Using (Iber) Hydrodynamic Model to Simulate the Flow of Polluted Water of Tigris River in Mosul City, Northern Iraq

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Abstract Iber Model was used to simulates fresh water flow and pollutant transport in various aquatic environments, focusing on the main valleys in Mosul City that discharge into Tigris River. These valleys, including Al-Rashidia, Al-Kharrazi, Al-Khosar, Al-Danffilli, Al-Shor, and Eqab, are heavily polluted with solid waste, sewage, and industrial runoff, especially during the rainy season. Total dissolved solids (TDS) concentrations were measured, revealing levels of 520, 500, 670, 660, 1820, and 660 mg/L, respectively. Iber model showed that mixing Tigris River fresh water with valleys water reduces TDS concentrations downstream mouth valleys, with varying distances of impact based on discharge and pollution levels: 293 m from Eqab, 323 m from Al-Khosar, 280 m from Al-Danffilli, and 650 m from Al-Shor. Al-Rashidia and Al-Kharazi showed minimal impact due to their low discharge. Overall, the valleys' discharges do not pose a significant concern for Tigris River's dissolved salt content.
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Mustafa, Kotayba T. Al-Youzbakey, Basma A.M. Al-Jawadi This is a preprint; it has not been peer reviewed by a journal. https://doi.org/ 10.21203/rs.3.rs-6589312/v1 This work is licensed under a CC BY 4.0 License Status: Posted Version 1 posted You are reading this latest preprint version Abstract Iber Model was used to simulates fresh water flow and pollutant transport in various aquatic environments, focusing on the main valleys in Mosul City that discharge into Tigris River. These valleys, including Al-Rashidia, Al-Kharrazi, Al-Khosar, Al-Danffilli, Al-Shor, and Eqab, are heavily polluted with solid waste, sewage, and industrial runoff, especially during the rainy season. Total dissolved solids (TDS) concentrations were measured, revealing levels of 520, 500, 670, 660, 1820, and 660 mg/L, respectively. Iber model showed that mixing Tigris River fresh water with valleys water reduces TDS concentrations downstream mouth valleys, with varying distances of impact based on discharge and pollution levels: 293 m from Eqab, 323 m from Al-Khosar, 280 m from Al-Danffilli, and 650 m from Al-Shor. Al-Rashidia and Al-Kharazi showed minimal impact due to their low discharge. Overall, the valleys' discharges do not pose a significant concern for Tigris River's dissolved salt content. Iber model Hydrodynamic Model Tigris River Mosul City Polluted water Figures Figure 1 Figure 2 Figure 3 1 Introduction River water is an essential source of life and a fundamental component of the ecosystem; yet, diverse human activities and the growing population in urban and rural areas close to rivers result in changes to water quality (Jazza et al., 2022 ; K. E et al., 2017; Karnataka et al., 2011 ). The sediment and rock composition of the river basin, the impacts of erosion on rocks and soils, and the influence of diverse human activities are the principal factors affecting the water quality requirements of rivers (Al-Youzbakey & Sulaiman, 2021 ; K. E et al., 2017; Kelantan et al., 2009 ). The pollution level of a river is determined by the inflow of freshwater and pollutants, governed by the prevailing water standards. If pollutants exceed permissible limits, the characteristics of the river change from fresh to polluted (Al-Dabbas et al., 2018 ; iya Sowjanya, 2015 ; Wang et al., 2016 ). The oversight and preservation of water quality are crucial for environmental and health concerns. Aquatic plants and animals flourish in ideal aquatic habitats, and both humans and wildlife rely on clean and drinkable water for sustenance (World Health Organization, 2022 ). Presently, waterborne infections cause millions of patients and deaths each year. Therefore, field tests must be combined with other disciplines to determine the extent of the pollution (Anas et al., 2021 ). The amalgamation of quantitative field experiments with simulation research may augment our understanding of core principles and promote the formulation of innovative solutions for environmental management and protection (Fritzson et al., 2020 ). The data volume necessary for simulation can be decreased through the utilization of an advanced modelling tool. Furthermore, simulation models can accurately forecast the necessary outputs in situations where field assessments are unfeasible. Therefore, hydraulic models employ the essential concepts of hydraulics to calculate water levels, flow velocities, and flow depths in rivers under actual or hypothetical conditions. The models are categorized into two types: hydrodynamic models and hydrological models. Hydrodynamic models are based on the whole hydraulic design process, incorporating all essential hydraulic concepts. In contrast, hydrological models depend on the software's algorithms to predict water flow under very simple settings (Sousa et al., 2021 ). Hydrodynamic modelling in water pollution research is recognized as a crucial tool for understanding the physical processes and intricacies of flow hydraulics related to mixing processes. This tool relates to diverse scales of water fluctuations at low to moderate levels, precisely representing the characteristics of velocity fields observed in laboratory flumes, channels, tidal inlets, confluences, bend escapes, reservoirs, and macro-scale catchment areas with river utilization (Xue et al., 2022 ). One of the hydrodynamic models Iber which is a two-dimensional model designed to simulate water flow in free surfaces, rivers, estuaries, bays, and reservoirs which it developed by a collaborative team of engineers and scientists from various institutes and universities (De Goede, 2020 ). The Iber model incorporates seasonal variations in water flow and pollutant concentrations. Various studies have utilised it to simulate water flow and pollutant transport across different seasons in multiple rivers and water bodies (Mesquita & Lima Neto, 2022 ). 1.1 Related works Research (Mustafa, 2009 ), corroborated by (Mustafa & Al-Youzbakey, 2021 ), identifies Tigris River in Mosul City as a location for the disposal of domestic, agricultural, and industrial waste, which is transported via the Eqab, Al-Rashidia, Al-Kharrazi, Al-Khosar, Al-Shor, and Al-Danffilli Valleys. All waste is conveyed through these valleys to Tigris River due to the absence of a sewage network connected to wastewater treatment facilities. A study indicated that the drinking water quality index (WQI) of Tigris River was excellent in northern Mosul City, transitioning to good in the southern region as the river exited the city. This is due to the adverse impacts of human activity on the river (Al-Assaf & Al-Saffawi, 2018 ). In (Ibrahim & Al-Youzbakey, 2024 ), the waters of the valleys discharging into Tigris River were classified according to TDS values. The waters of Al-Rashedia and Al-Kharrazi Valleys exhibit medium salinity, whereas the waters of Al-Khosar, Al-Danffilli, and Al-Shor Valleys are classified as having high salinity, attributed to the impact of domestic, industrial, and agricultural waste on these areas. In (García-Feal et al., 2020 ), the researchers employed the Iber hydrodynamic model to assess water quality in rivers and estuaries in Spain. The study examines three types of pollutants present in rivers: faecal contamination in coastal estuaries, combined sewer overflow in the Minno River, and organic matter contamination in estuaries. The study produces detailed maps illustrating the distribution and concentrations of polluted metals in river and estuary regions. The Delft 3D model was employed by (Tran et al., 2024 ) to simulate the water quality of Binh Thien Lake in Vietnam. The authors modeled the distribution of dissolved oxygen (DO) and biochemical oxygen demand (BOD) across the entire lake area for October 2022 and May 2023. Simulation results generated maps for dissolved oxygen (DO) and biochemical oxygen demand (BOD), illustrating the impact of incoming flow on DO and BOD levels in the lake. 1.2 The study area Mosul City is located in northern Iraq between longitudes 43°16″ − 43°30″ east and latitudes 36°15″ − 36°27″ north. It is a prominent and densely populated city in Iraq compared to other urban areas. The Tigris River divides the city into two separate parts. Both areas are characterized by high population density, agricultural and animal husbandry activities, and the presence of an industrial sector. Mosul has a semi-arid climate, with an average annual rainfall of 375 mm (Al-Jawadi, 2022 ; Awchi & Jasim, 2017 ). Tigris River flows through diverse geological formations, including igneous, metamorphic, and carbonate rocks, in southern Turkey before crossing into Iraq (Westaway et al., 2009 ). Upon entering Iraqi territory, Tigris River flows through diverse rock types linked to several geological formations. The Muqdadiya Formation is characterized by sandstones and conglomerates; the Injana Formation comprises sequences of sandstone, siltstone, and mudstone; the Fatha Formation consists of marl, limestone, and gypsum; and the Euphrates Formation is primarily limestone (Al-Dabbagh & Al-Naqib, 1991 ). Quaternary deposits are prevalent in the river basin leading to Mosul, characterized by floodplain sediments, river terraces, and sediments carried by tributary valleys (Buday, 1980 ). 1.3 The studied valleys Valleys in Mosul City are crucial for the drainage of rainwater and sewage into Tigris River. These valleys, as natural channels, have been subjected to numerous pollution factors due to the accumulation of solid waste and neglect, in addition to functioning as natural sewage drainage streams. This situation has resulted in the presence of various types of civil, industrial, and agricultural waste, which in turn promotes the growth of bushland and numerous plant species, including reeds. This article discusses six main valleys in the city. Figure 1 illustrates the mouth locations of these valleys on Tigris River. Al-Rashidia Valley originates near Talkef and traverses various residential and agricultural areas in Mosul City, including Kossites, Malaien, and Rashidia, before flowing into Tigris River. Al-Kharrazi Valley is located in the northeastern Mosul City region, has two tributaries, one from Sadah and Baweza and the other from the northern Al-Kindi establishment. Its two branches converge in the Andalusia Quarter and discharge into the Tigris River, but the valley is prone to pollution from sewage contaminants and household solid waste Al-Khosar Valley located in northern Iraq's Ba'azrah region, is the largest and most expansive valley of Tigris River in Mosul City. The influence of human activities, including domestic, industrial, and agricultural uses, increases the sources of pollutants that adversely effect on water quality of this valley during dry periods, especially the lacking of waste management, sewage networks, and treatment facilities. Al-Danffilli Valley originates at the residential complex in the Green Quarter and the Industrial Zone to the east of Mosul City, situated along Tigris River. The valley is regarded as one of the most polluted due to nearby industrial operations and population activities in the surrounding areas. Al-Shor Valley basin is situated to the east of Mosul City, between the Ba'shiqa and Ein Al-Safra Mountains. It is discharged into Tigris River from the left bank. The Industrial Zone is characterized by significant pollution sources stemming from local industrial activities and sewage discharge from neighboring areas adjacent to the valley. Eqab Valley is a significant valley located on the right side of Mosul City, extending from the Al-Nahruan Quarter through the industrial zone to the Al-Rabee Quarter, ultimately flowing into Tigris River. This valley is subject to significant pollution due to industrial activities, sanitation practices in residential areas, and drainage systems from adjacent agricultural zones. 