Experimental data and modeling of viscosity in the quinary system NaCl+KCl+CaCl2+MgCl2+H2O

Experimental data and modeling of viscosity in the quinary system NaCl+KCl+CaCl2+MgCl2+H2O | Research Square window.SnipcartSettings = { analytics: { enabled: false } }; (function() { var accessVector = localStorage.getItem('access_vector') || ''; window.dataLayer = window.dataLayer || []; if (accessVector) { window.dataLayer.push({ user: { profile: { profileInfo: { snid: accessVector } } } }); } })(); (function(w,d,s,l,i){w[l]=w[l]||[];w[l].push({'gtm.start':new Date().getTime(),event:'gtm.js'});var f=d.getElementsByTagName(s)[0],j=d.createElement(s),dl=l!='dataLayer'?'&l='+l:'';j.async=true;j.src='https://www.googletagmanager.com/gtm.js?id='+i+dl;f.parentNode.insertBefore(j,f);})(window,document,'script','dataLayer','GTM-K279D39R'); Browse Preprints In Review Journals COVID-19 Preprints AJE Video Bytes Research Tools Research Promotion AJE Professional Editing AJE Rubriq About Preprint Platform In Review Editorial Policies Our Team Advisory Board Help Center Sign In Submit a Preprint Cite Share Download PDF Research Article Experimental data and modeling of viscosity in the quinary system NaCl+KCl+CaCl 2 +MgCl 2 +H 2 O Sheng Wang, Mengjie Luo, Yuzhu Sun, Congying Wang, Xingfu Song This is a preprint; it has not been peer reviewed by a journal. https://doi.org/ 10.21203/rs.3.rs-4162162/v1 This work is licensed under a CC BY 4.0 License Status: Published Journal Publication published 21 Jul, 2024 Read the published version in Journal of Solution Chemistry → Version 1 posted 8 You are reading this latest preprint version Abstract The viscosities of the quinary system NaCl + KCl + CaCl 2 + MgCl 2 + H 2 O and its binary subsystems are measured in the temperature range of 288.15K-308.15K. The viscosity of binary solutions of MgCl 2 , NaCl, and CaCl 2 increases with the increase in concentration. In contrast, for the binary solution of KCl, the viscosity decreases with increasing concentration at low temperature and low concentration. The extended Jones-Dole model that incorporates higher-order term parameters is used to fit the viscosity of binary solutions, with a maximum Average Absolute Deviation (AAD) of 1.42%. By comparing the values of the Pearson correlation coefficients, it is found that MgCl 2 has the most significant impact on the viscosity of the quinary system MgCl 2 + KCl + NaCl + CaCl 2 + H 2 O, while the impact of KCl is the least. The modified extended Jones-Dole model, with the introduction of parameter G i , can accurately predict the quinary system, resulting in a maximum AAD value of 0.63%. Moreover, the Hu model is also applied to predict the viscosity of the quinary system, achieving a maximum AAD value being 1.54%. Compared to the Hu model, the modified extended Jones-Dole model performs better. The viscosity calculation models for the quinary system MgCl 2 + KCl + NaCl + CaCl 2 + H 2 O in this study contribute key parameters for the design and optimization of the potassium chloride production process. Viscosity prediction Quinary system Extended Jones-Dole model Hu model Full Text Additional Declarations No competing interests reported. Supplementary Files Supportinginformation.docx Cite Share Download PDF Status: Published Journal Publication published 21 Jul, 2024 Read the published version in Journal of Solution Chemistry → Version 1 posted Editorial decision: Revision requested 28 Apr, 2024 Reviews received at journal 08 Apr, 2024 Reviewers agreed at journal 08 Apr, 2024 Reviewers agreed at journal 06 Apr, 2024 Reviewers invited by journal 06 Apr, 2024 Submission checks completed at journal 26 Mar, 2024 Editor assigned by journal 26 Mar, 2024 First submitted to journal 25 Mar, 2024 You are reading this latest preprint version Research Square lets you share your work early, gain feedback from the community, and start making changes to your manuscript prior to peer review in a journal. As a division of Research Square Company, we’re committed to making research communication faster, fairer, and more useful. We do this by developing innovative software and high quality services for the global research community. 