Characterization of New Inorganic- Organic Hybrid Compounds: (C6H10N2).Cl2 (I), [C6H10N2]2ZnCl4 (II): Crystal Structure, Hirschfield Surface, IR and NMR spectroscopy Analysis.

Two new organic-inorganic hybrid materials, (C 6 H 10 N 2 ) . Cl 2 (I) and [C 6 H 10 N 2 ] 2 ZnCl 4 (II), have been synthesized by hydrothermal method and characterized by single-crystal X-ray diffraction and XRD pattern investigations. These two compounds are crystallized in the monoclinic system; C2/c space group. In the both structures, the anionic-cationic entities are interconnected by hydrogen bonding contacts and p-p Interaction forming three-dimensional networks. Intermolecular interactions were investigated by Hirshfeld surfaces and the contacts of the four different chloride atoms in ( II ) were compared. The vibrational absorption bands were identified by infrared spectroscopy. These compounds were also investigated by solid state 13 C NMR spectroscopy.