1.4 Aim of the study The study aims to evaluate the effectiveness of the Iber hydrodynamic model in predicting the flow of polluted water from valleys to Tigris River in Mosul City, by accurately determining the complex dynamics of the Tigris River in order to provide reliable predictions. 2 Methodology 2.1 Field sampling Duplicate four samples were collected from specific locations on the Tigris River that represent the mouths of the valleys, as follows: Sample (1) from upstream the confluence region each valley, Sample (2) at the confluence, Sample (3) at 100 meters downstream the confluence region and Sample (4) at 200 meters from the confluence, in addition to collecting duplicate samples from each valley before it drains into the river, which represents Sample (5). Physical testing was conducted utilizing a field device, with total dissolved solids (TDS) and electrical conductivity (E.C), measurements performed using a portable conductivity meter (Boqu Dds-1702, Shanghai Boqu Instrument Co., Ltd.). The pH was assessed using a portable instrument (Handheld pH ORP Meter, Shanghai Boqu Instrument Co., Ltd.), while turbidity was evaluated using a Turbidity Meter (Hanna HI 93703). Chemical analyses of duplicate water samples were performed in the Geochemistry Laboratory at the Dams and Water Resources Research Center – University of Mosul, following standard routine methodologies (S.A. Abbawi & M. S. Hassan, 1990). Sodium and potassium were quantified using the flame spectrometer method (Flame-photometer, type JENWAY PEP7). Total hardness (TH), calcium, and magnesium were assessed via the trituration method with EDTA, while bicarbonate and carbonate were determined through trituration with sulfuric acid, and chlorine was measured using trituration with silver nitrate. Sulfates and nitrates were quantified using colorimetric techniques with a UV-spectrophotometer (UV-Spectrophotometer model - OGAWA, OSK 7724). 2.2 Hydrodynamic Modelling: 2.2.1 Model Validation The Iber model calibration procedure involved five phases: sensitivity analysis to identify critical model factors affecting water levels, calibration of water level parameters through iterative testing over a specific period, calibration of discharge parameters, and calibration of lateral discharge to address performance difficulties in certain river segments. The final stage evaluated the model outcomes and comparing them with actual observation, ensuring a robust dependability assessment. The Iber model was calibrated and validated for Mosul City by (Al-Taiee & Mustafa, 2020 ), demonstrating its applicability in this environment. 2.2.2 Initial and boundary conditions: The initial and boundary conditions serve as fundamental inputs for any hydrodynamic model, upon which the simulation process for the subject under analysis is conducted. The initial conditions denote the water distribution in the research area prior to the commencement of the simulation, whereas the boundary conditions indicate the volume of water that entered the simulated river. The case study includes two categories of boundary conditions: the first is related to the Tigris River, and the second is related to the polluted water sources that flow into the river as shown in Table 1 . The initial condition of the Tigris River which represents the constant discharge of water into the river in sampling day which is equal to 350 m³/s with average total dissolved solids (TDS) Table 1 . Table 1 The boundary contaminant conditions for Tigris River and the polluted sources. Tigris River Polluted sources Valley name Valley symbol TDS (mg/l) upstream valley mouth Discharge (m 3 /sec) TDS (mg/l) Discharge (m 3 /sec) Al-Rashidia R 307 350 520 0.045 Al-Kharrazi Z 300 500 0.18 Al-Khoser Kh 310 670 3 Al-Danffili D 310 660 4.8 Al-Shor Sh 310 1820 0.535 Eqab E 340 660 0.612 Average 312 3 Results and Discussion The article's results are categorized into two parts: the first pertains to hydrodynamic modeling outcomes, while the second encompasses laboratory and field data. 3.1 Hydrodynamic results Precise modeling and simulation of pollutants in Tigris River were conducted following the provision of all necessary input data to the model. This simulation estimated maps delineating the regions impacted by pollution sources in Tigris River and the concentrations of these pollutants in the pertinent portions. The findings indicate that the pollution sources near Al-Rashidia and Al-Kharrazi Valleys along the Tigris River exerted a negligible impact on the river, attributable to their low discharge, which resulted in the dilution of these pollutants with significant volumes of fresh Tigris River water. Figure (2) shows the impact of the other four valleys on the river, which has a greater polluting effect than Al-Rashidia and Al-Kharrazi valleys. Figure 2 (a) shows the impact of pollution from Eqab on the river, which is mainly limited to the river bank due to its low discharge. Figure 2 (b, c & d) shows the impact of pollution sources from the Al-Khosar, Al-Danffilli and Al-Shor Valleys on the area in front of these estuaries, which is greater than Eqab due to the high discharge rates and total dissolved solids from the sources of these valleys, as shown in Table 1 . Figure 2 indicates that the extent of pollution in the affected areas of the valley varies from one to another, due to differences in water discharge and total dissolved solids (TDS) concentration of each valley. 3.2 Laboratory Results Sample (1) illustrates the chemical characteristics of Tigris River waters across all locations, revealing a significant resemblance in the concentrations of the main ions at sites along the left bank of Tigris River. Concentrations of all ions, except potassium and nitrate, are unusually high near the mouth of Eqab Valley on the right bank of the river, likely due to river sediment extraction activities in that area, Table 2 . Samples (2) show variations in the concentrations of ions due to the mixing of the valley polluted water with Tigris River water. This variance depends on the discharge of water dumped into the river and the ion concentrations in waters for each valley. The concentrations of ions in the waters of all valleys represented by sample (5) exceed those in the Tigris River. The high concentrations are attributed to water discharges from these valleys, which are a by-product of human activities (domestic, agricultural and industrial), and fluctuate based on the type of activities prevailing in the areas adjacent to these valleys, Table 2 . However, sample (5) shows the absence of ionic balance due to the effect of sewage, agricultural and industrial water on the valleys, Table 2 . While all samples show a precise (< 5) to acceptable (< 10) ionic balance (Baird et al., 2017 ). Ion concentrations decrease with increasing distance from the valley mouth due to the dilution effect resulting from mixing of valley water with Tigris River water, Table 2 . Table 2 The chemical and physical properties of water samples of the studied locations. Samp. Ca 2+ Mg 2+ Na + K + HCO 3− SO 4 2− Cl − NO 3 − Total Cations Total Anions Ionic balance pH EC µs cm − TDS mg L − TH mg L − Tr. NTU R1 (*) 57.3 14.8 13.1 3.2 142.1 81.2 27.8 3.5 7.7 345 307 207 2.1 (**) 2.86 1.22 0.57 0.08 2.33 1.69 0.78 0.06 4.73 4.86 1.38 R2 49.7 22.4 12.1 2.8 136.6 100 33.3 2.5 7.15 360 320 224 1.17 2.48 1.84 0.53 0.07 2.24 2.08 0.94 0.04 4.92 5.30 3.72 R3 48.1 20.6 11.2 2.5 146.4 32.5 72.8 1.4 7.65 342 300 212 1.33 2.40 1.69 0.49 0.06 2.40 0.68 2.05 0.02 4.65 5.15 5.17 R4 41.7 25.9 11 2.5 141.5 24.5 43.7 2.4 7.75 346 310 220 1.94 2.08 2.13 0.48 0.06 2.32 0.51 1.23 0.04 4.75 4.10 7.37 R5 80.3 25.9 33.1 11.8 209.8 310 66.6 1.2 7.33 520 520 310 1.02 4.01 2.13 1.44 0.30 3.44 6.45 1.88 0.02 7.88 11.79 19.89 Z1 56.2 17.5 11.5 2.8 151.2 95.5 39.5 2.4 7.79 341 300 212 4.28 2.80 1.44 0.50 0.07 2.48 1.99 1.11 0.04 4.82 5.62 7.70 Z2 43.3 19.7 12.6 2.8 146.4 18.5 35.3 3.5 7.65 344 290 196 2.72 2.16 1.62 0.55 0.07 2.40 0.39 1.00 0.06 4.40 3.84 6.84 Z3 49.7 20.6 12.8 2.5 136.6 64.5 33.3 2.2 7.32 338 300 216 1.38 2.48 1.69 0.56 0.06 2.24 1.34 0.94 0.04 4.79 4.56 2.55 Z4 48.1 22.4 12.7 2.5 131.2 127.5 33.3 2 7.66 342 290 220 1.91 2.40 1.84 0.55 0.06 2.15 2.65 0.94 0.03 4.86 5.78 8.63 Z5 69 25 34.5 9.5 195.2 20.5 58.3 8.5 7.18 530 500 284 3.02 3.44 2.06 1.50 0.24 3.20 0.43 1.64 0.14 7.24 5.41 14.50 Kh1 57.8 13.4 14.5 3.5 136.6 72.2 22.9 4.5 7.73 350 310 204 1.92 2.88 1.10 0.63 0.09 2.24 1.50 0.65 0.07 4.71 4.46 2.68 Kh2 48.1 17.9 15.5 2.6 131.7 71 18.7 6.5 7.57 473 440 200 3.93 2.40 1.47 0.67 0.07 2.16 1.48 0.53 0.10 4.61 4.27 3.87 Kh3 56.2 30.4 26.5 6 165.9 135 31.2 7.5 7.43 482 410 276 1.1 2.80 2.50 1.15 0.15 2.72 2.81 0.88 0.77 6.61 7.18 4.10 Kh4 49.7 32.2 24 5.5 175.6 72.2 29.1 16.5 7.4 468 330 268 1.64 2.48 2.65 1.04 0.14 2.88 1.50 0.82 0.27 6.31 5.47 7.17 Kh5 78.7 44.8 47.5 10.4 219.6 495 52 1 7.2 735 670 396 3.92 3.93 3.68 2.07 0.27 3.60 10.30 1.47 0.02 9.94 15.39 21.49 D1 57.8 13.4 13.5 3.4 136.6 76 20.8 8.5 7.6 353 310 204 1.89 2.88 1.10 0.59 0.09 2.24 1.58 0.59 0.14 4.66 4.54 1.25 D2 65.8 22.4 30 8.5 170.8 105 47.8 3.5 7.46 586 510 224 0.42 3.28 1.84 1.30 0.22 2.80 2.19 1.35 0.06 6.65 6.39 1.98 D3 59.4 24.19 22.5 4.4 165.9 100 35.3 14 7.43 503 450 264 1.02 2.96 1.99 0.98 0.11 2.72 2.08 1.00 0.23 6.04 6.02 0.18 D4 57.8 17.9 37.5 4.9 156.1 93 60.3 1.5 7.47 453 300 256 3.36 2.88 1.47 1.63 0.13 2.56 1.94 1.70 0.02 6.11 6.22 0.87 D5 50.2 32.7 42.3 5.5 200 137.5 104.1 16 7.35 693 660 316 3.6 2.50 2.69 1.84 0.14 3.28 2.86 2.94 0.26 7.17 9.33 13.09 Sh1 57.3 14.2 13.7 3.5 137.2 75.5 21.8 5.5 7.71 358 310 207 1.87 2.86 1.17 0.60 0.09 2.25 1.57 0.61 0.09 4.71 4.52 2.04 Sh2 128 48.5 104 7.5 280 420 135 7 7.9 925 1065 461 3.5 6.39 3.99 4.52 0.19 4.59 8.74 3.81 0.11 15.09 17.25 6.69 Sh3 99.5 46.5 100.4 6.4 244 375 122.8 1 7.1 866 850 456 1.43 4.97 3.82 4.37 0.16 4.00 7.81 3.46 0.02 13.32 15.28 6.88 Sh4 101.2 44.8 99.1 5.6 209.8 330 112.4 3 7.3 816 820 452 2.53 5.05 3.68 4.31 0.14 3.44 6.87 3.17 0.05 13.19 13.53 1.27 Sh5 199 86 200 16.1 370.8 825 314 10 8.1 1756 1820 880 5.17 9.93 7.07 8.70 0.41 6.08 17.17 8.86 0.16 26.11 32.27 10.55 E1 64.2 18.8 20 2.2 156.1 106 41.6 5 7.45 353 340 244 0.1 3.20 1.55 0.87 0.06 2.56 2.21 1.17 0.08 5.68 6.02 2.94 E2 67.4 18.8 30 2.5 156.1 107 49.9 5 7.7 398 400 252 1.3 3.36 1.55 1.30 0.06 2.56 2.23 1.41 0.08 6.28 6.27 0.03 E3 65.8 17.9 23 2.5 151.2 108 39.56 5 7.4 386 400 244 0.62 3.28 1.47 1.00 0.06 2.48 2.25 1.12 0.08 5.82 5.92 0.88 E4 59.4 21.5 20 2.3 156.1 102 37.4 5 7.6 353 360 244 2.09 2.96 1.77 0.87 0.06 2.56 2.12 1.05 0.08 5.66 5.82 1.36 E5 69 25 49 9.1 234.2 175 106.1 6 7.4 335 660 372 10.5 3.44 2.06 2.13 0.23 3.84 3.64 2.99 0.10 7.86 10.57 14.69 (*) in mg.L − ; (**) in meq The concentrations of the main ions reflect the physical properties of the water (Table 2 ), with total dissolved salts (TDS) ranging from 307 to 310 mg/L on the left bank of the Tigris River and 340 mg/L on the right bank within the research area. Total dissolved solids values ​​are higher in the valley waters, exceeding 500 mg/L, depending on the amount of water discharged and the concentration of dissolved salts in each valley. Figure 3 shows the fluctuations in the TDS content at each mouth and during the sampling path of the Tigris River, as the concentrations of TDS increase at the mouth of the valley and then decrease due to dilution with increasing distance from the mouth. This is evident in the valleys of Al-Khosar, Al-Danffilli, Al-Shor and Eqab, with little variation in the remaining valleys, which is attributed to the low volume of their water discharged into the Tigris River. The extent of pollution in the contaminated section of the river was determined at the mouths of each valley at a distance of 293 m from Eqab, 323 m from Al-Khosar, 280 m from Al-Danffalli, and 650 m from Al-Shor. The remaining physical parameters (electrical conductivity, total hardness, and turbidity) often adhere to the aforementioned context. The pH levels in the valley water samples are comparatively low due to the presence of waste materials in these waters. 