Synthesis, Structure, and Properties of a Dinuclear Cu(II) Coordination Polymer Based on Quinoxaline and 3,3-Thiodipropionic Acid Ligands

Synthesis, Structure, and Properties of a Dinuclear Cu(II) Coordination Polymer Based on Quinoxaline and 3,3-Thiodipropionic Acid Ligands | Research Square window.SnipcartSettings = { analytics: { enabled: false } }; (function() { var accessVector = localStorage.getItem('access_vector') || ''; window.dataLayer = window.dataLayer || []; if (accessVector) { window.dataLayer.push({ user: { profile: { profileInfo: { snid: accessVector } } } }); } })(); (function(w,d,s,l,i){w[l]=w[l]||[];w[l].push({'gtm.start':new Date().getTime(),event:'gtm.js'});var f=d.getElementsByTagName(s)[0],j=d.createElement(s),dl=l!='dataLayer'?'&l='+l:'';j.async=true;j.src='https://www.googletagmanager.com/gtm.js?id='+i+dl;f.parentNode.insertBefore(j,f);})(window,document,'script','dataLayer','GTM-K279D39R'); Browse Preprints In Review Journals COVID-19 Preprints AJE Video Bytes Research Tools Research Promotion AJE Professional Editing AJE Rubriq About Preprint Platform In Review Editorial Policies Our Team Advisory Board Help Center Sign In Submit a Preprint Cite Share Download PDF Research Article Synthesis, Structure, and Properties of a Dinuclear Cu(II) Coordination Polymer Based on Quinoxaline and 3,3-Thiodipropionic Acid Ligands Adedibu Clement Tella, Samson Owalude, Vincent Adimula, Adetola Oladipo, and 7 more This is a preprint; it has not been peer reviewed by a journal. https://doi.org/ 10.21203/rs.3.rs-209819/v1 This work is licensed under a CC BY 4.0 License Status: Published Journal Publication published 24 Mar, 2021 Read the published version in Journal of Inorganic and Organometallic Polymers and Materials → Version 1 posted 5 You are reading this latest preprint version Abstract The coordination polymer [Cu 2 (TDPH) 4 (QNX)].DMF, (QNX = Quinoxaline; TDPH = 3,3-thiodipropionic acid), has been prepared by reaction of copper acetate, TDPH, and quinoxaline. The compound was characterized by elemental analysis, FTIR spectroscopy, and single-crystal X-ray diffraction. The crystal is monoclinic with a P21/n space group and dimensions of a = 12.889(3) Å, b = 14.983(4) Å, c = 14.091(3) Å, α = 90 °, β = 90.200(11) °, γ = 90 °, V = 2721.18 (2) Å 3 , Z = 4. The ligands are hexagonally coordinated to the Cu(II) centre in the form of Cu 2 O 4 N with one nitrogen atom from the quinoxaline ligand, and four oxygen atoms from four TDPH molecules in a monodentate fashion. The Cu-Cu bond length was 2.642(1) and 2.629(1) Å for the Cu1----Cu1 and Cu2----Cu2 bonds. The QNX ligand bridged the two copper atoms. The catalytic reduction of 4-nitrophenol to 4-aminophenol using NaBH 4 in the presence of [Cu 2 (TDPH) 4 (QNX)].DMF, as catalyst was completed within 11 minutes. The 4-aminophenol product was confirmed using 1 H NMR spectroscopy. Materials Engineering Coordination polymer quinoxaline 3 3-thiodipropionic acid nitrophenol aminophenol Figures Figure 1 Figure 2 Figure 3 Figure 4 Figure 5 Figure 6 Figure 7 Figure 8 Figure 9 Figure 10 Figure 11 Figure 12 Figure 13 Full Text Due to technical limitations, full-text HTML conversion of this manuscript could not be completed. However, the latest manuscript can be downloaded and accessed as a PDF. Supplementary Files Tellaetal.Supplementaryinformation.docx checkcifAD128NIJTW.pdf scheme1.jpg Reaction scheme for the synthesis of [Cu2(TDPH)4(QNX)].DMF Cite Share Download PDF Status: Published Journal Publication published 24 Mar, 2021 Read the published version in Journal of Inorganic and Organometallic Polymers and Materials → Version 1 posted Editorial decision: Accept as is 04 Mar, 2021 Reviewers invited by journal 05 Feb, 2021 Reviews received at journal 05 