Scalable Glassy X-Ray Scintillators with Bright Singlet-Triplet Hybrid Self-Trapping Excitons

Scalable Glassy X-Ray Scintillators with Bright Singlet-Triplet Hybrid Self-Trapping Excitons | Research Square window.SnipcartSettings = { analytics: { enabled: false } }; (function() { var accessVector = localStorage.getItem('access_vector') || ''; window.dataLayer = window.dataLayer || []; if (accessVector) { window.dataLayer.push({ user: { profile: { profileInfo: { snid: accessVector } } } }); } })(); (function(w,d,s,l,i){w[l]=w[l]||[];w[l].push({'gtm.start':new Date().getTime(),event:'gtm.js'});var f=d.getElementsByTagName(s)[0],j=d.createElement(s),dl=l!='dataLayer'?'&l='+l:'';j.async=true;j.src='https://www.googletagmanager.com/gtm.js?id='+i+dl;f.parentNode.insertBefore(j,f);})(window,document,'script','dataLayer','GTM-K279D39R'); Browse Preprints In Review Journals COVID-19 Preprints AJE Video Bytes Research Tools Research Promotion AJE Professional Editing AJE Rubriq About Preprint Platform In Review Editorial Policies Our Team Advisory Board Help Center Sign In Submit a Preprint Cite Share Download PDF Article Scalable Glassy X-Ray Scintillators with Bright Singlet-Triplet Hybrid Self-Trapping Excitons Kai-Kai Liu, Shi-Yu Song, Chao-Jun Gao, Rui Zhou, Bingzhe Wang, and 5 more This is a preprint; it has not been peer reviewed by a journal. https://doi.org/ 10.21203/rs.3.rs-3942722/v1 This work is licensed under a CC BY 4.0 License Status: Under Review Version 1 posted You are reading this latest preprint version Abstract Size-scalable X-ray scintillators with high transparency and robust photon yield allow for imaging large objects with greater precision and detail. Solution-processable scintillators, typically crafted from quantum dots (QDs), are promising candidates for highly efficient scintillation applications. However, the restricted size, low transparency, and dark nature of triplet excitons in QD-based scintillators lead to less efficient X-ray imaging for large objects requiring high resolution. Herein, we demonstrate a meter-scale glassy ZnO QD scintillator with a visible range transmittance exceeding 96% at a thickness of 0.5 mm, showcasing bright singlet/triplet hybrid self-trapping hybrid excitons (STEs). The quantum yields (QYs) of singlet excitons and triplet excitons are 44.7% and 26.3%. Benefiting from a large Stokes shift and bright triplet excitons, the scintillator has a negligible self-absorption and elevated photon yields. Additionally, the scintillator exhibits exchange invariance, demonstrating identical optical performance upon exchanging the coordinates ( r ) of the QDs. Featuring bright singlet/triplet hybrid STEs and high transparency, the scintillator achieves high resolution X-ray imaging of 42 line pairs per millimeter (42 lp mm -1 ) at a meter scale. Moreover, demonstrations of 5000 cm 2 X-ray imaging and real-time dynamic X-ray imaging are presented. The lowest detectable dose rate for X-ray detection is as low as 38.4 nGy s −1 . This work provides a novel sizable and transparent scintillator with bright singlet/triplet hybrid excitons, showcasing their potential in high-resolution and sizable object X-ray imaging. Physical sciences/Optics and photonics/Optical physics/X-rays Physical sciences/Materials science/Nanoscale materials/Quantum dots Scintillator X-ray Imaging Singlet/triplet exciton High-resolution Figures Figure 1 Figure 2 Figure 3 Figure 4 Introduction The interaction of X-ray photons with luminescent materials induces their emission of photons in the visible region, playing a key role in high-energy X-ray nondestructive detection and imaging 1 – 5 . Sizable scintillators with high transparency and robust photon yield enhance precision imaging of large objects, contributing to advancements in medical diagnostics 6 – 9 , industrial inspection 10 – 13 , and so on. The challenge lies in producing efficient large-area scintillators with high transparency, including traditional scintillators generated via the Czochralski method and emerging perovskite scintillators generated via chemical methods 14 – 17 . Small Stokes shift and strong self-absorption effect could greatly decrease the efficiency of light out-coupling of the perovskite scintillator 18 – 20 . The high toxicity and poor stability of lead components and heavy metal elements should be considered in practical applications. When X-ray photons bombard the inner-shell electrons of atoms of the luminescent materials, a tremendous number of high energy electrons through photon-electron interaction and secondary electrons through electron-electron scattering and Auger processes, are generated. The non-equilibrium electrons undergo relaxation before they can emit photons, which result in electron–hole pairs 5 . The ionized electrons follow a 1:3 ratio in singlet and triplet, determined by spin-statistical charge recombination 21 – 23 . In most cases, conventional and perovskite scintillators only emit photons from singlet excitons after being irradiated because of the dark nature of triplet excitons. Thus, when exposed to X-ray, the generated triplet excitons in these scintillators are useless and functionally irrelevant for scintillation. Effectively utilizing triplet excitons presents an attractive way to enhance scintillation performance, especially in scintillators with fewer toxicant heavy metal elements. By chemically modifying the chromophores of thermally activated delayed fluorescence (TADF) and phosphoresce molecules with halogen atoms, there has been a significant enhancement in X-ray absorption cross-section while preserving the bright nature of triplet excitons, leading to outstanding scintillation performance 24 – 26 . Despite advancements, reported organic scintillators exhibit poor transparency in the visible region, resulting in strong light scattering of the X-ray-induced photons. High transparency scintillators could achieve good spatial resolution in X-ray imaging 27 – 29 . Additionally, the complex molecular design and synthesis processes result in limited production capacity, limiting the application of these materials in large-area, high-resolution X-ray imaging. Solution-processable QD scintillators emerge as highly promising candidates for efficient scintillation applications, although it has proven challenging to synthesize a monodispersed population of ultrasmall quantum dots and to retain their solution-phase properties during assembly into scintillator solids. Therefore, the exploration of novel large-size and transparent scintillators, characterized by bright triplet excitons holds significant importance for low-dose, high-resolution, and large-area X-ray imaging. In this study, a meter-scale scintillator with 96% transmittance in the visible region, is demonstrated through the disordered assembly of the ZnO QDs. Benefiting from the efficient utilization of bright singlet/triplet hybrid STEs in the scintillator, a photon yield of 18,038 photons/MeV is achieved under X-ray excitation. Importantly, we have achieved the high X-ray imaging resolution of 42 line pairs per millimeter (42 lp mm − 1 ) at a meter scale and the X-ray detectable dose rate of 38.4 nGy s − 1 , surpassing most reported organic and conventional inorganic scintillators. Furthermore, we demonstrated a high-resolution and large-area (5000 cm 2 ) X-ray imaging of a backpack and broken pork rib through a single scan, and real-time X-ray imaging was also achieved. Results and discussion Solution-processable QDs with strong X-ray absorption ability and bright triplet excitons are ideal candidates for novel highly efficient X-ray scintillators 30 , 31 . Here, the meter-scale transparent scintillator was constructed using approximately \({10}^{21}\) ZnO QDs as building blocks through disordered assembly process (Fig. 1 a). The manufactured scintillator is 1 meter in length, 0.5 meter in width, and 0.5 mm in thickness, and its size is adjustable to suit various dimensions for practical applications through this method. The scintillator screen shows bright luminescence and radioluminescence (RL) when subjected to 365 nm UV light and X-ray light, and a world map beneath the scintillator is clearly visible in daylight. The scintillator comprises an ensemble of the quasi-identical ZnO QDs, namely the fact that the QDs of the same type are fundamentally indistinguishable from each other. In the scintillator, there are n QD labeled with numbers r 1 , r 2 , ..., r n , the optical performance ( O ) of the scintillator is defined as the function of space coordinate r . We then randomly exchanged the coordinates ( r ) of the QDs through redispersion, the scintillator displayed identical optical performance ( O ), including wavelength, intensity, and lifetime in Figure S1 . Thus, the scintillator possesses exchange symmetry, namely exchange invariance, as depicted in Fig. 1 b. In this system, the interaction between the position and the ensemble optical properties can be described by the equations presented in Fig. 1 b. \(P\) is the exchange operator, specially, a chemical or physical reconstruction strategy for the scintillator. The exchange invariance of the scintillator indicates that the disordered assembly way is a universal method for the fabrication of the sizable scintillator with high transparency and good scintillation performance. The internal structure of the scintillator was investigated by transmission electron microscopy (TEM), and the QDs exhibited a disordered arranged state from the top and side view of the TEM images (Figure S2). The ZnO QDs exhibit a uniform size dispersion of 4.6 nm from the TEM image, as shown in the inset of Fig. 1 d and Figure S3. Notably, clear and integrated crystal structure can be observed from the high-resolution TEM image of QDs. ZnO QD with a wide band gap of 3.36 eV (Figure S4), small diameter, and large Stokes shift (about 210 nm) is a reasonable candidate for the fabrication of transparent scintillators. The scattering cross-section of ZnO QDs in water, alcohol and SiO 2 matrix was calculated based on Rayleigh scattering theory 32 , 33 , as shown in Figure S5. The scattering cross section decreases from 4.42× 10 − 20 /m 2 in a water matrix to 2.68× 10 − 20 /m 2 in a silica matrix at the wavelength 500 nm. Such a difference was ascribed to the Rayleigh scattering, where a small refractive-index difference can significantly mitigate the scattering effect. The premix including ZnO QDs, ethanol, and water, presented a white solution with a low light transmittance. As the water and ethanol evaporated, the premix became gradually transparent and the pattern beneath the QDs composites gradually became clear (Figure S6). In addition, the light transmittance ( T ) of a ZnO QD scintillator was investigated are shown in Fig. 1 d (more calculation details see Methods). The simulated light transmittance spectra show that the transmittance is highly sensitive to the radius of QDs. The 90 wt % loading of 5 nm QDs exhibits comparable transparency to its 10 wt % counterpart. The volumetric fraction of ZnO QDs in the scintillator is about 95%, showcasing impressive transparency up to 96% in the wavelength range from 380 to 800 nm (Fig. 1 e). It should be noted that each QD is isolated, and there are no distinct grain boundaries, resulting in minimal difference in refractive index. The transparent nature and disordered inter-arrange of the scintillator resemble glass, prompting us to rename it as a glassy scintillator. The SEM image shows that the QD glassy scintillator has a smooth surface in a large area (Figure S7), further decreasing the light scattering derived from the interface. X-ray diffraction (XRD) pattern of ZnO QD glassy scintillator and the XRD pattern of ZnO QD powders show the same diffraction peaks indexed to the ZnO (Figure S8), indicating the isolation of ZnO QDs within the scintillator. In this disordered assembly process, discrete ZnO QDs were organized into spherical nanoparticles with different sizes (Figure S9), resembling the snowball effect, while the QDs remained spatially well isolated (Figure S1 0). In the end, the ZnO QDs underwent fusion to form a continuum structure, resulting in the formation of the ZnO QD glassy scintillator. In the bottom of Fig. 1 f, the nanosecond and microsecond lifetime of the ZnO QDs can be detected, and the lifetime of the ZnO QDs collected at 575 nm, can be well fitted by bi-exponential function with lifetimes of τ 1 = 55.5 ns (63%) and τ 2 = 1.46 µs (37%). The electron spin resonance (ESR) signal of ZnO QDs manifests a time-dependent nature, disappearing after excitation for 1.9 µs (top of Fig. 1 f). This indicates the lifetime of triplet excitons is about 1.9 µs, which is in agreement with the long-lived component in luminescence lifetime. In addition to high transparency and large size, the scintillator possesses bright triplet excitons, which will be discussed in detail in the next part. The scintillation mechanism of the glassy scintillator is illustrated in Fig. 1 g. When exposed to X-ray photons, X-ray photons interact with the atom of the QDs by photoelectric effect and Compton scattering, inducing hot electrons generated from the directly excited process and ejected electrons from the ionized process. The hot electrons underwent thermal relaxation, forming