxxHHrooVahQgVuU4o4AklBxCKOoYYnBISAEBAC+YzA+vXrrWfPnjZq1ChnG0YQVt8lajhCQkCgyIPYYHO1YsUKV58QFYSZwAMR+ynqkLDJuvbaaw3jeEgPhIx8PCWbNWtmqPi4pr3hw4cbtmhcc+SafCRnOA58/fXX1qdPH0MyRx36w0uT8BPxBvsEdcVpAIkedYlDtvfeextxwbguXbq0YeN14IEHGqpXxkhMNGKQ4U1ZpUoVQ/pFX1xPmjTJhgwZYl6ViRND9erVjTZpTynaCIiIRXt9NDohIASEgBDIQAB1H6EnMG6H4EA0MrJj/4nR9fzzz7trbLIw5kc1iAF7rVq1HMlp3Lixcb+rlPFx8sknGyQKMkWg1pAqz5BWETj2qquucipE7MIgYEi6nnnmGeOafqpWrepIE4SIcvrNaDr2H3JUu3bt2DUG9HvssYcRh4xMJFwEoT3ppJNsxIgRhmQLqRhEDjs15kq4juuvv96wiWOcqDC59+KLLzZIHETynHPOceMkzhptE1vttddeM6SC1FWKLgIiYtFdG41MCAgBISAEtiCw8847W9myZQ3CRcK2akuRO0BeCNLKhT+nHgnpETZi2JNNnjzZkJShYkRCRjkJOy764H6fIGN4L8a3R336Ip9yrn2iHQgQ5aRq1aoZscNoE/Vl7969DecC7oMkYtRPHqpIVI7UIwVBYBBDVIy0Xb58eWdrxpgoJ9EXZSRswrCVIwYZpOzII490EjLmTV2l6CIgIhbdtdHIhEDBIaCehEAaIIAkatCgQUbcL0JM4KGYH9OGeLF9Eom4ZPSBLRfSKyRsSNHII0L/l19+adQjIWn7L8Tpueeei7VFe+wIEAQBXSlFGAERsQgvjoYmBISAEBACeYsAdlhE3Eealbct59waKkekVKggc66p0nRDIF2JWLqts+YrBISAEBACWxDAiB21YUGSMeKMoT7cMgQdhEAMARGxGBQ6EQJCQAgIASGQXwioXSGQGAERscS4KFcICAEhIASEgBAQAvmOgIhYvkOsDoRAeiKgWQsBISAEhMDWERAR2zpGqiEEhIAQEAJCQAgIgXxBQEQsz2BVQ0JACAgBISAEhIAQ2DYERMS2DS/VFgJCQAgIASEQDQQ0ipRAQEQsJZZRkxACQkAICAEhIASSEYGkJWKrV6+20047zRYuXJgJd4LmzZo1y21hkakgny/Y1JX9wvKqGzaTffvtt+3SSy91UaDzql21IwSSGAENXQgIASGQcghEgoitX7/eWrZsacWLF3cbJltaJgAAEABJREFUrT766KNu41OPNvtxsYFpkSJFjP242J6CrSnYMgLi5ev9+eefNmzYMPvxxx9txowZVqZMGbcJKvtusY2Er/fpp58a+3sVLVrUCOzHBqlsNbHrrrsaAf7oi81bLeMfm6oSiI9tJ9jbzOdnFGX6X716dXv55Zddv4wtU2HcBXucMfYXX3zR7UFGYMFjjjnG7rzzToPMDRkyxN3BfNk3bOPGje5aH0JACAgBISAEhEBqIRAJIgbBefLJJ2306NEG6Rk4cKC9+eabsV3jIUlcs4M9ErD69es7kjV79myrUqVKbEXYZ4vNXClv1aqVTZs2zdhri3p9+/Z1BI3KkLmXXnrJIGhPPfWUTZ061UaNGmUXXXSRFStWzN544w1jPzDqjhw50m3QCll6/fXXY/mUhRMbsXbs2NHtws9+YuGy+PMvvvjCbrnlFmNfsTvuuMM+++wz++CDDwzS161bN/vkk08MUlizZs34W3UtBISAEBACQkAIpBACkSBi4LnLLrs4VSOSJcgVhOTDDz+kyCUkVwceeKAjSn/88YctWrTI7r//flu5cqUr//zzz+3hhx+266+/3l3zUaZMGWvWrJnVq1fPxo0bZ2FpFv3tv//+5rec4Hr33Xd3EjE2huV+EhIy6pFXokQJsrJNkLEWLVrY448/btlJsf766y8ntWNuzLFGjRqOdNF/5cqVrX///nbwwQdn24cKhIAQEAJCQAjkFwJqt+ARiAwR81NHItW9e3eD/DRt2jQmxfLlHH///Xf7+OOPDRXmN998Q5aNHTvWihcvnoXEoFJs3LixXXPNNYZUbPjw4a5+fn2ceuqpNm/ePINoJepj06ZNjohBuo444ogsVSCbkLksBcoQAkJACAgBISAEUg6ByBExED700EOtV69eFgSBs6HyZIsyEurLqlWr2s4778ylYZO1ePFi23PPPd11/Ae2YG3atLGzzjrLbrjhBkPNyT3x9bhGkgWZQlLm05VXXklRLH399dfWsmVLO+CAA6xnz56uf1+ISnGnnXaKSeqwB5szZ441aNDA2aVh04b69Mgjj0w43iAIDOmbby98XL58uZPgQVJ79OgRU92G6+hcCAiBbUFAdYWAEBAChYtAJIkYkBx33HGG0fratWsNFV48GaOOT99//71RDrnxefFH1IaPPPKIswvDKB7PSkhRfD1I0PTp0+2rr76KJezIfD2IFUQMFeiSJUucnRfkzZejyoT4ffvtty4LezEkfJ06dXJSOzIhakj1EvVPeXaJMTMuHBGwlYOYZVdX+UJACAgBISAEhED0EYgsEQO6E0880fr162czZ860p59+2gjpQP72JsjYgw8+aEcffbR17drVsCvbnrZQKWLLtmzZMkcSkdAlamfDhg123XXX2SGHHGIjRowwQm5AwipVqmRLly5NqHZN1I7Pu+KKK9wpkjjGACl0GdvwoapCQAgIASEgBIRAdBCINBEDpjPOOMMZ4I8fP96+++47srIkDPlR12VnlxW+AXUjnooYzSNZCpfl5jwIAmdc/8QTT1iTJk2sd+/emW6DHKH2RE26YMECIxQGXpwY4NMvISlat25teGoiLct0c8YFITjw6MQhIeMy4f+ffvrJkUnmkrCCMoWAEBACQkAIRAMBjWIrCESGiEE8CNuAN+SUKVOMa8aOBKl58+YubASeheRBopBGISHD/grycvzxxxsEhXKfUA++++67hqqRc0hSEARGzC4IFJIq6tLemjVrjFhjnEPofvnlF4qM+1ADovrECN/nt2nTxryqkPhhrnLGB+MmRhgSK9qsWLGiNWrUyHlvrlu3znAewBgfR4S2bdsatl60j7pz4sSJdvPNN9sJJ5xgzJu5QeoIbeH75RqcKlSo4GKgZXSp/0JACAgBISAEhECSIhAZIgax6tOnjx177LGGRAj7K48pUqQbb7zRLr/8cpcFKSI2GJH1ISkY6iM5+/XXXw2y4yplfDz00ENGO5AcgsDisZiR7f6jWnzggQecxAqyhT0a9mGNMkgTHpheWjZo0CDDFqtBgwZGYFmfTyPEFiP2GNI4rklIuSpXruzmgZ3b3LlznQryhx9+MB/+gn7uueceI3YawWwhhVzTT7du3ax06dKG3RuxzYisv2rVKidBo33GQNyx8uXLG0SPPCUhIAQihICGIgSEgBDYBgQiQ8QgYKj7CMpKHC7ITHge++yzj7Vs2dJloZKDsFAXAoUHZdmyZa1Dhw4GmXOVMj4gONQhEU/MS9Qyitx/SNfhhx9uEKouXboY9XyCeFEJdaLP4wjhgyhee+21RoJsVatWjarOho2gtBjyoy5lTrVq1bKrr77aCFKLStJVzPggZhlenNjA0S6kjPs8qeOIPRtlpLp16zrpGW28//77rk0kY6Z/QkAICAEhIASEQNIiEBkilhcIIjErU6aMi5KfF+0lagOvSMJbtG/f3kgQI0JWUBeCBuE75ZRTuHQJj0lCXOCpWadOHZe3PR94YmKsjzqUfnE2OOmkk7anqby+R+0JASEgBISAEBAC24lAShExVJjYbhGHzEfc305csr0tCAIXbJZQGSQfywz7MezUUJdi3+UbwFOTetijhfN9eW6P2JYxL9ryCXKW2/tVTwgIASEgBIRAaiCQWrNIKSLG0kBYMHZHVcl1QSXUkxjQF1R/6kcICAEhIASEgBBIfgRSjogl/5JoBkJACAiBzAjoSggIgdRFQEQsdddWMxMCQkAICAEhIAQijoCIWMQXKD2Hp1kLASEgBISAEEgPBETE0mOdNUshIASEgBAQAkIgOwQKMV9ErBDBV9dCQAgIASEgBIRAeiMgIpbe66/ZCwEhkJ4IaNZCQAhEBAERsYgshIYhBISAEBACQkAIpB8CImLpt+bpOWPNWggIgbRC4O+//7YpU6bYkiVLssz7p59+snXr1hl1shTmU8b3339va9euzdPW169fb++++66x7V2eNqzGChQBEbEChVudCQEhIASEwPYg8Morr9g111zj0rPPPmubNm2KNbN69WpjX2Bf/vLLL9sff/xh9913n73++uuxepysWbPGxowZY8uWLbPOnTu79thr+KuvvqLYpd9++82GDRvmymjzrrvusv79+8euyRs6dKjbX3jChAmZ8tk/2DUS9/HPP//Y22+/bXPmzIkryf6SMQ0ePNhuuukma9u2rbEP89dff23Tp093N33xxRfWqVMnGz58uLvWR7QQyO1oRMRyi5TqCQEhIASEQKEhULt2batVq5aNHDnSevbsaTNnzoyN5YADDrALLrjASYfOO+88o+6uu+5qkKWrrroqVu/nn3+2Zs2auXJ2YLnooovsyy+/tIceesgGDhxov/76q6u7yy67WIMGDYw2KL/66qutcePGbnu7QYMG2X777WdnnXWWUY92GNeLL75ojOPiiy92bcR/+Hv69u1rCxYsiC/Ocj1jxgy78MILDbLVpEkTu/XWW+2www6za6+91nr16uXqH3300VasWDF3ro/kRUBELHnXTiMXAkJACEQIgfwdyr777mstWrRwUqz//e9/duedd8bUjhCi6tWr2z777GPnnnuuUffPP/+03XbbzXbeeWc3MCRS/fr1szPOOMNKly7tSBYkauzYsY5A/d///Z+NGDHCqLfDDju4vJo1a9qpp55qhx56qB100EFWqVIlC4LAHSFd1Nt7773t+OOPdyStbt26dvDBB7v+En3sueee1r59e5dQjyaqQx7qVIjX2Wefbffcc4+ddNJJdvjhh1v9+vUduWT83333nRUpUsQl7lFKXgRExJJ37TRyISAEhEDaIcB+wt26dbOddtrJunbtat9++20WDCBhH3zwgTVv3twGDBjgyleuXOmkaZdccom79h9BENiZZ57p1H8PPPCAjRs3zhflyxHCiGQOiVd2HUAIN27caEj3IHvhesWLF7cOHToYZDScr/PkRUBELHnXTiMvZATUvRAQAoWDwDHHHGOQsYULF1q7du2ykDHIS9myZe2bb76JDRBihhTqyCOPjOX5k7322stuvPFGp7K8/vrrbdKkSb4o4RG7LezEfGIs4b64CUJHOVI4rsMJid2sWbOcs8Bbb73lbMxQt3pjfkhahQoVrGTJkuHbYufly5d3ErhYRuiE8dMvdmNhO7pQFZ1GDAERsYgtiIYjBISAEBACOSMA0cIuC0KEbVb37t3t999/j92EtKxEiRLOhstnou7bf//9/WWWIzZcSMRQP6L2XLRoUZY6PgP1Z8eOHc2nVq1aGSpKX758+XLDK5NybMree+89X+SOpUqVcrZpkMMPP/zQSeMgYTgIoBrFVg3bL1SP7oZcfjz88MN2ww032OWXX26jRo2y+fPn5/JOVStMBLaBiBXmMNW3EBACQkAICIF/EYBsQcYw3n/ppZecV2OYjP1bc/MZ6krUmpuvEn+i9kOSRClemHhYch6fDjzwQDviiCNiCZstb4tGXWzKMO4vU6aMs+vCyJ58nxg7oTOw+4KsVaxY0Ro2bGh//fWXUzkiMYOYIcHz9+TmeMsttxgG/CeeeKLR5g8//JCb21SnkBEQESvkBVD3QkAICAEhkA0CucjGW5LwEkiAVqxYke0du+++u2F3lW2FLQUY/D/xxBOGMfxzzz23JXfbDjgPINWiHQgg1+EWIFyQMSR7Ph81ImpT8vDm/OSTT5xEK5EtGATxl19+8bdmOdI+zgU4FGQpVEbkEBARi9ySaEBCQAgIASGQHQLEDFu1alWsOAgCa9q0qZ1++ulOouQLfvzxRxdLjPrkISEiL57AQGqoA3GiHom6OALEEzckVBAjYnlRzyfyaZdQFz4PiReSLQgiUjufz5H4YIcccojz6uR6w4YNbuynnHKK88pE9YkDAapSJHTe/gzHhBdeeME++ugj592JBJAySCNEjrZItIfU7qijjuJSKeIIiIhFfIE0vLRCQJMVAkIgGwQgOeecc44L33DllVfGvCGpXrx4cUMtR2wvriFG2I1hzD9s2DB78MEHrWrVqgY5Wbx4MVVcuv/+++3kk092AV7btGkTi3yPmvG0006z3r17u3oQMoK/YjtGRo8ePYxAquRjA4YnJuSMkBPYi1EHooWtFkFYsRkjzyfmgloVqRh5EydOdKE3GB/X2KvRB21hB0eYDcjhzTffbITAqFOnju2xxx523XXXGXZmr776qt1+++0G0eR+5g4WhO/gWinaCIiIRXt9NDohIASEgBDIQID4XHgiQn4gPZCQjOzYfwzxMdwnA7LSp08fZ8APKcMOCzUd3oRIqJBWUQ8yhTQMadYzzzyTyUsRezKCs952222O9BClH4kUEjG2FoLEQYYI9gqxok3Kn376aRdxn0CspHfeeccFm6U/ElsSYTMGASSCPyQKwoi9GIFlUSsGQeDimDFeovEjAcR54PnnnzfIqCdY9MUOAoTDwFAfNSiSNMb0+eefG3OiPfpVii4ChUvEoouLRiYEhIAQEAIphkm87I8AABAASURBVMAVV1zh1JXTpk1zoSPya3p4QiJBI2HvBemiLwjka6+9ZpA4ovZDwNiOCaJFXcgfNmLU3Z4EMYNwEpwW4ojTAG1uT1u6p+AQEBErOKzVkxAQAkJACBQiApCfLl26OKN9jOGRYuXHcIjIj20Xiaj49IEtFyE02KII6Rd5NWrUcFIr6pFQbf4XIobkj3Z8YleAIAjoSinCCIiIRXhxNDQhIASEgBDIWwQwoGfrIEJL/BfSs62jIs4YxAu15Lbeq/qpjYCIWGqvr2aX9ggIACEgBOIRIFBq0aJFnYdifFl+XeMAgEQuv9pXu8mLgIhY8q5dZEeO8euCBQsMA9j4QX788ceGTQQGs0uXLo0vNmwrcPVm24/vv/8+S3miDDySnn32WfMpHMQQN2429cWIl3oY2obbwKCV8WAwi2FtuCzVzzEsnj59um0N5ylTptiyZcuyhQO3+ZkzZ7p9/MARO5hElXGxx/CYffQSrX2ie1I1DwNr1FQYYOc0x9mzZxvb3WRXB+yJns5vhqCm8bgSkgHM+W3wm+L3kF1byhcCQqBwEEg5IlY4MKpXjwB2F3g2Ef8GzyKfzxHvoW7duhkPaohahw4djAcNZaTXX3/dunbtasTYGT9+vOFBFE+cqBefcA+HAJAmTJhg/h6IBl5H7OmGMew999xj4QcVsXhwBycIJC7gBIUMk7j4flLpmrWZOnWq2+MObLKbGwQLDywe4tnVIa4R5ArXedYAO5dwm2zZwhrg+s8efqxvOntyYZfE9xAvN7zgssOV3xL7KPbv3z+7Kgb56tu3r40ePdoId0BYB7+dDmRvzJgxxjVkjEjxBBjNtjEVCAEhUCgIiIgVCuyp2ymxc7C9gASFZ8lDmgcFgQp5sEN6iGCNFxOu1zx02PSWKNlsvst+aRAFpFnhduLP33jjDatWrZoRy4f06KOPung81MMziQceDyAeaOXKlbOrrrqKIsOl/e677zaiT0PGiMGDtAAC6Sqk+AebHLNFCwbE2U0Vl3zwhzhnVwdShXdWkyZNHLaQCzzBBgwYYEhruA8pKOtNXCZI2k033eS2X6EsHRN2SURQZ+4eI87DiRANSCv5XYTzw+e8NBDQkxhZTz75pOExx7Y4fK+ph7SXfRP5LUHW+O3xm6JMKU8RiERjfJfS+QUnEouwnYMQEdtO4HRbYgSwuyDFl/JAQUoCSSOIIbYS559/vpGPyhD1Cg8OImRTjkFrqVKljAdIfFv+GskCDx2kaAQwhDiwjQnlEAQkAc2bN7dixYoZNiF4EM2dO9fmzZtn9Im6DQLB9iPE5cHFnIcasXhoI5UTGLMGQZDYowoigDqXIJc54YCEi1hIxHCCYGCQfN555xlBM1F5Ugbxql+/vguciaoMSU1ObaZ6WRAEBvbYDCWaK99rYk2VLFnSSpQokaiKywPr1q1bu9hXnB9//PFuX0NPnCF7FSpUcN9/bgiCwJVzrpR6CCAVbdGihaF54PeLJDr1ZpmaMxIRS811jdys/B+FsKSMGDcM9NNPP3U2SESTDoJ/iQFkDJUKdRIl/thAwIhejW0ZR1Sa1MVODSLAg4hrEsQuCAKnnvzss8/cXnLHHHMMRS5BEiETSHBcRpp+8FaNypgHO0E0s8AQyoA0kFgLn826gT0SRqKaowJGcoNUrFGjRkaATE8W/D06/osALyzgU7t2bduWGFCsG9JlJLz/tmaGGcD1119vqJnr1asXLtJ5iiHw5ptvGtskoXXA9pXvUYpNMSWnIyKWkssavUlBukiPPPKIYRSPatCrScqWLesGjJTAneTyg21NiDKNRIwHft26dQ0VJATAN7G1Nr0EzdfX0QxizBodd9xxWyUCxEsKgsBeeeUVF5sJSSTrioSG9cEpA2kZDwbUlUgckbTx9i6ssyKAuhG7Mb7LRG3PWiP7HIz/IcGXXXZZpkrYTPKSwUsQdno4TWSqoIuUQwDnDXYeQGLKxuWYhqTcJFNoQiJiW19M1cgDBFCx3Hvvvc5dnIcMUaQxrMemjAd+Tl2sW7fO2HONIIgkyBdqSH8PUiza6dSpkyEJg0T4Mh23HQFPaiFSW7u7fPnyhl0djhZIW/ijP2fOHEMSyZqjekayxh56qIB5W4csYEe2tbbTsRwbx4YNG1rp0qW3afpIJLEPwzkl/uUC/LGTZN9EpJOok7epcVUudARYW+xp+fuXXWKvzfBLKIQbG1qkoZiBYI5R6BPRABIiICKWEBZl5jUCQRBY9erVDWkJfxD444AaZciQIYatTOXKlZ2kDBUWfaPu4oGOKosHC0b87du3NxJ/kLD7ol44IXlBAkZ9/ljx8GcrE18HFQ2kjQfT0Ucf7WxrfDlSA+zHuH9rxNC3l4pHbPWeeuopY5NhtkohYdfFgxwv1nj7OfBEAsN9eEayMTF5eO9xZM1Rc/r7yMOGcFulPamIdfycUEni5Yg9HbiTcDYhj+9/dmomfjOo01Gz43wS3y7XkGCcJXCQSfTboY5SlBDIPBbsBZ955hnDwzu7hKNM+OUJtTbBa08//XTj7yw2g5lb1VVUEBARi8pKpNA4MNAmhhhePPHTwkuPUAgY4fMAR4pCHcgRHl54f/FgwdCedghxAbHCABxRO+nSSy81/uDwdj958mSnEoMs8KaP/VGZMmUMezO8xNjXjbdJbJaQwLHvGw8spDKo1ZDgILbHZgwj/l69ejGctEgYzUNAwcZPGAkXcavCCeKE3RGGwBj5Q7ogsKwT90GaUWcOHTrUCLXAA4F2KMNLFftAVJF8H1auXGnch9SH8nRN2HOBB+pCjwEPW1RKYexR29epU8fYOxASxVoRLmTNmjXuNq4JHYL0g+8xThK8UKAiRpLM74jvP/2Rj+fwiSee6O7VR+oiwDrzMoTXM+YBXKfubJN/ZiJiyb+GkZoBxvLYAfFAgBShmmKAPDAwrEd9CCGCJGE3FASbjfMxpMeYG6kK+UhlWrZsaTk9NJAC4JqPZx+xxCBjhEegPxIkACkAUjTyeTskpAVleEmiHkVCg3SO+GYYR9Mn5amecG5gncCMuRPwkzkjLeHNOZzACOkMEscgCAxyC96owyBWqMPAFa9XiGyDBg1oyiWINvvf0T4PBggF9f3+e66SmaXTEQJMqBWkw/wW8CqFNCG14oEZxp68Pffc06kqkRyDMaSYlxDIFr8x4uOxhqjvSW3btjVeYpCw8ZsCd2zDcHzBy5iXlHTCO53m6v+OEsqEFyL+fgZBkE4QJOVcRcSSctmiO2h++IMHDzakJjzosd1itDxMMBzFsJ6HARIuyBBlPtWqVcsee+wx46HCAx1SFATZ/xGhDYgf8ckIUwG5Q7Xo28NgnDLiXNEv7Ya9AJE2QAyog/0ahAEi4u9P5SOqW+K2QWaRZIXJU/y8eeijDvb57dq1c5IvJDSownjIgy0kGxWzr8cRIgERGDhwoLEG1KEtJGuUp2MilErjxo0NEkaYCmx7eElIhAU2PkgZfRnSXCRbderUcVJffksQOqRkPuEMwXe7SpUqhr0f9/OywQtOOqvdPYapeuQ7gdMM5JuXyvi/r6k671SYl4hYoaxi6naKyhC1n0+otZgtD17e1jBChiAhZSE/nMjjbR2pAA94HuLh8vhzSBdqSOojseEBF1+HP0Z4a1IPMhhfznjLli1rEEbqxpen6jWEE0z8OoF7dnMFHwLA+nLWD7yxQWGNwJ/1yg4/JDmU0xd2e3wXfFvpeAyCwMUHAw8S+IJRIiz4XoK1LwNvvs9gzfedc9oIJ9rjt0Rd7qeM3x1rSL5vS8fUQgDVNr9F1j21Zpb6sxERS/011gyFgBAQAkIg3RHQ/COLgIhYZJdGAxMCQkAICAEhIARSHQERsVRfYc1PCKQnApq1EBACQiApEBARS4pl0iCFgBAQAkIgrxHAa5hQIKT169cboVZ8H4RlIXYbZSQ8vylnL0ccIQge7esSBoawLIQjoS4Bp9klgbAheBdTNm7cOLff6vTp0/1tOgoBh4CImIMhBT40BSEgBISAENgmBAjjQjgQAhjjdR3e8YEo9ex0gAcice/YuxFCxY4R1MXhxXdGkFUCHuNBjNciIUWIiYgHOVt74diCkwvkzN+joxDwCIiIeSR0FAJCQAgIgbRCgHA7hPiAPBHK5fbbbzekWoBASBFC21xyySVGIGniEuKtSpw38imnHhIwAk8jISMmHO0RrqVp06ZGoF0SXrF4sHI/96RK0jzyBoEd8qYZtSIEhIAQEAJCIPkQYLstYhg2a9bMCFBMUFy2X/MzgXD50DfsDEK8NmLjEVCXOsTGI3A1gXTZY5U8JGAQL4JJIwkjT0kIZIeAiFh2yChfCAgBIZAJAV2kKgJBEBi7PRBQmh0IIFfsThA/X/IgYwSsxv7riy++MLaYIlA0wYyDIHMAamIdsoNHfDtco+bElgxJGlvCkaeUngiIiKXnumvWQkAICAEhEIfAGWec4XaNmDJlij3xxBNuq6hwFQLoVq1aNZblbb4gYbHMXJxAwthzFxXntddea+xyITKWC+BStIqIWIoubF5MS20IASEgBNINgRYtWhjbQbFfI1sG5TR/djeg3KspOc9tqlixorEfJFuMsY0Ytma5vVf1UgsBEbHUWk/NRggIASEgBP4jAhjm4xmJ9+PixYuzbY0thdg+atmyZbYtZIyt37gX1SVbWLH1l7YmcjCn5YeIWFouuyYtBISAEBACHoE///zTSMQDIw8D/ltuucVQOT7zzDNkxZKvR5wxvCGHDBlia9eutUGDBpmPRUY7mzZtMuy/evfu7e6lPnHIuN9lbPlAvYnKkz1Ct2TpkGYIiIil2YJrukJACEQIAQ2l0BGYNGmSEW5i9OjRRrBWP6D999/fHn/8cTvllFN8lq1atcqGDx9uBHqdOHGiYddVt25d69u3r2HkT/gLbMuee+45GzlypL366quGNyWBYydPnmzr1q2zZ5991ubNm+fapL3+/fvb3Xff7a71kZ4IiIil57pr1kJACAgBIZCBAJKqmjVr2gUXXGCEncjIiv0neCs2XDVq1HB5SLQgZvfee6+hknSZGR/ci8fl2WefbagdkYgh5WrevLkhXeO6VKlShnE+AWJpB1UmZI54Y8QuW7BgQUZL+p+OCIiIpeOqF96c1bMQEAJCIFII1K9f31q3bu0SISziB4ctF4l8jq1atXJ1GzRoYD66Pkb7Rx11lF144YWuDAIG4fIxxKgX7gebMLwlCW1x5pln2vnnn28bNmygC6U0REBELA0XXVMWAkJACAiBwkMAadrYsWNd5P1PP/3U3nvvPatTp07hDSile47+5ETEor9GGqEQEAJCQAgIASGQogiIiKXowmpaQkAIpCcCmrUQEALJhYCIWHKtl0YrBISAEBACQkAIpBACImIptJjpORXNWggIASEgBIRA8iIgIpa8a6eRCwEhIASEgBAQAgWNQB73JyKWx4CqOSEgBISAEBACQkAI5BYBEbG8B+81AAAA4UlEQVTcIqV6QkAICIH0RECzFgJCIB8REBHLR3DVtBAQAkJACAgBISAEckJARCwndFSWngho1kJACAgBISAECggBEbECAlrdCAEhIASEgBAQAkIgHgGIWHyeroWAEBACQkAICAEhIAQKAAERsQIAWV0IASEgBIRAGAGdCwEh4BEQEfNI6CgEhIAQEAJCQAgIgQJGIF+JWKdOnaxVq1ZKwiDtvwP6HejvgL4D+g4k43fg999/L2Bakn7d5SsRu/HGG61Lly5KwkDfAX0H9B3Qd0DfgST8DhQpUiT9mFEBz/j/AQAA//84yA1IAAAABklEQVQDAEqVHqC7hDUbAAAAAElFTkSuQmCC\"\u003e\u003c/p\u003e\n \u003cdiv class=\"gridtable\"\u003e\n \u003cdiv align=\"left\" class=\"colspec\"\u003e\u003cbr\u003e\u003c/div\u003e\n \u003cdiv align=\"left\" class=\"colspec\"\u003e\u003cbr\u003e\u003c/div\u003e\n \u003cdiv align=\"left\" class=\"colspec\"\u003e\u003cstrong\u003e3.5 Analysis of precipitates produced by the catalytic reaction of ammonia TMC\u003c/strong\u003e\u003c/div\u003e\n \u003c/div\u003e\n\u003c/div\u003e\n\u003cdiv id=\"Sec11\" class=\"Section2\"\u003e\n \u003cp\u003eAs can be seen from Figure. 4, a part of Co(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e6\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e and Ni(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e6\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e loses four ammonia coordinations to form Co(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e and Ni(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e at high temperatures, while Mn(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e, Cd(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e and Zn(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e remain unchanged in structure under the same high temperature conditions. As can be seen from the XRD pattern in Figure. 2, all TMCs are converted to diammonia coordination complexes at low concentrations. XRD data from Figure. 