A Simple Magneto-Structural Correlation for Dysprosium(III) Single-Molecule Magnets with Ligands on the Anisotropy Axis

2018 · doi:10.26434/chemrxiv.7083038.v1
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Abstract

By studying pentagonal-bipyramidal dysprosium(III) single-molecule magnets (SMMs) we show that the energy barrier for magnetization reversal ( U eff ) shows a linear correlation to the axial Dy-X bond lengths, adjusted for the ionic or covalent radii of the ligands bound.

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License: CC-BY-NC-ND-4.0