Structural, Dielectric and Thermal Properties of PVDF - Nickel Metal Organic Framework (Ni-MOF) Nanocomposites | Research Square window.SnipcartSettings = { analytics: { enabled: false } }; (function() { var accessVector = localStorage.getItem('access_vector') || ''; window.dataLayer = window.dataLayer || []; if (accessVector) { window.dataLayer.push({ user: { profile: { profileInfo: { snid: accessVector } } } }); } })(); (function(w,d,s,l,i){w[l]=w[l]||[];w[l].push({'gtm.start':new Date().getTime(),event:'gtm.js'});var f=d.getElementsByTagName(s)[0],j=d.createElement(s),dl=l!='dataLayer'?'&l='+l:'';j.async=true;j.src='https://www.googletagmanager.com/gtm.js?id='+i+dl;f.parentNode.insertBefore(j,f);})(window,document,'script','dataLayer','GTM-K279D39R'); Browse Preprints In Review Journals COVID-19 Preprints AJE Video Bytes Research Tools Research Promotion AJE Professional Editing AJE Rubriq About Preprint Platform In Review Editorial Policies Our Team Advisory Board Help Center Sign In Submit a Preprint Cite Share Download PDF Research Article Structural, Dielectric and Thermal Properties of PVDF - Nickel Metal Organic Framework (Ni-MOF) Nanocomposites Vikas Rathour, R. K. Tiwari, Sergej Iľkovič, Rohan Sagar, Pramod Kumar Singh, and 2 more This is a preprint; it has not been peer reviewed by a journal. https://doi.org/ 10.21203/rs.3.rs-8782231/v1 This work is licensed under a CC BY 4.0 License Status: Posted Version 1 posted You are reading this latest preprint version Abstract In this work, we introduce a metal-organic framework (MOF) that is 2D in nature into the poly (vinylidene fluoride) (PVDF) matrix, an area relatively underexplored. Using the chemical method, a highly 2D Ni-MOF was synthesized. Ni-MOF with different weight ratios was incorporated into PVDF matrixes by solvent casting. SEM and XRD were used to determine the nanocomposite structure. According to XRD, PVDF shifted towards the β phase with the incorporation of Ni MOF nanofiller. The dielectric constant decreases with frequency; however, higher MOF loadings cause the dielectric constant to decrease as dielectric loss increases. TGA/DSC shows that the thermal stability of PVDF-Ni-MOF nanocomposite is higher than that of pure PVDF due to the intermolecular interaction of Ni-MOF with PVDF. SEM XRD Dielectric permittivity DSC TGA Full Text Additional Declarations No competing interests reported. Cite Share Download PDF Status: Posted Version 1 posted You are reading this latest preprint version Research Square lets you share your work early, gain feedback from the community, and start making changes to your manuscript prior to peer review in a journal. As a division of Research Square Company, we’re committed to making research communication faster, fairer, and more useful. We do this by developing innovative software and high quality services for the global research community. Our growing team is made up of researchers and industry professionals working together to solve the most critical problems facing scientific publishing. Also discoverable on Platform About Our Team In Review Editorial Policies Advisory Board Help Center Resources Author Services Accessibility API Access RSS feed Manage Cookie Preferences © Research Square 2026 | ISSN 2693-5015 (online) Privacy Policy Terms of Service Do Not Sell My Personal Information {"props":{"pageProps":{"initialData":{"identity":"rs-8782231","acceptedTermsAndConditions":true,"allowDirectSubmit":true,"archivedVersions":[],"articleType":"Research Article","associatedPublications":[],"authors":[{"id":608582585,"identity":"ca6f18a0-3930-4de7-8285-577ad6d12322","order_by":0,"name":"Vikas