3 show that TMCs with strong coupling tendencies, such as CoCl\u003csub\u003e2\u003c/sub\u003e and NiCl\u003csub\u003e2\u003c/sub\u003e, will be converted to hexammonia coordination complexes: Co(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e6\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e and Ni(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e6\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e at high concentrations. TG analysis (Figure. 3) showed that under high temperature conditions, some Co(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e6\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e and Ni(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e6\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e degraded, each losing 4 ammonia molecules to form Co(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e and Ni(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e, while Mn(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e, Cd(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e and Zn(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e did not change their structure until 190\u0026deg;C. This shift to stable low-coordination species is further confirmed by the XRD maps in Figure. 4, which confirms the persistence of these reductive coordination complexes at high temperatures.\u003c/p\u003e\n\u003c/div\u003e\n\u003cdiv id=\"Sec12\" class=\"Section2\"\u003e\n \u003ch2\u003e3.6 Activity analysis of ammonia TMC\u003c/h2\u003e\n \u003cp\u003eThe catalytic activity of ammonia TMC complexes is summarized in Table\u0026nbsp;\u003cspan class=\"InternalRef\"\u003e1\u003c/span\u003e. The catalysts of Co(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e6\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e, Zn(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e, Mn(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e, Cd(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e and Ni(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e6\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e were subjected to a reaction at 190\u0026deg;C for 8 hours, and the DPC yields obtained were 2.64%, 1.93%, 1.59%, 1.36%, and 1.18%, respectively. It was observed that the catalytic activity of these ammonia TMC complexes were lower than those of the corresponding TMC, yet the sequence patterns remained unchanged. This observation suggests that the coordination of NH\u003csub\u003e3\u003c/sub\u003e to TMC during the reaction plays a critical role in modulating catalytic activity.\u003c/p\u003e\n\u003c/div\u003e\n\u003cdiv id=\"Sec13\" class=\"Section2\"\u003e\n \u003ch2\u003e3.7 Thermal decomposition analysis and catalytic activity comparison of ammonia TMC\u003c/h2\u003e\n \u003cp\u003eFigures. 3f-j show the initial decomposition temperatures of the post-catalyst products for the ammonia TMC complexes. Regionalize a tangent to the flat baseline before the first weightless step in the thermogravimetric curve, draw a tangent at the steepest part of the weightless step, and the intersection of the two tangents is the extrapolated starting temperature. Therefore the initial decomposition temperatures of ammonia TMC complexes were found follow the order: Co(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e (190.1\u0026deg;C)\u0026thinsp;\u0026lt;\u0026thinsp;Mn(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e (219.4\u0026deg;C)\u0026thinsp;\u0026lt;\u0026thinsp;Cd(NH\u003csub\u003e3\u003c/sub\u003e)Cl\u003csub\u003e2\u003c/sub\u003e (223.2\u0026deg;C)\u0026thinsp;\u0026lt;\u0026thinsp;Ni(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e (246.4\u0026deg;C), respectively. Notably, this sequence exhibits a negative correlation with the catalytic activity of the corresponding parent TMC precursors. Specifically, a lower initial decomposition temperature of the ammonia-TMC complex correlates with higher catalytic activity for diphenyl carbonate (DPC) synthesis. This relationship arises from the critical role of ammonia cyclin i.e., the absorption of NH\u003csub\u003e3\u003c/sub\u003e by TMC and its subsequent desorption from the ammonia-TMC complex during catalysis. The overall cycling rate is dominated by the desorption rate of ammonia from the ammonia-TMC complex, which is directly governed by the complex\u0026rsquo;s initial decomposition temperature. For Co(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e, the lowest initial decomposition temperature facilitates the fastest cycles of NH\u003csub\u003e3\u003c/sub\u003e absorption by CoCl\u003csub\u003e2\u003c/sub\u003e and desorption from Co(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e. This enhanced ammonia turnover explains why CoCl\u003csub\u003e2\u003c/sub\u003e exhibits the highest catalytic activity for DPC synthesis among the tested TMC.