Feb, 2021 Editor assigned by journal 04 Feb, 2021 First submitted to journal 04 Feb, 2021 You are reading this latest preprint version Research Square lets you share your work early, gain feedback from the community, and start making changes to your manuscript prior to peer review in a journal. As a division of Research Square Company, we’re committed to making research communication faster, fairer, and more useful. We do this by developing innovative software and high quality services for the global research community. Our growing team is made up of researchers and industry professionals working together to solve the most critical problems facing scientific publishing. Also discoverable on Platform About Our Team In Review Editorial Policies Advisory Board Help Center Resources Author Services Accessibility API Access RSS feed Manage Cookie Preferences © Research Square 2026 | ISSN 2693-5015 (online) Privacy Policy Terms of Service Do Not Sell My Personal Information {"props":{"pageProps":{"initialData":{"identity":"rs-209819","acceptedTermsAndConditions":true,"allowDirectSubmit":false,"archivedVersions":[],"articleType":"Research Article","associatedPublications":[],"authors":[{"id":10497250,"identity":"9a5abfa8-4c9b-4539-ac0d-6be241a80e9a","order_by":0,"name":"Adedibu Clement Tella","email":"","orcid":"","institution":"University of Ilorin","correspondingAuthor":false,"submittingAuthor":false,"prefix":"","firstName":"Adedibu","middleName":"Clement","lastName":"Tella","suffix":""},{"id":10497251,"identity":"d937ef7d-4942-4dd3-be99-ae73d9530ac7","order_by":1,"name":"Samson Owalude","email":"","orcid":"","institution":"University of 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16:00:32","currentVersionCode":1,"declarations":"","doi":"10.21203/rs.3.rs-209819/v1","doiUrl":"https://doi.org/10.21203/rs.3.rs-209819/v1","draftVersion":[],"editorialEvents":[{"content":"https://doi.org/10.1007/s10904-021-01966-7","type":"published","date":"2021-03-24T19:05:07+00:00"}],"editorialNote":"","failedWorkflow":false,"files":[{"id":6118867,"identity":"aaf5a8dc-33de-4e3f-820c-64eb35d5180b","added_by":"auto","created_at":"2021-02-19 00:42:49","extension":"jpg","order_by":1,"title":"Figure 1","display":"","copyAsset":false,"role":"figure","size":74515,"visible":true,"origin":"","legend":"ORTEP diagram of [Cu2(TDPH)4(QNX)].DMF","description":"","filename":"1.jpg","url":"https://assets-eu.researchsquare.com/files/rs-209819/v1/5324f4df0e4fe63ee72cc4ad.jpg"},{"id":6118556,"identity":"cfa705cc-1f7a-492b-9353-07504675cda3","added_by":"auto","created_at":"2021-02-19 00:39:48","extension":"jpg","order_by":2,"title":"Figure 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8","display":"","copyAsset":false,"role":"figure","size":36489,"visible":true,"origin":"","legend":"Absorption spectra of 4-nitrophenol in (a) the absence of NaBH4 (b) the presence of NaBH4","description":"","filename":"8.jpg","url":"https://assets-eu.researchsquare.com/files/rs-209819/v1/49b26c0b1162dc7617712768.jpg"},{"id":6119125,"identity":"7381b341-c7ec-47c3-be2f-40031e1660b5","added_by":"auto","created_at":"2021-02-19 00:45:48","extension":"jpg","order_by":9,"title":"Figure 9","display":"","copyAsset":false,"role":"figure","size":65152,"visible":true,"origin":"","legend":"UV-Vis Spectra showing the reduction of 4-NP by NaBH4 using the dinuclear [Cu2(TDPH)4(QNX)].DMF coordination polymers as catalysts","description":"","filename":"9.jpg","url":"https://assets-eu.researchsquare.com/files/rs-209819/v1/604b4115927a7ded489dde74.jpg"},{"id":6118869,"identity":"4209e8e6-d6f7-4f4b-b45d-b8569a60a8cc","added_by":"auto","created_at":"2021-02-19 00:42:49","extension":"jpg","order_by":10,"title":"Figure 10","display":"","copyAsset":false,"role":"figure","size":58775,"visible":true,"origin":"","legend":"Plot