4 Conclusion Chemical analyses confirmed the results of the Iber model that water from the main valleys, upon entering the Tigris River, is diluted along the river course downstream, with the degree of dilution varying based on the levels of pollution and discharge from each valley. Thus, both Al-Rashidia and Al-Kharrazi valleys showed little pollution due to their low discharge. The waters of the other valleys, such as Eqab, Al-Khosar, and Al-Danffilli, traverse approximately 300 meters, whilst the waters of Al-Shor Valley extend to 650 meters. Overall, the effluents from these valleys do not pose an issue for Tigris River regarding their dissolved salt content, owing to the low concentration of dissolved salts and discharge rates. Declarations The authors did not obtain assistance from any organisation for the submitted work. No financial support was obtained for the development of this manuscript. This study got no funding. No financial resources, grants, or other assistance were obtained. Mustafa S. Mustafa, Kotayba T. Al-Youzbakey and Basma A.M. Al-Jawadi announce the absence of financial interests. The authors possess no pertinent financial or non-financial interests to declare. The authors declare no relevant conflicts of interest pertaining to the content of this work. All authors affirm that they possess no affiliations or engagements with any organisation or institution that holds financial or non-financial interests in the subject matter or materials addressed in this publication. The writers possess no financial or proprietary interests in any materials referenced in this essay. Authors bear responsibility for the accuracy of the assertions made in the manuscript. 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Modeling, Identification and Control, 41 (4), 241–285. https://doi.org/10.4173/MIC.2020.4.1 García-Feal, O., Cea, L., González-Cao, J., Domínguez, J. M., & Gómez-Gesteira, M. (2020). IberWQ: A GPU Accelerated Tool for 2D Water Quality Modeling in Rivers and Estuaries. Water, 12 (2), 413. https://doi.org/10.3390/w12020413 Ibrahim, I. F., & Al-Youzbakey, K. T. (2024). Water Quality Evaluation of the Main Valleys for Agricultural Uses on the Left Side of Mosul City. Iraqi National Journal of Earth Science, 24 (1), 62–89. iya Sowjanya, V. (2015). Assessment of Coastal Water Quality through Weighted Arithmetic Water Quality Index around Visakhapatnam, Bay of Bengal, India. International Journal of Innovative Research in Science, Engineering and Technology, 4 (12), 11775–11781. https://doi.org/10.15680/ijirset.2015.0412016 Jazza, S. H., Najim, S. S., & Adnan, M. A. (2022). Using Heavy Metals Pollution Index (HPI) for assessment quality of drinking water in Maysan Province in Southern East in Iraq. Egyptian Journal of Chemistry, 65 (2), 703–709. https://doi.org/10.21608/EJCHEM.2021.89658.4295 K. E, L., J. O, N., & A.W, V. (2017). EVALUATION OF WATER QUALITY INDEX OF THE BRASS RIVER, BAYELSA STATE, SOUTH-SOUTH, NIGERIA. International Journal of Research -GRANTHAALAYAH, 5 (8), 277–287. https://doi.org/10.29121/granthaalayah.v5.i8.2017.2233 Karnataka, I., Simpi, B., Hiremath, S. M., Murthy, K., Chandrashekarappa, K. N., Patel, A. N., & Puttiah, E. T. (2011). USA) Analysis of Water Quality Using Physico-Chemical Parameters Hosahalli Tank in Shimoga District. Type: Double Blind Peer Reviewed International Research Journal Publisher: Global Journals Inc , 11 . Kelantan, S., Baseline Study Kualiti Air dan Kepekatan Logam Berat di dalam Sedimen Sungai Kelantan, A., Nilai Dasar AHMAD, K. A., Mushrifah, I., & Shuhaimi-othman, M. (2009). Water Quality and Heavy Metal Concentrations in Sediment of. Em Sains Malaysiana (Vol. 38, Número 4). Mesquita, J. B. de F., & Lima Neto, I. E. (2022). Coupling Hydrological and Hydrodynamic Models for Assessing the Impact of Water Pollution on Lake Evaporation. Sustainability (Switzerland), 14 (20). https://doi.org/10.3390/su142013465 Mustafa, M. H. (2009). Tigris River Grey Water, Sources, Impacts and Suggested Water Treatment Plants. First Scientific and Environmental Conference , 1–13. Mustafa, M. H., & Al-Youzbakey, K. T. (2021). Sustainability of Al-Khosar River Water - Ninavah Governorate / Iraq. International Journal of Environment & Water, 10 (2), 48–61. S.A. Abbawi, & M. S. Hassan. (1990). Practical Ecological Engineering, Water examination . Sousa, M. C., deCastro, M., Gago, J., Ribeiro, A. S., Des, M., Gómez-Gesteira, J. L., Dias, J. M., & Gomez-Gesteira, M. (2021). Modelling the distribution of microplastics released by wastewater treatment plants in Ria de Vigo (NW Iberian Peninsula). Marine Pollution Bulletin, 166 , 112227. https://doi.org/10.1016/j.marpolbul.2021.112227 Tran, N. C., Nguyen, T. H., Nguyen, T. M. T., Doan, T. N., Nguyen, T. B. P., & Dao, T. V. H. (2024). Simulation of Water Quality in Bung Binh Thien Lake, An Giang Province, Vietnam, Using the Delft3D Model. International Journal of Geoinformatics, 20 (8), 56–71. https://doi.org/10.52939/ijg.v20i8.3455 Wang, L., Stuart, M. E., Lewis, M. A., Ward, R. S., Skirvin, D., Naden, P. S., Collins, A. L., & Ascott, M. J. (2016). The changing trend in nitrate concentrations in major aquifers due to historical nitrate loading from agricultural land across England and Wales from 1925 to 2150. Science of The Total Environment, 542 , 694–705. https://doi.org/10.1016/j.scitotenv.2015.10.127 Westaway, R., Guillou, H., Seyrek, A., Demir, T., Bridgland, D., Scaillet, S., & Beck, A. (2009). Late Cenozoic surface uplift, basaltic volcanism, and incision by the River Tigris around Diyarbakır, SE Turkey. International Journal of Earth Sciences, 98 (3), 601–625. https://doi.org/10.1007/s00531-007-0266-z World Health Organization. (2022). Guidelines for drinking-water quality: incorporating the first and second addenda (4th Edition). Xue, J., Wang, Q., & Zhang, M. (2022). A review of non-point source water pollution modeling for the urban–rural transitional areas of China: Research status and prospect. Science of The Total Environment, 826 , 154146. https://doi.org/10.1016/j.scitotenv.2022.154146 Additional Declarations No competing interests reported. Cite Share Download PDF Status: Posted Version 1 posted You are reading this latest preprint version Research Square lets you share your work early, gain feedback from the community, and start making changes to your manuscript prior to peer review in a journal. As a division of Research Square Company, we’re committed to making research communication faster, fairer, and more useful. We do this by developing innovative software and high quality services for the global research community. Our growing team is made up of researchers and industry professionals working together to solve the most critical problems facing scientific publishing. Also discoverable on Platform About Our Team In Review Editorial Policies Advisory Board Help Center Resources Author Services Accessibility API Access RSS feed Manage Cookie Preferences © Research Square 2026 | ISSN 2693-5015 (online) Privacy Policy Terms of Service Do Not Sell My Personal Information {"props":{"pageProps":{"initialData":{"identity":"rs-6589312","acceptedTermsAndConditions":true,"allowDirectSubmit":true,"archivedVersions":[],"articleType":"Research Article","associatedPublications":[],"authors":[{"id":451871907,"identity":"e5a28e7d-a309-4a4c-9f63-4da20c690a21","order_by":0,"name":"Mustafa S. Mustafa","email":"data:image/png;base64,iVBORw0KGgoAAAANSUhEUgAAAZAAAAAyAQMAAABI0h/eAAAABlBMVEX///8AAABVwtN+AAAACXBIWXMAAA7EAAAOxAGVKw4bAAAA20lEQVRIiWNgGAWjYLCCCgYbKKsAiA+AEQFwhiENyjIgXsthVC14gW7/6cQPB/ecT+wXO3z4M48BgxzfjQTGA2/waDG7kbtZ4sCz24kzZ6elSQO1GEveSGA4OAevFt4N0h8O3E7ccDvHjBmoJXEDUMthHnxazp/d/OPAgXMgLcYgh9UT1nIgd5vEgQMHQFoMQA5LMCCo5UbuNosDB5KNQX6RnGMgYTjzzMMG/H4BOuzGgQN2sv3SyYc/vKmwkec7DmLg0YIOJICYsYEBn8NwADK0jIJRMApGwfAFAH0zWV0jyOMjAAAAAElFTkSuQmCC","orcid":"","institution":"University of Mosul","correspondingAuthor":true,"prefix":"","firstName":"Mustafa","middleName":"S.","lastName":"Mustafa","suffix":""},{"id":451871908,"identity":"8723f5c8-20a8-481b-b3da-da3724f4d13a","order_by":1,"name":"Kotayba T. Al-Youzbakey","email":"","orcid":"","institution":"University of Mosul","correspondingAuthor":false,"prefix":"","firstName":"Kotayba","middleName":"T.","lastName":"Al-Youzbakey","suffix":""},{"id":451871911,"identity":"c8711688-e6f9-4b6b-933c-4e74ab27de36","order_by":2,"name":"Basma A.M. Al-Jawadi","email":"","orcid":"","institution":"University of Mosul","correspondingAuthor":false,"prefix":"","firstName":"Basma","middleName":"A.M.","lastName":"Al-Jawadi","suffix":""}],"badges":[],"createdAt":"2025-05-04 16:08:15","currentVersionCode":1,"declarations":"","doi":"10.21203/rs.3.rs-6589312/v1","doiUrl":"https://doi.org/10.21203/rs.3.rs-6589312/v1","draftVersion":[],"editorialEvents":[],"editorialNote":"","failedWorkflow":false,"files":[{"id":82043929,"identity":"58609535-b8f3-414f-a219-879e95abb76f","added_by":"auto","created_at":"2025-05-06 09:27:40","extension":"jpeg","order_by":1,"title":"Figure 1","display":"","copyAsset":false,"role":"figure","size":1047723,"visible":true,"origin":"","legend":"\u003cp\u003eThe studied valleys in Mosul City.\u003c/p\u003e","description":"","filename":"floatimage1.jpeg","url":"https://assets-eu.researchsquare.com/files/rs-6589312/v1/3065a79c95739debdb172086.jpeg"},{"id":82045473,"identity":"19ffe180-ca07-4a19-808b-2732625e6202","added_by":"auto","created_at":"2025-05-06 09:35:40","extension":"jpeg","order_by":2,"title":"Figure 2","display":"","copyAsset":false,"role":"figure","size":2017543,"visible":true,"origin":"","legend":"\u003cp\u003eThe polluted Tigris River reach for each valley: (a) Eqab, (b) Al-Khosar, (c) Al-Danffilli, (d) Al-Shor.\u003c/p\u003e","description":"","filename":"floatimage2.jpeg","url":"https://assets-eu.researchsquare.com/files/rs-6589312/v1/e8fd82f86f0573e80dae3ec2.jpeg"},{"id":82043930,"identity":"c03d5548-3c63-48be-97b1-0f2ef39954cf","added_by":"auto","created_at":"2025-05-06 09:27:40","extension":"jpeg","order_by":3,"title":"Figure 3","display":"","copyAsset":false,"role":"figure","size":514821,"visible":true,"origin":"","legend":"\u003cp\u003eThe TDS variation along Tigris River for each valley in the studied locations.\u003c/p\u003e","description":"","filename":"floatimage3.jpeg","url":"https://assets-eu.researchsquare.com/files/rs-6589312/v1/0d0d5876b31228b2ddaa0d53.jpeg"},{"id":83248527,"identity":"64e9d405-b1d1-465a-855f-b0327b92d4d7","added_by":"auto","created_at":"2025-05-21 18:23:32","extension":"pdf","order_by":0,"title":"","display":"","copyAsset":false,"role":"manuscript-pdf","size":4700683,"visible":true,"origin":"","legend":"","description":"","filename":"manuscript.pdf","url":"https://assets-eu.researchsquare.com/files/rs-6589312/v1/fd724529-16c2-4d05-9938-444db432581b.pdf"}],"financialInterests":"No competing interests reported.","formattedTitle":"Using (Iber) Hydrodynamic Model to Simulate the Flow of Polluted Water of Tigris River in Mosul City, Northern Iraq","fulltext":[{"header":"1 Introduction","content":"\u003cp\u003eRiver water is an essential source of life and a fundamental component of the ecosystem; yet, diverse human activities and the growing population in urban and rural areas close to rivers result in changes to water quality (Jazza et al., \u003cspan citationid=\"CR16\" class=\"CitationRef\"\u003e2022\u003c/span\u003e; K. E et al., 2017; Karnataka et al., \u003cspan citationid=\"CR18\" class=\"CitationRef\"\u003e2011\u003c/span\u003e). The sediment and rock composition of the river basin, the impacts of erosion on rocks and soils, and the influence of diverse human activities are the principal factors affecting the water quality requirements of rivers (Al-Youzbakey \u0026amp; Sulaiman, \u003cspan citationid=\"CR6\" class=\"CitationRef\"\u003e2021\u003c/span\u003e; K. E et al., 2017; Kelantan et al., \u003cspan citationid=\"CR19\" class=\"CitationRef\"\u003e2009\u003c/span\u003e).