\u003c/p\u003e\n\u003c/div\u003e\n\u003cdiv id=\"Sec14\" class=\"Section2\"\u003e\n \u003ch2\u003e3.8 Catalytic mechanism.\u003c/h2\u003e\n \u003cp\u003eAccording to the principle of coordination chemistry\u003csup\u003e\u003cspan class=\"CitationRef\"\u003e24\u003c/span\u003e\u003c/sup\u003e, the proposed reaction mechanism for transition metal cations in DPC synthesis is illustrated in Fig. \u003cspan class=\"InternalRef\"\u003e4\u003c/span\u003e. First, urea reacts with n-propanol to form the intermediate PC. The process begins with the nucleophilic attack of the oxygen atom in n-propanol on the carbonyl carbon of urea, forming an amphiphilic intermediate that undergoes deamination to PC. Secondly, the PC intermediate subsequently undergoes further deamination to generate DPC. The propanol molecule coordinates with the transition metal cation to form the complex Me(n-propanol)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e (Me represents the metal salt). This complex undergoes intramolecular rearrangement, facilitating the transfer of a hydroxyl H atom to a N atom, which form NH\u003csub\u003e3\u003c/sub\u003e and complex with TMC to form Me(NH\u003csub\u003e3\u003c/sub\u003e)(n-propanol)Cl\u003csub\u003e2\u003c/sub\u003e. The oxygen atom of the coordinated n-propanol in Me(NH\u003csub\u003e3\u003c/sub\u003e)(n-propanol)Cl\u003csub\u003e2\u003c/sub\u003e then attacks the carbonyl C of the PC intermediate, leading to the formation of Me(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e and DPC. Since Me(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e is unstable at the reaction temperature of 190 ℃, one ammonia of Me(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e is replaced by n-propanol molecules to obtain Me(NH\u003csub\u003e3\u003c/sub\u003e)(n-propanol)Cl\u003csub\u003e2\u003c/sub\u003e again, completing the catalytic cycle. As shown in Figure. 4, the initial decomposition temperature is higher than the reaction temperature, and Me(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e does not lose ammonia molecules in the reaction.\u003c/p\u003e\n\u003c/div\u003e"},{"header":"4. Conclusion","content":"\u003cp\u003eIn this study, the optimum reaction conditions for the synthesis of DPC via urea alcoholysis reaction were determined using TMC as catalyst, and the catalytic activity of various TMC was evaluated. The results showed that the order of catalytic activity was CoCl\u003csub\u003e2\u003c/sub\u003e \u0026gt; ZnCl\u003csub\u003e2\u003c/sub\u003e \u0026gt; MnCl\u003csub\u003e2\u003c/sub\u003e \u0026gt; CdCl\u003csub\u003e2\u003c/sub\u003e \u0026gt; ZnCl\u003csub\u003e2\u003c/sub\u003e. Subsequently, the initial decomposition temperatures of the corresponding ammonia-TMC complexes were investigated, yielding the sequence: Co(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e \u0026lt; Mn(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e \u0026lt; Cd(NH\u003csub\u003e3\u003c/sub\u003e)Cl\u003csub\u003e2\u003c/sub\u003e \u0026lt; Ni(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e. A critical relationship between the catalytic performance of TMC and the thermal stability of their ammonia-TMC complexes was established: a lower initial decomposition temperature of the ammonia-TMC complex correlated with higher catalytic activity of the parent TMC. This negative correlation underscores the role of ammonia turnover (absorption by TMC and desorption from the ammonia-TMC complex) in driving the catalytic cycle, where faster desorption (facilitated by lower decomposition temperatures) enhances DPC synthesis efficiency.\u003c/p\u003e"},{"header":"Declarations","content":"\u003cp\u003e\u003cstrong\u003eCRediT authorship contribution statement\u003c/strong\u003e\u003c/p\u003e\n\u003cp\u003eLiangchun He, Dongxia Wang and Zhiyong Xu have made equal contributions to this work. Liangchun He: Conceptualization, Methodology, Data Management and Writing - Original Manuscript. Dongxia Wang: Conceptualization, Methodology, Data Management and Writing - Original Manuscript. Zhiyong Xu: Conceptualization, Methodology, Data Management and Writing - Original Manuscript. Songyi Ji: Supervision and project management. Rong Zhang:Supervision and Project Management. Wenbo Zhao: Supervision and Project Management.\u003c/p\u003e\n\u003cp\u003e\u003cstrong\u003eDeclaration of Competing Interest\u003c/strong\u003e\u003c/p\u003e\n\u003cp\u003eThe authors declare no competing financial interest.