excitons with holes, and returned to the ground state by emitting visible photons. The ejected electrons would be injected into the adjacent QDs, and the injected electrons would be populated in singlets and triplets following the ratio of 1:3, according to the rule of spin conservation. The ratio of directedly excited ZnO QDs to ionized ZnO QDs is set as 1:k, and the singlet/triplet states ratio ( S n : T n ) is (k + 4):(3k). For extremely ionizing radiation, k approaches infinity, the triplet states recombination would be favored. At the opposite k approaches zero, only singlet states are populated. For the ZnO QDs glassy scintillator, 37% of directly excited ZnO QDs, were populated into triplet state through intersystem crossing (ISC). Thus, the ultimate ratio of S n to T n is expressed as 0.63(1 + k/4):(0.37(1 + 1k/4) + 3k/4)), which can be further simplified to (2.52 + 0.63k):(1.48 + 3.37k), when the scintillator exposed to X-ray photons. The bright nature of the triplet excitons increases the X-ray to visible photons conversion efficiency, by elevating the utilization rate of excitons. The exciton nature of the ZnO QD glassy scintillator and the dynamic processes were further investigated. Figure S11a displays broadband PL at room temperature upon UV excitation, with a peak centered at around 575 nm. The broadband PL is a characteristic of STE emission, a feature previously confirmed in our earlier research 34 . This includes a large Stokes shift (210 nm) and a remarkable full width at half-maximum (FWHM) of 193 nm, due to strong coupling of the excitons with phonons. The absolute PL QY of the ZnO QD powders and ZnO QD glassy scintillator was measured (detail spectra can be found in Figure S12), exhibiting an increase from 58–71%. This increase indicates that the high transparency is a significant factor contributing to the high light yields of ZnO QDs. The 3D contour plots of emission versus excitation spectra are presented in Figure S13, clearly revealing a broad emission range and excitation-independent characteristics. The emission spectra, spanning from 350 to 850 nm, exhibit identical shapes and features across various excitation wavelengths, implying the recombination of a single initial excited state. Furthermore, the temperature-dependent PL spectra were recorded to investigate the electron-phonon coupling, STE binding energy, and Huang-Rhys factor (S), as shown in Figure S11b. The calculated STE binding energy is ∼97.8 meV (Figure S14) by the following equation: $${I}_{T}={I}_{0}/(1+Aexp\left(-\frac{{E}_{b}}{{k}_{B}T}\right))$$ Where I 0 and I T are the emission intensity at 0 K and T K, respectively; A is a constant, E b is the binding energy, k B is the Boltzmann constant. The FWHM of PL spectra undergoes broadening as the temperature from rises 77 K to 317 K (Figure S11c). The Huang-Rhys factor (S) and optical phonon frequency (ћω phonon ) can be described by the Eq. 3 5 : Where ω phonon is phonon frequency, ℏ is reduced Planck constant, T is temperature, and k B is Boltzmann constant. The calculated Huang-Rhys factor S and the phonon energy ℏω phonon are 31.2 and 36.7 meV, respectively. This implies a strong electron-phonon coupling in ZnO QDs, due to the opposite symmetry vibration of zine and oxygen atoms (as depicted in Fig. 2 a), which facilitates the formation of STE with the large Stokes shift emission feature. The spectra from ZnO QDs versus excitation power over 4 orders of magnitude were recorded (Figure S15), and the emission intensity shows a linear dependence on the excitation intensity (Fig. 2 b), excluding the emission from permanent defects. The PL onset time demonstrates a wavelength-dependent characteristic, wherein photons with low energy show slower emergence compared with that of high energy, as shown in Fig. 2 c. This phenomenon serves as direct evidence of STE emission. Additionally, in the 3D time-resolved emission spectra of ZnO QDs (Figure S16), the presence of two distinct lifetimes is evident, signifying the existence of different exciton recombination processes. To explore the kinetics of carrier’s transfer, we further investigated the temperature-dependent PL decay dynamics properties from 77–317 K, as shown in Fig. 2 d and Figure S17. The short lifetime (τ 1 ) decreases from 212 ns to 63.5 ns with escalating temperature, while the long lifetime (τ 2 ) gradually increases first (77–137 K) and then decreases (137–317 K). In the cryogenic region (77–137 K), the long lifetime is suppressed compared with the high-temperature region (over 137 K), due to insufficient energy for electrons in the triplet state back to the singlet state 36 , 37 . The above results suggest that the emission of ZnO QDs originates from the singlet/triplet hybrid STE states. The average lifetimes (τ ave ) of ZnO QDs at 180–300 K were recorded, as shown in Figure S18, and the emission model can be fitted well with the functional relationship by the Eq. 3 8 : $${\tau }_{ave}=\frac{3+exp(- \frac{{\varDelta E}_{ST}}{{K}_{B}T})}{3/{\tau }_{T}+1/{\tau }_{S}exp(- \frac{{\varDelta E}_{ST}}{{K}_{B}T})}$$ where k B is the Boltzmann constant, τ S and τ T are the decay time of singlet and triplet states at 0 K (they are fitted decay lifetime at 77 K for this case), and ΔE ST is the splitting energy gap between singlet and triplet, respectively. The fitted ΔE ST is 48 meV, and such small singlet-triplet energy splitting was consistent with the theoretical calculations of 58 meV in our previous work 34 . To further investigate the dynamic processes of the generated carriers after excitation, excited state spectra of ZnO QDs were performed using broad femtosecond transient absorption (TA) spectroscopy in Fig. 2 e. Negative Δ A features (blue) are discernible in the spectral region spanning regions of 330–350 nm and 560–570 nm, while positive features (highlighted in red) are evident within the wavelength range of 490–540 nm. The TA spectra at different time delays, along with the corresponding decay spectra at 345, 360 and 520 nm, are presented in Figs. 2 f and 2 g. The 330 to 350 nm spectral region is dominated by ground-state photobleaching (PB), exhibiting a consistent match with the steady-state absorption spectrum. Noting that, the signal at around 360 nm shows a negative response within 100 ps, followed by a transition to a positive signal thereafter. This alteration serves as a direct indicator of triplet photoabsorption (PA). Thus, the decay curve at 360 nm represents a hybrid signal including both PB and triplet PA. The broad excited-state absorption in the green region from 485 to 520 nm corresponds to the singlet state PA, and the corresponding lifetime associated with the state at 520 nm state is approximately ~ 1 ns. Species-associated difference spectra (SAS) of the ZnO QDs TA data reveal three components with lifetimes of 9.9 ps, 147.6 ps and 18.7 ns as shown in Fig. 2 h and Figure S19. The kinetics of carriers’ evolution in various excited energy levels can be clearly observed. The generated hot carriers undergo relaxation to the free excitons (FE) state within 109.7 fs, followed by a further relaxation to the singlet STE state within 9.9 ps due to the strong electron-phonon coupling. The singlet STE state evolution can be directly resolved by the decay curves at 520 nm. Subsequently, the singlet STE state converts into the long-lived species within 147.6 ps through an intersystem crossing (ISC) process, characterized by distinct excited-state absorption at 360 nm. Compared with PL decay spectra, the average lifetimes of ZnO QDs at 375 nm and 575 nm are 2.7 ns and 1030 ns, and a plausible mechanism model for carrier evolution is shown in Fig. 2 i. The above results confirm that the emission of the ZnO QDs is attributed to the radiative recombination of singlet/triplet hybrid STE, rendering it highly advantageous for scintillator applications. The RL spectra of the ZnO QD glassy scintillator under excitation of a 45 kV X-ray source and UV excitation (at 80 and 300 K) were recorded, as shown in Fig. 3 a. A broad and intense yellow RL band, peaking at 590 nm can be observed, suggesting the RL originates from the emission of hybrid excitons. The RL spectrum, resembling that of ZnO QDs measured at 80 K but with a 15 nm red-shift in peak position compared to the PL spectrum measured at 300 K, implies the pivotal involvement of triplet excitons in the ZnO QDs scintillator. Figure 3 b and Figure S20 illustrate the X-ray photon absorption coefficient of ZnO QD glassy scintillator (highest atomic number Z max = 30, Kα = 8.6 keV) as a function of thickness at an X-ray photon energy of 10–50 keV 39 . It can be found that the ZnO QD scintillator can absorb 90% of the X-ray photon energy at a thickness of 500 µm. Thus, it is reasonable to expect that the hybrid singlet/triplets of the scintillator can be populated under the excitation of photons with energy ranging from a few hundred eV to a few hundred keV, particularly with a thickness over 500 µm. Besides, the high PL QY, transparency, zero self-absorption and intense light output of the ZnO QD scintillator can lead to a high scintillation light yield. The X-ray to light conversion efficiencies were measured, as shown in Fig. 3 c. The ZnO QD scintillator exhibits light conversion efficiencies of 18038 photons/MeV, presenting a more favorable performance compared to the widely used commercial bulk BGO scintillator 40 , 41 . Furthermore, the ZnO QD scintillator screen was assessed for its ability to absorb X-ray photons from all angles, as illustrated in Fig. 3 d. Tuning the X-ray source under a 360-degree circular motion to excite the scintillator, the RL intensity was measured with an optical fiber spectrometer, as shown in Fig. 3 e. The RL intensity shows a degree-dependent characteristic property, laying a solid foundation for the design of X-ray imaging applications. In addition, a comparative experiment with different detection angles approach shown in Figure S21 was designed. The intensity of the RL gradually increases as the irradiation angles increase from 0° to 90°, primarily attributed to the optical channel crosstalk, causing the reduction in the transmitted efficiency of the RL. Figure 3 f schematically shows the internal mechanism of the RL in ZnO QD scintillators. Upon X-ray irradiation, inner electrons are ejected from the atom and substantial hot electrons and holes can be created. Following X-ray irradiation, the ejected electrons subsequently inject into nearby QDs following a singlet/triplet ratio of 1:3. The remaining hot electrons then undergo relaxation through electron-photon interaction, following a singlet/triplet ratio of 0.63:0.37. The energy distribution spectra of the continuous X-ray sources, containing the characteristic X-ray peak and the bremsstrahlung, are shown in Fig. 3 g. The X-ray flux can be as high as 10 6 photons / (s*mrad 2 ), and the average photon energy increases from 6.85 keV to 16.03 keV as the operating voltage increases from 10 kV to 45 kV. In Fig. 3 h, the RL intensity of the ZnO QD scintillator shows a significant enhancement with increasing voltage, indicating an effective X-ray photons conversion to visible photons. The integrated RL intensity of the ZnO QD scintillator shown in Fig. 3 i presents an excellent linear response to the X-ray dose rates in a large range from 38.4 nGy s − 1 to 900 µGy s − 1 . A low detection limit of 38.4 nGy s⁻¹ for this transparent ZnO QDs glassy scintillator can be derived from the fitting curve when the signal-to-noise ratio is 3, which is lower than the typical medical imaging dose (5.5 µGy s − 1 ) 42–44 . The RL intensity of the ZnO QD scintillator can remain constant after working for 40 days (Figure S22). The photostability was further examined under continuous or repeated cycles of X-ray illumination, and it can be activated repeatedly with no obvious decrease, indicating the good photostability of the ZnO QD scintillator as shown in Fig. 3 j. In addition, Figure S23 shows the cost analysis of the ZnO QD scintillator compared to other widely reported scintillators. The lower cost and ease of preparation of the ZnO QD scintillator may arouse intense interest in its commercial competitiveness in view of the scintillator application. Regarding the excellent RL performance, highly transparence, and large size of the ZnO QD scintillator, we next implemented X-ray imaging with the ZnO QD scintillator as an imaging screen, and the corresponding imaging setup is illustrated in Fig. 4 a. The RL intensity exhibits a notable increase with the growing thickness of the ZnO QD scintillator, while the transmittance remains 90% at 1 mm. The spatial resolution ZnO QD glassy scintillator with 1 mm for X-ray imaging was assessed by using an X-ray standard test pattern panel consisting of lines with widths ranging from 1 to 30 lp mm − 1 . The X-ray imaging of the linear mask closely mirrored the corresponding optical image, as revealed on the ZnO QD scintillator screen (left of Fig. 4 b). Lines with a width of 16 µm can be clearly resolved (right of Fig. 4 b), demonstrating a spatial resolution of 30 lp mm − 1 . Note that the modulation transfer function (MTF) provides a spatial resolution of 42 lp mm − 1 at the value of 0.2 (Fig. 4 c), and the clear internal structure of a chip can be