Designing if CZTSSe Based PbS Thin Film Solar Cell for Improved Conversion Efficiency

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In this paper, we simulated a novel CZTSSe (copper-zinc-tin-sulfide-selenide) thin film solar cell with two absorber layers and PbS(a lead sulfide) layer by SCAPS-1D. We investigated the effect of changes in the thickness of the absorbing layer and the acceptor concentration on this cell. Meanwhile, we also optimized the bandgap width of CZTSSe and the thickness of PbS. Moreover, an effective method has been applied in the aim of boosting the conversion efficiency, by adding a BSF (back surface field) layer in the cell. The BSF layer helps to enhance optical behavior and reduces recombination losses, consequently reducing the Voc (open circuit voltage) deficit. With the highest conversion efficiency calculated in the simulation, a cell conversion efficiency of 27.70% can be achieved, which is significantly higher than the basic structure, and provides a large electrical power as well as a more optimal filling factor at the same time.
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Designing if CZTSSe Based PbS Thin Film Solar Cell for Improved Conversion Efficiency | Research Square window.SnipcartSettings = { analytics: { enabled: false } }; (function() { var accessVector = localStorage.getItem('access_vector') || ''; window.dataLayer = window.dataLayer || []; if (accessVector) { window.dataLayer.push({ user: { profile: { profileInfo: { snid: accessVector } } } }); } })(); (function(w,d,s,l,i){w[l]=w[l]||[];w[l].push({'gtm.start':new Date().getTime(),event:'gtm.js'});var f=d.getElementsByTagName(s)[0],j=d.createElement(s),dl=l!='dataLayer'?'&l='+l:'';j.async=true;j.src='https://www.googletagmanager.com/gtm.js?id='+i+dl;f.parentNode.insertBefore(j,f);})(window,document,'script','dataLayer','GTM-K279D39R'); Browse Preprints In Review Journals COVID-19 Preprints AJE Video Bytes Research Tools Research Promotion AJE Professional Editing AJE Rubriq About Preprint Platform In Review Editorial Policies Our Team Advisory Board Help Center Sign In Submit a Preprint Cite Share Download PDF Research Article Designing if CZTSSe Based PbS Thin Film Solar Cell for Improved Conversion Efficiency xin zhou, yuming xue, luoxin wang This is a preprint; it has not been peer reviewed by a journal. https://doi.org/ 10.21203/rs.3.rs-4148947/v1 This work is licensed under a CC BY 4.0 License Status: Posted Version 1 posted You are reading this latest preprint version Abstract In this paper, we simulated a novel CZTSSe (copper-zinc-tin-sulfide-selenide) thin film solar cell with two absorber layers and PbS(a lead sulfide) layer by SCAPS-1D. We investigated the effect of changes in the thickness of the absorbing layer and the acceptor concentration on this cell. Meanwhile, we also optimized the bandgap width of CZTSSe and the thickness of PbS. Moreover, an effective method has been applied in the aim of boosting the conversion efficiency, by adding a BSF (back surface field) layer in the cell. The BSF layer helps to enhance optical behavior and reduces recombination losses, consequently reducing the Voc (open circuit voltage) deficit. With the highest conversion efficiency calculated in the simulation, a cell conversion efficiency of 27.70% can be achieved, which is significantly higher than the basic structure, and provides a large electrical power as well as a more optimal filling factor at the same time. CZTSSe two absorber layers back surface field SCAPS-1D Full Text Additional Declarations No competing interests reported. Cite Share Download PDF Status: Posted Version 1 posted You are reading this latest preprint version Research Square lets you share your work early, gain feedback from the community, and start making changes to your manuscript prior to peer review in a journal. As a division of Research Square Company, we’re committed to making research communication faster, fairer, and more useful. We do this by developing innovative software and high quality services for the global research community. Our growing team is made up of researchers