Pervasive hydrous carbonatitic liquids mediate transfer of carbon from the slab to the subarc mantle

Abstract Carbonatitic liquids, as a medium to transfer carbon from the slab to the mantle at subarc depths, are thought to be restricted to the hottest conditions, or hydrous melting of calcium-rich lithologies (i.e. carbonated gabbro and limestone rocks) in subduction zones. Here, high-pressure experiments on carbonated, hydrous pelites, however, demonstrate that whilst silicate melts are produced at 2.5-4 GPa, hydrous carbonatitic liquids clearly dominates at 5–6 GPa. The stability of Ca-rich carbonate is strongly depressed by water at pressures exceeding ~ 4 GPa, which promotes formation of hydrous carbonatitic liquids at temperatures as low as ~ 850–900℃, corresponding to intermediate thermal regimes at depths of 150–180 km. Hence, carbonatite production beneath arcs is more pervasive than previously thought, and the carbon cycle is most likely confined to depths of less than 200 km for many subduction zones.