observed, as shown in the inset of Fig. 4 c. The spatial resolution is much higher than the recently reported scintillator screens, such as CsPbBr 3 (12.5 lp mm − 1 ) 45 , Cs 3 Cu 2 I 5 (6.8 lp mm − 1 ) 46 , lanthanide-doped nanoscintillators (25 lp mm − 1 ) 47 and so on. This is attributed to the superior transparency and excellent RL performance of the ZnO QD scintillator. Subsequently, we evaluated the feasibility of sizable ZnO QD scintillator screen (3600 cm 2 ) for X-ray imaging in safety inspection. The X-ray images of a backpack with various samples (bearings, pliers, knife, earphones, scissor) were monitored, as shown in Fig. 4 d. The outline of the internal objects can be distinctly observed, and the color variations were a result of their differences in X-ray absorptions. The internal structures of a small computer mouse can be observed using the sizable scintillator (Figure S24a), indicating the ability for objects of various sizes. The ZnO QD scintillator can also be employed for imaging the internal structure of a finger (Fig. 4 e) and a moving finger (Figure S24b). Obvious biological tissue phase contrast and clear joint details can be observed in the randomly selected X-ray images at different time points. Moreover, the feasibility of large-area medical single-scan X-ray imaging was explored, the optical image and pseudo-color images are shown in Fig. 4 f. The original X-ray images are shown in Figure S24c, the internal biological tissue and bones of the pork ribs were observed under high X-ray photon energy. Subsequently, the details of the broken bone joint were analyzed, and obvious increases in gray value in the fractured area can be observed, as further revealed by the magnified images in the inset. In our case, large-area X-ray imaging can cover an expansive area of 2500 cm 2 through a single scan, representing a record for a single large-area X-ray imaging scan to date to the best of our knowledge. In addition, real-time X-ray dynamic imaging (24 frames per second) was demonstrated, and the corresponding sketch map is illustrated in Fig. 4 g. The twelve Chinese zodiac characters exhibit clear identification of sharp edges without the ghosting effect in the captured photos at different time intervals, attributed to the fast response of the ZnO QD scintillator (Fig. 4 h). The sizable ZnO QD scintillator, exhibits efficient conversion of X-ray photons into visible light, characterized by high transparency, notable RL performance, and superior spatial resolution, rendering it suitable for diverse applications in X-ray imaging and safety inspection at a low cost. In conclusion, the sizable ZnO QD glassy scintillator featuring singlet/triplet hybrid STEs was demonstrated through a disordered assembly technique, with the aim of achieving high-resolution X-ray imaging for large objects. Compared to the way of QDs coupled with the organic polymer and conventional Czochralski method, the key attributes of the ZnO QD glassy scintillator are room temperature solution-based large-area synthesis, high QD loading, relatively low toxicity, high transparency, and robust RL. Importantly, our work has efficiently harnessed the X-ray-induced generation of hybrid STE, not only showcasing the potential for enhanced RL performance but also laying the foundation for the design of innovative scintillators. Moreover, the successful creation of a large transparent ZnO QD glassy scintillator, measuring 1 m * 0.5 m and with 96% transparency, represents a significant stride forward. This scintillator enables high-resolution (42 lp mm − 1 ), low-dose (38.47 nGy s − 1 ), large-area (5000 cm 2 ), and real-time X-ray imaging. This glassy scintillator route may help redefine the paradigm for QD-based scintillator manufacturing, which not only provides a versatile approach for the preparation of QD scintillators but also may open a series of exciting applications for advancing radiation detection and medical imaging. Declarations Acknowledgements This work is supported by the National Natural Science Foundation of China (Grant Nos. 62075198, 11974317, 61804136) and the Outstanding Youth Foundation of Henan (Grant nos. 222300420087). We express gratitude to H. Zeng and J. G. W for their technical assistance and thank the Ultrafast X-ray Dynamic Experimental Station at the Synergetic Extreme Condition User Facility in China. Competing interests The authors declare no competing interests. Methods Materials All the chemicals were purchased from Aladdin Chemistry Co. and they were all analytical grade: Zinc acetate dihydrate (Zn (Ac) 2 ∙ 2H 2 O), potassium hydroxide (KOH), (3-aminopropyl) triethoxysilane (APTES) were purchased from Aladdin Chemistry Co. Ltd. (Shanghai, China). The source of absolute ethanol was Tianjin Kaitong Chemical Reagent Co. Ltd. (Tianjin, China). Synthesis of the ZnO QDs In the first step, 923.7 g Zn(Ac) 2 ∙ 2H 2 O and 343.3 g KOH were dispersed in 20 L and 5 L of pure ethanol. Subsequently, the KOH solution was added into the Zn(Ac) 2 ∙ 2H 2 O solution followed by continuous stirring for 2 h. The complex solution above was filled with 66.5 mL APTES and stirred continuously for 8 hours. The precipitate was centrifuged and washed with absolute ethanol three times. Eventually, ZnO nanocrystals were obtained after drying in a blast oven at 70 o C for 12 h. Growth of the ZnO QD glassy scintillator In a typical procedure, the ZnO QDs, are dispersed in water (1:2 by mass) and sonicated for 30 min to ensure its homogeneity. The resulting composites were degassed in a vacuum container to remove air bubbles. The viscous mixture solution was carefully coated on the quartz plates (or poured into a round plastic plate (9 × 9 cm 2 )) for glassy scintillator fabrication. The solution was poured into a square glass plate (100 cm* 50 cm) for meter-scale glassy scintillator fabrication. The mixture solution was finally heated at 45 °C for 6 h. After cooling to room temperature, the as-fabricated glassy scintillator was used for X-ray imaging. The light transmittance (T) of the ZnO QD glassy scintillator calculations Rayleigh cross section was calculated following the equation: Physical characterization Transmission Electron Microscope (TEM) images were measured on TEM (TecnaiG2 F20 S-TWIN) at 200-kV acceleration voltage to characterize the microstructures of all the ZnO QDs. FTIR spectra were recognized on an FTIR (Nicolet 6700) spectrometer. XRD patterns were collected with a Smartlab X-ray diffractometer (Rigaku, Japan) using Cu Kα radiation. XPS patterns were obtained using an X-ray photoelectron spectrometer to measure the bonding state of the QDs. The cross-section and surface of the ZnO QDs glassy scintillator were observed by a JSM-6700F (JEOL, Japan) field emission scanning electron microscope (FESEM). Special Aberration Corrected Transmission Electron Microscope (AC-TEM) images of the ZnO QD glassy scintillator were measured by transmission electron microscope (FEI Talos F200) under an acceleration voltage of 200 kV. Photographs of X-ray-induced luminescence and radioluminescence-based X-ray imaging were acquired with a digital camera (Canon EOS 5D Mark IV) in an all-manual mode. Optical characterization The fluorescence spectra and excitation-emission spectra of the ZnO QDs were measured on an Edinburgh FLS1000 fluorescence spectrophotometer. Ultraviolet-visible (UV–vis) absorption and transmittance spectra of the ZnO QDs were obtained using Hitachi UH 4150 UV–vis spectrophotometers, respectively. The lifetimes, kinetic measurements, and time-resolved emission spectra were measured using an Edinburgh FLS1000 fluorescence spectrophotometer equipped with a microsecond flash-lamp (uF2), a xenon arc lamp (Xe2), and a nanosecond hydrogen flashlamp (nF920), respectively. The temperature-dependent spectra of the samples were measured using an FLS1000 spectrophotometer equipped with temperature control instruments (Advanced Research Systems) at various temperatures from 317 to 12 K. Absolute photoluminescence quantum-yield measurements at room temperature were performed on an FLS1000 spectrometer with calibrated integrating sphere. For the transient absorption spectrum measurements, a regeneratively amplified femtosecond Ti: Sapphire laser system (150 fs, 1 kHz) was employed. In this system, a 280 nm pump pulse was focused on the samples through an automated TOPAS Optical Parametric Amplifier (OPA). Then, the probe beam was focused and passed through the sample by an Al parabolic reflector. After passing through the sample, the transmission changes of the probe light were detected by a fiber spectrometer. And the absorbance change of the sample was calculated with two adjacent probe pulses. 50 mg mL −1 ZnO QDs solution was selected to measure the transient absorption spectrum. Radioluminescence measurement for the ZnO QD glassy scintillator The measurement of X-ray-induced luminescence was performed using a solid ZnO QD glassy scintillator. The radioluminescence spectra were recorded using an Edinburgh FLS-1000 fluorescence spectrophotometer with a miniature X-ray source. The 360-degree omnidirectional radiation detection radioluminescence spectra were measured through our home-built X-ray imaging system including the rotating test platform with an optical fiber spectrometer. Large-area X-ray imaging and dynamic X-ray imaging The large area X-ray scintillation detector was constructed by preparing of meter-scale ZnO QD glassy scintillator with a layer thickness of 800 μm. In order to maximize the collection of visible photons, the ZnO QD glassy scintillator was coupled with a normal digital camera. For X-ray imaging, a backpack filled with different samples (bearings, pliers, knife, earphones, scissor) and a broken pork rib were utilized. Dynamic X-ray imaging was achieved using mechanical Chinese character turntables as imaging objects that were equipped with a glassy scintillator. The objects and the ZnO QD scintillator wafers were arranged vertically before the incident X-rays, with the scintillators anchored directly behind them. The object's speed of rotation is 300 cm/s and its record rate is 99 frames per second. References Kim, Y. C. et al. Printable organometallic perovskite enables large-area, low-dose X-ray imaging. Nature 550 , 87-91 (2017). Yi, L., Hou, B., Zhao, H. & Liu, X. X-ray-to-visible light-field detection through pixelated colour conversion. Nature 618 , 281-286 (2023). Yaffe, M. J. & Rowlands, J. A. X-ray detectors for digital radiography. Phys. Med. Biol. 42, 1–39 (1997). Zhao, J. et al. Perovskite-filled membranes for flexible and large-area direct-conversion X-ray detector arrays. Nat. Photon. 14 , 612-617 (2020). Roques-Carmes, C. et al. A framework for scintillation in nanophotonics. Science 375 , eabm9293 (2022). Li, B. et al. Zero‐dimensional luminescent metal halide hybrids enabling bulk transparent medium as large‐area X‐ray scintillators. Adv. Opt. Mater. 10 , 2102793 (2022). Kakavelakis, G. et al. Metal halide perovskites for high-energy radiation detection. Adv. Sci. 7 , 2002098 (2020). Hou, B. et al. A swallowable X-ray dosimeter for the real-time monitoring of radiotherapy. Nat. Biomed. Eng. , 7, 1242–1251 (2023). Wang, X. et al. Organic phosphorescent nanoscintillator for low-dose X-ray-induced photodynamic therapy. Nat. Commun. 13 , 5091 (2022). Zhou, X. et al. Energy-trapping management in X-ray storage phosphors for flexible 3D imaging. Adv. Mater. 35 , e2212022 (2023). Xu, L. J., Lin, X., He, Q., Worku, M. & Ma, B. Highly efficient eco-friendly X-ray scintillators based on an organic manganese halide. Nat. Commun. 11 , 4329 (2020). Zhang, F. et al. Thermally activated delayed fluorescence zirconium-based perovskites for large-area and ultraflexible X-ray scintillator screens. Adv. Mater. 34 , e2204801 (2022). Zhou, Y. et al. Large-area perovskite-related copper halide film for high-resolution flexible X-ray imaging scintillation screens. ACS Energy Lett. 7 , 844-846 (2022). Zaffalon, M. L. et al. Extreme γ-ray radiation hardness and high scintillation yield in perovskite nanocrystals. Nat. Photon. 16 , 860-868 (2022). Fraboni, B., Fraleoni-Morgera, A. & Zaitseva, N. Ionizing radiation detectors based on solution-grown organic single crystals. Adv. Funct. Mater. 26 , 2276-2291 (2016). Weber, M. J. Inorganic scintillators: today and tomorrow. J. Lumin. 100, 35–45 (2002). Wu, H., Ge, Y., Niu, G. & Tang, J. Metal halide perovskites for X-ray detection and imaging. Matter 4 , 144-163 (2021). Yang, B. et al. Lead-free halide Rb 2 CuBr 3 as sensitive X-ray scintillator. Adv. Mater. 31 , e1904711 (2019). Morad, V. et al. Disphenoidal zero-dimensional lead, tin, and germanium halides: highly emissive singlet and triplet self-trapped excitons and X-ray scintillation. J. Am. Chem. Soc. 141 , 9764-9768 (2019). Chen, Q. et al. All-inorganic perovskite nanocrystal scintillators. Nature 561 , 88-93 (2018). Hirata, S. et al. Highly efficient blue electroluminescence based on thermally activated delayed fluorescence. Nat. Mater . 14 , 330-336 (2015). Wang, J.-X. et al. Heavy-atom engineering of thermally activated delayed fluorophores for high-performance X-ray imaging scintillators. Nat. Photon. 