\u003c/p\u003e\n\u003cp\u003e\u003cstrong\u003eAcknowledgments\u003c/strong\u003e\u003c/p\u003e\n\u003cp\u003eThis work is supported by the National Natural Science Foundation of China (Grant No. 22278198, 22068016, 21666011), Yunnan province high level talents special support plan (YNWR-QNBJ-2018-369), Yunnan Major Scientific and Technological Projects (Grant NO.202302AG050002). Yunnan Fundamental Research Projects (grant NO. 202501CF070138).\u003c/p\u003e\n\u003cp\u003e\u003cstrong\u003eEthics declarations\u003c/strong\u003e\u003c/p\u003e\n\u003cp\u003eEthics approval, Consent to participate, and Consent to publish: Not applicable.\u003c/p\u003e"},{"header":"References","content":"\u003col\u003e\n \u003cli\u003e Marshall, M. A. P. L. Review of Dimethyl Carbonate (DMC) Manufacture and Its Characteristics as a Fuel Additive.\u003cem\u003e\u0026nbsp;Energy \u0026amp; Fuels.\u0026nbsp;\u003c/em\u003e\u003cstrong\u003e1997\u003c/strong\u003e.\u003cem\u003e11\u003c/em\u003e, 2-29\u003c/li\u003e\n \u003cli\u003e\u0026nbsp;Moumouzias, G.; Ritzoulis, G.; Siapkas, D.; Terzidis, D. Comparative study of LiBF4, LiAsF\u003csub\u003e6\u003c/sub\u003e, LiPF\u003csub\u003e6\u003c/sub\u003e, and LiClO\u003csub\u003e4\u003c/sub\u003e as electrolytes in propylene carbonate\u0026ndash;diethyl carbonate solutions for Li/LiMn\u003csub\u003e2\u003c/sub\u003eO\u003csub\u003e4\u003c/sub\u003e cells. \u003cem\u003eJ. Power Sources\u003c/em\u003e\u003cem\u003e.\u003cstrong\u003e\u0026nbsp;\u003c/strong\u003e\u003c/em\u003e\u003cstrong\u003e2003\u003c/strong\u003e, \u003cem\u003e122\u003c/em\u003e (1), 57-66\u003c/li\u003e\n \u003cli\u003e\u0026nbsp;Herstedt, M.; Stjerndahl, M.; Gustafsson, T.; Edstr\u0026ouml;m, K. Anion receptor for enhanced thermal stability of the graphite anode interface in a Li-ion battery. \u003cem\u003eElectrochem. Commun.\u0026nbsp;\u003c/em\u003e\u003cstrong\u003e2003\u003c/strong\u003e, \u003cem\u003e5\u003c/em\u003e (6), 467-472.\u0026nbsp;\u003c/li\u003e\n \u003cli\u003e\u0026nbsp;Giardi, C.; Lapinte, V.; Nielloud, F.; Devoisselle, J. M.; Robin, J. J. Synthesis of polyoxazolines using glycerol carbonate derivative and end chains functionalization via carbonate and isocyanate routes. \u003cem\u003eJ. Polym. Sci., Part A: Polym. Chem.\u0026nbsp;\u003c/em\u003e\u003cstrong\u003e2010\u003c/strong\u003e, \u003cem\u003e48\u003c/em\u003e (18), 4027-4035.\u003c/li\u003e\n \u003cli\u003eChai, X.; Huang, S.; Huang, Z.; Wu, C.; Lu, P.; Ye, C.; Qiu, T. Aminolysis of Toluene Diisocyanate Tar Residue Based on Polyamines: Efficient Conversion and Mechanism Exploration. \u003cem\u003eInd. Eng. Chem. Res.\u003c/em\u003e 2025, \u003cem\u003e64\u003c/em\u003e (29), 14319-14328.\u003c/li\u003e\n \u003cli\u003eBhadauria, S.; Saxena, S.; Prasad, R.; Sharma, P.; Prasad, R.; Dwivedi, R. Synthesis of ethylene carbonate from cyclocondensation of ethylene glycol and urea over ZnO\u0026bull;Cr\u003csub\u003e2\u003c/sub\u003eO\u003csub\u003e3\u003c/sub\u003e catalyst system controlled by co-precipitation method. \u003cem\u003eChem. Eur. J.\u0026nbsp;\u003c/em\u003e\u003cstrong\u003e2012\u003c/strong\u003e, \u003cem\u003e3\u003c/em\u003e (2), 235-240.\u003c/li\u003e\n \u003cli\u003e\u0026nbsp;Wang, X.; Fu, T.; Zheng, H.; Zhang, G.; Li, Z. The influence of the pore structure in ordered mesoporous carbon over the formation of Cu species and their catalytic activity towards the methanol oxidative carbonylation. \u003cem\u003eJ. Mater. Sci.\u0026nbsp;\u003c/em\u003e\u003cstrong\u003e2016\u003c/strong\u003e, \u003cem\u003e51\u003c/em\u003e (11), 5514-5528.\u003c/li\u003e\n \u003cli\u003e\u0026nbsp;Mahloujifar, M.; Mansournia, M. A comparative study on the catalytic performances of alkali metals-loaded KAlSiO4 for biodiesel production from sesame oil. \u003cem\u003eFuel.\u0026nbsp;\u003c/em\u003e\u003cstrong\u003e2021\u003c/strong\u003e, \u003cem\u003e291\u003c/em\u003e, 120145.\u003c/li\u003e\n \u003cli\u003e\u0026nbsp;Hu, L.; Chen, L.; Peng, X.; Zhang, J.; Mo, X.; Liu, Y.; Yan, Z. Bifunctional metal-doped ZIF-8: A highly efficient catalyst for the synthesis of cyclic carbonates from CO\u003csub\u003e2\u003c/sub\u003e cycloaddition. \u003cem\u003eMicroporous Mesoporous Mater.\u0026nbsp;\u003c/em\u003e\u003cstrong\u003e2020\u003c/strong\u003e, \u003cem\u003e299\u003c/em\u003e, 110123.\u003c/li\u003e\n \u003cli\u003e\u0026nbsp;M.A.P.J. Hacking, F. v. R., R.A. Sheldon). Lipase catalyzed reactions of aliphatic and arylaliphatic carbonic acid esters. J. Mol. Catal. B: Enzym. 2000, 9, 201\u0026ndash;208.