Titanocene Pnictinidene Complexes
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CC-BY-NC-ND-4.0
Abstract
The phospha-Wittig reagent Mes TerPPMe 3 ( Mes Ter = 2,6-{2,4,6-Me 3 -C 6 H 2 }-C 6 H 3 ) and arsa-Wittig reagent Dip TerAsPMe 3 ( Dip Ter = 2,6-{2,6- i Pr 2 -C 6 H 3 }-C 6 H 3 ) have been employed to synthesize the titanocene complexes Cp 2 Ti(PMe 3 )PnAr (Pn = P, As) with terminal phosphinidene or arsinidene ligands, respectively. Ab initio studies show that the description as singlet biradicaloids in their ground state is warranted.
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- europepmc
- last seen: 2026-05-19T01:45:01.086888+00:00
- unpaywall
- last seen: 2026-05-28T02:00:01.590549+00:00
License: CC-BY-NC-ND-4.0