A One-Pot Synthesis of Axially and Centrally Chiral A-type Nanogrids
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Abstract
A novel type of A-type nanogrids (AGs) with axial and central chirality was synthesized via Friedel-Crafts gridization of thiophenes and difluorenyl biaromatic derivatives, yielding 9–30%. Additionally, the effect of stereoisomers of 1,1’-binaphthyl difluorenols (BINDFOH) was investigated to demonstrate that R/S-BINDFOH is more advantageous for the synthesis of AGs than Mix-BINDFOH. Furthermore, Tests on OFET memory devices showed that AGs have a larger storage window, indicating potential for data storage applications.
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- last seen: 2026-05-19T01:45:01.086888+00:00