Isotopic and Geochemical Signatures of Dolostones and Their Implications for Carbonate Incipient Weathering Processes in the Datangpo Region, Guizhou, China

Determining carbon sources and sinks is crucial for understanding the global carbon cycle; however, the enigma of the 'missing' sinks remains unresolved. Recent studies have proposed carbonate weathering as a potential carbon sink, underscoring the need to clarify its mechanisms. Previous investigations of carbonate weathering largely relied on soil profiles, which were limited by the rarity of incipient weathering layers. Therefore, we have little knowledge about carbonate incipient weathering processes. To address this gap, spheroidal-weathered dolostones were collected from Neoproterozoic Liangjiehe Formation (Nanhua System) in Guizhou, China. The pristine dolostone exhibits δ13C values ranging from -5.26 to -3.35‰ and δ18O values from -13.79 to -12.83‰. These isotopic signatures suggest that the dolostone formed under the high-latitude, cold climatic conditions that were prevalent during the Nanhua Period. Comprehensive petrographic and geochemical analyses of the spheroidal-weathered dolostones revealed two distinct stages of incipient weathering. In Stage I, nickel (Ni) and cobalt (Co) contents decrease. The δ13C values fluctuate between -7.61 and -2.52‰, while δ18O values range from -12.22 to -8.06‰. These observations indicate a weakly acidic microenvironment. In Stage II, there is an enrichment of manganese (Mn), with δ13C values extending from -16.56 to -12.43‰ and δ18O values from -8.46 to -7.03‰. These clues suggest a transition to a neutral microenvironment, with the isotopic compositions of carbon and oxygen in the dolomite influenced by atmospheric carbon dioxide (CO2) and atmospheric precipitation. This study presents a pioneering investigation into the mineralogical and geochemical variations associated with carbonate incipient weathering processes. The variation in C-O isotopes during carbonate incipient weathering may indicate the re-precipitation of HCO3⁻, suggesting that the carbon-sink contribution of carbonate weathering to the global carbon cycle could be overestimated.