Exfoliated g-C3N4/γ-Fe2O3/ZnO yolk-shell nanoparticles: A novel and magnetic recyclable photocatalyst towards eco-friendly degradation of organic pollutants using visible light irradiation

Abstract Herein, a new visible-light active exfoliated g-C3N4/γ-Fe2O3/ZnO yolk-shell nanoparticles (NPs) was synthesized as a magnetically separable photocatalyst. For an in-depth understanding of the magnetic photocatalyst's structural, morphological, and optical properties, the products were extensively characterized with FT-IR, XRD, TEM, FESEM, EDS, VSM, DRS, EIS, and Photocurrent. The photocatalyst was then utilized to degrade Levofloxacin (LEVO) and Indigo Carmine (IC) by visible light at room temperature. The exfoliated g-C3N4/γ-Fe2O3/ZnO yolk-shell NPs photocatalyst revealed 80% and 95.6% degradation efficiency for Levofloxacin and Indigo Carmine within 25 and 15 min, respectively. In addition, the optimal factors such as concentration, loading of photocatalyst and pH was also assessed. Levofloxacin degradation mechanistic studies showed that electrons and holes significantly contribute to the photocatalytic process of photocatalyst degradation. In addition, after 5 times regeneration, exfoliated g-C3N4/γ-Fe2O3/ZnO yolk-shell NPs remained as an excellent magnetic photocatalyst for the environmental-friendly degradation of Levofloxacin and Indigo Carmine (76% and 90%), respectively.