Model Smoke Stream Adsorption over Cellulose Acetate Stick with Three-dimensional Temperature Gradient by Combining in-situ DRIFTS with Infrared Thermal Imaging

Model Smoke Stream Adsorption over Cellulose Acetate Stick with Three-dimensional Temperature Gradient by Combining in-situ DRIFTS with Infrared Thermal Imaging | Research Square window.SnipcartSettings = { analytics: { enabled: false } }; (function() { var accessVector = localStorage.getItem('access_vector') || ''; window.dataLayer = window.dataLayer || []; if (accessVector) { window.dataLayer.push({ user: { profile: { profileInfo: { snid: accessVector } } } }); } })(); (function(w,d,s,l,i){w[l]=w[l]||[];w[l].push({'gtm.start':new Date().getTime(),event:'gtm.js'});var f=d.getElementsByTagName(s)[0],j=d.createElement(s),dl=l!='dataLayer'?'&l='+l:'';j.async=true;j.src='https://www.googletagmanager.com/gtm.js?id='+i+dl;f.parentNode.insertBefore(j,f);})(window,document,'script','dataLayer','GTM-K279D39R'); Browse Preprints In Review Journals COVID-19 Preprints AJE Video Bytes Research Tools Research Promotion AJE Professional Editing AJE Rubriq About Preprint Platform In Review Editorial Policies Our Team Advisory Board Help Center Sign In Submit a Preprint Cite Share Download PDF Research Article Model Smoke Stream Adsorption over Cellulose Acetate Stick with Three-dimensional Temperature Gradient by Combining in-situ DRIFTS with Infrared Thermal Imaging Xin Xu, Xi Du, Feng Zheng, Lisheng Guo, Panwei Shi, Mengmeng Li, and 4 more This is a preprint; it has not been peer reviewed by a journal. https://doi.org/ 10.21203/rs.3.rs-883660/v1 This work is licensed under a CC BY 4.0 License Status: Published Journal Publication published 10 Jan, 2022 Read the published version in Cellulose → Version 1 posted 4 You are reading this latest preprint version Abstract Understanding the adsorption of the smoke stream (SR) on cellulose acetate stick as cigarette filter with different temperatures is beneficial for controlling chemical emissions and reducing the toxic effect of smoking on human health. However the investigation of corresponding adsorption properties was missing because the adsorption of smoke stream (SR) on cigarette cellulose acetate stick is sensitive with the three-dimensional temperature gradient. In this work, the adsorption of typical smoke stream substances, such as CO, propylene glycol, formaldehyde, and acetone, on cellulose acetate stick were studied by in-situ diffuse reflectance Fourier transform infrared spectroscopy with different temperatures assisted by the infrared thermal imaging method. The adsorption capacities of cellulose acetate stick to these typical smoke stream substances is dependent on the adsorption time and temperature. The adsorption properties all fitted well with the Freundlich model. By a spectroscopic and mathematical explanation, quantifying contours of adsorption was performed. The 3D model of the normalized CO adsorption of cellulose acetate stick versus the spatial coordinates and time was established. This study gives unparalleled insight into smoking release characteristics of tobacco filtered by cellulose acetate and regulating cellulose acetate stick for reducing the negative effect of smoke on human health. Biological Chemistry Chemical Engineering Cellulose Acetate Stick in -situ DRIFTS CO Smoke Stream Temperature Distribution 3D Adsorption Model Full Text Supplementary Files SIsubmission.docx Cite Share Download PDF Status: Published Journal Publication published 10 Jan, 2022 Read the published version in Cellulose → Version 1 posted Reviews received at journal 14 Sep, 2021 Reviewers invited by journal 13 Sep, 2021 Editor invited by journal 12 Sep, 2021 First submitted to journal 06 Sep, 2021 You are reading this latest preprint version Research Square lets you share your work early, gain feedback from the