Numerical simulation model for the curing of photosensitive acrylate resin in a stereolithography process

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Abstract Controlling the precision and mechanical cohesion of 3D-printed parts remains a central concern in the development of additive manufacturing. A two-dimensional finite element model of the photopolymerization of a sensitive resin in a stereolithography apparatus is proposed as a tool for predicting and optimizing formulation and printing parameters. By considering light illumination, chemical reaction and heat transfer in a resin exposed to a moving UV laser source, this first approach accounts for monomer-to-polymer conversion and polymerization rate in agreement with experimental results obtained by FT-IR monitoring and the use of semi-empirical models. The temperature gradient along the exposed photosensitive material was also estimated. By varying the photoinitiator content and simulating the addition of an absorbing filler via the molar extinction coefficient, it was shown that a higher photoinitiator concentration and the presence of strongly absorbing fillers lead to a reduction in the light penetration depth, which can result in structural defects without adaptation of the layer thickness to be printed.
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Numerical simulation model for the curing of photosensitive acrylate resin in a stereolithography process | Research Square window.SnipcartSettings = { analytics: { enabled: false } }; (function() { var accessVector = localStorage.getItem('access_vector') || ''; window.dataLayer = window.dataLayer || []; if (accessVector) { window.dataLayer.push({ user: { profile: { profileInfo: { snid: accessVector } } } }); } })(); (function(w,d,s,l,i){w[l]=w[l]||[];w[l].push({'gtm.start':new Date().getTime(),event:'gtm.js'});var f=d.getElementsByTagName(s)[0],j=d.createElement(s),dl=l!='dataLayer'?'&l='+l:'';j.async=true;j.src='https://www.googletagmanager.com/gtm.js?id='+i+dl;f.parentNode.insertBefore(j,f);})(window,document,'script','dataLayer','GTM-K279D39R'); Browse Preprints In Review Journals COVID-19 Preprints AJE Video Bytes Research Tools Research Promotion AJE Professional Editing AJE Rubriq About Preprint Platform In Review Editorial Policies Our Team Advisory Board Help Center Sign In Submit a Preprint Cite Share Download PDF Research Article Numerical simulation model for the curing of photosensitive acrylate resin in a stereolithography process Pauline Blyweert, Vincent Nicolas, Vanessa Fierro, Alain Celzard This is a preprint; it has not been peer reviewed by a journal. https://doi.org/ 10.21203/rs.3.rs-4528874/v1 This work is licensed under a CC BY 4.0 License Status: Published Journal Publication published 15 Nov, 2024 Read the published version in The International Journal of Advanced Manufacturing Technology → Version 1 posted 5 You are reading this latest preprint version Abstract Controlling the precision and mechanical cohesion of 3D-printed parts remains a central concern in the development of additive manufacturing. A two-dimensional finite element model of the photopolymerization of a sensitive resin in a stereolithography apparatus is proposed as a tool for predicting and optimizing formulation and printing parameters. By considering light illumination, chemical reaction and heat transfer in a resin exposed to a moving UV laser source, this first approach accounts for monomer-to-polymer conversion and polymerization rate in agreement with experimental results obtained by FT-IR monitoring and the use of semi-empirical models. The temperature gradient along the exposed photosensitive material was also estimated. By varying the photoinitiator content and simulating the addition of an absorbing filler via the molar extinction coefficient, it was shown that a higher photoinitiator concentration and the presence of strongly absorbing fillers lead to a reduction in the light penetration depth, which can result in structural defects without adaptation of the layer thickness to be printed. Simulation Stereolithography Photopolymerization Acrylate resin Full Text Cite Share Download PDF Status: Published Journal Publication published 15 Nov, 2024 Read the published version in The International Journal of Advanced Manufacturing Technology → Version 1 posted Editorial decision: Major Revisions Needed 14 Jul, 2024 Reviewers agreed at journal 09 Jun, 2024 Reviewers invited by journal 09 Jun, 2024 Editor assigned by journal 06 Jun, 2024 First submitted to journal 04 Jun, 2024 You are reading this latest preprint version Research Square lets you share your work early, gain feedback from the community, and start making changes to your manuscript prior to peer review in a journal. As a division of Research Square Company, we’re committed to making research communication faster, fairer, and more useful. We do this by developing innovative software and high quality services for the global research community. Our growing team is made up of researchers and industry professionals working together to solve the most critical problems facing scientific publishing. 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