Identification and Characterization of Sticky Contaminants in Multiple Recycled Paper Grades

Organic sticky contaminants represent one of the biggest technical challenges in the paper recycling process. These contaminants reduce paper strength, cause plugging of wires and felts, and stick to or deposit on machine parts affecting the runnability of the paper machine. The removal of these sticky contaminants is difficult to achieve along the process due to the heterogeneous nature of these organic contaminants. In this study, the nature of sticky contaminants in multiple wastepaper grades was analyzed and characterized using screening, solvent extraction with subsequent analysis such as FT-IR, GC-MS, and SEM. The content of stickies in wastepaper varies among different paper grades and their recovery methods. The majority of wastepaper grades collected from a recycled paper mill contains 3–5 wt% stickies, while a sample from a curb side collection from a residential area contains about 15 wt% stickies. Polyvinyl acetate (PVA) polymers, styrene butadiene rubber (SBR), paraffin waxes and polyamines are the major components in the extracted sticky contaminants. In addition, these stickies deposit heavily on fibers surface leading to high negative charge in fibers suspension ranging between 2 ~ 4.5 µeq/L. It is expected that these findings will assist addressing the knowledge gaps in understanding the nature of stickies and their behaviors, and to eventually develop highly efficient technologies for contamination removal in the paper recycling process.