Microwave combustion synthesis of La 1-x Gd x FeO 3 (x=0 to 0.25) nanoparticles: structural, magnetic, vibrational, morphology, and optical behavior

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Abstract

La 1  − x Gd x FeO 3 ( x  = 0 to 0.25) nanoparticles are prepared by microwave combustion process (MCP) with L-alanine as a fuel. The synthesized samples are confirmed by different instrumental characterization for evaluating the nanostructured materials such as XRD, TEM, SAED, XPS, FE-SEM, EDX, FTIR, DRS-UV and VSManalysis.XRD and FT-IR are confirmed that lanthanum ferrite was orthorhombic structure with average crystallite size ranged ̴ 57.8 to 37.9 nm. The energy gap values were estimated using UV-vis spectra and it is in the range between 2.17 and 2.43 eV. The elements like Gd, La, Fe and O are present in EDX and XPS analysis. FE-SEM images reveal aggregated spherical morphology. VSM analysis are shows strong ferro magnetic behavior of La 1 −x Gd x FeO 3 nanoparticles. The M s and M r values are in the range between1.06 to 1.71and 1.94 to 6.53 emu/g for La 1 −x Gd x FeO 3 respectively.

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europepmc
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License: CC-BY-4.0