Rathour","email":"","orcid":"","institution":"PDPM- Indian Institute of Information Technology, Design and Manufacturing","correspondingAuthor":false,"prefix":"","firstName":"Vikas","middleName":"","lastName":"Rathour","suffix":""},{"id":608582586,"identity":"971e7448-3a05-4c62-aebd-684280065f87","order_by":1,"name":"R. K. Tiwari","email":"","orcid":"","institution":"Hindustan College of Science and Technology","correspondingAuthor":false,"prefix":"","firstName":"R.","middleName":"K.","lastName":"Tiwari","suffix":""},{"id":608582587,"identity":"6040a4d7-d890-4859-9454-9d1d75e49dfb","order_by":2,"name":"Sergej Iľkovič","email":"","orcid":"","institution":"University of Prešov","correspondingAuthor":false,"prefix":"","firstName":"Sergej","middleName":"","lastName":"Iľkovič","suffix":""},{"id":608582588,"identity":"016f3af2-069b-49d0-9b00-117ba8fa19b0","order_by":3,"name":"Rohan Sagar","email":"","orcid":"","institution":"Hindustan College of Science and Technology","correspondingAuthor":false,"prefix":"","firstName":"Rohan","middleName":"","lastName":"Sagar","suffix":""},{"id":608582589,"identity":"df5a7166-65a2-48f8-affb-958c1acdba6d","order_by":4,"name":"Pramod Kumar Singh","email":"","orcid":"","institution":"Hindustan College of Science and Technology","correspondingAuthor":false,"prefix":"","firstName":"Pramod","middleName":"Kumar","lastName":"Singh","suffix":""},{"id":608582590,"identity":"9dec0afd-c9a5-4604-933a-225f4e3a5a01","order_by":5,"name":"M. S. Gaur","email":"data:image/png;base64,iVBORw0KGgoAAAANSUhEUgAAAZAAAAAyAQMAAABI0h/eAAAABlBMVEX///8AAABVwtN+AAAACXBIWXMAAA7EAAAOxAGVKw4bAAAA7ElEQVRIiWNgGAWjYDADAxDxAYjZSNHC2DiDZC3NPMSo1O0/wPziZ9s9BnP2488f2/ypleNjYD728QseLWY3Etgse9uKGSx7cgybc9uOG7MxsCXPlsGrhYHNgLctgcHgBg9jc27DscQ2Bh5jZgl8Ws4fYDP8C9bC/rDZ4s+xesJaDiQwP4bYwmDYzMBWk8AG1ML4Aa/DEtuYZc4l8BicyTGc2dt2wLCNmS2ZGY8OoMMOH/74pixBzuD48Qcffvypk5dvbz7M+AOfHgbGNpDDYTFymIEBaAUzgQhiRnZ4HcQY/LaMglEwCkbBCAMA075JuMCywrMAAAAASUVORK5CYII=","orcid":"","institution":"Hindustan College of Science and Technology","correspondingAuthor":true,"prefix":"","firstName":"M.","middleName":"S.","lastName":"Gaur","suffix":""},{"id":608582591,"identity":"db25d10e-f527-4959-9aca-2d8d0dd561cb","order_by":6,"name":"M. K. Roy","email":"","orcid":"","institution":"PDPM- Indian Institute of Information Technology, Design and Manufacturing","correspondingAuthor":false,"prefix":"","firstName":"M.","middleName":"K.","lastName":"Roy","suffix":""}],"badges":[],"createdAt":"2026-02-04 05:53:32","currentVersionCode":1,"declarations":"","doi":"10.21203/rs.3.rs-8782231/v1","doiUrl":"https://doi.org/10.21203/rs.3.rs-8782231/v1","draftVersion":[],"editorialEvents":[],"editorialNote":"","failedWorkflow":false,"files":[{"id":105728155,"identity":"27aa8051-ef89-4267-85e1-75aadf0844e1","added_by":"auto","created_at":"2026-03-30 11:10:20","extension":"pdf","order_by":1,"title":"","display":"","copyAsset":false,"role":"manuscript-pdf","size":1461177,"visible":true,"origin":"","legend":"","description":"","filename":"ManuscriptRevisonon3Feb2026.pdf","url":"https://assets-eu.researchsquare.com/files/rs-8782231/v1_covered_ea5ede02-f7db-4450-8086-2a563a7f21a6.pdf"}],"financialInterests":"No competing interests reported.","formattedTitle":"Structural, Dielectric and Thermal Properties of PVDF - Nickel Metal Organic Framework (Ni-MOF) Nanocomposites","fulltext":[],"fulltextSource":"","fullText":"","funders":[],"hasAdminPriorityOnWorkflow":false,"hasManuscriptDocX":false,"hasOptedInToPreprint":true,"hasPassedJournalQc":"","hasAnyPriority":false,"hideJournal":true,"highlight":"","institution":"","isAcceptedByJournal":false,"isAuthorSuppliedPdf":true,"isDeskRejected":"","isHiddenFromSearch":false,"isInQc":false,"isInWorkflow":false,"isPdf":true,"isPdfUpToDate":true,"isWithdrawnOrRetracted":false,"journal":{"display":true,"email":"