\u003c/li\u003e\n \u003cli\u003eXiao, Y.; Xiang, C.; Lei, H.; Jin, S.; Yin, X.; Ding, Y.; Du, Z. Effect of change of Ca, P and Mg on the surface of catalyst prepared from phosphate tailing on urea alcoholysis. \u003cem\u003eCatal. Commun.\u0026nbsp;\u003c/em\u003e\u003cstrong\u003e2019\u003c/strong\u003e, \u003cem\u003e128\u003c/em\u003e, 105712\u003c/li\u003e\n \u003cli\u003e\u0026nbsp;Gao, Z. W.; Wang, S. F.; Xia, C. G. Synthesis of propylene carbonate from urea and 1,2-propanediol. \u003cem\u003eChin. Chem. Lett.\u003c/em\u003e\u003cem\u003e\u0026nbsp;\u003c/em\u003e\u003cstrong\u003e2009\u003c/strong\u003e, \u003cem\u003e20\u003c/em\u003e (2), 131-135.\u003c/li\u003e\n \u003cli\u003e\u0026nbsp;Wu, C.; Zhao, X.; Wang, Y. Effect of reduction treatment on catalytic performance of Zn-based catalyst for the alcoholysis of urea to dimethyl carbonate. \u003cem\u003eCatal. Commun.\u0026nbsp;\u003c/em\u003e\u003cstrong\u003e2005\u003c/strong\u003e, \u003cem\u003e6\u003c/em\u003e (10), 694-698.\u003c/li\u003e\n \u003cli\u003e\u0026nbsp;Li, Q.; Zhang, W.; Zhao, N.; Wei, W.; Sun, Y. Synthesis of cyclic carbonates from urea and diols over metal oxides. \u003cem\u003eCatal. Today.\u0026nbsp;\u003c/em\u003e\u003cstrong\u003e2006\u003c/strong\u003e, \u003cem\u003e115\u003c/em\u003e (1-4), 111-116.\u003c/li\u003e\n \u003cli\u003e\u0026nbsp;Fu-Yu Zhong, H.-L. P., Duan-Jian Tao, Ping-Keng Wu, Jie-Ping Fan; Huang, a. K. Phenol-Based Ternary Deep Eutectic Solvents for Highly Efficient and Reversible Absorption of NH\u003csub\u003e3\u003c/sub\u003e. \u003cem\u003eACS Sustain. Chem. Eng.\u0026nbsp;\u003c/em\u003e\u003cstrong\u003e2019\u003c/strong\u003e, \u003cem\u003e5\u003c/em\u003e, 6284\u0026minus;6295.\u003c/li\u003e\n \u003cli\u003e\u0026nbsp;Du, Z.; Chen, F.; Lin, Z.; Li, X.; Yuan, H.; Wu, Y. Effect of MgO on the catalytic performance of MgTiO\u003csub\u003e3\u003c/sub\u003e in urea alcoholysis to propylene carbonate. \u003cem\u003eChem. Eng. J.\u0026nbsp;\u003c/em\u003e\u003cstrong\u003e2015\u003c/strong\u003e, \u003cem\u003e278\u003c/em\u003e, 79-84.\u003c/li\u003e\n \u003cli\u003e\u0026nbsp;Zhao, X.; Jia, Z.; Wang, Y. Clean synthesis of propylene carbonate from urea and 1,2‐propylene glycol over zinc\u0026ndash;iron double oxide catalyst. \u003cem\u003eJ. Chem. Technol. Biotechnol.\u0026nbsp;\u003c/em\u003e\u003cstrong\u003e2006\u003c/strong\u003e, \u003cem\u003e81\u003c/em\u003e (5), 794-798.\u003c/li\u003e\n \u003cli\u003eWeil, K. S. The synthesis of transition metal nitrides via thermolysis of metal\u0026ndash;ammine complexes, Part I: Chromium nitride.\u0026nbsp;\u003cem\u003eJ. Solid State Chem.\u0026nbsp;\u003c/em\u003e\u003cstrong\u003e2008\u003c/strong\u003e, \u003cem\u003e181\u003c/em\u003e (1), 199-210.\u003c/li\u003e\n \u003cli\u003eZhang, Z.; Zhong, H.; Xu, Y.; Zhang, M.; Zhang, H.; Wang, J.; Yang, Y. Impacts of Heat Treatment and Long-Term Storage on Methylaluminoxane Composition, Catalytic Activity, and Polyethylene Properties. \u003cem\u003eInd. Eng. Chem. Res.\u003c/em\u003e 2025, \u003cem\u003e64\u003c/em\u003e (26), 12968-12977.\u003c/li\u003e\n \u003cli\u003eYu, Y.; Wang, Y.; Yang, F.; Feng, D.; Yang, M.; Xie, P. F.; Zhu, Y.; Shao, M.; Mei, Y.; Li, J. C. Meso/Microporous Single-Atom Catalysts Featuring Curved Fe-N\u003csub\u003e4\u003c/sub\u003e Sites Boost the Oxygen Reduction Reaction Activity. \u003cem\u003eAngew. Chem. Int. Ed.\u0026nbsp;\u003c/em\u003e2025, \u003cem\u003e64\u0026nbsp;\u003c/em\u003e(3), e202415691.\u003c/li\u003e\n \u003cli\u003eDas, R.; Alagarsamy, P.; Choudhary, R. N. P. Studies of Structural, Electrical, and Magnetic Characteristics of Double Perovskite Ceramic: La\u003csub\u003e2\u003c/sub\u003eFeMnO\u003csub\u003e6\u003c/sub\u003e. \u003cem\u003ePhys. Status Solidi B.\u0026nbsp;\u003c/em\u003e\u003cstrong\u003e2021\u003c/strong\u003e, \u003cem\u003e258\u003c/em\u003e (12), 2100299.\u003c/li\u003e\n \u003cli\u003e\u0026nbsp;Ding, Z.; Xu, W.; Zhang, X.; Liu, Z.; Shen, J.; Liang, J.; Jiang, M.; Ren, X. Controllable Acid/Base Propriety of Sulfate Modified Mixed Metal Oxide Derived from Hydrotalcite for Synthesis of Propylene Carbonate. \u003cem\u003eCatalysts.\u0026nbsp;\u003c/em\u003e\u003cstrong\u003e2019\u003c/strong\u003e, \u003cem\u003e9\u003c/em\u003e (5), 470.\u003c/li\u003e\n \u003cli\u003eSchroder, K. W.; Dylla, A. G.; Harris, S. J.; Webb, L. J.; Stevenson, K. J. Role of surface oxides in the formation of solid-electrolyte interphases at silicon electrodes for lithium-ion batteries. \u003cem\u003eACS Appl. Mater. Interfaces.\u0026nbsp;\u003c/em\u003e\u003cstrong\u003e2014\u003c/strong\u003e, \u003cem\u003e6\u003c/em\u003e (23), 21510-21524.