community, and start making changes to your manuscript prior to peer review in a journal. As a division of Research Square Company, we’re committed to making research communication faster, fairer, and more useful. We do this by developing innovative software and high quality services for the global research community. Our growing team is made up of researchers and industry professionals working together to solve the most critical problems facing scientific publishing. Also discoverable on Platform About Our Team In Review Editorial Policies Advisory Board Help Center Resources Author Services Accessibility API Access RSS feed Manage Cookie Preferences © Research Square 2026 | ISSN 2693-5015 (online) Privacy Policy Terms of Service Do Not Sell My Personal Information {"props":{"pageProps":{"initialData":{"identity":"rs-883660","acceptedTermsAndConditions":true,"allowDirectSubmit":false,"archivedVersions":[],"articleType":"Research Article","associatedPublications":[],"authors":[{"id":51998657,"identity":"3336b1f7-6583-46d0-b1c4-fc0c1bbaa0e6","order_by":0,"name":"Xin Xu","email":"","orcid":"","institution":"China Tobacco Yunnan Industrial Co Ltd","correspondingAuthor":false,"submittingAuthor":false,"prefix":"","firstName":"Xin","middleName":"","lastName":"Xu","suffix":""},{"id":51998658,"identity":"f6dfb339-623a-4f33-8b97-3f7e7b31b0bf","order_by":1,"name":"Xi Du","email":"","orcid":"","institution":"Eastman Shuangwei Fibers Company Ltd","correspondingAuthor":false,"submittingAuthor":false,"prefix":"","firstName":"Xi","middleName":"","lastName":"Du","suffix":""},{"id":51998659,"identity":"9749a4a8-1777-4156-8c0e-8192ae6f302d","order_by":2,"name":"Feng Zheng","email":"","orcid":"","institution":"Anhui Tobacco Industrial Co Ltd","correspondingAuthor":false,"submittingAuthor":false,"prefix":"","firstName":"Feng","middleName":"","lastName":"Zheng","suffix":""},{"id":51998660,"identity":"382a0f17-5759-421e-b8c9-6490ca5548bd","order_by":3,"name":"Lisheng Guo","email":"","orcid":"","institution":"Anhui University","correspondingAuthor":false,"submittingAuthor":false,"prefix":"","firstName":"Lisheng","middleName":"","lastName":"Guo","suffix":""},{"id":51998661,"identity":"f2c96b33-f0a7-42a5-91ee-3a1f37bed69a","order_by":4,"name":"Panwei Shi","email":"","orcid":"","institution":"Eastman Shuangwei Fibers Company Ltd","correspondingAuthor":false,"submittingAuthor":false,"prefix":"","firstName":"Panwei","middleName":"","lastName":"Shi","suffix":""},{"id":51998662,"identity":"8fc628ef-444e-4d9b-83bc-2e6fbf9363b5","order_by":5,"name":"Mengmeng Li","email":"","orcid":"","institution":"Anhui University","correspondingAuthor":false,"submittingAuthor":false,"prefix":"","firstName":"Mengmeng","middleName":"","lastName":"Li","suffix":""},{"id":51998663,"identity":"bc1c2069-eea2-46e3-869f-834983c8f738","order_by":6,"name":"Zhengyu Fang","email":"","orcid":"","institution":"Anhui University","correspondingAuthor":false,"submittingAuthor":false,"prefix":"","firstName":"Zhengyu","middleName":"","lastName":"Fang","suffix":""},{"id":51998664,"identity":"f482aa5d-92e5-45e5-b267-7640486d9874","order_by":7,"name":"Jiuyi Liu","email":"","orcid":"","institution":"Anhui University","correspondingAuthor":false,"submittingAuthor":false,"prefix":"","firstName":"Jiuyi","middleName":"","lastName":"Liu","suffix":""},{"id":51998665,"identity":"e81b8448-c542-4309-8809-ddff55011740","order_by":8,"name":"Mengdie Cai","email":"data:image/png;base64,iVBORw0KGgoAAAANSUhEUgAAAZAAAAAyAQMAAABI0h/eAAAABlBMVEX///8AAABVwtN+AAAACXBIWXMAAA7EAAAOxAGVKw4bAAAA/UlEQVRIiWNgGAWjYFACxgYw2cbA2Pjg4z8bHn7+BqK1MDcbzmBLk5GccYBou9jbpHnYDtsYNCTgV8rffrh1w8cdtbJ97I1tkjN4zvMYMBxg/PAxB7cWiTOJbTdnnjlu3MZzsNnig8RtHnPmBmbJmdtwazFgSGy7zdt2LLFNIrHx5gyD2zyWDQfYmHnxaeF/2Hb7L0iL/MMGaZ6EczwGBxIIaJEA2sLYVgO0hbFJmufAAcJaJG48bLvZ23YA6JfEZsOZDck8kjMONuP1C39/+rMbP9vqZOe3H3/44GODnT0/f/PBDx/xaIGCw8gcSOQSAnXEKBoFo2AUjIKRCgCw4Vw9Z9wwYgAAAABJRU5ErkJggg==","orcid":"https://orcid.org/0000-0002-7605-4895","institution":"Anhui