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Also discoverable on Platform About Our Team In Review Editorial Policies Advisory Board Help Center Resources Author Services Accessibility API Access RSS feed Manage Cookie Preferences © Research Square 2026 | ISSN 2693-5015 (online) Privacy Policy Terms of Service Do Not Sell My Personal Information {"props":{"pageProps":{"initialData":{"identity":"rs-4162162","acceptedTermsAndConditions":true,"allowDirectSubmit":false,"archivedVersions":[],"articleType":"Research Article","associatedPublications":[],"authors":[{"id":285833420,"identity":"18db0812-e3da-4ef0-acc2-f16856369315","order_by":0,"name":"Sheng Wang","email":"","orcid":"","institution":"East China University of Science and Technology","correspondingAuthor":false,"prefix":"","firstName":"Sheng","middleName":"","lastName":"Wang","suffix":""},{"id":285833421,"identity":"b02af3b9-e73f-463b-b54f-85afa9c77ed9","order_by":1,"name":"Mengjie 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NaCl+KCl+CaCl\u003c/strong\u003e\u003csub\u003e\u003cstrong\u003e2\u003c/strong\u003e\u003c/sub\u003e\u003cstrong\u003e+MgCl\u003c/strong\u003e\u003csub\u003e\u003cstrong\u003e2\u003c/strong\u003e\u003c/sub\u003e\u003cstrong\u003e+H\u003c/strong\u003e\u003csub\u003e\u003cstrong\u003e2\u003c/strong\u003e\u003c/sub\u003e\u003cstrong\u003eO\u003c/strong\u003e\u003c/p\u003e","fulltext":[],"fulltextSource":"","fullText":"","funders":[],"hasAdminPriorityOnWorkflow":false,"hasManuscriptDocX":false,"hasOptedInToPreprint":true,"hasPassedJournalQc":"","hasAnyPriority":false,"hideJournal":false,"highlight":"","institution":"","isAcceptedByJournal":true,"isAuthorSuppliedPdf":true,"isDeskRejected":"","isHiddenFromSearch":false,"isInQc":false,"isInWorkflow":false,"isPdf":true,"isPdfUpToDate":true,"isWithdrawnOrRetracted":false,"journal":{"display":true,"email":"[email protected]","identity":"journal-of-solution-chemistry","isNatureJournal":false,"hasQc":true,"allowDirectSubmit":false,"externalIdentity":"josl","sideBox":"Learn more about [Journal of Solution Chemistry](http://link.springer.com/journal/10953)","snPcode":"10953","submissionUrl":"https://submission.nature.com/new-submission/10953/3","title":"Journal of Solution Chemistry","twitterHandle":"","acdcEnabled":true,"dfaEnabled":true,"editorialSystem":"em","reportingPortfolio":"Springer Hybrid","inReviewEnabled":true,"inReviewRevisionsEnabled":false},"keywords":"Viscosity prediction, Quinary system, Extended Jones-Dole model, Hu model","lastPublishedDoi":"10.21203/rs.3.rs-4162162/v1","lastPublishedDoiUrl":"https://doi.org/10.21203/rs.3.rs-4162162/v1","license":{"name":"CC BY 4.0","url":"https://creativecommons.org/licenses/by/4.0/"},"manuscriptAbstract":"\u003cp\u003eThe viscosities of the quinary system NaCl\u0026thinsp;+\u0026thinsp;KCl\u0026thinsp;+\u0026thinsp;CaCl\u003csub\u003e2\u003c/sub\u003e\u0026thinsp;+\u0026thinsp;MgCl\u003csub\u003e2\u003c/sub\u003e\u0026thinsp;+\u0026thinsp;H\u003csub\u003e2\u003c/sub\u003eO and its binary subsystems are measured in the temperature range of 288.15K-308.15K. The viscosity of binary solutions of MgCl\u003csub\u003e2\u003c/sub\u003e, NaCl, and CaCl\u003csub\u003e2\u003c/sub\u003e increases with the increase in concentration. In contrast, for the binary solution of KCl, the viscosity decreases with increasing concentration at low temperature and low concentration. The extended Jones-Dole model that incorporates higher-order term parameters is used to fit the viscosity of binary solutions, with a maximum Average Absolute Deviation (AAD) of 1.42%. By comparing the values of the Pearson correlation coefficients, it is found that MgCl\u003csub\u003e2\u003c/sub\u003e has the most significant impact on the viscosity of the quinary system