[email protected]","identity":"researchsquare","isNatureJournal":false,"hasQc":true,"allowDirectSubmit":true,"externalIdentity":"","sideBox":"","snPcode":"","submissionUrl":"/submission","title":"Research Square","twitterHandle":"researchsquare","acdcEnabled":true,"dfaEnabled":false,"editorialSystem":"","reportingPortfolio":"","inReviewEnabled":false,"inReviewRevisionsEnabled":true},"keywords":"SEM, XRD, Dielectric permittivity, DSC, TGA","lastPublishedDoi":"10.21203/rs.3.rs-8782231/v1","lastPublishedDoiUrl":"https://doi.org/10.21203/rs.3.rs-8782231/v1","license":{"name":"CC BY 4.0","url":"https://creativecommons.org/licenses/by/4.0/"},"manuscriptAbstract":"\u003cp\u003eIn this work, we introduce a metal-organic framework (MOF) that is 2D in nature into the poly (vinylidene fluoride) (PVDF) matrix, an area relatively underexplored. Using the chemical method, a highly 2D Ni-MOF was synthesized. Ni-MOF with different weight ratios was incorporated into PVDF matrixes by solvent casting. SEM and XRD were used to determine the nanocomposite structure. According to XRD, PVDF shifted towards the β phase with the incorporation of Ni MOF nanofiller. \u003cb\u003eThe dielectric constant decreases with frequency; however, higher MOF loadings cause the dielectric constant to decrease as dielectric loss increases.\u003c/b\u003e TGA/DSC shows that the thermal stability of PVDF-Ni-MOF nanocomposite is higher than that of pure PVDF due to the intermolecular interaction of Ni-MOF with PVDF.\u003c/p\u003e","manuscriptTitle":"Structural, Dielectric and Thermal Properties of PVDF - Nickel Metal Organic Framework (Ni-MOF) Nanocomposites","msid":"","msnumber":"","nonDraftVersions":[{"code":1,"date":"2026-03-23 15:50:33","doi":"10.21203/rs.3.rs-8782231/v1","editorialEvents":[{"type":"communityComments","content":0}],"status":"published","journal":{"display":true,"email":"
[email protected]","identity":"researchsquare","isNatureJournal":false,"hasQc":true,"allowDirectSubmit":true,"externalIdentity":"","sideBox":"","snPcode":"","submissionUrl":"/submission","title":"Research Square","twitterHandle":"researchsquare","acdcEnabled":true,"dfaEnabled":false,"editorialSystem":"","reportingPortfolio":"","inReviewEnabled":false,"inReviewRevisionsEnabled":true}}],"origin":"","ownerIdentity":"ff4e883f-7561-4252-891d-61ba7837ce40","owner":[],"postedDate":"March 23rd, 2026","published":true,"recentEditorialEvents":[],"rejectedJournal":[],"revision":"","amendment":"","status":"posted","subjectAreas":[],"tags":[],"updatedAt":"2026-03-23T15:50:33+00:00","versionOfRecord":[],"versionCreatedAt":"2026-03-23 15:50:33","video":"","vorDoi":"","vorDoiUrl":"","workflowStages":[]},"version":"v1","identity":"rs-8782231","journalConfig":"researchsquare"},"__N_SSP":true},"page":"/article/[identity]/[[...version]]","query":{"redirect":"/article/rs-8782231","identity":"rs-8782231","version":["v1"]},"buildId":"XKTyCvWXoU3ODBz1xrDgd","isFallback":false,"isExperimentalCompile":false,"dynamicIds":[84888],"gssp":true,"scriptLoader":[]}
Text is read by the "Ask this paper" AI Q&A widget below.
Extraction quality varies by source — PMC NXML preserves structure
cleanly, OA-HTML may include some navigation residue, and OA-PDF can
have broken hyphenation. The publisher copy
(via DOI)
is the canonical version.