University","correspondingAuthor":true,"submittingAuthor":false,"prefix":"","firstName":"Mengdie","middleName":"","lastName":"Cai","suffix":""},{"id":51998666,"identity":"17196273-33ce-4ea6-a808-fe7fbcac2d3b","order_by":9,"name":"Song Sun","email":"","orcid":"","institution":"Anhui University","correspondingAuthor":false,"submittingAuthor":false,"prefix":"","firstName":"Song","middleName":"","lastName":"Sun","suffix":""}],"badges":[],"createdAt":"2021-09-07 17:24:23","currentVersionCode":1,"declarations":"","doi":"10.21203/rs.3.rs-883660/v1","doiUrl":"https://doi.org/10.21203/rs.3.rs-883660/v1","draftVersion":[],"editorialEvents":[{"content":"https://doi.org/10.1007/s10570-022-04415-x","type":"published","date":"2022-01-10T13:50:50+00:00"}],"editorialNote":"","failedWorkflow":false,"files":[{"id":17159268,"identity":"3ca94c85-e9fe-4e40-b585-e01ef9990b20","added_by":"auto","created_at":"2022-01-10 13:51:03","extension":"pdf","order_by":1,"title":"","display":"","copyAsset":false,"role":"manuscript-pdf","size":1155395,"visible":true,"origin":"","legend":"","description":"","filename":"ManuscriptESFCsubmission.pdf","url":"https://assets-eu.researchsquare.com/files/rs-883660/v1_covered.pdf"},{"id":13783417,"identity":"ef383bc3-cb49-452e-9bab-648dea7ac65c","added_by":"auto","created_at":"2021-09-20 15:56:54","extension":"pdf","order_by":1,"title":"","display":"","copyAsset":false,"role":"manuscript-pdf","size":1150288,"visible":true,"origin":"","legend":"","description":"","filename":"ManuscriptESFCsubmission.pdf","url":"https://assets-eu.researchsquare.com/files/rs-883660/v1_covered.pdf"},{"id":13783390,"identity":"cc89be4a-115c-4a5c-807e-2802c8f5ea5c","added_by":"auto","created_at":"2021-09-20 15:56:48","extension":"docx","order_by":4,"title":"","display":"","copyAsset":false,"role":"supplement","size":2034786,"visible":true,"origin":"","legend":"","description":"","filename":"SIsubmission.docx","url":"https://assets-eu.researchsquare.com/files/rs-883660/v1/da68d6ff0ff0851032d755d8.docx"}],"financialInterests":"","formattedTitle":"Model Smoke Stream Adsorption over Cellulose Acetate Stick with Three-dimensional Temperature Gradient by Combining in-situ DRIFTS with Infrared Thermal Imaging","fulltext":[{"header":"Full Text","content":"This preprint is available for \u003ca href='/article/rs-883660/latest.pdf' target='_blank'\u003edownload as a PDF\u003c/a\u003e."}],"fulltextSource":"","fullText":"","funders":[],"hasAdminPriorityOnWorkflow":false,"hasManuscriptDocX":false,"hasOptedInToPreprint":true,"hasPassedJournalQc":"","hasAnyPriority":false,"hideJournal":false,"highlight":"","institution":"","isAcceptedByJournal":true,"isAuthorSuppliedPdf":true,"isDeskRejected":"","isHiddenFromSearch":false,"isInQc":false,"isInWorkflow":true,"isPdf":false,"isPdfUpToDate":true,"isWithdrawnOrRetracted":false,"journal":{"display":true,"email":"[email protected]","identity":"cellulose","isNatureJournal":false,"hasQc":true,"allowDirectSubmit":false,"externalIdentity":"cels","sideBox":"Learn more about [Cellulose](https://www.springer.com/journal/10570)","snPcode":"10570","submissionUrl":"https://submission.nature.com/new-submission/10570/3","title":"Cellulose","twitterHandle":"","acdcEnabled":true,"dfaEnabled":true,"editorialSystem":"em","reportingPortfolio":"Springer Hybrid","inReviewEnabled":true,"inReviewRevisionsEnabled":false},"keywords":"Cellulose Acetate Stick, in -situ, DRIFTS, CO, Smoke Stream, Temperature Distribution, 3D Adsorption Model","lastPublishedDoi":"10.21203/rs.3.rs-883660/v1","lastPublishedDoiUrl":"https://doi.org/10.21203/rs.3.rs-883660/v1","license":{"name":"CC BY 4.0","url":"https://creativecommons.org/licenses/by/4.0/"},"manuscriptAbstract":"Understanding the adsorption of the smoke