Mapping Risks Associated with Soil Copper Contamination Using Availability and Bio-Availability Proxies at the European Scale

Abstract Soil contamination by trace elements like copper (Cu) can affect soil functioning. Environmental policies with guidelines and soil survey measurements still refer to the total contents of Cu in soils. However, Cu contents in soil solution or free Cu contents have been shown to be better proxies of risks of Cu mobility or (bio)availability for soil organisms. Several empirical equations have been defined at the local scale to predict the amounts of Cu in soil solution based on both total soil Cu contents and main soil parameters involved in the soil/solution partitioning. Nevertheless, despite the relevance for risk assessment, these equations are not applied at a large spatial scale due to difficulties to perform changes from local to regional. To progress in this challenge, we collected several empirical equations from literature and selected those allowing estimation of the amount of Cu in solution, used as a proxy of available Cu, from the knowledge of both total soil Cu contents and soil parameters. We did the same for the estimation of free Cu in solution, used as a proxy of bioavailable Cu These equations were used to provide European maps of (bio-)available Cu based on the one of total soil Cu over Europe. Results allowed comparing the maps of available and bio-available Cu at the European scale. This was done with respective median values of each form of Cu to identify specific areas of risks linked to these two proxies. Higher discrepancies were highlighted between the map of bioavailable Cu and the map of soil total Cu compared to the Cu available map. Such results can be used to assess environmental-related issues for land use planning.