Direct C--H Arylation of Heteroarenes by Merging Nitrate Reduction with Photocatalysis

Direct C--H Arylation of Heteroarenes by Merging Nitrate Reduction with Photocatalysis | Authorea try { document.documentElement.classList.add('js'); } catch (e) { } var _gaq = _gaq || []; _gaq.push(['_setAccount', 'G-8VDV14Y67G']); _gaq.push(['_trackPageview']); (function() { var ga = document.createElement('script'); ga.type = 'text/javascript'; ga.async = true; ga.src = ('https:' == document.location.protocol ? 'https://ssl' : 'http://www') + '.google-analytics.com/ga.js'; var s = document.getElementsByTagName('script')[0]; s.parentNode.insertBefore(ga, s); })(); Skip to main content Preprints Collections Wiley Open Research IET Open Research Ecological Society of Japan All Collections About About Authorea FAQs Contact Us Quick Search anywhere Search for preprint articles, keywords, etc. Search Search ADVANCED SEARCH SCROLL This is a preprint and has not been peer reviewed. Data may be preliminary. 12 November 2025 V1 Latest version Share on Direct C--H Arylation of Heteroarenes by Merging Nitrate Reduction with Photocatalysis Authors : Liang Wang 0000-0002-5367-1516 [email protected] , Jing-Yao Zhou , Yan Yang , Yi-Xie Tan , Xin-Chun Zhang , Li-Jun Xu , and Yong-Sheng Zhou Authors Info & Affiliations https://doi.org/10.22541/au.176293498.82811018/v1 187 views 109 downloads Contents Abstract Supplementary Material Information & Authors Metrics & Citations View Options References Figures Tables Media Share Abstract Aryldiazonium salts continue to play a significant role in organic synthesis, but their synthetic processes remain considerably hazardous. Herein, a green arylation of heteroarenes from simple anilines was achieved by merging nitrate reduction with photocatalysis. Anilines were initially converted to the fleeting diazonium salts in the presence of iron(III) nitrate and sodium thiosulfate, followed by coupling with heteroarenes under photocatalysis. This reaction utilizes low-hazard and readily available starting materials, affording a series of arylated heteroarenes with good yields in a safer single step. Supplementary Material File (manuscript.doc) Download 6.45 MB Information & Authors Information Version history V1 Version 1 12 November 2025 Copyright This work is licensed under a Non Exclusive No Reuse License. Keywords aryldiazonium salts c–h arylation heteroarenes nitrate reduction photocatalysis Authors Affiliations Liang Wang 0000-0002-5367-1516 [email protected] Changzhou Vocational Institute of Engineering View all articles by this author Jing-Yao Zhou Changzhou Vocational Institute of Engineering View all articles by this author Yan Yang Changzhou University School of Petrochemical Engineering View all articles by this author Yi-Xie Tan Changzhou Vocational Institute of Engineering View all articles by this author Xin-Chun Zhang Changzhou Vocational Institute of Engineering View all articles by this author Li-Jun Xu Changzhou Vocational Institute of Engineering View all articles by this author Yong-Sheng Zhou Changzhou University School of Petrochemical Engineering View all articles by this author Metrics & Citations Metrics Article Usage 187 views 109 downloads .FvxKWukQNSOunydq8rnd { width: 100px; } Citations Download citation Liang Wang, Jing-Yao Zhou, Yan Yang, et al. Direct C--H Arylation of Heteroarenes by Merging Nitrate Reduction with Photocatalysis. Authorea . 12 November 2025. DOI: https://doi.org/10.22541/au.176293498.82811018/v1 If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download. For more information or tips please see 'Downloading to a citation manager' in the Help menu . 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