Enantioselective PCCP Brønsted Acid Catalyzed Aminalization of Aldehydes
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Abstract
Here we present an enantioselective aminalization of aldehydes catalyzed by Brønsted acids based on pentacarboxycyclopentadienes (PCCPs). Cyclization reaction using readily available anthranilamides as building-blocks provides an access to valuable 2,3-dihydroquinazolinones containing one stereogenic carbon center with high degree of enantioselectivities ( ee up to 81 %) and excellent yields (up to 97%).
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- europepmc
- last seen: 2026-05-19T01:45:01.086888+00:00