\u003c/li\u003e\n \u003cli\u003e\u0026nbsp;Zhao, W.; Feng, D.; Nong, J.; Cao, G.; Liu, X.; Tang, Z.; Chen, Y. Catalysis effect and conversion process of transition metal chlorides in the synthesis of diethyl carbonate from ethyl carbamate and ethanol. \u003cem\u003eReact. Kinet. Mech. Catal.\u003cstrong\u003e\u0026nbsp;\u003c/strong\u003e\u003c/em\u003e\u003cstrong\u003e2015\u003c/strong\u003e, \u003cem\u003e117\u003c/em\u003e (2), 639-654.\u003c/li\u003e\n\u003c/ol\u003e"}],"fulltextSource":"","fullText":"","funders":[],"hasAdminPriorityOnWorkflow":false,"hasManuscriptDocX":true,"hasOptedInToPreprint":true,"hasPassedJournalQc":"","hasAnyPriority":false,"hideJournal":true,"highlight":"","institution":"","isAcceptedByJournal":false,"isAuthorSuppliedPdf":false,"isDeskRejected":"","isHiddenFromSearch":false,"isInQc":false,"isInWorkflow":false,"isPdf":false,"isPdfUpToDate":true,"isWithdrawnOrRetracted":false,"journal":{"display":true,"email":"[email protected]","identity":"researchsquare","isNatureJournal":false,"hasQc":true,"allowDirectSubmit":true,"externalIdentity":"","sideBox":"","snPcode":"","submissionUrl":"/submission","title":"Research Square","twitterHandle":"researchsquare","acdcEnabled":true,"dfaEnabled":false,"editorialSystem":"","reportingPortfolio":"","inReviewEnabled":false,"inReviewRevisionsEnabled":true},"keywords":"dipropyl carbonate, decomposition temperature, transition metal chloride salts, catalysis","lastPublishedDoi":"10.21203/rs.3.rs-7334198/v1","lastPublishedDoiUrl":"https://doi.org/10.21203/rs.3.rs-7334198/v1","license":{"name":"CC BY 4.0","url":"https://creativecommons.org/licenses/by/4.0/"},"manuscriptAbstract":"\u003cp\u003eHerein, dipropyl carbonate was synthesized using a series of transition metal chloride (TMC) as catalysts. The catalytic activity of different TMCs was compared and the optimal catalytic conditions were systematically investigated. The catalytic activity order is CoCl\u003csub\u003e2\u003c/sub\u003e \u0026gt; ZnCl\u003csub\u003e2\u003c/sub\u003e \u0026gt; MnCl\u003csub\u003e2\u003c/sub\u003e \u0026gt; CdCl\u003csub\u003e2\u003c/sub\u003e \u0026gt; NiCl\u003csub\u003e2\u003c/sub\u003e. Thermal decomposition behavior of ammine TMC complexes revealed that Co(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e exhibited the lowest decomposition temperature, whereas Ni(NH\u003csub\u003e3\u003c/sub\u003e)\u003csub\u003e2\u003c/sub\u003eCl\u003csub\u003e2\u003c/sub\u003e showed the highest; these decomposition temperatures were negatively correlated with the catalytic activities of the respective ammine TMC complexes. Notably, although the catalytic activity of ammine TMC complexes lower than their parent TMCs but with consistent activity order with the parent salts. These findings highlight the crucial role of the catalyst’s ammonia-binding and -release capacity in DPC synthesis. The weaker the metal-ammonia interaction (evidenced by lower decomposition temperatures), the higher the catalytic activity, presumably due to more facile ammonia desorption, which facilitates active site regeneration and urea activation.\u003c/p\u003e","manuscriptTitle":"Transition Metal Chloride Catalyzed the Synthesis of Dipropyl Carbonate from Urea Alcoholysis: Influence of Initial Decomposition Temperature of Ammine Transition Metal Chloride","msid":"","msnumber":"","nonDraftVersions":[{"code":1,"date":"2025-08-29 12:31:07","doi":"10.21203/rs.3.rs-7334198/v1","editorialEvents":[{"type":"communityComments","content":0}],"status":"published","journal":{"display":true,"email":"[email protected]","identity":"researchsquare","isNatureJournal":false,"hasQc":true,"allowDirectSubmit":true,"externalIdentity":"","sideBox":"","snPcode":"","submissionUrl":"/submission","title":"Research Square","twitterHandle":"researchsquare","acdcEnabled":true,"dfaEnabled":false,"editorialSystem":"","reportingPortfolio":"","inReviewEnabled":false,"inReviewRevisionsEnabled":true}}],"origin":"","ownerIdentity":"816eab5b-400b-4274-a28d-09d2c2ad62d3","owner":[],"postedDate":"August 29th, 2025","published":true,"recentEditorialEvents":[],"rejectedJournal":[],"revision":"","amendment":"","status":"posted","subjectAreas":[],"tags":[],"updatedAt":"2025-09-22T14:55:19+00:00","versionOfRecord":[],"versionCreatedAt":"2025-08-29 12:31:07","video":"","vorDoi":"","vorDoiUrl":"","workflowStages":[]},"version":"v1","identity":"rs-7334198","journalConfig":"researchsquare"},"__N_SSP":true},"page":"/article/[identity]/[[...version]]","query":{"redirect":"/article/rs-7334198","identity":"rs-7334198","version":["v1"]},"buildId":"8U1c8b4HqxoKbykW_rLl7","isFallback":false,"isExperimentalCompile":false,"dynamicIds":[84888],"gssp":true,"scriptLoader":[]}