Impact of B2O3 on Physical, Optical Characteristics and Radiation Attenuation Factors of Borotellurite Glasses

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This study synthesized borotellurite glasses and found that a specific composition with 25 mol% B2O3 exhibited superior physical, optical, and radiation shielding properties compared to other samples.

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The paper synthesizes a series of borotellurite glasses with varying B2O3 content in the composition [(60–X)TeO2–(20+X)B2O3–10Li2O–10Bi2O3] (X = 5–20 mol% in steps of 5) and measures physical properties (e.g., density, molar volume, oxygen packing density), UV optical spectra (200–800 nm), optical band gap, refractive index, and optical basicity. It experimentally determines mass absorption coefficients using an HPGe detector and compares them with XCOM and MCNP5 calculations across 0.121–1.408 MeV photon energies, also computing radiation-shielding parameters such as HVL, effective atomic/electron densities, and macroscopic removal cross-section. The sample with composition [55TeO2–25B2O3–10Bi2O3–10Li2O] reports the highest mass absorption coefficient (μm = 1.192 ± 0.033 cm2/g), Z eff = 56.12, and ∑R = 0.101499 cm−1 at 121 keV, alongside low HVL and MFP values, leading the authors to identify it as the best gamma-ray shielding material among the prepared glasses. This paper does not explicitly discuss endometriosis or adenomyosis; it was included in the corpus via a keyword match in the upstream search index.

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Abstract

Borotellurite glasses with a composition [(60-X)TeO 2 -(20+X)B 2 O 3 -10Li 2 O-10Bi 2 O 3 ] where x= 5-20 in steps of 5 mol% have been synthesized. Glass density, molar volume, oxygen packing density, and many other physical parameters were measured. UV-spectra in the wave length range (200-800) nm have been measured for the whole glass series. The optical energy band gap E opt , refractive index, and optical basicity were measured. The mass absorption coefficients (μ m ) are determined experimentally by the HPGe detector and compared with the theoretical values obtained by XCOM program and MCNP5 simulation code within (0.121–1.408) MeV photon energy range. Half value layer (HVL), effective atomic number and electron density (Z eff and N eff ), and macroscopic removal cross-section (∑R) were evaluated. The sample [55TeO 2 – 25B 2 O 3 – 10Bi 2 O 3 – 10Li 2 O] possess the highest values of (μ m = 1.192 ± 0.033 cm 2 /g, Z eff = 56.12 e/atom and ∑ R = 0.101499 cm -1 ) at energy 121 keV also lower values of (HVL = 0.121 cm, TVL = 0.1 cm and MFP = 0.174 cm) at photon energy 121 keV, therefore this sample considered the best gamma ray shielding material among the prepared glasses.
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Impact of B2O3 on Physical, Optical Characteristics and Radiation Attenuation Factors of Borotellurite Glasses | Research Square window.SnipcartSettings = { analytics: { enabled: false } }; (function() { var accessVector = localStorage.getItem('access_vector') || ''; window.dataLayer = window.dataLayer || []; if (accessVector) { window.dataLayer.push({ user: { profile: { profileInfo: { snid: accessVector } } } }); } })(); (function(w,d,s,l,i){w[l]=w[l]||[];w[l].push({'gtm.start':new Date().getTime(),event:'gtm.js'});var f=d.getElementsByTagName(s)[0],j=d.createElement(s),dl=l!='dataLayer'?'&l='+l:'';j.async=true;j.src='https://www.googletagmanager.com/gtm.js?id='+i+dl;f.parentNode.insertBefore(j,f);})(window,document,'script','dataLayer','GTM-K279D39R'); Browse Preprints In Review Journals COVID-19 Preprints AJE Video Bytes Research Tools Research Promotion AJE Professional Editing AJE Rubriq About Preprint Platform In Review Editorial Policies Our Team Advisory Board Help Center Sign In Submit a Preprint Cite Share Download PDF Research Article Impact of B2O3 on Physical, Optical Characteristics and Radiation Attenuation Factors of Borotellurite Glasses R. El-Mallawany, Weam aboutaleb, M.A. Naeem, S.M. Kotb, M.E. Krar, and 1 more This is a preprint; it has not been peer reviewed by a journal. https://doi.org/ 10.21203/rs.3.rs-1231390/v1 This work is licensed under a CC BY 4.0 License Status: Published Journal Publication published 28 Feb, 2022 Read the published version in Journal of Materials Research and Technology → Version 1 posted You are reading this latest preprint version Abstract Borotellurite glasses with a composition [(60-X)TeO 2 -(20+X)B 2 O 3 -10Li 2 O-10Bi 2 O 3 ] where x= 5-20 in steps of 5 mol% have been synthesized. Glass density, molar volume, oxygen packing density, and many other physical parameters were measured. UV-spectra in the wave length range (200-800) nm have been measured for the whole glass series. The optical energy band gap E opt , refractive index, and optical basicity were measured. The mass absorption coefficients (μ m ) are determined experimentally by the HPGe detector and compared with the theoretical values obtained by XCOM program and MCNP5 simulation code within (0.121–1.408) MeV photon energy range. Half value layer (HVL), effective atomic number and electron density (Z eff and N eff ), and macroscopic removal cross-section (∑R) were evaluated. The sample [55TeO 2 – 25B 2 O 3 – 10Bi 2 O 3 – 10Li 2 O] possess the highest values of (μ m = 1.192 ± 0.033 cm 2 /g, Z eff = 56.12 e/atom and ∑ R = 0.101499 cm -1 ) at energy 121 keV also lower values of (HVL = 0.121 cm, TVL = 0.1 cm and MFP = 0.174 cm) at photon energy 121 keV, therefore this sample considered the best gamma ray shielding material among the prepared glasses. Inorganic Chemistry Organic Chemistry Glasses Optical properties Radiation shielding MCNP5 code XCOM software Full Text Cite Share Download PDF Status: Published Journal Publication published 28 Feb, 2022 Read the published version in Journal of Materials Research and Technology → Version 1 posted You are reading this latest preprint version Research Square lets you share your work early, gain feedback from the community, and start making changes to your manuscript prior to peer review in a journal. As a division of Research Square Company, we’re committed to making research communication faster, fairer, and more useful. We do this by developing innovative software and high quality services for the global research community. Our growing team is made up of researchers and industry professionals working together to solve the most critical problems facing scientific publishing. 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