Spin-Crossover Phenomena of Ni(cyclam)I2 Complex: Magnetostructural Correlations in Two Polymorphs
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CC-BY-NC-ND-4.0
Abstract
Two crystal polymorphs of Ni(cyclam)I 2 (cyclam = 1,4,8,11- tetraazacyclotetradecane) were identified by X-ray structural analysis and their magnetic properties were investigated. Gradual spin-crossover behaviors were found in both polymorphs. Entropy differences between high- and low-spin states obtained by assuming the spin equilibrium model reflected subtle difference of the coordination environment of nickel(II) ion in two polymorphs.
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- europepmc
- last seen: 2026-05-19T01:45:01.086888+00:00
- unpaywall
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License: CC-BY-NC-ND-4.0