16 , 869-875 (2022). Dong, C. et al. Influence of isomerism on radioluminescence of purely organic phosphorescence scintillators. Angew. Chem. Int. Ed. 60 , 27195-27200 (2021). Wang, X. et al. Organic phosphors with bright triplet excitons for efficient X-ray-excited luminescence. Nat. Photon. 15 , 187-192 (2021). Ma, W. et al. Thermally activated delayed fluorescence (TADF) organic molecules for efficient X-ray scintillation and imaging. Nat. Mater. 21 , 210-216 (2022). Tang, L. et al. X-ray excited ultralong room-temperature phosphorescence for organic afterglow scintillators. Chem. Commun. 56 , 13559-13562 (2020). Zhang, X., Shi, Y., Wang, X., Liu, Y. & Zhang, Y. Flexible and transparent ceramic nanocomposite for laboratory X-ray imaging of micrometer resolution. ACS Nano 16, 21576-21582 (2022). Ma, W. et al. Highly Resolved and robust dynamic X-ray imaging using perovskite glass-ceramic scintillator with reduced light scattering. Adv. Sci. 8 , e2003728 (2021). Han, K. et al. Seed-crystal-induced cold sintering toward metal halide transparent ceramic scintillators. Adv. Mater. 34 , e2110420 (2022). Jana, A., Park, S., Cho, S., Kim, H. & Im, H. Bounce back with triplet excitons for efficient X-ray scintillation. Matter 5 , 20-22 (2022). Pei, P. et al. X-ray-activated persistent luminescence nanomaterials for NIR-II imaging. Nat. Nanotechnol. 16 , 1011-1018 (2021). Rayleigh, L. XXXIV. On the transmission of light through an atmosphere containing small particles in suspension, and on the origin of the blue of the sky. London, Edinburgh, Dublin Philos. Mag. J. Sci. 47, 375−384 (1899). Dorum, H. P.; Aksnes, E.; Nilsson, S.; Bjorholt, P. G. Light scattering theory. Tidsskr. den Nor. Laegeforening 100, 1−13 (1980). Zhou, R. et al. Multiphoton excited singlet/triplet mixed self-trapped exciton emission. Nat. Commun. 14 , 1310 (2023). Luo, J. et al. Efficient and stable emission of warm-white light from lead-free halide double perovskites. Nature 563 , 541-545 (2018). Hamze, R. et al. Eliminating nonradiative decay in Cu(I) emitters: >99% quantum efficiency and microsecond lifetime. Science 363, 601–606 (2019). Han, Z. et al. Ultrastable atomically precise chiral silver clusters with more than 95% quantum efficiency. Sci. Adv. 6, eaay0107 (2020). Liu, S. et al. Efficient thermally activated delayed fluorescence from all-inorganic cesium zirconium halide perovskite nanocrystals. Angew. Chem. Int. Ed. 59 , 21925-21929 (2020). Berger, M. J. et al. XCOM: Photon Cross Sections Database; https://www.nist.gov/ pml/xcom-photon-cross-sections-database (2013). Zhu, W. et al. Low-dose real-time X-ray imaging with nontoxic double perovskite scintillators. Light Sci. Appl. 9 , 112 (2020). Wang, Y. et al. Efficient X-ray luminescence imaging with ultrastable and eco-friendly copper(I)-iodide cluster microcubes. Light Sci. Appl. 12 , 155 (2023). Haruta, Y. et al. Scalable fabrication of metal halide perovskites for direct X-ray flat-panel detectors: a perspective. Chem. Mater. 34 , 5323-5333 (2022). Li, Z. et al. Halide perovskites for high-performance X-ray detector. Mater. Today 48 , 155-175 (2021). Wang, B. et al. Template assembled large‐Size CsPbBr 3 nanocomposite films toward flexible, stable, and high‐performance X‐ray scintillators. Laser Photonics Rev. 16 , 2100736 (2022). Chen, W. et al. All‐inorganic perovskite polymer–ceramics for flexible and refreshable X‐ray imaging. Adv. Funct. Mater. 32 , 2107424 (2021). Li, N. et al. Flexible, high scintillation yield Cu 3 Cu 2 I 5 film made of ball‐milled powder for high spatial resolution X‐ray imaging. Adv. Opt. Mater. 10 , 2102232 (2022). Ou, X. et al. High-resolution X-ray luminescence extension imaging. Nature 590 , 410-415 (2021). Additional Declarations There is NO Competing Interest. Supplementary Files Supportinformarion.docx Supplementary and additional information Cite Share Download PDF Status: Under Review Version 1 posted You are reading this latest preprint version Research Square lets you share your work early, gain feedback from the community, and start making changes to your manuscript prior to peer review in a journal. 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Also discoverable on Platform About Our Team In Review Editorial Policies Advisory Board Help Center Resources Author Services Accessibility API Access RSS feed Manage Cookie Preferences © Research Square 2026 | ISSN 2693-5015 (online) Privacy Policy Terms of Service Do Not Sell My Personal Information {"props":{"pageProps":{"initialData":{"identity":"rs-3942722","acceptedTermsAndConditions":true,"allowDirectSubmit":false,"archivedVersions":[],"articleType":"Article","associatedPublications":[],"authors":[{"id":274141452,"identity":"edaa30bb-67be-48a8-8dfd-91ba634d6acf","order_by":0,"name":"Kai-Kai Liu","email":"data:image/png;base64,iVBORw0KGgoAAAANSUhEUgAAAZAAAAAyAQMAAABI0h/eAAAABlBMVEX///8AAABVwtN+AAAACXBIWXMAAA7EAAAOxAGVKw4bAAAA20lEQVRIiWNgGAWjYBACPmYGZgYGgwQGNvYGsABjAyEtbHAtPAeI1cIA0sKQwMAgkUCsFnYeY4MfBWnyfJLPH3/mYbCR3XCA+dkD/A7jMU7sMcgxbJNOSDDmYUgz3nCAzdyAkJYDPAYVjEAtB5J5GA4nbjjAwyZBSMvBPwYV9m2SBxsO8zD8J05LMo9BTmKbBDNjMw/DAWK0sBUbyxikJbfxpDEzzjFINp55mM0MrxZ+/sObJd/8Sbad33788Yc3FXayfcebn+HVggZAQcVMgvpRMApGwSgYBdgBADnKO3ztD2tAAAAAAElFTkSuQmCC","orcid":"","institution":"Zhengzhou University","correspondingAuthor":true,"prefix":"","firstName":"Kai-Kai","middleName":"","lastName":"Liu","suffix":""},{"id":274141453,"identity":"095700a9-6aa4-4780-b9bf-522114b443dd","order_by":1,"name":"Shi-Yu Song","email":"","orcid":"","institution":"Zhengzhou University","correspondingAuthor":false,"prefix":"","firstName":"Shi-Yu","middleName":"","lastName":"Song","suffix":""},{"id":274141454,"identity":"a95cf9bc-b6ce-4d44-adac-1566bcf3f423","order_by":2,"name":"Chao-Jun Gao","email":"","orcid":"","institution":"Zhengzhou University","correspondingAuthor":false,"prefix":"","firstName":"Chao-Jun","middleName":"","lastName":"Gao","suffix":""},{"id":274141455,"identity":"362a45fe-84e6-4652-bb51-dd5a9cc48e6a","order_by":3,"name":"Rui Zhou","email":"","orcid":"","institution":"Zhengzhou University","correspondingAuthor":false,"prefix":"","firstName":"Rui","middleName":"","lastName":"Zhou","suffix":""},{"id":274141456,"identity":"d20768cb-eb9b-4d43-b410-1d835bb7a903","order_by":4,"name":"Bingzhe Wang","email":"","orcid":"","institution":"Institute of Applied Physics and Materials Engineering,University of Macau","correspondingAuthor":false,"prefix":"","firstName":"Bingzhe","middleName":"","lastName":"Wang","suffix":""},{"id":274141457,"identity":"b2cebac0-3085-4a69-b777-82badad62ffd","order_by":5,"name":"Wen-Bo Zhao","email":"","orcid":"","institution":"Zhengzhou University","correspondingAuthor":false,"prefix":"","firstName":"Wen-Bo","middleName":"","lastName":"Zhao","suffix":""},{"id":274141458,"identity":"6d60eab1-17b2-4ad4-8c2c-abf17a0ee085","order_by":6,"name":"Qing Cao","email":"","orcid":"","institution":"Zhengzhou University","correspondingAuthor":false,"prefix":"","firstName":"Qing","middleName":"","lastName":"Cao","suffix":""},{"id":274141459,"identity":"e99d6d50-6a4f-47d5-8101-aec52009aa57","order_by":7,"name":"Yan-Wei Hu","email":"","orcid":"","institution":"Zhengzhou University","correspondingAuthor":false,"prefix":"","firstName":"Yan-Wei","middleName":"","lastName":"Hu","suffix":""},{"id":274141460,"identity":"945fe184-bcb8-4afc-8e5e-7be89e340dab","order_by":8,"name":"Lin Dong","email":"","orcid":"https://orcid.org/0000-0002-4126-6812","institution":"Zhengzhou University","correspondingAuthor":false,"prefix":"","firstName":"Lin","middleName":"","lastName":"Dong","suffix":""},{"id":274141461,"identity":"9c53f4cd-7c43-4a3e-b6fb-7d27fa3c414f","order_by":9,"name":"Chong-Xin Shan","email":"","orcid":"https://orcid.org/0000-0001-7119-5325","institution":"Henan Key Laboratory of Diamond Optoelectronic Materials and Devices, School of Physics and Engineering, Zhengzhou University","correspondingAuthor":false,"prefix":"","firstName":"Chong-Xin","middleName":"","lastName":"Shan","suffix":""}],"badges":[],"createdAt":"2024-02-09 10:35:22","currentVersionCode":1,"declarations":"","doi":"10.21203/rs.3.rs-3942722/v1","doiUrl":"https://doi.org/10.21203/rs.3.rs-3942722/v1","draftVersion":[],"editorialEvents":[],"editorialNote":"","failedWorkflow":false,"files":[{"id":52041809,"identity":"dbc3bb94-3c3f-4da8-b9a1-c5677a29ca1c","added_by":"auto","created_at":"2024-03-05 18:21:25","extension":"png","order_by":1,"title":"Figure 1","display":"","copyAsset":false,"role":"figure","size":621243,"visible":true,"origin":"","legend":"\u003cp\u003e\u003cstrong\u003eIllustrations of design, structures, and mechanism of the scintillator. a,\u003c/strong\u003e Image of a meter-scale (1 m * 0.5 m) transparent scintillator through the disordered assembly of the ZnO QDs (left, UV and X-ray excitation; right, bright-field image). \u003cstrong\u003eb,\u003c/strong\u003e Schematic representation of exchange invariance in the scintillator. The application of exchange operator \u003cem\u003eP\u003c/em\u003e ensures the preservation of the scintillator’s optical properties. \u003cstrong\u003ec,\u003c/strong\u003e Schematic diagram of the internal structure of the scintillator. \u003cstrong\u003ed\u003c/strong\u003e, The simulated light transmittance spectrum of the scintillator with numerical parameter settings (d = 30 μm, \u003cem\u003en\u003c/em\u003e\u003csub\u003e\u003cem\u003ep\u003c/em\u003e\u003c/sub\u003e = 2.008, \u003cem\u003en\u003c/em\u003e\u003csub\u003e\u003cem\u003em\u003c/em\u003e\u003c/sub\u003e\u003cem\u003e \u003c/em\u003e= 1.6), the insert images are the TEM image and the high-resolution TEM image of the ZnO QDs.\u003cstrong\u003e e,\u003c/strong\u003e Transmission spectrum of the scintillator. High transparency can be observed in the visible region, (insert: a 5 cm diameter ZnO QD scintillator of 300 μm in thickness).\u003cstrong\u003e f, \u003c/strong\u003eTime-dependent ESR signal of ZnO QDs (top), PL decay curves of the ZnO QDs under 375 nm excitation (bottom). \u003cstrong\u003eg, \u003c/strong\u003eSchematic diagram of the X-ray induced scintillation process in the ZnO QD scintillator.\u003c/p\u003e","description":"","filename":"1.png","url":"https://assets-eu.researchsquare.com/files/rs-3942722/v1/6206dffe8af851d54052bfc8.png"},{"id":52041813,"identity":"061e847c-33a7-4b77-a2e2-d60b23fba858","added_by":"auto","created_at":"2024-03-05 18:21:26","extension":"png","order_by":2,"title":"Figure 2","display":"","copyAsset":false,"role":"figure","size":349254,"visible":true,"origin":"","legend":"\u003cp\u003e\u003cstrong\u003eInvestigation luminescence mechanism for singlet/triplet hybrid excitons. a,\u003c/strong\u003e Schematic diagram of the generation of STEs in ZnO QDs upon photoexcitation.\u003cstrong\u003e b, \u003c/strong\u003eThe PL intensity signal as a function of the intensity of the laser power. \u003cem\u003eR\u003c/em\u003e\u003csup\u003e2\u003c/sup\u003e\u003csub\u003eAdjusted\u003c/sub\u003e = 0.996, for emission at 575 nm. \u003cstrong\u003ec, \u003c/strong\u003ePL decay curves of the ZnO QDs at the selected wavelength from 450 nm to 570 nm.\u003cstrong\u003e d,\u003c/strong\u003e Temperature-dependent PL lifetime decay spectra for the ZnO QDs. \u003cstrong\u003ee, \u003c/strong\u003eTA contour maps of ZnO OQs between 20 fs to 7.5 ns under 280 nm excitation. \u003cstrong\u003ef, \u003c/strong\u003eTA spectra collected at the indicated time from 1 to 5000 ps.\u003cstrong\u003e g,\u003c/strong\u003e TA kinetic processes were probed at 345 nm, 360 nm, and 520 nm. The data were fitted using a biexponential decay model. \u003cstrong\u003eh,\u003c/strong\u003e Species-associated difference spectra by the global analysis fitting. \u003cstrong\u003ei, \u003c/strong\u003eSchematic diagram of the singlet/triplet hybrid STE emission process in the ZnO QDs.\u003c/p\u003e","description":"","filename":"2.png","url":"https://assets-eu.researchsquare.com/files/rs-3942722/v1/56d708555ccf45226a72e0ab.png"},{"id":52041810,"identity":"e01a0a84-c224-4bf2-b52f-1e18a11e0b61","added_by":"auto","created_at":"2024-03-05 18:21:25","extension":"png","order_by":3,"title":"Figure 3","display":"","copyAsset":false,"role":"figure","size":388604,"visible":true,"origin":"","legend":"\u003cp\u003e\u003cstrong\u003eInvestigation of singlet/triplet hybrid STEs emission upon X-ray excitation. a, \u003c/strong\u003eNormalized PL at 80 K and 300 K, and RL spectra of the ZnO QD glassy scintillator.\u003cstrong\u003e b,\u003c/strong\u003e X-ray attenuation efficiencies of ZnO QD glassy scintillator versus varied thicknesses, from 10 keV to 50 keV. \u003cstrong\u003ec,\u003c/strong\u003e Normalized RL spectra of the ZnO QD glassy scintillator, CsI: Tl and Bi\u003csub\u003e4\u003c/sub\u003eGe\u003csub\u003e3\u003c/sub\u003eO\u003csub\u003e12 \u003c/sub\u003e(BGO).\u003cstrong\u003e d, \u003c/strong\u003eSchematic diagram showing omnidirectional radiation detection. \u003cstrong\u003ee,\u003c/strong\u003e The light intensity in different directions (0-360 degrees) at the same dose rate. \u003cstrong\u003ef, \u003c/strong\u003eIllustration of the mechanism in the formation of multiple excited charge carriers in ZnO QDs. \u003cstrong\u003eg,\u003c/strong\u003e X-ray photon energy spectra generated at accelerating voltage from 10 kV to 45 kV.