Time-Resolved UV-IR Experiments that Suggest Photoactivated Fe-Cu Dinuclear Catalyst

2021 · doi:10.26434/chemrxiv.14176646.v1
preprint OA: closed CC-BY-NC-ND-4.0
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⚙ AI-generated summary by claude@2026-07, 2026-07-17 ⓘ

Time-resolved UV-IR experiments on a triethylsilyl-substituted Fe-Cu complex demonstrated photoactivation of a heterodinuclear species for arene borylation.

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Abstract

This work reports the synthesis of a triethylsilyl-substituted Fe-Cu complex that provided cyclohexane solubility to conduct time-resolved UV-IR studies. These studies suggest that UV light induces a photochemically active heterodinuclear species for arene borylation catalysis.

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License: CC-BY-NC-ND-4.0