Aqueous Micellar-Catalyzed Thioetherification for the Synthesis of Aggregation-Induced Emission Molecules

Aqueous Micellar-Catalyzed Thioetherification for the Synthesis of Aggregation-Induced Emission Molecules | Authorea try { document.documentElement.classList.add('js'); } catch (e) { } var _gaq = _gaq || []; _gaq.push(['_setAccount', 'G-8VDV14Y67G']); _gaq.push(['_trackPageview']); (function() { var ga = document.createElement('script'); ga.type = 'text/javascript'; ga.async = true; ga.src = ('https:' == document.location.protocol ? 'https://ssl' : 'http://www') + '.google-analytics.com/ga.js'; var s = document.getElementsByTagName('script')[0]; s.parentNode.insertBefore(ga, s); })(); Skip to main content Preprints Collections Wiley Open Research IET Open Research Ecological Society of Japan All Collections About About Authorea FAQs Contact Us Quick Search anywhere Search for preprint articles, keywords, etc. Search Search ADVANCED SEARCH SCROLL This is a preprint and has not been peer reviewed. Data may be preliminary. 21 April 2025 V1 Latest version Share on Aqueous Micellar-Catalyzed Thioetherification for the Synthesis of Aggregation-Induced Emission Molecules Authors : Zhike Qiu , Yulan Chen , Linxi Hou , Xiangyu Ying , Jianquan Hong , and Xin Ge 0000-0001-9058-0544 [email protected] Authors Info & Affiliations https://doi.org/10.22541/au.174527842.22309912/v1 Published Chem & Bio Engineering Version of record Peer review timeline 190 views 81 downloads Contents Abstract Supplementary Material Information & Authors Metrics & Citations View Options References Figures Tables Media Share Abstract 1,1-Diphenylvinyl sulfide (DPVS) exhibits aggregation-induced emission (AIE) behavior by restricting intramolecular motion, making it a valuable aggregation-induced luminescent material. However, the synthesis of such AIE molecules typically involves organic sulfur reagents and toxic organic solvents, which limits their development in green synthesis conditions. In this study, we present a method for the multi-component cross-coupling synthesis of DPVS in aqueous micellar conditions, utilizing iodine-mediated inorganic sulfur sources, such as elemental sulfur. The broad applicability of this method is demonstrated by the high-yield synthesis of over twenty different DPVS compounds using various inorganic sulfur sources. Furthermore, the glycosylated nonionic surfactant GluM can modify the coordination complexes formed by copper salts and ligands, significantly enhancing the solubility of substrates. Notably, when emulsions are used as detection reagents, the accuracy of detecting nitroaromatic explosives improves significantly, with a quenching constant of 92.28×10 7 . This advancement facilitates the application of AIE molecules in chemical sensing. Supplementary Material File (aqueous micellar-catalyzed 250418.docx) Download 3.79 MB Information & Authors Information Version history V1 Version 1 21 April 2025 Peer review timeline Published Chem & Bio Engineering Version of Record 4 Mar 2026 Published Copyright This work is licensed under a Non Exclusive No Reuse License. Keywords aie micellar catalysis thioetherification Authors Affiliations Zhike Qiu Fuzhou University School of Chemical Engineering View all articles by this author Yulan Chen Fuzhou University School of Chemical Engineering View all articles by this author Linxi Hou Fuzhou University School of Chemical Engineering View all articles by this author Xiangyu Ying Fuzhou University School of Chemical Engineering View all articles by this author Jianquan Hong Jiangnan University School of Chemical and Material Engineering View all articles by this author Xin Ge 0000-0001-9058-0544 [email protected] Fuzhou University School of Chemical Engineering View all articles by this author Metrics & Citations Metrics Article Usage 190 views 81 downloads .FvxKWukQNSOunydq8rnd { width: 100px; } Citations Download citation Zhike Qiu, Yulan Chen, Linxi Hou, et al. Aqueous Micellar-Catalyzed Thioetherification for the Synthesis of Aggregation-Induced Emission Molecules. Authorea . 21 April 2025. 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