\u003cstrong\u003e h, \u003c/strong\u003eRL spectra of ZnO QDs under different X-ray photons, the insets are the corresponding images. \u003cstrong\u003ei,\u003c/strong\u003e The dose rate dependence of the RL intensity of ZnO QDs. The detection limit of 38.4 nGy s\u003csup\u003e−1\u003c/sup\u003e is derived from the slope of the fitting line, with a signal-to-noise ratio of 3. \u003cstrong\u003ej,\u003c/strong\u003e The emission photostability at a peak of 575 nm for the ZnO QDs versus continuous irradiation (top) and repeated on–off cycles of X-rays (bottom).\u003c/p\u003e","description":"","filename":"3.png","url":"https://assets-eu.researchsquare.com/files/rs-3942722/v1/13915c05829351cd39fe84ed.png"},{"id":52041812,"identity":"6145680d-d93e-4696-83a9-c1ae28672e5b","added_by":"auto","created_at":"2024-03-05 18:21:26","extension":"png","order_by":4,"title":"Figure 4","display":"","copyAsset":false,"role":"figure","size":692030,"visible":true,"origin":"","legend":"\u003cp\u003e\u003cstrong\u003eHigh-resolution and large-area X-ray imaging utilizing ZnO QD glassy scintillator. a,\u003c/strong\u003e Schematic diagram of the experimental setup used for X-ray imaging of samples. \u003cstrong\u003eb, \u003c/strong\u003ePhotograph of the standard X-ray test-pattern plate. X-ray images of the test-pattern plate based on ZnO QD glassy scintillator (X-ray tube voltage: 40 kV).\u003cstrong\u003e c, \u003c/strong\u003eSpatial resolution of the X-ray imaging system, characterized by the modulation transfer function. The spatial resolution of the ZnO QD glassy scintillator is 30 lp mm\u003csup\u003e−1\u003c/sup\u003e at MTF = 0.4 and 42 lp mm\u003csup\u003e-1\u003c/sup\u003e at MTF = 0.2. Insert: photographs of the test chip and the corresponding X-ray image. \u003cstrong\u003ed,\u003c/strong\u003e Bright- (left) and dark-field (right) photographs of the backpack, recorded before and after X-ray exposure.\u003cstrong\u003e e, \u003c/strong\u003eX-ray image of the finger. \u003cstrong\u003ef,\u003c/strong\u003e X-ray images of broken pork rib using the large area ZnO QD scintillator. \u003cstrong\u003eg, \u003c/strong\u003eSchematic diagram of the experimental setup used for real-time X-ray imaging. \u003cstrong\u003eh,\u003c/strong\u003e Dynamic X-ray images of twelve patterns.\u003c/p\u003e","description":"","filename":"4.png","url":"https://assets-eu.researchsquare.com/files/rs-3942722/v1/cdfbe80be99fd443753bb810.png"},{"id":52042126,"identity":"ccdcc410-ecaa-4743-aab3-abbe6cd2c540","added_by":"auto","created_at":"2024-03-05 18:29:27","extension":"pdf","order_by":0,"title":"","display":"","copyAsset":false,"role":"manuscript-pdf","size":2474711,"visible":true,"origin":"","legend":"","description":"","filename":"manuscript.pdf","url":"https://assets-eu.researchsquare.com/files/rs-3942722/v1/a70fc1d2-472e-47b0-8c94-fd5a7fe263a8.pdf"},{"id":52041811,"identity":"ab4f6ef3-805f-4093-91e7-b2c46e009c3d","added_by":"auto","created_at":"2024-03-05 18:21:26","extension":"docx","order_by":1,"title":"","display":"","copyAsset":false,"role":"supplement","size":38115668,"visible":true,"origin":"","legend":"Supplementary and additional information","description":"","filename":"Supportinformarion.docx","url":"https://assets-eu.researchsquare.com/files/rs-3942722/v1/358656c469b71c9143c81200.docx"}],"financialInterests":"There is \u003cb\u003eNO\u003c/b\u003e Competing Interest.","formattedTitle":"Scalable Glassy X-Ray Scintillators with Bright Singlet-Triplet Hybrid Self-Trapping Excitons","fulltext":[{"header":"Introduction","content":"\u003cp\u003eThe interaction of X-ray photons with luminescent materials induces their emission of photons in the visible region, playing a key role in high-energy X-ray nondestructive detection and imaging\u003csup\u003e\u003cspan additionalcitationids=\"CR2 CR3 CR4\" citationid=\"CR1\" class=\"CitationRef\"\u003e1\u003c/span\u003e\u0026ndash;\u003cspan citationid=\"CR5\" class=\"CitationRef\"\u003e5\u003c/span\u003e\u003c/sup\u003e. Sizable scintillators with high transparency and robust photon yield enhance precision imaging of large objects, contributing to advancements in medical diagnostics\u003csup\u003e\u003cspan additionalcitationids=\"CR7 CR8\" citationid=\"CR6\" class=\"CitationRef\"\u003e6\u003c/span\u003e\u0026ndash;\u003cspan citationid=\"CR9\" class=\"CitationRef\"\u003e9\u003c/span\u003e\u003c/sup\u003e, industrial inspection\u003csup\u003e\u003cspan additionalcitationids=\"CR11 CR12\" citationid=\"CR10\" class=\"CitationRef\"\u003e10\u003c/span\u003e\u0026ndash;\u003cspan citationid=\"CR13\" class=\"CitationRef\"\u003e13\u003c/span\u003e\u003c/sup\u003e, and so on. The challenge lies in producing efficient large-area scintillators with high transparency, including traditional scintillators generated via the Czochralski method and emerging perovskite scintillators generated via chemical methods\u003csup\u003e\u003cspan additionalcitationids=\"CR15 CR16\" citationid=\"CR14\" class=\"CitationRef\"\u003e14\u003c/span\u003e\u0026ndash;\u003cspan citationid=\"CR17\" class=\"CitationRef\"\u003e17\u003c/span\u003e\u003c/sup\u003e. Small Stokes shift and strong self-absorption effect could greatly decrease the efficiency of light out-coupling of the perovskite scintillator\u003csup\u003e\u003cspan additionalcitationids=\"CR19\" citationid=\"CR18\" class=\"CitationRef\"\u003e18\u003c/span\u003e\u0026ndash;\u003cspan citationid=\"CR20\" class=\"CitationRef\"\u003e20\u003c/span\u003e\u003c/sup\u003e. The high toxicity and poor stability of lead components and heavy metal elements should be considered in practical applications. When X-ray photons bombard the inner-shell electrons of atoms of the luminescent materials, a tremendous number of high energy electrons through photon-electron interaction and secondary electrons through electron-electron scattering and Auger processes, are generated. The non-equilibrium electrons undergo relaxation before they can emit photons, which result in electron\u0026ndash;hole pairs\u003csup\u003e\u003cspan citationid=\"CR5\" class=\"CitationRef\"\u003e5\u003c/span\u003e\u003c/sup\u003e. The ionized electrons follow a 1:3 ratio in singlet and triplet, determined by spin-statistical charge recombination\u003csup\u003e\u003cspan additionalcitationids=\"CR22\" citationid=\"CR21\" class=\"CitationRef\"\u003e21\u003c/span\u003e\u0026ndash;\u003cspan citationid=\"CR23\" class=\"CitationRef\"\u003e23\u003c/span\u003e\u003c/sup\u003e. In most cases, conventional and perovskite scintillators only emit photons from singlet excitons after being irradiated because of the dark nature of triplet excitons. Thus, when exposed to X-ray, the generated triplet excitons in these scintillators are useless and functionally irrelevant for scintillation.\u003c/p\u003e \u003cp\u003eEffectively utilizing triplet excitons presents an attractive way to enhance scintillation performance, especially in scintillators with fewer toxicant heavy metal elements. By chemically modifying the chromophores of thermally activated delayed fluorescence (TADF) and phosphoresce molecules with halogen atoms, there has been a significant enhancement in X-ray absorption cross-section while preserving the bright nature of triplet excitons, leading to outstanding scintillation performance\u003csup\u003e\u003cspan additionalcitationids=\"CR25\" citationid=\"CR24\" class=\"CitationRef\"\u003e24\u003c/span\u003e\u0026ndash;\u003cspan citationid=\"CR26\" class=\"CitationRef\"\u003e26\u003c/span\u003e\u003c/sup\u003e. Despite advancements, reported organic scintillators exhibit poor transparency in the visible region, resulting in strong light scattering of the X-ray-induced photons. High transparency scintillators could achieve good spatial resolution in X-ray imaging\u003csup\u003e\u003cspan additionalcitationids=\"CR28\" citationid=\"CR27\" class=\"CitationRef\"\u003e27\u003c/span\u003e\u0026ndash;\u003cspan citationid=\"CR29\" class=\"CitationRef\"\u003e29\u003c/span\u003e\u003c/sup\u003e. Additionally, the complex molecular design and synthesis processes result in limited production capacity, limiting the application of these materials in large-area, high-resolution X-ray imaging. Solution-processable QD scintillators emerge as highly promising candidates for efficient scintillation applications, although it has proven challenging to synthesize a monodispersed population of ultrasmall quantum dots and to retain their solution-phase properties during assembly into scintillator solids. Therefore, the exploration of novel large-size and transparent scintillators, characterized by bright triplet excitons holds significant importance for low-dose, high-resolution, and large-area X-ray imaging.\u003c/p\u003e \u003cp\u003eIn this study, a meter-scale scintillator with 96% transmittance in the visible region, is demonstrated through the disordered assembly of the ZnO QDs. Benefiting from the efficient utilization of bright singlet/triplet hybrid STEs in the scintillator, a photon yield of 18,038 photons/MeV is achieved under X-ray excitation. Importantly, we have achieved the high X-ray imaging resolution of 42 line pairs per millimeter (42 lp mm\u003csup\u003e\u0026minus;\u0026thinsp;1\u003c/sup\u003e) at a meter scale and the X-ray detectable dose rate of 38.4 nGy s\u003csup\u003e\u0026minus;\u0026thinsp;1\u003c/sup\u003e, surpassing most reported organic and conventional inorganic scintillators. Furthermore, we demonstrated a high-resolution and large-area (5000 cm\u003csup\u003e\u003cspan citationid=\"CR2\" class=\"CitationRef\"\u003e2\u003c/span\u003e\u003c/sup\u003e) X-ray imaging of a backpack and broken pork rib through a single scan, and real-time X-ray imaging was also achieved.\u003c/p\u003e"},{"header":"Results and discussion","content":"\u003cp\u003eSolution-processable QDs with strong X-ray absorption ability and bright triplet excitons are ideal candidates for novel highly efficient X-ray scintillators\u003csup\u003e\u003cspan class=\"CitationRef\"\u003e30\u003c/span\u003e,\u003cspan class=\"CitationRef\"\u003e31\u003c/span\u003e\u003c/sup\u003e. Here, the meter-scale transparent scintillator was constructed using approximately \u003cspan class=\"InlineEquation\"\u003e\u003cspan class=\"mathinline\"\u003e\\({10}^{21}\\)\u003c/span\u003e\u003c/span\u003e ZnO QDs as building blocks through disordered assembly process (Fig. \u003cspan class=\"InternalRef\"\u003e1\u003c/span\u003ea). The manufactured scintillator is 1 meter in length, 0.5 meter in width, and 0.5 mm in thickness, and its size is adjustable to suit various dimensions for practical applications through this method. The scintillator screen shows bright luminescence and radioluminescence (RL) when subjected to 365 nm UV light and X-ray light, and a world map beneath the scintillator is clearly visible in daylight. The scintillator comprises an ensemble of the quasi-identical ZnO QDs, namely the fact that the QDs of the same type are fundamentally indistinguishable from each other. In the scintillator, there are n QD labeled with numbers r\u003csub\u003e1\u003c/sub\u003e, r\u003csub\u003e2\u003c/sub\u003e, ..., r\u003csub\u003en\u003c/sub\u003e, the optical performance (\u003cem\u003eO\u003c/em\u003e) of the scintillator is defined as the function of space coordinate \u003cem\u003er\u003c/em\u003e. We then randomly exchanged the coordinates (\u003cem\u003er\u003c/em\u003e) of the QDs through redispersion, the scintillator displayed identical optical performance (\u003cem\u003eO\u003c/em\u003e), including wavelength, intensity, and lifetime in Figure \u003cspan class=\"InternalRef\"\u003eS1\u003c/span\u003e. Thus, the scintillator possesses exchange symmetry, namely exchange invariance, as depicted in Fig. \u003cspan class=\"InternalRef\"\u003e1\u003c/span\u003eb. In this system, the interaction between the position and the ensemble optical properties can be described by the equations presented in Fig. \u003cspan class=\"InternalRef\"\u003e1\u003c/span\u003eb. \u003cspan class=\"InlineEquation\"\u003e\u003cspan class=\"mathinline\"\u003e\\(P\\)\u003c/span\u003e\u003c/span\u003e is the exchange operator, specially, a chemical or physical reconstruction strategy for the scintillator. The exchange invariance of the scintillator indicates that the disordered assembly way is a universal method for the fabrication of the sizable scintillator with high transparency and good scintillation performance. The internal structure of the scintillator was investigated by transmission electron microscopy (TEM), and the QDs exhibited a disordered arranged state from the top and side view of the TEM images (Figure S2). The ZnO QDs exhibit a uniform size dispersion of 4.6 nm from the TEM image, as shown in the inset of Fig. \u003cspan class=\"InternalRef\"\u003e1\u003c/span\u003ed and Figure S3. Notably, clear and integrated crystal structure can be observed from the high-resolution TEM image of QDs. ZnO QD with a wide band gap of 3.36 eV (Figure S4), small diameter, and large Stokes shift (about 210 nm) is a reasonable candidate for the fabrication of transparent scintillators. The scattering cross-section of ZnO QDs in water, alcohol and SiO\u003csub\u003e2\u003c/sub\u003e matrix was calculated based on Rayleigh scattering theory\u003csup\u003e\u003cspan class=\"CitationRef\"\u003e32\u003c/span\u003e,\u003cspan class=\"CitationRef\"\u003e33\u003c/span\u003e\u003c/sup\u003e, as shown in Figure S5. The