Large eddy simulations of Zinc ions transfer to turbulent flows from hyporheic zone

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This paper uses large-eddy simulations to study how zinc ions (Zn2+) adsorbed in the hyporheic zone are released into overlying turbulent flows, modeling sediment in-flow, adsorption, and convective diffusion with the volume-averaged Navier–Stokes equations and an advection–diffusion equation including an adsorption term. It investigates how sediment bed permeability and anisotropy, along with pH, alter Zn2+ concentration distributions and mass transfer by analyzing time-averaged statistics of flow and concentration fields. The results show that increasing pH strengthens adsorption, producing a slow rise and a lower steady-state Zn2+ concentration in the water layer, while higher overall and wall-normal permeability enhance exchanges near the sediment-water interface, increasing wall-normal turbulent intensity and Zn2+ flux and effective diffusion. The paper’s main limitation is that it is a preprint and therefore not peer reviewed, and the simulation framework described does not provide additional real-world validation beyond the computational setup. The paper does not explicitly discuss endometriosis or adenomyosis; it was included in the corpus via a keyword match in the upstream search index.

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Abstract

Abstract Metal contaminants from surface water pollution events often enter hyporheic zones, under certain conditions, they may be released back into streams, causing secondary pollution to the water quality. The present study investigated the effects of adsorption, permeability, and anisotropy of sediment beds on the release of zinc ions (Zn2+) from the hyporheic zone into overlying turbulent flows using large-eddy simulations (LES). The volume-averaged Navier-Stokes equations and advection-diffusion equation with adsorption term were used to describe the sediment in-flow, adsorption, and convective diffusion of Zn2+ within the sediment layer. The effects of sediment permeability on the Zn2+ concentration distribution and mass transfer processes were investigated by time-averaged statistics of flow and concentration fields. The results show that adsorption becomes stronger as the pH value increases, leading to a slow increase in Zn2+ concentration in the overlying water layer and reaching a lower steady-state concentration. Higher overall permeability of the sediment layer can enhance mass and momentum exchange near the sediment-water interface (SWI), and intensify the release of Zn2+ from the sediment layer into the overlying water. As the wall-normal permeability of the sediment layer increases, the normal turbulent intensity strengthens, momentum transport enhances the wall-normal Zn2+ concentration flux increases, the effective diffusion coefficient increases, and the concentration in the overlying water increases.
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Large eddy simulations of Zinc ions transfer to turbulent flows from hyporheic zone | Research Square window.SnipcartSettings = { analytics: { enabled: false } }; (function() { var accessVector = localStorage.getItem('access_vector') || ''; window.dataLayer = window.dataLayer || []; if (accessVector) { window.dataLayer.push({ user: { profile: { profileInfo: { snid: accessVector } } } }); } })(); (function(w,d,s,l,i){w[l]=w[l]||[];w[l].push({'gtm.start':new Date().getTime(),event:'gtm.js'});var f=d.getElementsByTagName(s)[0],j=d.createElement(s),dl=l!='dataLayer'?'&l='+l:'';j.async=true;j.src='https://www.googletagmanager.com/gtm.js?id='+i+dl;f.parentNode.insertBefore(j,f);})(window,document,'script','dataLayer','GTM-K279D39R'); Browse Preprints In Review Journals COVID-19 Preprints AJE Video Bytes Research Tools Research Promotion AJE Professional Editing AJE Rubriq About Preprint Platform In Review Editorial Policies Our Team Advisory Board Help Center Sign In Submit a Preprint Cite Share Download PDF Research Article Large eddy simulations of Zinc ions transfer to turbulent flows from hyporheic zone Yiming Jin, Jinfeng Chen, Jinlong Zhang, Zehao Zhao, Dongliang Fan, and 1 more This is a preprint; it has not been peer reviewed by a journal. https://doi.org/ 10.21203/rs.3.rs-4321429/v1 This work is licensed under a CC BY 4.0 License Status: Under Review Version 1 posted 5 You are reading this latest preprint version Abstract Metal contaminants from surface water pollution events often enter hyporheic zones, under certain conditions, they may be released back into streams, causing secondary pollution to the water quality. The present study investigated the effects of adsorption, permeability, and anisotropy of sediment beds on the release of zinc ions (Zn2+) from the hyporheic zone into overlying turbulent flows using large-eddy simulations (LES). The volume-averaged Navier-Stokes equations and advection-diffusion equation with adsorption term were used to describe the sediment in-flow, adsorption, and convective diffusion of Zn2+ within the sediment layer. The effects of sediment permeability on the Zn2+ concentration distribution and mass transfer processes were investigated by time-averaged statistics of flow and concentration fields. The results show that adsorption becomes stronger as the pH value increases, leading to a slow increase in Zn2+ concentration in the overlying water layer and reaching a lower steady-state concentration. Higher overall permeability of the sediment layer can enhance mass and momentum exchange near the sediment-water interface (SWI), and intensify the release of Zn2+ from the sediment layer into the overlying water. As the wall-normal permeability of the sediment layer increases, the normal turbulent intensity strengthens, momentum transport enhances the wall-normal Zn2+ concentration flux increases, the effective diffusion coefficient increases, and the concentration in the overlying water increases. Zn2+ contaminants adsorption hyporheic exchange turbulent flow large eddy simulation Full Text Cite Share Download PDF Status: Under Review Version 1 posted Editorial decision: Minor revisions 07 Jun, 2024 Reviewers agreed at journal 03 May, 2024 Reviewers invited by journal 03 May, 2024 Editor assigned by journal 30 Apr, 2024 First submitted to journal 26 Apr, 2024 You are reading this latest preprint version Research Square lets you share your work early, gain feedback from the community, and start making changes to your manuscript prior to peer review in a journal. As a division of Research Square Company, we’re committed to making research communication faster, fairer, and more useful. We do this by developing innovative software and high quality services for the global research community. Our growing team is made up of researchers and industry professionals working together to solve the most critical problems facing scientific publishing. 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