\u003c/p\u003e \u003cp\u003eThe pollution level of a river is determined by the inflow of freshwater and pollutants, governed by the prevailing water standards. If pollutants exceed permissible limits, the characteristics of the river change from fresh to polluted (Al-Dabbas et al., \u003cspan citationid=\"CR3\" class=\"CitationRef\"\u003e2018\u003c/span\u003e; iya Sowjanya, \u003cspan citationid=\"CR15\" class=\"CitationRef\"\u003e2015\u003c/span\u003e; Wang et al., \u003cspan citationid=\"CR26\" class=\"CitationRef\"\u003e2016\u003c/span\u003e).\u003c/p\u003e \u003cp\u003eThe oversight and preservation of water quality are crucial for environmental and health concerns. Aquatic plants and animals flourish in ideal aquatic habitats, and both humans and wildlife rely on clean and drinkable water for sustenance (World Health Organization, \u003cspan citationid=\"CR28\" class=\"CitationRef\"\u003e2022\u003c/span\u003e). Presently, waterborne infections cause millions of patients and deaths each year. Therefore, field tests must be combined with other disciplines to determine the extent of the pollution (Anas et al., \u003cspan citationid=\"CR7\" class=\"CitationRef\"\u003e2021\u003c/span\u003e). The amalgamation of quantitative field experiments with simulation research may augment our understanding of core principles and promote the formulation of innovative solutions for environmental management and protection (Fritzson et al., \u003cspan citationid=\"CR12\" class=\"CitationRef\"\u003e2020\u003c/span\u003e). The data volume necessary for simulation can be decreased through the utilization of an advanced modelling tool. Furthermore, simulation models can accurately forecast the necessary outputs in situations where field assessments are unfeasible. Therefore, hydraulic models employ the essential concepts of hydraulics to calculate water levels, flow velocities, and flow depths in rivers under actual or hypothetical conditions. The models are categorized into two types: hydrodynamic models and hydrological models. Hydrodynamic models are based on the whole hydraulic design process, incorporating all essential hydraulic concepts. In contrast, hydrological models depend on the software's algorithms to predict water flow under very simple settings (Sousa et al., \u003cspan citationid=\"CR24\" class=\"CitationRef\"\u003e2021\u003c/span\u003e).\u003c/p\u003e \u003cp\u003eHydrodynamic modelling in water pollution research is recognized as a crucial tool for understanding the physical processes and intricacies of flow hydraulics related to mixing processes. This tool relates to diverse scales of water fluctuations at low to moderate levels, precisely representing the characteristics of velocity fields observed in laboratory flumes, channels, tidal inlets, confluences, bend escapes, reservoirs, and macro-scale catchment areas with river utilization (Xue et al., \u003cspan citationid=\"CR29\" class=\"CitationRef\"\u003e2022\u003c/span\u003e).\u003c/p\u003e \u003cp\u003eOne of the hydrodynamic models Iber which is a two-dimensional model designed to simulate water flow in free surfaces, rivers, estuaries, bays, and reservoirs which it developed by a collaborative team of engineers and scientists from various institutes and universities (De Goede, \u003cspan citationid=\"CR11\" class=\"CitationRef\"\u003e2020\u003c/span\u003e). The Iber model incorporates seasonal variations in water flow and pollutant concentrations. Various studies have utilised it to simulate water flow and pollutant transport across different seasons in multiple rivers and water bodies (Mesquita \u0026amp; Lima Neto, \u003cspan citationid=\"CR20\" class=\"CitationRef\"\u003e2022\u003c/span\u003e).\u003c/p\u003e \u003cdiv id=\"Sec2\" class=\"Section2\"\u003e \u003ch2\u003e1.1 Related works\u003c/h2\u003e \u003cp\u003eResearch (Mustafa, \u003cspan citationid=\"CR21\" class=\"CitationRef\"\u003e2009\u003c/span\u003e), corroborated by (Mustafa \u0026amp; Al-Youzbakey, \u003cspan citationid=\"CR6\" class=\"CitationRef\"\u003e2021\u003c/span\u003e), identifies Tigris River in Mosul City as a location for the disposal of domestic, agricultural, and industrial waste, which is transported via the Eqab, Al-Rashidia, Al-Kharrazi, Al-Khosar, Al-Shor, and Al-Danffilli Valleys. All waste is conveyed through these valleys to Tigris River due to the absence of a sewage network connected to wastewater treatment facilities.\u003c/p\u003e \u003cp\u003eA study indicated that the drinking water quality index (WQI) of Tigris River was excellent in northern Mosul City, transitioning to good in the southern region as the river exited the city. This is due to the adverse impacts of human activity on the river (Al-Assaf \u0026amp; Al-Saffawi, \u003cspan citationid=\"CR1\" class=\"CitationRef\"\u003e2018\u003c/span\u003e).\u003c/p\u003e \u003cp\u003eIn (Ibrahim \u0026amp; Al-Youzbakey, \u003cspan citationid=\"CR14\" class=\"CitationRef\"\u003e2024\u003c/span\u003e), the waters of the valleys discharging into Tigris River were classified according to TDS values. The waters of Al-Rashedia and Al-Kharrazi Valleys exhibit medium salinity, whereas the waters of Al-Khosar, Al-Danffilli, and Al-Shor Valleys are classified as having high salinity, attributed to the impact of domestic, industrial, and agricultural waste on these areas.\u003c/p\u003e \u003cp\u003eIn (Garc\u0026iacute;a-Feal et al., \u003cspan citationid=\"CR13\" class=\"CitationRef\"\u003e2020\u003c/span\u003e), the researchers employed the Iber hydrodynamic model to assess water quality in rivers and estuaries in Spain. The study examines three types of pollutants present in rivers: faecal contamination in coastal estuaries, combined sewer overflow in the Minno River, and organic matter contamination in estuaries. The study produces detailed maps illustrating the distribution and concentrations of polluted metals in river and estuary regions.\u003c/p\u003e \u003cp\u003eThe Delft 3D model was employed by (Tran et al., \u003cspan citationid=\"CR25\" class=\"CitationRef\"\u003e2024\u003c/span\u003e) to simulate the water quality of Binh Thien Lake in Vietnam. The authors modeled the distribution of dissolved oxygen (DO) and biochemical oxygen demand (BOD) across the entire lake area for October 2022 and May 2023. Simulation results generated maps for dissolved oxygen (DO) and biochemical oxygen demand (BOD), illustrating the impact of incoming flow on DO and BOD levels in the lake.\u003c/p\u003e \u003c/div\u003e \u003cdiv id=\"Sec3\" class=\"Section2\"\u003e \u003ch2\u003e1.2 The study area\u003c/h2\u003e \u003cp\u003eMosul City is located in northern Iraq between longitudes 43\u0026deg;16\u0026Prime; \u0026minus;\u0026thinsp;43\u0026deg;30\u0026Prime; east and latitudes 36\u0026deg;15\u0026Prime; \u0026minus;\u0026thinsp;36\u0026deg;27\u0026Prime; north. It is a prominent and densely populated city in Iraq compared to other urban areas. The Tigris River divides the city into two separate parts. Both areas are characterized by high population density, agricultural and animal husbandry activities, and the presence of an industrial sector. Mosul has a semi-arid climate, with an average annual rainfall of 375 mm (Al-Jawadi, \u003cspan citationid=\"CR4\" class=\"CitationRef\"\u003e2022\u003c/span\u003e; Awchi \u0026amp; Jasim, \u003cspan citationid=\"CR8\" class=\"CitationRef\"\u003e2017\u003c/span\u003e).\u003c/p\u003e \u003cp\u003eTigris River flows through diverse geological formations, including igneous, metamorphic, and carbonate rocks, in southern Turkey before crossing into Iraq (Westaway et al., \u003cspan citationid=\"CR27\" class=\"CitationRef\"\u003e2009\u003c/span\u003e). Upon entering Iraqi territory, Tigris River flows through diverse rock types linked to several geological formations. The Muqdadiya Formation is characterized by sandstones and conglomerates; the Injana Formation comprises sequences of sandstone, siltstone, and mudstone; the Fatha Formation consists of marl, limestone, and gypsum; and the Euphrates Formation is primarily limestone (Al-Dabbagh \u0026amp; Al-Naqib, \u003cspan citationid=\"CR2\" class=\"CitationRef\"\u003e1991\u003c/span\u003e). Quaternary deposits are prevalent in the river basin leading to Mosul, characterized by floodplain sediments, river terraces, and sediments carried by tributary valleys (Buday, \u003cspan citationid=\"CR10\" class=\"CitationRef\"\u003e1980\u003c/span\u003e).\u003c/p\u003e \u003c/div\u003e \u003cdiv id=\"Sec4\" class=\"Section2\"\u003e \u003ch2\u003e1.3 The studied valleys\u003c/h2\u003e \u003cp\u003eValleys in Mosul City are crucial for the drainage of rainwater and sewage into Tigris River. These valleys, as natural channels, have been subjected to numerous pollution factors due to the accumulation of solid waste and neglect, in addition to functioning as natural sewage drainage streams. This situation has resulted in the presence of various types of civil, industrial, and agricultural waste, which in turn promotes the growth of bushland and numerous plant species, including reeds. This article discusses six main valleys in the city. Figure\u0026nbsp;\u003cspan refid=\"Fig1\" class=\"InternalRef\"\u003e1\u003c/span\u003e illustrates the mouth locations of these valleys on Tigris River.\u003c/p\u003e \u003cp\u003e \u003col\u003e \u003cspan\u003e \u003cli\u003e \u003cp\u003eAl-Rashidia Valley originates near Talkef and traverses various residential and agricultural areas in Mosul City, including Kossites, Malaien, and Rashidia, before flowing into Tigris River.\u003c/p\u003e \u003c/li\u003e \u003c/span\u003e \u003cspan\u003e \u003cli\u003e \u003cp\u003eAl-Kharrazi Valley is located in the northeastern Mosul City region, has two tributaries, one from Sadah and Baweza and the other from the northern Al-Kindi establishment. Its two branches converge in the Andalusia Quarter and discharge into the Tigris River, but the valley is prone to pollution from sewage contaminants and household solid waste\u003c/p\u003e \u003c/li\u003e \u003c/span\u003e \u003cspan\u003e \u003cli\u003e \u003cp\u003eAl-Khosar Valley located in northern Iraq's Ba'azrah region, is the largest and most expansive valley of Tigris River in Mosul City. The influence of human activities, including domestic, industrial, and agricultural uses, increases the sources of pollutants that adversely effect on water quality of this valley during dry periods, especially the lacking of waste management, sewage networks, and treatment facilities.\u003c/p\u003e \u003c/li\u003e \u003c/span\u003e \u003cspan\u003e \u003cli\u003e \u003cp\u003eAl-Danffilli Valley originates at the residential complex in the Green Quarter and the Industrial Zone to the east of Mosul City, situated along Tigris River. The valley is regarded as one of the most polluted due to nearby industrial operations and population activities in the surrounding areas.\u003c/p\u003e \u003c/li\u003e \u003c/span\u003e \u003cspan\u003e \u003cli\u003e \u003cp\u003eAl-Shor Valley basin is situated to the east of Mosul City, between the Ba'shiqa and Ein Al-Safra Mountains. It is discharged into Tigris River from the left bank. The Industrial Zone is characterized by significant pollution sources stemming from local industrial activities and sewage discharge from neighboring areas adjacent to the valley.\u003c/p\u003e \u003c/li\u003e \u003c/span\u003e \u003cspan\u003e \u003cli\u003e \u003cp\u003eEqab Valley is a significant valley located on the right side of Mosul City, extending from the Al-Nahruan Quarter through the industrial zone to the Al-Rabee Quarter, ultimately flowing into Tigris River. This valley is subject to significant pollution due to industrial activities, sanitation practices in residential areas, and drainage systems from adjacent agricultural zones.\u003c/p\u003e \u003c/li\u003e \u003c/span\u003e \u003c/ol\u003e \u003c/p\u003e \u003cp\u003e \u003c/p\u003e \u003c/div\u003e \u003cdiv id=\"Sec5\" class=\"Section2\"\u003e \u003ch2\u003e1.4 Aim of the study\u003c/h2\u003e \u003cp\u003eThe study aims to evaluate the effectiveness of the Iber hydrodynamic model in predicting the flow of polluted water from valleys to Tigris River in Mosul City, by accurately determining the complex dynamics of the Tigris River in order to provide reliable predictions.