MgCl\u003csub\u003e2\u003c/sub\u003e\u0026thinsp;+\u0026thinsp;KCl\u0026thinsp;+\u0026thinsp;NaCl\u0026thinsp;+\u0026thinsp;CaCl\u003csub\u003e2\u003c/sub\u003e\u0026thinsp;+\u0026thinsp;H\u003csub\u003e2\u003c/sub\u003eO, while the impact of KCl is the least. The modified extended Jones-Dole model, with the introduction of parameter \u003cem\u003eG\u003c/em\u003e\u003csub\u003e\u003cem\u003ei\u003c/em\u003e\u003c/sub\u003e, can accurately predict the quinary system, resulting in a maximum AAD value of 0.63%. Moreover, the Hu model is also applied to predict the viscosity of the quinary system, achieving a maximum AAD value being 1.54%. Compared to the Hu model, the modified extended Jones-Dole model performs better. The viscosity calculation models for the quinary system MgCl\u003csub\u003e2\u003c/sub\u003e\u0026thinsp;+\u0026thinsp;KCl\u0026thinsp;+\u0026thinsp;NaCl\u0026thinsp;+\u0026thinsp;CaCl\u003csub\u003e2\u003c/sub\u003e\u0026thinsp;+\u0026thinsp;H\u003csub\u003e2\u003c/sub\u003eO in this study contribute key parameters for the design and optimization of the potassium chloride production process.\u003c/p\u003e","manuscriptTitle":"Experimental data and modeling of viscosity in the quinary system NaCl+KCl+CaCl2+MgCl2+H2O","msid":"","msnumber":"","nonDraftVersions":[{"code":1,"date":"2024-04-03 08:47:11","doi":"10.21203/rs.3.rs-4162162/v1","editorialEvents":[{"type":"communityComments","content":0},{"type":"decision","content":"Revision requested","date":"2024-04-28T06:53:19+00:00","index":"","fulltext":""},{"type":"editorInvitedReview","content":"","date":"2024-04-08T20:42:48+00:00","index":"hide","fulltext":""},{"type":"reviewerAgreed","content":"8af22bd3-96e6-41c6-810c-b7331087108c","date":"2024-04-08T20:27:56+00:00","index":"hide","fulltext":""},{"type":"reviewerAgreed","content":"044368e8-8330-4272-9366-af6833a652ae","date":"2024-04-06T21:15:11+00:00","index":"hide","fulltext":""},{"type":"reviewersInvited","content":"","date":"2024-04-06T17:25:01+00:00","index":"","fulltext":""},{"type":"checksComplete","content":"","date":"2024-03-26T11:42:38+00:00","index":"","fulltext":""},{"type":"editorAssigned","content":"","date":"2024-03-26T11:42:38+00:00","index":"","fulltext":""},{"type":"submitted","content":"Journal of Solution Chemistry","date":"2024-03-25T09:25:05+00:00","index":"","fulltext":""}],"status":"published","journal":{"display":true,"email":"[email protected]","identity":"journal-of-solution-chemistry","isNatureJournal":false,"hasQc":true,"allowDirectSubmit":false,"externalIdentity":"josl","sideBox":"Learn more about [Journal of Solution Chemistry](http://link.springer.com/journal/10953)","snPcode":"10953","submissionUrl":"https://submission.nature.com/new-submission/10953/3","title":"Journal of Solution Chemistry","twitterHandle":"","acdcEnabled":true,"dfaEnabled":true,"editorialSystem":"em","reportingPortfolio":"Springer Hybrid","inReviewEnabled":true,"inReviewRevisionsEnabled":false}}],"origin":"","ownerIdentity":"368ffbd0-d98d-4067-aadb-b2cbef239731","owner":[],"postedDate":"April 3rd, 2024","published":true,"recentEditorialEvents":[],"rejectedJournal":[],"revision":"","amendment":"","status":"published-in-journal","subjectAreas":[],"tags":[],"updatedAt":"2024-08-01T16:13:50+00:00","versionOfRecord":{"articleIdentity":"rs-4162162","link":"https://doi.org/10.1007/s10953-024-01400-9","journal":{"identity":"journal-of-solution-chemistry","isVorOnly":false,"title":"Journal of Solution Chemistry"},"publishedOn":"2024-07-21 16:04:50","publishedOnDateReadable":"July 21st, 2024"},"versionCreatedAt":"2024-04-03 08:47:11","video":"","vorDoi":"10.1007/s10953-024-01400-9","vorDoiUrl":"https://doi.org/10.1007/s10953-024-01400-9","workflowStages":[]},"version":"v1","identity":"rs-4162162","journalConfig":"researchsquare"},"__N_SSP":true},"page":"/article/[identity]/[[...version]]","query":{"redirect":"/article/rs-4162162","identity":"rs-4162162","version":["v1"]},"buildId":"qtupq5eGEP_6zYnWcrvyt","isFallback":false,"isExperimentalCompile":false,"dynamicIds":[84888],"gssp":true,"scriptLoader":[]}