of ln (At/Ao) versus reaction time for the reduction of 4-NP using [Cu2(TDPH)4(QNX)].DMF as catalyst","description":"","filename":"10.jpg","url":"https://assets-eu.researchsquare.com/files/rs-209819/v1/37c6dd13e02a6c9d9c7ac816.jpg"},{"id":6118571,"identity":"a69facd5-552a-4247-81b8-11fd689def5c","added_by":"auto","created_at":"2021-02-19 00:39:49","extension":"jpg","order_by":11,"title":"Figure 11","display":"","copyAsset":false,"role":"figure","size":76409,"visible":true,"origin":"","legend":"Plots of ln (At/Ao) against time for the reduction of 4-NP at different temperatures","description":"","filename":"11.jpg","url":"https://assets-eu.researchsquare.com/files/rs-209819/v1/94e800a1abbe8ba6f0c7cfa7.jpg"},{"id":6118564,"identity":"2e8baad5-35f5-4997-8fa5-6f5b608c369c","added_by":"auto","created_at":"2021-02-19 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[Cu2(TDPH)4(QNX)].DMF","description":"","filename":"13.jpg","url":"https://assets-eu.researchsquare.com/files/rs-209819/v1/4259b1b1c09333e72d55be09.jpg"},{"id":13591139,"identity":"e06136b2-d27a-497d-bc62-a75322593850","added_by":"auto","created_at":"2021-09-17 05:07:41","extension":"pdf","order_by":1,"title":"","display":"","copyAsset":false,"role":"manuscript-pdf","size":1444797,"visible":true,"origin":"","legend":"","description":"","filename":"TellaetalJIOPM.pdf","url":"https://assets-eu.researchsquare.com/files/rs-209819/v1_covered.pdf"},{"id":6119388,"identity":"68d5ab3c-cb7c-45cb-8e79-b1ed7eb60af7","added_by":"auto","created_at":"2021-02-19 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Text","content":"Due to technical limitations, full-text HTML conversion of this manuscript could not be completed. However, the latest manuscript can be downloaded and \u003ca href='/article/rs-209819/latest.pdf' target='_blank'\u003e accessed as a PDF.\u003c/a\u003e"}],"fulltextSource":"","fullText":"","funders":[],"hasAdminPriorityOnWorkflow":false,"hasManuscriptDocX":false,"hasOptedInToPreprint":true,"hasPassedJournalQc":"","hasAnyPriority":false,"hideJournal":false,"highlight":"","institution":"","isAcceptedByJournal":true,"isAuthorSuppliedPdf":true,"isDeskRejected":"","isHiddenFromSearch":false,"isInQc":false,"isInWorkflow":false,"isPdf":false,"isPdfUpToDate":true,"isWithdrawnOrRetracted":false,"journal":{"display":true,"email":"[email protected]","identity":"journal-of-inorganic-and-organometallic-polymers-and-materials","isNatureJournal":false,"hasQc":true,"allowDirectSubmit":false,"externalIdentity":"joip","sideBox":"Learn more about [Journal of Inorganic and Organometallic Polymers and Materials](https://www.springer.com/journal/10904)","snPcode":"10904","submissionUrl":"https://submission.nature.com/new-submission/10904/3","title":"Journal of Inorganic and Organometallic Polymers and Materials","twitterHandle":"","acdcEnabled":true,"dfaEnabled":true,"editorialSystem":"em","reportingPortfolio":"Springer Hybrid","inReviewEnabled":true,"inReviewRevisionsEnabled":false},"keywords":"Coordination polymer, quinoxaline, 3,3-thiodipropionic acid, nitrophenol, aminophenol","lastPublishedDoi":"10.21203/rs.3.rs-209819/v1","lastPublishedDoiUrl":"https://doi.org/10.21203/rs.3.rs-209819/v1","license":{"name":"CC BY 4.0","url":"https://creativecommons.org/licenses/by/4.0/"},"manuscriptAbstract":"\u003cp\u003eThe coordination polymer [Cu\u003csub\u003e2\u003c/sub\u003e(TDPH)\u003csub\u003e4\u003c/sub\u003e(QNX)].DMF, (QNX = Quinoxaline; TDPH = 3,3-thiodipropionic acid), has been prepared by reaction of copper acetate, TDPH, and quinoxaline. The compound was characterized by elemental analysis, FTIR spectroscopy, and single-crystal X-ray diffraction. The crystal is monoclinic with a P21/n space group and dimensions