\u003c/p\u003e \u003c/div\u003e"},{"header":"2 Methodology","content":"\u003cdiv id=\"Sec7\" class=\"Section2\"\u003e \u003ch2\u003e2.1 Field sampling\u003c/h2\u003e \u003cp\u003eDuplicate four samples were collected from specific locations on the Tigris River that represent the mouths of the valleys, as follows: Sample (1) from upstream the confluence region each valley, Sample (2) at the confluence, Sample (3) at 100 meters downstream the confluence region and Sample (4) at 200 meters from the confluence, in addition to collecting duplicate samples from each valley before it drains into the river, which represents Sample (5).\u003c/p\u003e \u003cp\u003ePhysical testing was conducted utilizing a field device, with total dissolved solids (TDS) and electrical conductivity (E.C), measurements performed using a portable conductivity meter (Boqu Dds-1702, Shanghai Boqu Instrument Co., Ltd.). The pH was assessed using a portable instrument (Handheld pH ORP Meter, Shanghai Boqu Instrument Co., Ltd.), while turbidity was evaluated using a Turbidity Meter (Hanna HI 93703).\u003c/p\u003e \u003cp\u003eChemical analyses of duplicate water samples were performed in the Geochemistry Laboratory at the Dams and Water Resources Research Center \u0026ndash; University of Mosul, following standard routine methodologies (S.A. Abbawi \u0026amp; M. S. Hassan, 1990). Sodium and potassium were quantified using the flame spectrometer method (Flame-photometer, type JENWAY PEP7). Total hardness (TH), calcium, and magnesium were assessed via the trituration method with EDTA, while bicarbonate and carbonate were determined through trituration with sulfuric acid, and chlorine was measured using trituration with silver nitrate. Sulfates and nitrates were quantified using colorimetric techniques with a UV-spectrophotometer (UV-Spectrophotometer model - OGAWA, OSK 7724).\u003c/p\u003e \u003c/div\u003e \u003cdiv id=\"Sec8\" class=\"Section2\"\u003e \u003ch2\u003e2.2 Hydrodynamic Modelling:\u003c/h2\u003e \u003cdiv id=\"Sec9\" class=\"Section3\"\u003e \u003ch2\u003e2.2.1 Model Validation\u003c/h2\u003e \u003cp\u003eThe Iber model calibration procedure involved five phases: sensitivity analysis to identify critical model factors affecting water levels, calibration of water level parameters through iterative testing over a specific period, calibration of discharge parameters, and calibration of lateral discharge to address performance difficulties in certain river segments. The final stage evaluated the model outcomes and comparing them with actual observation, ensuring a robust dependability assessment. The Iber model was calibrated and validated for Mosul City by (Al-Taiee \u0026amp; Mustafa, \u003cspan citationid=\"CR5\" class=\"CitationRef\"\u003e2020\u003c/span\u003e), demonstrating its applicability in this environment.\u003c/p\u003e \u003c/div\u003e \u003cdiv id=\"Sec10\" class=\"Section3\"\u003e \u003ch2\u003e2.2.2 Initial and boundary conditions:\u003c/h2\u003e \u003cp\u003eThe initial and boundary conditions serve as fundamental inputs for any hydrodynamic model, upon which the simulation process for the subject under analysis is conducted. The initial conditions denote the water distribution in the research area prior to the commencement of the simulation, whereas the boundary conditions indicate the volume of water that entered the simulated river.\u003c/p\u003e \u003cp\u003eThe case study includes two categories of boundary conditions: the first is related to the Tigris River, and the second is related to the polluted water sources that flow into the river as shown in Table\u0026nbsp;\u003cspan refid=\"Tab1\" class=\"InternalRef\"\u003e1\u003c/span\u003e. The initial condition of the Tigris River which represents the constant discharge of water into the river in sampling day which is equal to 350 m\u0026sup3;/s with average total dissolved solids (TDS) Table\u0026nbsp;\u003cspan refid=\"Tab1\" class=\"InternalRef\"\u003e1\u003c/span\u003e.\u003c/p\u003e \u003cp\u003e \u003cdiv class=\"gridtable\"\u003e\u003ctable float=\"Yes\" id=\"Tab1\" border=\"1\"\u003e \u003ccaption language=\"En\"\u003e \u003cdiv class=\"CaptionNumber\"\u003eTable 1\u003c/div\u003e \u003cdiv class=\"CaptionContent\"\u003e \u003cp\u003eThe boundary contaminant conditions for Tigris River and the polluted sources.\u003c/p\u003e \u003c/div\u003e \u003c/caption\u003e \u003ccolgroup cols=\"7\"\u003e \u003cdiv align=\"left\" class=\"colspec\" colname=\"c1\" colnum=\"1\"\u003e\u003c/div\u003e \u003cdiv align=\"left\" class=\"colspec\" colname=\"c2\" colnum=\"2\"\u003e\u003c/div\u003e \u003cdiv align=\"left\" class=\"colspec\" colname=\"c3\" colnum=\"3\"\u003e\u003c/div\u003e \u003cdiv align=\"left\" class=\"colspec\" colname=\"c4\" colnum=\"4\"\u003e\u003c/div\u003e \u003cdiv align=\"left\" class=\"colspec\" colname=\"c5\" colnum=\"5\"\u003e\u003c/div\u003e \u003cdiv align=\"left\" class=\"colspec\" colname=\"c6\" colnum=\"6\"\u003e\u003c/div\u003e \u003cdiv align=\"left\" class=\"colspec\" colname=\"c7\" colnum=\"7\"\u003e\u003c/div\u003e \u003cthead\u003e \u003ctr\u003e \u003cth align=\"left\" colname=\"c1\"\u003e\u0026nbsp;\u003c/th\u003e \u003cth align=\"left\" colname=\"c2\"\u003e\u0026nbsp;\u003c/th\u003e \u003cth align=\"left\" colspan=\"2\" nameend=\"c4\" namest=\"c3\"\u003e \u003cp\u003eTigris River\u003c/p\u003e \u003c/th\u003e \u003cth align=\"left\" colspan=\"3\" nameend=\"c7\" namest=\"c5\"\u003e \u003cp\u003ePolluted sources\u003c/p\u003e \u003c/th\u003e \u003c/tr\u003e \u003c/thead\u003e \u003ctbody\u003e \u003ctr\u003e \u003ctd align=\"left\" colname=\"c1\"\u003e \u003cp\u003eValley name\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c2\"\u003e \u003cp\u003eValley symbol\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c3\"\u003e \u003cp\u003eTDS (mg/l) upstream valley mouth\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colspan=\"2\" nameend=\"c5\" namest=\"c4\"\u003e \u003cp\u003eDischarge \u003c/p\u003e \u003cp\u003e(m\u003csup\u003e3\u003c/sup\u003e/sec)\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c6\"\u003e \u003cp\u003eTDS \u003c/p\u003e \u003cp\u003e(mg/l)\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c7\"\u003e \u003cp\u003eDischarge \u003c/p\u003e \u003cp\u003e(m\u003csup\u003e3\u003c/sup\u003e/sec)\u003c/p\u003e \u003c/td\u003e \u003c/tr\u003e \u003ctr\u003e \u003ctd align=\"left\" colname=\"c1\"\u003e \u003cp\u003eAl-Rashidia\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c2\"\u003e \u003cp\u003eR\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c3\"\u003e \u003cp\u003e307\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colspan=\"2\" morerows=\"5\" nameend=\"c5\" namest=\"c4\" rowspan=\"6\"\u003e \u003cp\u003e350\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c6\"\u003e \u003cp\u003e520\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c7\"\u003e \u003cp\u003e0.045\u003c/p\u003e \u003c/td\u003e \u003c/tr\u003e \u003ctr\u003e \u003ctd align=\"left\" colname=\"c1\"\u003e \u003cp\u003eAl-Kharrazi\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c2\"\u003e \u003cp\u003eZ\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c3\"\u003e \u003cp\u003e300\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c6\"\u003e \u003cp\u003e500\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c7\"\u003e \u003cp\u003e0.18\u003c/p\u003e \u003c/td\u003e \u003c/tr\u003e \u003ctr\u003e \u003ctd align=\"left\" colname=\"c1\"\u003e \u003cp\u003eAl-Khoser\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c2\"\u003e \u003cp\u003eKh\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c3\"\u003e \u003cp\u003e310\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c6\"\u003e \u003cp\u003e670\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c7\"\u003e \u003cp\u003e3\u003c/p\u003e \u003c/td\u003e \u003c/tr\u003e \u003ctr\u003e \u003ctd align=\"left\" colname=\"c1\"\u003e \u003cp\u003eAl-Danffili\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c2\"\u003e \u003cp\u003eD\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c3\"\u003e \u003cp\u003e310\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c6\"\u003e \u003cp\u003e660\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c7\"\u003e \u003cp\u003e4.8\u003c/p\u003e \u003c/td\u003e \u003c/tr\u003e \u003ctr\u003e \u003ctd align=\"left\" colname=\"c1\"\u003e \u003cp\u003eAl-Shor\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c2\"\u003e \u003cp\u003eSh\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c3\"\u003e \u003cp\u003e310\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c6\"\u003e \u003cp\u003e1820\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c7\"\u003e \u003cp\u003e0.535\u003c/p\u003e \u003c/td\u003e \u003c/tr\u003e \u003ctr\u003e \u003ctd align=\"left\" colname=\"c1\"\u003e \u003cp\u003eEqab\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c2\"\u003e \u003cp\u003eE\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c3\"\u003e \u003cp\u003e340\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c6\"\u003e \u003cp\u003e660\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c7\"\u003e \u003cp\u003e0.612\u003c/p\u003e \u003c/td\u003e \u003c/tr\u003e \u003ctr\u003e \u003ctd align=\"left\" colspan=\"2\" nameend=\"c2\" namest=\"c1\"\u003e \u003cp\u003e\u003cb\u003eAverage\u003c/b\u003e\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c3\"\u003e \u003cp\u003e\u003cb\u003e312\u003c/b\u003e\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colspan=\"2\" nameend=\"c5\" namest=\"c4\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c6\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c7\"\u003e\u0026nbsp;\u003c/td\u003e \u003c/tr\u003e \u003c/tbody\u003e \u003c/colgroup\u003e \u003c/table\u003e\u003c/div\u003e \u003c/p\u003e \u003c/div\u003e \u003c/div\u003e"},{"header":"3 Results and Discussion","content":"\u003cp\u003eThe article's results are categorized into two parts: the first pertains to hydrodynamic modeling outcomes, while the second encompasses laboratory and field data.\u003c/p\u003e \u003cdiv id=\"Sec12\" class=\"Section2\"\u003e \u003ch2\u003e3.1 Hydrodynamic results\u003c/h2\u003e \u003cp\u003ePrecise modeling and simulation of pollutants in Tigris River were conducted following the provision of all necessary input data to the model. This simulation estimated maps delineating the regions impacted by pollution sources in Tigris River and the concentrations of these pollutants in the pertinent portions. The findings indicate that the pollution sources near Al-Rashidia and Al-Kharrazi Valleys along the Tigris River exerted a negligible impact on the river, attributable to their low discharge, which resulted in the dilution of these pollutants with significant volumes of fresh Tigris River water.\u003c/p\u003e \u003cp\u003eFigure (2) shows the impact of the other four valleys on the river, which has a greater polluting effect than Al-Rashidia and Al-Kharrazi valleys. Figure\u0026nbsp;\u003cspan refid=\"Fig2\" class=\"InternalRef\"\u003e2\u003c/span\u003e (a) shows the impact of pollution from Eqab on the river, which is mainly limited to the river bank due to its low discharge. Figure\u0026nbsp;\u003cspan refid=\"Fig2\" class=\"InternalRef\"\u003e2\u003c/span\u003e (b, c \u0026amp; d) shows the impact of pollution sources from the Al-Khosar, Al-Danffilli and Al-Shor Valleys on the area in front of these estuaries, which is greater than Eqab due to the high discharge rates and total dissolved solids from the sources of these valleys, as shown in Table\u0026nbsp;\u003cspan refid=\"Tab1\" class=\"InternalRef\"\u003e1\u003c/span\u003e.\u003c/p\u003e \u003cp\u003eFigure \u003cspan refid=\"Fig2\" class=\"InternalRef\"\u003e2\u003c/span\u003e indicates that the extent of pollution in the affected areas of the valley varies from one to another, due to differences in water discharge and total dissolved solids (TDS) concentration of each valley.