stream (SR) on cellulose acetate stick as cigarette filter with different temperatures is beneficial for controlling chemical emissions and reducing the toxic effect of smoking on human health. However the investigation of corresponding adsorption properties was missing because the adsorption of smoke stream (SR) on cigarette cellulose acetate stick is sensitive with the three-dimensional temperature gradient. In this work, the adsorption of typical smoke stream substances, such as CO, propylene glycol, formaldehyde, and acetone, on cellulose acetate stick were studied by in-situ diffuse reflectance Fourier transform infrared spectroscopy with different temperatures assisted by the infrared thermal imaging method. The adsorption capacities of cellulose acetate stick to these typical smoke stream substances is dependent on the adsorption time and temperature. The adsorption properties all fitted well with the Freundlich model. By a spectroscopic and mathematical explanation, quantifying contours of adsorption was performed. The 3D model of the normalized CO adsorption of cellulose acetate stick versus the spatial coordinates and time was established. This study gives unparalleled insight into smoking release characteristics of tobacco filtered by cellulose acetate and regulating cellulose acetate stick for reducing the negative effect of smoke on human health.","manuscriptTitle":"Model Smoke Stream Adsorption over Cellulose Acetate Stick with Three-dimensional Temperature Gradient by Combining in-situ DRIFTS with Infrared Thermal Imaging","msid":"","msnumber":"","nonDraftVersions":[{"code":1,"date":"2021-09-20 15:56:46","doi":"10.21203/rs.3.rs-883660/v1","editorialEvents":[{"type":"communityComments","content":0},{"type":"editorInvitedReview","content":"","date":"2021-09-14T17:52:28+00:00","index":0,"fulltext":""},{"type":"reviewersInvited","content":"","date":"2021-09-14T00:37:24+00:00","index":"","fulltext":""},{"type":"editorInvited","content":"Cellulose","date":"2021-09-12T15:11:09+00:00","index":"","fulltext":""},{"type":"submitted","content":"Cellulose","date":"2021-09-06T10:26:37+00:00","index":"","fulltext":""}],"status":"published","journal":{"display":true,"email":"[email protected]","identity":"cellulose","isNatureJournal":false,"hasQc":true,"allowDirectSubmit":false,"externalIdentity":"cels","sideBox":"Learn more about [Cellulose](https://www.springer.com/journal/10570)","snPcode":"10570","submissionUrl":"https://submission.nature.com/new-submission/10570/3","title":"Cellulose","twitterHandle":"","acdcEnabled":true,"dfaEnabled":true,"editorialSystem":"em","reportingPortfolio":"Springer Hybrid","inReviewEnabled":true,"inReviewRevisionsEnabled":false}}],"origin":"","ownerIdentity":"334c6580-3cbb-48a3-b44c-7a923bed8510","owner":[],"postedDate":"September 20th, 2021","published":true,"recentEditorialEvents":[],"rejectedJournal":[],"revision":"","amendment":"","status":"published-in-journal","subjectAreas":[{"id":7296077,"name":"Biological Chemistry"},{"id":7296078,"name":"Chemical Engineering"}],"tags":[],"updatedAt":"2022-01-10T13:50:50+00:00","versionOfRecord":{"articleIdentity":"rs-883660","link":"https://doi.org/10.1007/s10570-022-04415-x","journal":{"identity":"cellulose","isVorOnly":false,"title":"Cellulose"},"publishedOn":"2022-01-10 13:50:50","publishedOnDateReadable":"January 10th, 2022"},"versionCreatedAt":"2021-09-20 15:56:46","video":"","vorDoi":"10.1007/s10570-022-04415-x","vorDoiUrl":"https://doi.org/10.1007/s10570-022-04415-x","workflowStages":[]},"version":"v1","identity":"rs-883660","journalConfig":"researchsquare"},"__N_SSP":true},"page":"/article/[identity]/[[...version]]","query":{"redirect":"/article/rs-883660","identity":"rs-883660","version":["v1"]},"buildId":"7rjqhiLT3MXkJMwkYKINL","isFallback":false,"isExperimentalCompile":false,"dynamicIds":[84888],"gssp":true,"scriptLoader":[]}