of a = 12.889(3) Å, b = 14.983(4) Å, c = 14.091(3) Å, α = 90 °, β = 90.200(11) °, γ = 90 °, V = 2721.18 (2) Å\u003csup\u003e3\u003c/sup\u003e, Z = 4. The ligands are hexagonally coordinated to the Cu(II) centre in the form of Cu\u003csub\u003e2\u003c/sub\u003eO\u003csub\u003e4\u003c/sub\u003eN with one nitrogen atom from the quinoxaline ligand, and four oxygen atoms from four TDPH molecules in a monodentate fashion. The Cu-Cu bond length was 2.642(1) and 2.629(1) Å for the Cu1----Cu1 and Cu2----Cu2 bonds. The QNX ligand bridged the two copper atoms. The catalytic reduction of 4-nitrophenol to 4-aminophenol using NaBH\u003csub\u003e4\u003c/sub\u003e in the presence of [Cu\u003csub\u003e2\u003c/sub\u003e(TDPH)\u003csub\u003e4\u003c/sub\u003e(QNX)].DMF, as catalyst was completed within 11 minutes. The 4-aminophenol product was confirmed using \u003csup\u003e1\u003c/sup\u003eH NMR spectroscopy.\u0026nbsp;\u003c/p\u003e","manuscriptTitle":"Synthesis, Structure, and Properties of a Dinuclear Cu(II) Coordination Polymer Based on Quinoxaline and 3,3-Thiodipropionic Acid Ligands","msid":"","msnumber":"","nonDraftVersions":[{"code":1,"date":"2021-02-19 00:39:46","doi":"10.21203/rs.3.rs-209819/v1","editorialEvents":[{"type":"communityComments","content":0},{"type":"decision","content":"Accept as is","date":"2021-03-04T15:28:20+00:00","index":"","fulltext":""},{"type":"reviewersInvited","content":"","date":"2021-02-06T00:00:00+00:00","index":"","fulltext":""},{"type":"editorInvitedReview","content":"","date":"2021-02-06T00:00:00+00:00","index":0,"fulltext":""},{"type":"editorAssigned","content":"","date":"2021-02-05T00:00:00+00:00","index":"","fulltext":""},{"type":"submitted","content":"Journal of Inorganic and Organometallic Polymers and Materials","date":"2021-02-04T07:50:21+00:00","index":"","fulltext":""}],"status":"published","journal":{"display":true,"email":"[email protected]","identity":"journal-of-inorganic-and-organometallic-polymers-and-materials","isNatureJournal":false,"hasQc":true,"allowDirectSubmit":false,"externalIdentity":"joip","sideBox":"Learn more about [Journal of Inorganic and Organometallic Polymers and Materials](https://www.springer.com/journal/10904)","snPcode":"10904","submissionUrl":"https://submission.nature.com/new-submission/10904/3","title":"Journal of Inorganic and Organometallic Polymers and Materials","twitterHandle":"","acdcEnabled":true,"dfaEnabled":true,"editorialSystem":"em","reportingPortfolio":"Springer Hybrid","inReviewEnabled":true,"inReviewRevisionsEnabled":false}}],"origin":"","ownerIdentity":"cac94529-a0c3-48ba-9706-39a9c3061469","owner":[],"postedDate":"February 19th, 2021","published":true,"recentEditorialEvents":[],"rejectedJournal":[],"revision":"","amendment":"","status":"published-in-journal","subjectAreas":[{"id":2483148,"name":"Materials Engineering"}],"tags":[],"updatedAt":"2021-08-18T19:46:50+00:00","versionOfRecord":{"articleIdentity":"rs-209819","link":"https://doi.org/10.1007/s10904-021-01966-7","journal":{"identity":"journal-of-inorganic-and-organometallic-polymers-and-materials","isVorOnly":false,"title":"Journal of Inorganic and Organometallic Polymers and Materials"},"publishedOn":"2021-03-24 19:05:07","publishedOnDateReadable":"March 24th, 2021"},"versionCreatedAt":"2021-02-19 00:39:46","video":"","vorDoi":"10.1007/s10904-021-01966-7","vorDoiUrl":"https://doi.org/10.1007/s10904-021-01966-7","workflowStages":[]},"version":"v1","identity":"rs-209819","journalConfig":"researchsquare"},"__N_SSP":true},"page":"/article/[identity]/[[...version]]","query":{"redirect":"/article/rs-209819","identity":"rs-209819","version":["v1"]},"buildId":"7rjqhiLT3MXkJMwkYKINL","isFallback":false,"isExperimentalCompile":false,"dynamicIds":[84888],"gssp":true,"scriptLoader":[]}