scattering cross section decreases from 4.42\u0026times; 10\u003csup\u003e\u0026minus;\u0026thinsp;20\u003c/sup\u003e /m\u003csup\u003e2\u003c/sup\u003e in a water matrix to 2.68\u0026times; 10\u003csup\u003e\u0026minus;\u0026thinsp;20\u003c/sup\u003e /m\u003csup\u003e2\u003c/sup\u003e in a silica matrix at the wavelength 500 nm. Such a difference was ascribed to the Rayleigh scattering, where a small refractive-index difference can significantly mitigate the scattering effect. The premix including ZnO QDs, ethanol, and water, presented a white solution with a low light transmittance. As the water and ethanol evaporated, the premix became gradually transparent and the pattern beneath the QDs composites gradually became clear (Figure S6). In addition, the light transmittance (\u003cem\u003eT\u003c/em\u003e) of a ZnO QD scintillator was investigated are shown in Fig. \u003cspan class=\"InternalRef\"\u003e1\u003c/span\u003ed (more calculation details see Methods). The simulated light transmittance spectra show that the transmittance is highly sensitive to the radius of QDs. The 90 wt % loading of 5 nm QDs exhibits comparable transparency to its 10 wt % counterpart. The volumetric fraction of ZnO QDs in the scintillator is about 95%, showcasing impressive transparency up to 96% in the wavelength range from 380 to 800 nm (Fig. \u003cspan class=\"InternalRef\"\u003e1\u003c/span\u003ee). It should be noted that each QD is isolated, and there are no distinct grain boundaries, resulting in minimal difference in refractive index. The transparent nature and disordered inter-arrange of the scintillator resemble glass, prompting us to rename it as a glassy scintillator. The SEM image shows that the QD glassy scintillator has a smooth surface in a large area (Figure S7), further decreasing the light scattering derived from the interface. X-ray diffraction (XRD) pattern of ZnO QD glassy scintillator and the XRD pattern of ZnO QD powders show the same diffraction peaks indexed to the ZnO (Figure S8), indicating the isolation of ZnO QDs within the scintillator. In this disordered assembly process, discrete ZnO QDs were organized into spherical nanoparticles with different sizes (Figure S9), resembling the snowball effect, while the QDs remained spatially well isolated (Figure \u003cspan class=\"InternalRef\"\u003eS1\u003c/span\u003e0). In the end, the ZnO QDs underwent fusion to form a continuum structure, resulting in the formation of the ZnO QD glassy scintillator. In the bottom of Fig. \u003cspan class=\"InternalRef\"\u003e1\u003c/span\u003ef, the nanosecond and microsecond lifetime of the ZnO QDs can be detected, and the lifetime of the ZnO QDs collected at 575 nm, can be well fitted by bi-exponential function with lifetimes of \u0026tau;\u003csub\u003e1\u003c/sub\u003e\u0026thinsp;=\u0026thinsp;55.5 ns (63%) and \u0026tau;\u003csub\u003e2\u003c/sub\u003e\u0026thinsp;=\u0026thinsp;1.46 \u0026micro;s (37%). The electron spin resonance (ESR) signal of ZnO QDs manifests a time-dependent nature, disappearing after excitation for 1.9 \u0026micro;s (top of Fig. \u003cspan class=\"InternalRef\"\u003e1\u003c/span\u003ef). This indicates the lifetime of triplet excitons is about 1.9 \u0026micro;s, which is in agreement with the long-lived component in luminescence lifetime. In addition to high transparency and large size, the scintillator possesses bright triplet excitons, which will be discussed in detail in the next part. The scintillation mechanism of the glassy scintillator is illustrated in Fig. \u003cspan class=\"InternalRef\"\u003e1\u003c/span\u003eg. When exposed to X-ray photons, X-ray photons interact with the atom of the QDs by photoelectric effect and Compton scattering, inducing hot electrons generated from the directly excited process and ejected electrons from the ionized process. The hot electrons underwent thermal relaxation, forming excitons with holes, and returned to the ground state by emitting visible photons. The ejected electrons would be injected into the adjacent QDs, and the injected electrons would be populated in singlets and triplets following the ratio of 1:3, according to the rule of spin conservation. The ratio of directedly excited ZnO QDs to ionized ZnO QDs is set as 1:k, and the singlet/triplet states ratio (\u003cem\u003eS\u003c/em\u003e\u003csub\u003e\u003cem\u003en\u003c/em\u003e\u003c/sub\u003e:\u003cem\u003eT\u003c/em\u003e\u003csub\u003e\u003cem\u003en\u003c/em\u003e\u003c/sub\u003e) is (k\u0026thinsp;+\u0026thinsp;4):(3k). For extremely ionizing radiation, k approaches infinity, the triplet states recombination would be favored. At the opposite k approaches zero, only singlet states are populated. For the ZnO QDs glassy scintillator, 37% of directly excited ZnO QDs, were populated into triplet state through intersystem crossing (ISC). Thus, the ultimate ratio of \u003cem\u003eS\u003c/em\u003e\u003csub\u003e\u003cem\u003en\u003c/em\u003e\u003c/sub\u003e to \u003cem\u003eT\u003c/em\u003e\u003csub\u003e\u003cem\u003en\u003c/em\u003e\u003c/sub\u003e is expressed as 0.63(1\u0026thinsp;+\u0026thinsp;k/4):(0.37(1\u0026thinsp;+\u0026thinsp;1k/4)\u0026thinsp;+\u0026thinsp;3k/4)), which can be further simplified to (2.52\u0026thinsp;+\u0026thinsp;0.63k):(1.48\u0026thinsp;+\u0026thinsp;3.37k), when the scintillator exposed to X-ray photons. The bright nature of the triplet excitons increases the X-ray to visible photons conversion efficiency, by elevating the utilization rate of excitons.\u003c/p\u003e\n\u003cp\u003eThe exciton nature of the ZnO QD glassy scintillator and the dynamic processes were further investigated. Figure S11a displays broadband PL at room temperature upon UV excitation, with a peak centered at around 575 nm. The broadband PL is a characteristic of STE emission, a feature previously confirmed in our earlier research\u003csup\u003e\u003cspan class=\"CitationRef\"\u003e34\u003c/span\u003e\u003c/sup\u003e. This includes a large Stokes shift (210 nm) and a remarkable full width at half-maximum (FWHM) of 193 nm, due to strong coupling of the excitons with phonons. The absolute PL QY of the ZnO QD powders and ZnO QD glassy scintillator was measured (detail spectra can be found in Figure S12), exhibiting an increase from 58\u0026ndash;71%. This increase indicates that the high transparency is a significant factor contributing to the high light yields of ZnO QDs. The 3D contour plots of emission versus excitation spectra are presented in Figure S13, clearly revealing a broad emission range and excitation-independent characteristics. The emission spectra, spanning from 350 to 850 nm, exhibit identical shapes and features across various excitation wavelengths, implying the recombination of a single initial excited state. Furthermore, the temperature-dependent PL spectra were recorded to investigate the electron-phonon coupling, STE binding energy, and Huang-Rhys factor (S), as shown in Figure S11b. The calculated STE binding energy is \u0026sim;97.8 meV (Figure S14) by the following equation:\u003c/p\u003e\n\u003cdiv id=\"Equa\" class=\"Equation\"\u003e\n \u003cdiv class=\"mathdisplay\" id=\"FileID_Equa\" name=\"EquationSource\"\u003e$${I}_{T}={I}_{0}/(1+Aexp\\left(-\\frac{{E}_{b}}{{k}_{B}T}\\right))$$\u003c/div\u003e\u003c/div\u003e\u003cp\u003eWhere \u003cem\u003eI\u003c/em\u003e\u003csub\u003e\u003cem\u003e0\u003c/em\u003e\u003c/sub\u003e and \u003cem\u003eI\u003c/em\u003e\u003csub\u003e\u003cem\u003eT\u003c/em\u003e\u003c/sub\u003e are the emission intensity at 0 K and T K, respectively; A is a constant, \u003cem\u003eE\u003c/em\u003e\u003csub\u003e\u003cem\u003eb\u003c/em\u003e\u003c/sub\u003e is the binding energy, \u003cem\u003ek\u003c/em\u003e\u003csub\u003e\u003cem\u003eB\u003c/em\u003e\u003c/sub\u003e is the Boltzmann constant. The FWHM of PL spectra undergoes broadening as the temperature from rises 77 K to 317 K (Figure S11c). The Huang-Rhys factor (S) and optical phonon frequency \u003cem\u003e(ћ\u0026omega;\u003c/em\u003e\u003csub\u003ephonon\u003c/sub\u003e) can be described by the Eq.\u0026nbsp;3\u003csup\u003e5\u003c/sup\u003e:\u003c/p\u003e\u003cdiv id=\"Equb\" class=\"Equation\"\u003e\u003cdiv class=\"mathdisplay\" id=\"FileID_Equb\" name=\"EquationSource\"\u003e\u003cimg src=\"data:image/png;base64,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\"\u003e\u003c/div\u003e\u003c/div\u003e\u003cp\u003eWhere \u003cem\u003e\u0026omega;\u003c/em\u003e\u003csub\u003e\u003cem\u003ephonon\u003c/em\u003e\u003c/sub\u003e is phonon frequency, ℏ is reduced Planck constant, \u003cem\u003eT\u003c/em\u003e is temperature, and \u003cem\u003ek\u003c/em\u003e\u003csub\u003e\u003cem\u003eB\u003c/em\u003e\u003c/sub\u003e is Boltzmann constant. The calculated Huang-Rhys factor \u003cem\u003eS\u003c/em\u003e and the phonon energy \u003cem\u003eℏ\u0026omega;\u003c/em\u003e\u003csub\u003e\u003cem\u003ephonon\u003c/em\u003e\u003c/sub\u003e are 31.2 and 36.7 meV, respectively. This implies a strong electron-phonon coupling in ZnO QDs, due to the opposite symmetry vibration of zine and oxygen atoms (as depicted in Fig. \u003cspan class=\"InternalRef\"\u003e2\u003c/span\u003ea), which facilitates the formation of STE with the large Stokes shift emission feature. The spectra from ZnO QDs versus excitation power over 4 orders of magnitude were recorded (Figure S15), and the emission intensity shows a linear dependence on the excitation intensity (Fig. \u003cspan class=\"InternalRef\"\u003e2\u003c/span\u003eb), excluding the emission from permanent defects. The PL onset time demonstrates a wavelength-dependent characteristic, wherein photons with low energy show slower emergence compared with that of high energy, as shown in Fig. \u003cspan class=\"InternalRef\"\u003e2\u003c/span\u003ec. This phenomenon serves as direct evidence of STE emission. Additionally, in the 3D time-resolved emission spectra of ZnO QDs (Figure S16), the presence of two distinct lifetimes is evident, signifying the existence of different exciton recombination processes. To explore the kinetics of carrier\u0026rsquo;s transfer, we further investigated the temperature-dependent PL decay dynamics properties from 77\u0026ndash;317 K, as shown in Fig. \u003cspan class=\"InternalRef\"\u003e2\u003c/span\u003ed and Figure S17. The short lifetime (\u0026tau;\u003csub\u003e1\u003c/sub\u003e) decreases from 212 ns to 63.5 ns with escalating temperature, while the long lifetime (\u0026tau;\u003csub\u003e2\u003c/sub\u003e) gradually increases first (77\u0026ndash;137 K) and then decreases (137\u0026ndash;317 K). In the cryogenic region (77\u0026ndash;137 K), the long lifetime is suppressed compared with the high-temperature region (over 137 K), due to insufficient energy for electrons in the triplet state back to the singlet state\u003csup\u003e\u003cspan class=\"CitationRef\"\u003e36\u003c/span\u003e,\u003cspan class=\"CitationRef\"\u003e37\u003c/span\u003e\u003c/sup\u003e. The above results suggest that the emission of ZnO QDs originates from the singlet/triplet hybrid STE states. The average lifetimes (\u0026tau;\u003csub\u003eave\u003c/sub\u003e) of ZnO QDs at 180\u0026ndash;300 K were recorded, as shown in Figure S18, and the emission model can be fitted well with the functional relationship by the Eq.\u0026nbsp;3\u003csup\u003e8\u003c/sup\u003e:\u003c/p\u003e\u003cdiv id=\"Equc\" class=\"Equation\"\u003e\u003cdiv class=\"mathdisplay\" id=\"FileID_Equc\" name=\"EquationSource\"\u003e$${\\tau }_{ave}=\\frac{3+exp(- \\frac{{\\varDelta E}_{ST}}{{K}_{B}T})}{3/{\\tau }_{T}+1/{\\tau }_{S}exp(- \\frac{{\\varDelta E}_{ST}}{{K}_{B}T})}$$\u003c/div\u003e\u003c/div\u003e\u003cp\u003ewhere \u003cem\u003ek\u003c/em\u003e\u003csub\u003e\u003cem\u003eB\u003c/em\u003e\u003c/sub\u003e is the Boltzmann constant, \u003cem\u003e\u0026tau;\u003c/em\u003e\u003csub\u003e\u003cem\u003eS\u003c/em\u003e\u003c/sub\u003e and \u003cem\u003e\u0026tau;\u003c/em\u003e\u003csub\u003e\u003cem\u003eT\u003c/em\u003e\u003c/sub\u003e are the decay time of singlet and triplet states at 0 K (they are fitted decay lifetime at 77 K for this case), and \u003cem\u003e\u0026Delta;E\u003c/em\u003e\u003csub\u003e\u003cem\u003eST\u003c/em\u003e\u003c/sub\u003e is the splitting energy gap between singlet and triplet, respectively. The fitted \u003cem\u003e\u0026Delta;E\u003c/em\u003e\u003csub\u003e\u003cem\u003eST\u003c/em\u003e is\u003c/sub\u003e 48 meV, and such small singlet-triplet energy splitting was consistent with the theoretical calculations of 58 meV in our previous work\u003csup\u003e\u003cspan class=\"CitationRef\"\u003e34\u003c/span\u003e\u003c/sup\u003e. To further investigate the dynamic processes of the generated carriers after excitation, excited state spectra of ZnO QDs were performed using broad femtosecond transient absorption (TA) spectroscopy in Fig. \u003cspan class=\"InternalRef\"\u003e2\u003c/span\u003ee. Negative \u0026Delta;\u003cem\u003eA\u003c/em\u003e features (blue) are discernible in the spectral region spanning regions of 330\u0026ndash;350 nm and 560\u0026ndash;570 nm, while positive features (highlighted in red) are evident within the wavelength range of 490\u0026ndash;540 nm. The TA spectra at different time delays, along with the corresponding decay spectra at 345, 360 and 520 nm, are presented in Figs. \u003cspan class=\"InternalRef\"\u003e2\u003c/span\u003ef