\u003c/p\u003e \u003c/div\u003e \u003cdiv id=\"Sec13\" class=\"Section2\"\u003e \u003ch2\u003e3.2 Laboratory Results\u003c/h2\u003e \u003cp\u003eSample (1) illustrates the chemical characteristics of Tigris River waters across all locations, revealing a significant resemblance in the concentrations of the main ions at sites along the left bank of Tigris River. Concentrations of all ions, except potassium and nitrate, are unusually high near the mouth of Eqab Valley on the right bank of the river, likely due to river sediment extraction activities in that area, Table\u0026nbsp;\u003cspan refid=\"Tab2\" class=\"InternalRef\"\u003e2\u003c/span\u003e. Samples (2) show variations in the concentrations of ions due to the mixing of the valley polluted water with Tigris River water. This variance depends on the discharge of water dumped into the river and the ion concentrations in waters for each valley.\u003c/p\u003e \u003cp\u003eThe concentrations of ions in the waters of all valleys represented by sample (5) exceed those in the Tigris River. The high concentrations are attributed to water discharges from these valleys, which are a by-product of human activities (domestic, agricultural and industrial), and fluctuate based on the type of activities prevailing in the areas adjacent to these valleys, Table\u0026nbsp;\u003cspan refid=\"Tab2\" class=\"InternalRef\"\u003e2\u003c/span\u003e. However, sample (5) shows the absence of ionic balance due to the effect of sewage, agricultural and industrial water on the valleys, Table\u0026nbsp;\u003cspan refid=\"Tab2\" class=\"InternalRef\"\u003e2\u003c/span\u003e. While all samples show a precise (\u0026lt;\u0026thinsp;5) to acceptable (\u0026lt;\u0026thinsp;10) ionic balance (Baird et al., \u003cspan citationid=\"CR9\" class=\"CitationRef\"\u003e2017\u003c/span\u003e). Ion concentrations decrease with increasing distance from the valley mouth due to the dilution effect resulting from mixing of valley water with Tigris River water, Table\u0026nbsp;\u003cspan refid=\"Tab2\" class=\"InternalRef\"\u003e2\u003c/span\u003e.\u003c/p\u003e \u003cp\u003e \u003cdiv class=\"gridtable\"\u003e\u003ctable float=\"Yes\" id=\"Tab2\" border=\"1\"\u003e \u003ccaption language=\"En\"\u003e \u003cdiv class=\"CaptionNumber\"\u003eTable 2\u003c/div\u003e \u003cdiv class=\"CaptionContent\"\u003e \u003cp\u003eThe chemical and physical properties of water samples of the studied locations.\u003c/p\u003e \u003c/div\u003e \u003c/caption\u003e \u003ccolgroup cols=\"17\"\u003e \u003cdiv align=\"left\" class=\"colspec\" colname=\"c1\" colnum=\"1\"\u003e\u003c/div\u003e \u003cdiv align=\"left\" class=\"colspec\" colname=\"c2\" colnum=\"2\"\u003e\u003c/div\u003e \u003cdiv align=\"left\" class=\"colspec\" colname=\"c3\" colnum=\"3\"\u003e\u003c/div\u003e \u003cdiv align=\"left\" class=\"colspec\" colname=\"c4\" colnum=\"4\"\u003e\u003c/div\u003e \u003cdiv align=\"left\" class=\"colspec\" colname=\"c5\" colnum=\"5\"\u003e\u003c/div\u003e \u003cdiv align=\"left\" class=\"colspec\" colname=\"c6\" colnum=\"6\"\u003e\u003c/div\u003e \u003cdiv align=\"left\" class=\"colspec\" colname=\"c7\" colnum=\"7\"\u003e\u003c/div\u003e \u003cdiv align=\"left\" class=\"colspec\" colname=\"c8\" colnum=\"8\"\u003e\u003c/div\u003e \u003cdiv align=\"left\" class=\"colspec\" colname=\"c9\" colnum=\"9\"\u003e\u003c/div\u003e \u003cdiv align=\"left\" class=\"colspec\" colname=\"c10\" colnum=\"10\"\u003e\u003c/div\u003e \u003cdiv align=\"left\" class=\"colspec\" colname=\"c11\" colnum=\"11\"\u003e\u003c/div\u003e \u003cdiv align=\"left\" class=\"colspec\" colname=\"c12\" colnum=\"12\"\u003e\u003c/div\u003e \u003cdiv align=\"left\" class=\"colspec\" colname=\"c13\" colnum=\"13\"\u003e\u003c/div\u003e \u003cdiv align=\"left\" class=\"colspec\" colname=\"c14\" colnum=\"14\"\u003e\u003c/div\u003e \u003cdiv align=\"left\" class=\"colspec\" colname=\"c15\" colnum=\"15\"\u003e\u003c/div\u003e \u003cdiv align=\"left\" class=\"colspec\" colname=\"c16\" colnum=\"16\"\u003e\u003c/div\u003e \u003cdiv align=\"left\" class=\"colspec\" colname=\"c17\" colnum=\"17\"\u003e\u003c/div\u003e \u003cthead\u003e \u003ctr\u003e \u003cth align=\"left\" colname=\"c1\"\u003e \u003cp\u003eSamp.\u003c/p\u003e \u003c/th\u003e \u003cth align=\"left\" colname=\"c2\"\u003e \u003cp\u003eCa\u003csup\u003e2+\u003c/sup\u003e\u003c/p\u003e \u003c/th\u003e \u003cth align=\"left\" colname=\"c3\"\u003e \u003cp\u003eMg\u003csup\u003e2+\u003c/sup\u003e\u003c/p\u003e \u003c/th\u003e \u003cth align=\"left\" colname=\"c4\"\u003e \u003cp\u003eNa\u003csup\u003e+\u003c/sup\u003e\u003c/p\u003e \u003c/th\u003e \u003cth align=\"left\" colname=\"c5\"\u003e \u003cp\u003eK\u003csup\u003e+\u003c/sup\u003e\u003c/p\u003e \u003c/th\u003e \u003cth align=\"left\" colname=\"c6\"\u003e \u003cp\u003eHCO\u003csup\u003e3\u0026minus;\u003c/sup\u003e\u003c/p\u003e \u003c/th\u003e \u003cth align=\"left\" colname=\"c7\"\u003e \u003cp\u003eSO\u003csub\u003e4\u003c/sub\u003e\u003csup\u003e2\u0026minus;\u003c/sup\u003e\u003c/p\u003e \u003c/th\u003e \u003cth align=\"left\" colname=\"c8\"\u003e \u003cp\u003eCl\u003csup\u003e\u0026minus;\u003c/sup\u003e\u003c/p\u003e \u003c/th\u003e \u003cth align=\"left\" colname=\"c9\"\u003e \u003cp\u003eNO\u003csub\u003e3\u003c/sub\u003e\u003csup\u003e\u0026minus;\u003c/sup\u003e\u003c/p\u003e \u003c/th\u003e \u003cth align=\"left\" colname=\"c10\"\u003e \u003cp\u003eTotal Cations\u003c/p\u003e \u003c/th\u003e \u003cth align=\"left\" colname=\"c11\"\u003e \u003cp\u003eTotal\u003c/p\u003e \u003cp\u003eAnions\u003c/p\u003e \u003c/th\u003e \u003cth align=\"left\" colname=\"c12\"\u003e \u003cp\u003eIonic\u003c/p\u003e \u003cp\u003ebalance\u003c/p\u003e \u003c/th\u003e \u003cth align=\"left\" colname=\"c13\"\u003e \u003cp\u003epH\u003c/p\u003e \u003c/th\u003e \u003cth align=\"left\" colname=\"c14\"\u003e \u003cp\u003eEC\u003c/p\u003e \u003cp\u003e\u0026micro;s cm\u003csup\u003e\u0026minus;\u003c/sup\u003e\u003c/p\u003e \u003c/th\u003e \u003cth align=\"left\" colname=\"c15\"\u003e \u003cp\u003eTDS\u003c/p\u003e \u003cp\u003emg L\u003csup\u003e\u0026minus;\u003c/sup\u003e\u003c/p\u003e \u003c/th\u003e \u003cth align=\"left\" colname=\"c16\"\u003e \u003cp\u003eTH\u003c/p\u003e \u003cp\u003emg L\u003csup\u003e\u0026minus;\u003c/sup\u003e\u003c/p\u003e \u003c/th\u003e \u003cth align=\"left\" colname=\"c17\"\u003e \u003cp\u003eTr.\u003c/p\u003e \u003cp\u003eNTU\u003c/p\u003e \u003c/th\u003e \u003c/tr\u003e \u003c/thead\u003e \u003ctbody\u003e \u003ctr\u003e \u003ctd align=\"left\" colname=\"c1\"\u003e \u003cp\u003eR1 (*)\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c2\"\u003e \u003cp\u003e57.3\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c3\"\u003e \u003cp\u003e14.8\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c4\"\u003e \u003cp\u003e13.1\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c5\"\u003e \u003cp\u003e3.2\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c6\"\u003e \u003cp\u003e142.1\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c7\"\u003e \u003cp\u003e81.2\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c8\"\u003e \u003cp\u003e27.8\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c9\"\u003e \u003cp\u003e3.5\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c13\"\u003e \u003cp\u003e7.7\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c14\"\u003e \u003cp\u003e345\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c15\"\u003e \u003cp\u003e307\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c16\"\u003e \u003cp\u003e207\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c17\"\u003e \u003cp\u003e2.1\u003c/p\u003e \u003c/td\u003e \u003c/tr\u003e \u003ctr\u003e \u003ctd align=\"left\" colname=\"c1\"\u003e \u003cp\u003e(**)\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c2\"\u003e \u003cp\u003e2.86\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c3\"\u003e \u003cp\u003e1.22\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c4\"\u003e \u003cp\u003e0.57\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c5\"\u003e \u003cp\u003e0.08\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c6\"\u003e \u003cp\u003e2.33\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c7\"\u003e \u003cp\u003e1.69\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c8\"\u003e \u003cp\u003e0.78\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c9\"\u003e \u003cp\u003e0.06\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c10\"\u003e \u003cp\u003e4.73\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c11\"\u003e \u003cp\u003e4.86\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c12\"\u003e \u003cp\u003e1.38\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c13\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c14\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c15\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c16\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c17\"\u003e\u0026nbsp;\u003c/td\u003e \u003c/tr\u003e \u003ctr\u003e \u003ctd align=\"left\" colname=\"c1\"\u003e \u003cp\u003eR2\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c2\"\u003e \u003cp\u003e49.7\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c3\"\u003e \u003cp\u003e22.4\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c4\"\u003e \u003cp\u003e12.1\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c5\"\u003e \u003cp\u003e2.8\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c6\"\u003e \u003cp\u003e136.6\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c7\"\u003e \u003cp\u003e100\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c8\"\u003e \u003cp\u003e33.3\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c9\"\u003e \u003cp\u003e2.5\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c13\"\u003e \u003cp\u003e7.15\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c14\"\u003e \u003cp\u003e360\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c15\"\u003e \u003cp\u003e320\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c16\"\u003e \u003cp\u003e224\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c17\"\u003e \u003cp\u003e1.17\u003c/p\u003e \u003c/td\u003e \u003c/tr\u003e \u003ctr\u003e \u003ctd align=\"left\" colname=\"c1\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c2\"\u003e \u003cp\u003e2.48\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c3\"\u003e \u003cp\u003e1.84\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c4\"\u003e \u003cp\u003e0.53\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c5\"\u003e \u003cp\u003e0.07\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c6\"\u003e \u003cp\u003e2.24\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c7\"\u003e \u003cp\u003e2.08\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c8\"\u003e \u003cp\u003e0.94\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c9\"\u003e \u003cp\u003e0.04\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c10\"\u003e \u003cp\u003e4.92\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c11\"\u003e \u003cp\u003e5.30\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c12\"\u003e \u003cp\u003e3.72\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c13\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c14\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c15\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c16\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c17\"\u003e\u0026nbsp;\u003c/td\u003e \u003c/tr\u003e \u003ctr\u003e \u003ctd align=\"left\" colname=\"c1\"\u003e \u003cp\u003eR3\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c2\"\u003e \u003cp\u003e48.1\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c3\"\u003e \u003cp\u003e20.6\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c4\"\u003e \u003cp\u003e11.2\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c5\"\u003e \u003cp\u003e2.5\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c6\"\u003e \u003cp\u003e146.4\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c7\"\u003e \u003cp\u003e32.5\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c8\"\u003e \u003cp\u003e72.8\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c9\"\u003e \u003cp\u003e1.4\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c13\"\u003e \u003cp\u003e7.65\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c14\"\u003e \u003cp\u003e342\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c15\"\u003e \u003cp\u003e300\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c16\"\u003e \u003cp\u003e212\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c17\"\u003e \u003cp\u003e1.33\u003c/p\u003e \u003c/td\u003e \u003c/tr\u003e \u003ctr\u003e \u003ctd align=\"left\" colname=\"c1\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c2\"\u003e \u003cp\u003e2.40\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c3\"\u003e \u003cp\u003e1.69\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c4\"\u003e \u003cp\u003e0.49\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c5\"\u003e \u003cp\u003e0.06\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c6\"\u003e \u003cp\u003e2.40\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c7\"\u003e \u003cp\u003e0.68\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c8\"\u003e \u003cp\u003e2.05\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c9\"\u003e \u003cp\u003e0.02\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c10\"\u003e \u003cp\u003e4.65\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c11\"\u003e \u003cp\u003e5.15\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c12\"\u003e \u003cp\u003e5.17\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c13\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c14\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c15\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c16\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c17\"\u003e\u0026nbsp;\u003c/td\u003e \u003c/tr\u003e \u003ctr\u003e \u003ctd align=\"left\" colname=\"c1\"\u003e 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colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c13\"\u003e \u003cp\u003e7.75\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c14\"\u003e \u003cp\u003e346\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c15\"\u003e \u003cp\u003e310\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c16\"\u003e \u003cp\u003e220\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c17\"\u003e \u003cp\u003e1.94\u003c/p\u003e \u003c/td\u003e \u003c/tr\u003e \u003ctr\u003e \u003ctd align=\"left\" colname=\"c1\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c2\"\u003e \u003cp\u003e2.08\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c3\"\u003e \u003cp\u003e2.13\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c4\"\u003e \u003cp\u003e0.48\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c5\"\u003e \u003cp\u003e0.06\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c6\"\u003e \u003cp\u003e2.32\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c7\"\u003e \u003cp\u003e0.51\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c8\"\u003e \u003cp\u003e1.23\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c9\"\u003e \u003cp\u003e0.04\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c10\"\u003e \u003cp\u003e4.75\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c11\"\u003e \u003cp\u003e4.10\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c12\"\u003e \u003cp\u003e7.37\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c13\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c14\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c15\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c16\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" 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colname=\"c1\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c2\"\u003e \u003cp\u003e6.39\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c3\"\u003e \u003cp\u003e3.99\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c4\"\u003e \u003cp\u003e4.52\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c5\"\u003e \u003cp\u003e0.19\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c6\"\u003e \u003cp\u003e4.59\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c7\"\u003e \u003cp\u003e8.74\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c8\"\u003e \u003cp\u003e3.81\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c9\"\u003e \u003cp\u003e0.11\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c10\"\u003e \u003cp\u003e15.09\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c11\"\u003e \u003cp\u003e17.25\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c12\"\u003e \u003cp\u003e6.69\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c13\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c14\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c15\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c16\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c17\"\u003e\u0026nbsp;\u003c/td\u003e \u003c/tr\u003e \u003ctr\u003e \u003ctd align=\"left\" colname=\"c1\"\u003e \u003cp\u003eSh3\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c2\"\u003e \u003cp\u003e99.5\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c3\"\u003e \u003cp\u003e46.5\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c4\"\u003e \u003cp\u003e100.4\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c5\"\u003e \u003cp\u003e6.4\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c6\"\u003e 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colname=\"c11\"\u003e \u003cp\u003e15.28\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c12\"\u003e \u003cp\u003e6.88\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c13\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c14\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c15\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c16\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c17\"\u003e\u0026nbsp;\u003c/td\u003e \u003c/tr\u003e \u003ctr\u003e \u003ctd align=\"left\" colname=\"c1\"\u003e \u003cp\u003eSh4\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c2\"\u003e \u003cp\u003e101.2\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c3\"\u003e \u003cp\u003e44.8\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c4\"\u003e \u003cp\u003e99.1\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c5\"\u003e 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colname=\"c10\"\u003e \u003cp\u003e13.19\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c11\"\u003e \u003cp\u003e13.53\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c12\"\u003e \u003cp\u003e1.27\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c13\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c14\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c15\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c16\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c17\"\u003e\u0026nbsp;\u003c/td\u003e \u003c/tr\u003e \u003ctr\u003e \u003ctd align=\"left\" colname=\"c1\"\u003e \u003cp\u003eSh5\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c2\"\u003e \u003cp\u003e199\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c3\"\u003e \u003cp\u003e86\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c4\"\u003e 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\u003ctd align=\"left\" colname=\"c3\"\u003e \u003cp\u003e18.8\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c4\"\u003e \u003cp\u003e30\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c5\"\u003e \u003cp\u003e2.5\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c6\"\u003e \u003cp\u003e156.1\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c7\"\u003e \u003cp\u003e107\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c8\"\u003e \u003cp\u003e49.9\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c9\"\u003e \u003cp\u003e5\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c13\"\u003e \u003cp\u003e7.7\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c14\"\u003e 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align=\"left\" colname=\"c8\"\u003e \u003cp\u003e1.41\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c9\"\u003e \u003cp\u003e0.08\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c10\"\u003e \u003cp\u003e6.28\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c11\"\u003e \u003cp\u003e6.27\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c12\"\u003e \u003cp\u003e0.03\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c13\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c14\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c15\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c16\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c17\"\u003e\u0026nbsp;\u003c/td\u003e \u003c/tr\u003e \u003ctr\u003e \u003ctd align=\"left\" colname=\"c1\"\u003e \u003cp\u003eE3\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c2\"\u003e 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\u003c/td\u003e \u003ctd align=\"left\" colname=\"c14\"\u003e \u003cp\u003e386\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c15\"\u003e \u003cp\u003e400\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c16\"\u003e \u003cp\u003e244\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c17\"\u003e \u003cp\u003e0.62\u003c/p\u003e \u003c/td\u003e \u003c/tr\u003e \u003ctr\u003e \u003ctd align=\"left\" colname=\"c1\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c2\"\u003e \u003cp\u003e3.28\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c3\"\u003e \u003cp\u003e1.47\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c4\"\u003e \u003cp\u003e1.00\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c5\"\u003e \u003cp\u003e0.06\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c6\"\u003e \u003cp\u003e2.48\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c7\"\u003e \u003cp\u003e2.25\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c8\"\u003e \u003cp\u003e1.12\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c9\"\u003e \u003cp\u003e0.08\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c10\"\u003e \u003cp\u003e5.82\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c11\"\u003e \u003cp\u003e5.92\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c12\"\u003e \u003cp\u003e0.88\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c13\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c14\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c15\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c16\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c17\"\u003e\u0026nbsp;\u003c/td\u003e \u003c/tr\u003e \u003ctr\u003e \u003ctd align=\"left\" colname=\"c1\"\u003e \u003cp\u003eE4\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c2\"\u003e \u003cp\u003e59.4\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c3\"\u003e \u003cp\u003e21.5\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c4\"\u003e \u003cp\u003e20\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c5\"\u003e \u003cp\u003e2.3\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c6\"\u003e \u003cp\u003e156.1\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c7\"\u003e \u003cp\u003e102\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c8\"\u003e \u003cp\u003e37.4\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c9\"\u003e \u003cp\u003e5\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c13\"\u003e \u003cp\u003e7.6\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c14\"\u003e \u003cp\u003e353\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c15\"\u003e \u003cp\u003e360\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c16\"\u003e \u003cp\u003e244\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c17\"\u003e \u003cp\u003e2.09\u003c/p\u003e \u003c/td\u003e \u003c/tr\u003e \u003ctr\u003e \u003ctd align=\"left\" colname=\"c1\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c2\"\u003e \u003cp\u003e2.96\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c3\"\u003e \u003cp\u003e1.77\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c4\"\u003e \u003cp\u003e0.87\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c5\"\u003e \u003cp\u003e0.06\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c6\"\u003e \u003cp\u003e2.56\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c7\"\u003e \u003cp\u003e2.12\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c8\"\u003e \u003cp\u003e1.05\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c9\"\u003e \u003cp\u003e0.08\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c10\"\u003e \u003cp\u003e5.66\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c11\"\u003e \u003cp\u003e5.82\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c12\"\u003e \u003cp\u003e1.36\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c13\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c14\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c15\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c16\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c17\"\u003e\u0026nbsp;\u003c/td\u003e \u003c/tr\u003e \u003ctr\u003e \u003ctd align=\"left\" colname=\"c1\"\u003e \u003cp\u003eE5\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c2\"\u003e \u003cp\u003e69\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c3\"\u003e \u003cp\u003e25\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c4\"\u003e \u003cp\u003e49\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c5\"\u003e \u003cp\u003e9.1\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c6\"\u003e \u003cp\u003e234.2\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c7\"\u003e \u003cp\u003e175\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c8\"\u003e \u003cp\u003e106.1\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c9\"\u003e \u003cp\u003e6\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c10\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c11\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c12\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c13\"\u003e \u003cp\u003e7.4\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c14\"\u003e \u003cp\u003e335\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c15\"\u003e \u003cp\u003e660\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c16\"\u003e \u003cp\u003e372\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c17\"\u003e \u003cp\u003e10.5\u003c/p\u003e \u003c/td\u003e \u003c/tr\u003e \u003ctr\u003e \u003ctd align=\"left\" colname=\"c1\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c2\"\u003e \u003cp\u003e3.44\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c3\"\u003e \u003cp\u003e2.06\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c4\"\u003e \u003cp\u003e2.13\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c5\"\u003e \u003cp\u003e0.23\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c6\"\u003e \u003cp\u003e3.84\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c7\"\u003e \u003cp\u003e3.64\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c8\"\u003e \u003cp\u003e2.99\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c9\"\u003e \u003cp\u003e0.10\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c10\"\u003e \u003cp\u003e7.86\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c11\"\u003e \u003cp\u003e10.57\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c12\"\u003e \u003cp\u003e14.69\u003c/p\u003e \u003c/td\u003e \u003ctd align=\"left\" colname=\"c13\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c14\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c15\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c16\"\u003e\u0026nbsp;\u003c/td\u003e \u003ctd align=\"left\" colname=\"c17\"\u003e\u0026nbsp;\u003c/td\u003e \u003c/tr\u003e \u003c/tbody\u003e \u003c/colgroup\u003e \u003ctfoot\u003e \u003ctr\u003e\u003ctd colspan=\"17\"\u003e(*) in mg.L\u003csup\u003e\u0026minus;\u003c/sup\u003e ; (**) in meq\u003c/td\u003e\u003c/tr\u003e \u003c/tfoot\u003e \u003c/table\u003e\u003c/div\u003e \u003c/p\u003e \u003cp\u003e \u003c/p\u003e \u003cp\u003eThe concentrations of the main ions reflect the physical properties of the water (Table\u0026nbsp;\u003cspan refid=\"Tab2\" class=\"InternalRef\"\u003e2\u003c/span\u003e), with total dissolved salts (TDS) ranging from 307 to 310 mg/L on the left bank of the Tigris River and 340 mg/L on the right bank within the research area. Total dissolved solids values ​​are higher in the valley waters, exceeding 500 mg/L, depending on the amount of water discharged and the concentration of dissolved salts in each valley. Figure\u0026nbsp;\u003cspan refid=\"Fig3\" class=\"InternalRef\"\u003e3\u003c/span\u003e shows the fluctuations in the TDS content at each mouth and during the sampling path of the Tigris River, as the concentrations of TDS increase at the mouth of the valley and then decrease due to dilution with increasing distance from the mouth. This is evident in the valleys of Al-Khosar, Al-Danffilli, Al-Shor and Eqab, with little variation in the remaining valleys, which is attributed to the low volume of their water discharged into the Tigris River. The extent of pollution in the contaminated section of the river was determined at the mouths of each valley at a distance of 293 m from Eqab, 323 m from Al-Khosar, 280 m from Al-Danffalli, and 650 m from Al-Shor.\u003c/p\u003e \u003cp\u003e \u003c/p\u003e \u003cp\u003eThe remaining physical parameters (electrical conductivity, total hardness, and turbidity) often adhere to the aforementioned context. The pH levels in the valley water samples are comparatively low due to the presence of waste materials in these waters.\u003c/p\u003e \u003c/div\u003e"},{"header":"4 Conclusion","content":"\u003cp\u003eChemical analyses confirmed the results of the Iber model that water from the main valleys, upon entering the Tigris River, is diluted along the river course downstream, with the degree of dilution varying based on the levels of pollution and discharge from each valley. Thus, both Al-Rashidia and Al-Kharrazi valleys showed little pollution due to their low discharge. The waters of the other valleys, such as Eqab, Al-Khosar, and Al-Danffilli, traverse approximately 300 meters, whilst the waters of Al-Shor Valley extend to 650 meters. Overall, the effluents from these valleys do not pose an issue for Tigris River regarding their dissolved salt content, owing to the low concentration of dissolved salts and discharge rates.\u003c/p\u003e"},{"header":"Declarations","content":"\u003cp\u003eThe authors did not obtain assistance from any organisation for the submitted work. No financial support was obtained for the development of this manuscript. This study got no funding. No financial resources, grants, or other assistance were obtained.\u003c/p\u003e\n\u003cp\u003eMustafa S. Mustafa, Kotayba T. Al-Youzbakey and Basma A.M. Al-Jawadi announce the absence of financial interests.\u003c/p\u003e\n\u003cp\u003eThe authors possess no pertinent financial or non-financial interests to declare. The authors declare no relevant conflicts of interest pertaining to the content of this work. All authors affirm that they possess no affiliations or engagements with any organisation or institution that holds financial or non-financial interests in the subject matter or materials addressed in this publication. The writers possess no financial or proprietary interests in any materials referenced in this essay.\u003c/p\u003e\n\u003cp\u003eAuthors bear responsibility for the accuracy of the assertions made in the manuscript.\u003c/p\u003e\n\u003cp\u003e\u003cstrong\u003eAcknowledgments\u003c/strong\u003e\u003c/p\u003e\n\u003cp\u003eThe authors thank the management of Dams and Water Resources Research Center for providing the requirements to complete the research.\u003c/p\u003e"},{"header":"References","content":"\u003col\u003e\u003cli\u003e\u003cspan\u003eAl-Assaf, A. Y. R., \u0026amp; Al-Saffawi, A. Y. T. (2018). 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Science of The Total Environment, \u003cem\u003e826\u003c/em\u003e, 154146. \u003cspan class=\"ExternalRef\"\u003e\u003cspan class=\"RefSource\"\u003ehttps://doi.org/10.1016/j.scitotenv.2022.154146\u003c/span\u003e\u003cspan address=\"10.1016/j.scitotenv.2022.154146\" targettype=\"DOI\" class=\"RefTarget\"\u003e\u003c/span\u003e\u003c/span\u003e\u003c/span\u003e\u003c/li\u003e\u003c/ol\u003e"}],"fulltextSource":"","fullText":"","funders":[],"hasAdminPriorityOnWorkflow":false,"hasManuscriptDocX":true,"hasOptedInToPreprint":true,"hasPassedJournalQc":"","hasAnyPriority":true,"hideJournal":true,"highlight":"","institution":"","isAcceptedByJournal":false,"isAuthorSuppliedPdf":false,"isDeskRejected":"","isHiddenFromSearch":false,"isInQc":false,"isInWorkflow":false,"isPdf":false,"isPdfUpToDate":true,"isWithdrawnOrRetracted":false,"journal":{"display":true,"email":"[email protected]","identity":"researchsquare","isNatureJournal":false,"hasQc":true,"allowDirectSubmit":true,"externalIdentity":"","sideBox":"","snPcode":"","submissionUrl":"/submission","title":"Research Square","twitterHandle":"researchsquare","acdcEnabled":true,"dfaEnabled":false,"editorialSystem":"","reportingPortfolio":"","inReviewEnabled":false,"inReviewRevisionsEnabled":true},"keywords":"Iber model, Hydrodynamic Model, Tigris River, Mosul City, Polluted water","lastPublishedDoi":"10.21203/rs.3.rs-6589312/v1","lastPublishedDoiUrl":"https://doi.org/10.21203/rs.3.rs-6589312/v1","license":{"name":"CC BY 4.0","url":"https://creativecommons.org/licenses/by/4.0/"},"manuscriptAbstract":"\u003cp\u003eIber Model was used to simulates fresh water flow and pollutant transport in various aquatic environments, focusing on the main valleys in Mosul City that discharge into Tigris River. These valleys, including Al-Rashidia, Al-Kharrazi, Al-Khosar, Al-Danffilli, Al-Shor, and Eqab, are heavily polluted with solid waste, sewage, and industrial runoff, especially during the rainy season. Total dissolved solids (TDS) concentrations were measured, revealing levels of 520, 500, 670, 660, 1820, and 660 mg/L, respectively. Iber model showed that mixing Tigris River fresh water with valleys water reduces TDS concentrations downstream mouth valleys, with varying distances of impact based on discharge and pollution levels: 293 m from Eqab, 323 m from Al-Khosar, 280 m from Al-Danffilli, and 650 m from Al-Shor. Al-Rashidia and Al-Kharazi showed minimal impact due to their low discharge. Overall, the valleys' discharges do not pose a significant concern for Tigris River's dissolved salt content.\u003c/p\u003e","manuscriptTitle":"Using (Iber) Hydrodynamic Model to Simulate the Flow of Polluted Water of Tigris River in Mosul City, Northern Iraq","msid":"","msnumber":"","nonDraftVersions":[{"code":1,"date":"2025-05-06 09:27:35","doi":"10.21203/rs.3.rs-6589312/v1","editorialEvents":[{"type":"communityComments","content":0}],"status":"published","journal":{"display":true,"email":"[email protected]","identity":"researchsquare","isNatureJournal":false,"hasQc":true,"allowDirectSubmit":true,"externalIdentity":"","sideBox":"","snPcode":"","submissionUrl":"/submission","title":"Research Square","twitterHandle":"researchsquare","acdcEnabled":true,"dfaEnabled":false,"editorialSystem":"","reportingPortfolio":"","inReviewEnabled":false,"inReviewRevisionsEnabled":true}}],"origin":"","ownerIdentity":"7d51788c-14e4-4fed-a3c1-9c25cfa0c248","owner":[],"postedDate":"May 6th, 2025","published":true,"recentEditorialEvents":[],"rejectedJournal":[],"revision":"","amendment":"","status":"posted","subjectAreas":[],"tags":[],"updatedAt":"2025-05-21T18:23:15+00:00","versionOfRecord":[],"versionCreatedAt":"2025-05-06 09:27:35","video":"","vorDoi":"","vorDoiUrl":"","workflowStages":[]},"version":"v1","identity":"rs-6589312","journalConfig":"researchsquare"},"__N_SSP":true},"page":"/article/[identity]/[[...version]]","query":{"redirect":"/article/rs-6589312","identity":"rs-6589312","version":["v1"]},"buildId":"8U1c8b4HqxoKbykW_rLl7","isFallback":false,"isExperimentalCompile":false,"dynamicIds":[84888],"gssp":true,"scriptLoader":[]}

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