and industry professionals working together to solve the most critical problems facing scientific publishing. Also discoverable on Platform About Our Team In Review Editorial Policies Advisory Board Help Center Resources Author Services Accessibility API Access RSS feed Manage Cookie Preferences © Research Square 2026 | ISSN 2693-5015 (online) Privacy Policy Terms of Service Do Not Sell My Personal Information {"props":{"pageProps":{"initialData":{"identity":"rs-4148947","acceptedTermsAndConditions":true,"allowDirectSubmit":true,"archivedVersions":[],"articleType":"Research Article","associatedPublications":[],"authors":[{"id":283432492,"identity":"24a39a42-b5ea-46a1-b958-1ff4bb333d6b","order_by":0,"name":"xin zhou","email":"","orcid":"","institution":"Tianjin University of Technology","correspondingAuthor":false,"prefix":"","firstName":"xin","middleName":"","lastName":"zhou","suffix":""},{"id":283432494,"identity":"16bc6ed2-ecca-46e8-9a5f-5d4b8bd08aff","order_by":1,"name":"yuming xue","email":"data:image/png;base64,iVBORw0KGgoAAAANSUhEUgAAAZAAAAAyAQMAAABI0h/eAAAABlBMVEX///8AAABVwtN+AAAACXBIWXMAAA7EAAAOxAGVKw4bAAAA1ElEQVRIiWNgGAWjYLCCBwUMcgwMB0BMZiK1JBgwGPMwHGBsIElLYg8DA5Fa+KXPGD5IMDicvp/xjPkDhgrrxAb2swfwapHsyzE2SDBIy+1hOGPYwHAmPbGBJy8BrxaDM7zbJBIMbCBaGNsOJzZI8BgQ0rL9R4KBRDoPWMs/4rRsA3rfJgGipYEILZI9/J+BDksz7DlwrHBGwrF04zaeHPxa+HnYEj98qDgszz7j8IYPH2qsZfvZz+DXggASB4ARBKTZiFQPsq+BeLWjYBSMglEwsgAAPDhDPoEWZMwAAAAASUVORK5CYII=","orcid":"","institution":"Tianjin University of Technology","correspondingAuthor":true,"prefix":"","firstName":"yuming","middleName":"","lastName":"xue","suffix":""},{"id":283432495,"identity":"1c009d74-9783-4af4-9c35-7cfd04c18857","order_by":2,"name":"luoxin wang","email":"","orcid":"","institution":"Tianjin University of Technology","correspondingAuthor":false,"prefix":"","firstName":"luoxin","middleName":"","lastName":"wang","suffix":""}],"badges":[],"createdAt":"2024-03-22 10:20:11","currentVersionCode":1,"declarations":"","doi":"10.21203/rs.3.rs-4148947/v1","doiUrl":"https://doi.org/10.21203/rs.3.rs-4148947/v1","draftVersion":[],"editorialEvents":[],"editorialNote":"","failedWorkflow":false,"files":[{"id":53962874,"identity":"966c5df4-42c1-4f9e-afdf-65ff1bd7cff7","added_by":"auto","created_at":"2024-04-02 18:29:45","extension":"pdf","order_by":1,"title":"","display":"","copyAsset":false,"role":"manuscript-pdf","size":468113,"visible":true,"origin":"","legend":"","description":"","filename":"manuscript.pdf","url":"https://assets-eu.researchsquare.com/files/rs-4148947/v1_covered_125c290a-ab95-4507-a598-a6e6961a166c.pdf"}],"financialInterests":"No competing interests reported.","formattedTitle":"Designing if CZTSSe Based PbS Thin Film Solar Cell for Improved Conversion Efficiency","fulltext":[],"fulltextSource":"","fullText":"","funders":[],"hasAdminPriorityOnWorkflow":false,"hasManuscriptDocX":false,"hasOptedInToPreprint":true,"hasPassedJournalQc":"","hasAnyPriority":false,"hideJournal":true,"highlight":"","institution":"","isAcceptedByJournal":false,"isAuthorSuppliedPdf":true,"isDeskRejected":"","isHiddenFromSearch":false,"isInQc":false,"isInWorkflow":false,"isPdf":true,"isPdfUpToDate":true,"isWithdrawnOrRetracted":false,"journal":{"display":true,"email":"[email protected]","identity":"researchsquare","isNatureJournal":false,"hasQc":true,"allowDirectSubmit":true,"externalIdentity":"","sideBox":"","snPcode":"","submissionUrl":"/submission","title":"Research Square","twitterHandle":"researchsquare","acdcEnabled":true,"dfaEnabled":false,"editorialSystem":"","reportingPortfolio":"","inReviewEnabled":false,"inReviewRevisionsEnabled":true},"keywords":"CZTSSe, two absorber layers, back surface field, SCAPS-1D","lastPublishedDoi":"10.21203/rs.3.rs-4148947/v1","lastPublishedDoiUrl":"https://doi.org/10.21203/rs.3.rs-4148947/v1","license":{"name":"CC BY 4.0","url":"https://creativecommons.org/licenses/by/4.0/"},"manuscriptAbstract":"\u003cp\u003eIn this paper, we simulated a novel CZTSSe (copper-zinc-tin-sulfide-selenide) thin film solar cell with two absorber layers and PbS(a lead sulfide) layer by SCAPS-1D. 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