and \u003cspan class=\"InternalRef\"\u003e2\u003c/span\u003eg. The 330 to 350 nm spectral region is dominated by ground-state photobleaching (PB), exhibiting a consistent match with the steady-state absorption spectrum. Noting that, the signal at around 360 nm shows a negative response within 100 ps, followed by a transition to a positive signal thereafter. This alteration serves as a direct indicator of triplet photoabsorption (PA). Thus, the decay curve at 360 nm represents a hybrid signal including both PB and triplet PA. The broad excited-state absorption in the green region from 485 to 520 nm corresponds to the singlet state PA, and the corresponding lifetime associated with the state at 520 nm state is approximately\u0026thinsp;~\u0026thinsp;1 ns. Species-associated difference spectra (SAS) of the ZnO QDs TA data reveal three components with lifetimes of 9.9 ps, 147.6 ps and 18.7 ns as shown in Fig. \u003cspan class=\"InternalRef\"\u003e2\u003c/span\u003eh and Figure S19. The kinetics of carriers\u0026rsquo; evolution in various excited energy levels can be clearly observed. The generated hot carriers undergo relaxation to the free excitons (FE) state within 109.7 fs, followed by a further relaxation to the singlet STE state within 9.9 ps due to the strong electron-phonon coupling. The singlet STE state evolution can be directly resolved by the decay curves at 520 nm. Subsequently, the singlet STE state converts into the long-lived species within 147.6 ps through an intersystem crossing (ISC) process, characterized by distinct excited-state absorption at 360 nm. Compared with PL decay spectra, the average lifetimes of ZnO QDs at 375 nm and 575 nm are 2.7 ns and 1030 ns, and a plausible mechanism model for carrier evolution is shown in Fig. \u003cspan class=\"InternalRef\"\u003e2\u003c/span\u003ei. The above results confirm that the emission of the ZnO QDs is attributed to the radiative recombination of singlet/triplet hybrid STE, rendering it highly advantageous for scintillator applications.\u003c/p\u003e\u003cp\u003eThe RL spectra of the ZnO QD glassy scintillator under excitation of a 45 kV X-ray source and UV excitation (at 80 and 300 K) were recorded, as shown in Fig. \u003cspan class=\"InternalRef\"\u003e3\u003c/span\u003ea. A broad and intense yellow RL band, peaking at 590 nm can be observed, suggesting the RL originates from the emission of hybrid excitons. The RL spectrum, resembling that of ZnO QDs measured at 80 K but with a 15 nm red-shift in peak position compared to the PL spectrum measured at 300 K, implies the pivotal involvement of triplet excitons in the ZnO QDs scintillator. Figure \u003cspan class=\"InternalRef\"\u003e3\u003c/span\u003eb and Figure S20 illustrate the X-ray photon absorption coefficient of ZnO QD glassy scintillator (highest atomic number Z\u003csub\u003emax\u003c/sub\u003e = 30, K\u0026alpha;\u0026thinsp;=\u0026thinsp;8.6 keV) as a function of thickness at an X-ray photon energy of 10\u0026ndash;50 keV\u003csup\u003e\u003cspan class=\"CitationRef\"\u003e39\u003c/span\u003e\u003c/sup\u003e. It can be found that the ZnO QD scintillator can absorb 90% of the X-ray photon energy at a thickness of 500 \u0026micro;m. Thus, it is reasonable to expect that the hybrid singlet/triplets of the scintillator can be populated under the excitation of photons with energy ranging from a few hundred eV to a few hundred keV, particularly with a thickness over 500 \u0026micro;m. Besides, the high PL QY, transparency, zero self-absorption and intense light output of the ZnO QD scintillator can lead to a high scintillation light yield. The X-ray to light conversion efficiencies were measured, as shown in Fig. \u003cspan class=\"InternalRef\"\u003e3\u003c/span\u003ec. The ZnO QD scintillator exhibits light conversion efficiencies of 18038 photons/MeV, presenting a more favorable performance compared to the widely used commercial bulk BGO scintillator\u003csup\u003e\u003cspan class=\"CitationRef\"\u003e40\u003c/span\u003e,\u003cspan class=\"CitationRef\"\u003e41\u003c/span\u003e\u003c/sup\u003e. Furthermore, the ZnO QD scintillator screen was assessed for its ability to absorb X-ray photons from all angles, as illustrated in Fig. \u003cspan class=\"InternalRef\"\u003e3\u003c/span\u003ed. Tuning the X-ray source under a 360-degree circular motion to excite the scintillator, the RL intensity was measured with an optical fiber spectrometer, as shown in Fig. \u003cspan class=\"InternalRef\"\u003e3\u003c/span\u003ee. The RL intensity shows a degree-dependent characteristic property, laying a solid foundation for the design of X-ray imaging applications. In addition, a comparative experiment with different detection angles approach shown in Figure S21 was designed. The intensity of the RL gradually increases as the irradiation angles increase from 0\u0026deg; to 90\u0026deg;, primarily attributed to the optical channel crosstalk, causing the reduction in the transmitted efficiency of the RL. Figure \u003cspan class=\"InternalRef\"\u003e3\u003c/span\u003ef schematically shows the internal mechanism of the RL in ZnO QD scintillators. Upon X-ray irradiation, inner electrons are ejected from the atom and substantial hot electrons and holes can be created. Following X-ray irradiation, the ejected electrons subsequently inject into nearby QDs following a singlet/triplet ratio of 1:3. The remaining hot electrons then undergo relaxation through electron-photon interaction, following a singlet/triplet ratio of 0.63:0.37. The energy distribution spectra of the continuous X-ray sources, containing the characteristic X-ray peak and the bremsstrahlung, are shown in Fig. \u003cspan class=\"InternalRef\"\u003e3\u003c/span\u003eg. The X-ray flux can be as high as 10\u003csup\u003e6\u003c/sup\u003e photons / (s*mrad\u003csup\u003e2\u003c/sup\u003e), and the average photon energy increases from 6.85 keV to 16.03 keV as the operating voltage increases from 10 kV to 45 kV. In Fig. \u003cspan class=\"InternalRef\"\u003e3\u003c/span\u003eh, the RL intensity of the ZnO QD scintillator shows a significant enhancement with increasing voltage, indicating an effective X-ray photons conversion to visible photons. The integrated RL intensity of the ZnO QD scintillator shown in Fig. \u003cspan class=\"InternalRef\"\u003e3\u003c/span\u003ei presents an excellent linear response to the X-ray dose rates in a large range from 38.4 nGy s\u003csup\u003e\u0026minus;\u0026thinsp;1\u003c/sup\u003e to 900 \u0026micro;Gy s\u003csup\u003e\u0026minus;\u0026thinsp;1\u003c/sup\u003e. A low detection limit of 38.4 nGy s⁻\u0026sup1; for this transparent ZnO QDs glassy scintillator can be derived from the fitting curve when the signal-to-noise ratio is 3, which is lower than the typical medical imaging dose (5.5 \u0026micro;Gy s\u003csup\u003e\u0026minus;\u0026thinsp;1\u003c/sup\u003e)\u003csup\u003e42\u0026ndash;44\u003c/sup\u003e. The RL intensity of the ZnO QD scintillator can remain constant after working for 40 days (Figure S22). The photostability was further examined under continuous or repeated cycles of X-ray illumination, and it can be activated repeatedly with no obvious decrease, indicating the good photostability of the ZnO QD scintillator as shown in Fig. \u003cspan class=\"InternalRef\"\u003e3\u003c/span\u003ej. In addition, Figure S23 shows the cost analysis of the ZnO QD scintillator compared to other widely reported scintillators. The lower cost and ease of preparation of the ZnO QD scintillator may arouse intense interest in its commercial competitiveness in view of the scintillator application.\u003c/p\u003e\u003cp\u003eRegarding the excellent RL performance, highly transparence, and large size of the ZnO QD scintillator, we next implemented X-ray imaging with the ZnO QD scintillator as an imaging screen, and the corresponding imaging setup is illustrated in Fig. \u003cspan class=\"InternalRef\"\u003e4\u003c/span\u003ea. The RL intensity exhibits a notable increase with the growing thickness of the ZnO QD scintillator, while the transmittance remains 90% at 1 mm. The spatial resolution ZnO QD glassy scintillator with 1 mm for X-ray imaging was assessed by using an X-ray standard test pattern panel consisting of lines with widths ranging from 1 to 30 lp mm\u003csup\u003e\u0026minus;\u0026thinsp;1\u003c/sup\u003e. The X-ray imaging of the linear mask closely mirrored the corresponding optical image, as revealed on the ZnO QD scintillator screen (left of Fig. \u003cspan class=\"InternalRef\"\u003e4\u003c/span\u003eb). Lines with a width of 16 \u0026micro;m can be clearly resolved (right of Fig. \u003cspan class=\"InternalRef\"\u003e4\u003c/span\u003eb), demonstrating a spatial resolution of 30 lp mm\u003csup\u003e\u0026minus;\u0026thinsp;1\u003c/sup\u003e. Note that the modulation transfer function (MTF) provides a spatial resolution of 42 lp mm\u003csup\u003e\u0026minus;\u0026thinsp;1\u003c/sup\u003e at the value of 0.2 (Fig. \u003cspan class=\"InternalRef\"\u003e4\u003c/span\u003ec), and the clear internal structure of a chip can be observed, as shown in the inset of Fig. \u003cspan class=\"InternalRef\"\u003e4\u003c/span\u003ec. The spatial resolution is much higher than the recently reported scintillator screens, such as CsPbBr\u003csub\u003e3\u003c/sub\u003e (12.5 lp mm\u003csup\u003e\u0026minus;\u0026thinsp;1\u003c/sup\u003e)\u003csup\u003e45\u003c/sup\u003e, Cs\u003csub\u003e3\u003c/sub\u003eCu\u003csub\u003e2\u003c/sub\u003eI\u003csub\u003e5\u003c/sub\u003e (6.8 lp mm\u003csup\u003e\u0026minus;\u0026thinsp;1\u003c/sup\u003e)\u003csup\u003e46\u003c/sup\u003e, lanthanide-doped nanoscintillators (25 lp mm\u003csup\u003e\u0026minus;\u0026thinsp;1\u003c/sup\u003e)\u003csup\u003e47\u003c/sup\u003e and so on. This is attributed to the superior transparency and excellent RL performance of the ZnO QD scintillator. Subsequently, we evaluated the feasibility of sizable ZnO QD scintillator screen (3600 cm\u003csup\u003e\u003cspan class=\"CitationRef\"\u003e2\u003c/span\u003e\u003c/sup\u003e) for X-ray imaging in safety inspection. The X-ray images of a backpack with various samples (bearings, pliers, knife, earphones, scissor) were monitored, as shown in Fig. \u003cspan class=\"InternalRef\"\u003e4\u003c/span\u003ed. The outline of the internal objects can be distinctly observed, and the color variations were a result of their differences in X-ray absorptions. The internal structures of a small computer mouse can be observed using the sizable scintillator (Figure S24a), indicating the ability for objects of various sizes. The ZnO QD scintillator can also be employed for imaging the internal structure of a finger (Fig. \u003cspan class=\"InternalRef\"\u003e4\u003c/span\u003ee) and a moving finger (Figure S24b). Obvious biological tissue phase contrast and clear joint details can be observed in the randomly selected X-ray images at different time points. Moreover, the feasibility of large-area medical single-scan X-ray imaging was explored, the optical image and pseudo-color images are shown in Fig. \u003cspan class=\"InternalRef\"\u003e4\u003c/span\u003ef. The original X-ray images are shown in Figure S24c, the internal biological tissue and bones of the pork ribs were observed under high X-ray photon energy. Subsequently, the details of the broken bone joint were analyzed, and obvious increases in gray value in the fractured area can be observed, as further revealed by the magnified images in the inset. In our case, large-area X-ray imaging can cover an expansive area of 2500 cm\u003csup\u003e\u003cspan class=\"CitationRef\"\u003e2\u003c/span\u003e\u003c/sup\u003e through a single scan, representing a record for a single large-area X-ray imaging scan to date to the best of our knowledge. In addition, real-time X-ray dynamic imaging (24 frames per second) was demonstrated, and the corresponding sketch map is illustrated in Fig. \u003cspan class=\"InternalRef\"\u003e4\u003c/span\u003eg. The twelve Chinese zodiac characters exhibit clear identification of sharp edges without the ghosting effect in the captured photos at different time intervals, attributed to the fast response of the ZnO QD scintillator (Fig. \u003cspan class=\"InternalRef\"\u003e4\u003c/span\u003eh). The sizable ZnO QD scintillator, exhibits efficient conversion of X-ray photons into visible light, characterized by high transparency, notable RL performance, and superior spatial resolution, rendering it suitable for diverse applications in X-ray imaging and safety inspection at a low cost.\u003c/p\u003e\u003cp\u003eIn conclusion, the sizable ZnO QD glassy scintillator featuring singlet/triplet hybrid STEs was demonstrated through a disordered assembly technique, with the aim of achieving high-resolution X-ray imaging for large objects. Compared to the way of QDs coupled with the organic polymer and conventional Czochralski method, the key attributes of the ZnO QD glassy scintillator are room temperature solution-based large-area synthesis, high QD loading, relatively low toxicity, high transparency, and robust RL. Importantly, our work has efficiently harnessed the X-ray-induced generation of hybrid STE, not only showcasing the potential for enhanced RL performance but also laying the foundation for the design of innovative scintillators.\u003c/p\u003e\u003cp\u003eMoreover, the successful creation of a large transparent ZnO QD glassy scintillator, measuring 1 m * 0.5 m and with 96% transparency, represents a significant stride forward. This scintillator enables high-resolution (42 lp mm\u003csup\u003e\u0026minus;\u0026thinsp;1\u003c/sup\u003e), low-dose (38.47 nGy s\u003csup\u003e\u0026minus;\u0026thinsp;1\u003c/sup\u003e), large-area (5000 cm\u003csup\u003e\u003cspan class=\"CitationRef\"\u003e2\u003c/span\u003e\u003c/sup\u003e), and real-time X-ray imaging. This glassy scintillator route may help redefine the paradigm for QD-based scintillator manufacturing, which not only provides a versatile approach for the preparation of QD scintillators but also may open a series of exciting applications for advancing radiation detection and medical imaging.\u003c/p\u003e"},{"header":"Declarations","content":"\u003cp\u003e\u003cstrong\u003eAcknowledgements\u003c/strong\u003e\u003c/p\u003e\n\u003cp\u003eThis work is supported by the National Natural Science Foundation of China (Grant Nos. 62075198, 11974317, 61804136) and the Outstanding Youth Foundation of Henan (Grant nos. 222300420087). We express gratitude to H. Zeng and J. G. W for their technical assistance and thank the Ultrafast X-ray Dynamic Experimental Station at the Synergetic Extreme Condition User Facility in China.\u003c/p\u003e\n\u003cp\u003e\u003cstrong\u003eCompeting interests\u003c/strong\u003e\u003c/p\u003e\n\u003cp\u003eThe authors declare no competing interests.\u003c/p\u003e"},{"header":"Methods","content":"\u003cp\u003e\u003cstrong\u003eMaterials\u003c/strong\u003e\u003c/p\u003e\n\u003cp\u003eAll the chemicals were purchased from Aladdin Chemistry Co. and they were all analytical grade: Zinc acetate dihydrate (Zn (Ac)\u003csub\u003e2\u003c/sub\u003e ∙ 2H\u003csub\u003e2\u003c/sub\u003eO), potassium hydroxide (KOH), (3-aminopropyl) triethoxysilane (APTES) were purchased from Aladdin Chemistry Co. Ltd. (Shanghai, China). The source of absolute ethanol was Tianjin Kaitong Chemical Reagent Co. Ltd. (Tianjin, China).\u003c/p\u003e\n\u003cp\u003e\u003cstrong\u003eSynthesis of the ZnO QDs\u003c/strong\u003e\u003c/p\u003e\n\u003cp\u003eIn the first step, 923.7 g Zn(Ac)\u003csub\u003e2\u003c/sub\u003e ∙ 2H\u003csub\u003e2\u003c/sub\u003eO and 343.3 g KOH were dispersed in 20 L and 5 L of pure ethanol. Subsequently, the KOH solution was added into the Zn(Ac)\u003csub\u003e2\u003c/sub\u003e ∙ 2H\u003csub\u003e2\u003c/sub\u003eO solution followed by continuous stirring for 2 h. The complex solution above was filled with 66.5 mL APTES and stirred continuously for 8 hours. The precipitate was centrifuged and washed with absolute ethanol three times. Eventually, ZnO nanocrystals were obtained after drying in a blast oven at 70 \u003csup\u003eo\u003c/sup\u003eC for 12 h.\u003c/p\u003e\n\u003cp\u003e\u003cstrong\u003eGrowth of the ZnO QD glassy scintillator\u003c/strong\u003e\u003c/p\u003e\n\u003cp\u003eIn a typical procedure, the\u003cstrong\u003e\u0026nbsp;\u003c/strong\u003eZnO QDs, are dispersed in water (1:2 by mass) and sonicated for 30 min to ensure its homogeneity. The resulting composites were degassed in a vacuum container to remove air bubbles. The viscous mixture solution was carefully coated on the quartz plates (or poured into a round plastic plate (9 \u0026times; 9 cm\u003csup\u003e2\u003c/sup\u003e)) for glassy scintillator fabrication. The solution was poured into a square glass plate (100 cm* 50 cm) for meter-scale glassy scintillator fabrication. The mixture solution was finally heated at 45 \u0026deg;C for 6 h. After cooling to room temperature, the as-fabricated glassy scintillator was used for X-ray imaging.\u003c/p\u003e\n\u003cp\u003e\u003cstrong\u003eThe light transmittance (T) of the ZnO QD glassy scintillator calculations\u003c/strong\u003e\u003c/p\u003e\n\u003cp\u003eRayleigh cross section was calculated following the equation:\u003c/p\u003e\n\u003cp\u003e\u003cimg 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\"\u003e\u003cbr\u003e\u003c/p\u003e\n\u003cp\u003e\u003cstrong\u003ePhysical characterization\u003c/strong\u003e\u003c/p\u003e\n\u003cp\u003eTransmission Electron Microscope (TEM) images were measured on TEM (TecnaiG2 F20 S-TWIN) at 200-kV acceleration voltage to characterize the microstructures of all the ZnO QDs. FTIR spectra were recognized on an FTIR (Nicolet 6700) spectrometer. XRD patterns were collected with a Smartlab X-ray diffractometer (Rigaku, Japan) using Cu K\u0026alpha; radiation. XPS patterns were obtained using an X-ray photoelectron spectrometer to measure the bonding state of the QDs. The cross-section and surface of the ZnO QDs glassy scintillator were observed by a JSM-6700F (JEOL, Japan) field emission scanning electron microscope (FESEM). Special Aberration Corrected Transmission Electron Microscope (AC-TEM) images of the ZnO QD glassy scintillator were measured by transmission electron microscope (FEI Talos F200) under an acceleration voltage of 200 kV. Photographs of X-ray-induced luminescence and radioluminescence-based X-ray imaging were acquired with a digital camera (Canon EOS 5D Mark IV) in an all-manual mode.\u0026nbsp;\u003c/p\u003e\n\u003cp\u003e\u003cstrong\u003eOptical characterization\u003c/strong\u003e\u003c/p\u003e\n\u003cp\u003eThe fluorescence spectra and excitation-emission spectra of the ZnO QDs were measured on an Edinburgh FLS1000 fluorescence spectrophotometer. Ultraviolet-visible (UV\u0026ndash;vis) absorption and transmittance spectra of the ZnO QDs were obtained using Hitachi UH 4150 UV\u0026ndash;vis spectrophotometers, respectively. The lifetimes, kinetic measurements, and time-resolved emission spectra were measured using an Edinburgh FLS1000 fluorescence spectrophotometer equipped with a microsecond flash-lamp (uF2), a xenon arc lamp (Xe2), and a nanosecond hydrogen flashlamp (nF920), respectively. The temperature-dependent spectra of the samples were measured using an FLS1000 spectrophotometer equipped with temperature control instruments (Advanced Research Systems) at various temperatures from 317 to 12 K. Absolute photoluminescence quantum-yield measurements at room temperature were performed on an FLS1000 spectrometer with calibrated integrating sphere. For the transient absorption spectrum measurements, a regeneratively amplified femtosecond Ti: Sapphire laser system (150 fs, 1 kHz) was employed. In this system, a 280 nm pump pulse was focused on the samples through an automated TOPAS Optical Parametric Amplifier (OPA). Then, the probe beam was focused and passed through the sample by an Al parabolic reflector. After passing through the sample, the transmission changes of the probe light were detected by a fiber spectrometer. And the absorbance change of the sample was calculated with two adjacent probe pulses. 50 mg mL\u003csup\u003e\u0026minus;1\u003c/sup\u003e ZnO QDs solution was selected to measure the transient absorption spectrum.\u003c/p\u003e\n\u003cp\u003e\u003cstrong\u003eRadioluminescence measurement for the ZnO QD glassy scintillator\u003c/strong\u003e\u003c/p\u003e\n\u003cp\u003eThe measurement of X-ray-induced luminescence was performed using a solid ZnO QD glassy scintillator. The radioluminescence spectra were recorded using an Edinburgh FLS-1000 fluorescence spectrophotometer with a miniature X-ray source. The 360-degree omnidirectional radiation detection radioluminescence spectra were measured through our home-built X-ray imaging system including the rotating test platform with an optical fiber spectrometer.\u003c/p\u003e\n\u003cp\u003e\u003cstrong\u003eLarge-area X-ray imaging and dynamic X-ray imaging\u003c/strong\u003e\u003c/p\u003e\n\u003cp\u003eThe large area X-ray scintillation detector was constructed by preparing of meter-scale ZnO QD glassy scintillator with a layer thickness of 800 \u0026mu;m. In order to maximize the collection of visible photons, the ZnO QD glassy scintillator was coupled with a normal digital camera. For X-ray imaging, a backpack filled with different samples (bearings, pliers, knife, earphones, scissor) and a broken pork rib were utilized. Dynamic X-ray imaging was achieved using mechanical Chinese character turntables as imaging objects that were equipped with a glassy scintillator. 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Opt. Mater.\u003c/em\u003e \u003cstrong\u003e10\u003c/strong\u003e, 2102232 (2022).\u003c/li\u003e\n\u003cli\u003eOu, X.\u003cem\u003e et al.\u003c/em\u003e High-resolution X-ray luminescence extension imaging. \u003cem\u003eNature\u003c/em\u003e \u003cstrong\u003e590\u003c/strong\u003e, 410-415 (2021).\u003c/li\u003e\n\u003c/ol\u003e"}],"fulltextSource":"","fullText":"","funders":[],"hasAdminPriorityOnWorkflow":false,"hasManuscriptDocX":true,"hasOptedInToPreprint":true,"hasPassedJournalQc":"","hasAnyPriority":true,"hideJournal":false,"highlight":"","institution":"","isAcceptedByJournal":false,"isAuthorSuppliedPdf":false,"isDeskRejected":"","isHiddenFromSearch":false,"isInQc":false,"isInWorkflow":false,"isPdf":false,"isPdfUpToDate":true,"isWithdrawnOrRetracted":false,"journal":{"display":true,"email":"[email protected]","identity":"nature-portfolio","isNatureJournal":true,"hasQc":false,"allowDirectSubmit":false,"externalIdentity":"","sideBox":"","snPcode":"","submissionUrl":"","title":"Nature Portfolio","twitterHandle":"","acdcEnabled":false,"dfaEnabled":false,"editorialSystem":"ejp","reportingPortfolio":"","inReviewEnabled":true,"inReviewRevisionsEnabled":false},"keywords":"Scintillator, X-ray, Imaging, Singlet/triplet exciton, High-resolution","lastPublishedDoi":"10.21203/rs.3.rs-3942722/v1","lastPublishedDoiUrl":"https://doi.org/10.21203/rs.3.rs-3942722/v1","license":{"name":"CC BY 4.0","url":"https://creativecommons.org/licenses/by/4.0/"},"manuscriptAbstract":"\u003cp\u003eSize-scalable X-ray scintillators with high transparency and robust photon yield allow for imaging large objects with greater precision and detail. Solution-processable scintillators, typically crafted from quantum dots (QDs), are promising candidates for highly efficient scintillation applications. However, the restricted size, low transparency, and dark nature of triplet excitons in QD-based scintillators lead to less efficient X-ray imaging for large objects requiring high resolution. Herein, we demonstrate a meter-scale glassy ZnO QD scintillator with a visible range transmittance exceeding 96% at a thickness of 0.5 mm, showcasing bright singlet/triplet hybrid self-trapping hybrid excitons (STEs). The quantum yields (QYs) of singlet excitons and triplet excitons are 44.7% and 26.3%. Benefiting from a large Stokes shift and bright triplet excitons, the scintillator has a negligible self-absorption and elevated photon yields. Additionally, the scintillator exhibits exchange invariance, demonstrating identical optical performance upon exchanging the coordinates (\u003cem\u003er\u003c/em\u003e) of the QDs. Featuring bright singlet/triplet hybrid STEs and high transparency, the scintillator achieves high resolution X-ray imaging of 42 line pairs per millimeter (42 lp mm\u003csup\u003e-1\u003c/sup\u003e) at a meter scale. Moreover, demonstrations of 5000 cm\u003csup\u003e2\u003c/sup\u003e X-ray imaging and real-time dynamic X-ray imaging are presented. The lowest detectable dose rate for X-ray detection is as low as 38.4 nGy s\u003csup\u003e−1\u003c/sup\u003e. This work provides a novel sizable and transparent scintillator with bright singlet/triplet hybrid excitons, showcasing their potential in high-resolution and sizable object X-ray imaging.\u003c/p\u003e","manuscriptTitle":"Scalable Glassy X-Ray Scintillators with Bright Singlet-Triplet Hybrid Self-Trapping Excitons","msid":"","msnumber":"","nonDraftVersions":[{"code":1,"date":"2024-03-05 18:21:20","doi":"10.21203/rs.3.rs-3942722/v1","editorialEvents":[],"status":"published","journal":{"display":true,"email":"[email protected]","identity":"nature-communications","isNatureJournal":true,"hasQc":false,"allowDirectSubmit":false,"externalIdentity":"NCOMMS","sideBox":"Learn more about [Nature Communications](http://www.nature.com/ncomms/)","snPcode":"","submissionUrl":"https://mts-ncomms.nature.com/","title":"Nature Communications","twitterHandle":"","acdcEnabled":true,"dfaEnabled":true,"editorialSystem":"ejp","reportingPortfolio":"Nature Communications","inReviewEnabled":true,"inReviewRevisionsEnabled":false}}],"origin":"","ownerIdentity":"71825392-61ea-47db-9c41-e3b136533a86","owner":[],"postedDate":"March 5th, 2024","published":true,"recentEditorialEvents":[],"rejectedJournal":[],"revision":"","amendment":"","status":"under-review","subjectAreas":[{"id":28896802,"name":"Physical sciences/Optics and photonics/Optical physics/X-rays"},{"id":28896803,"name":"Physical sciences/Materials science/Nanoscale materials/Quantum dots"}],"tags":[],"updatedAt":"2024-12-01T15:30:28+00:00","versionOfRecord":[],"versionCreatedAt":"2024-03-05 18:21:20","video":"","vorDoi":"","vorDoiUrl":"","workflowStages":[]},"version":"v1","identity":"rs-3942722","journalConfig":"researchsquare"},"__N_SSP":true},"page":"/article/[identity]/[[...version]]","query":{"redirect":"/article/rs-3942722","identity":"rs-3942722","version":["v1"]},"buildId":"qtupq5eGEP_6zYnWcrvyt","isFallback":false,"isExperimentalCompile":false,"dynamicIds":[84888],"gssp":true,"scriptLoader":[]}