Direct Access to (±)-10-Desbromoarborescidine A from Tryptamine and Pentan-1,5-diol

2019 · doi:10.26434/chemrxiv.11341379.v1
preprint OA: closed CC-BY-NC-ND-4.0
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Abstract

A single step synthetic strategy for (±)10- Desbromoarborescidine A is described. Starting from tryptamine and pentan-1,5-diol, this acceptorless dehydrogenative condensation process is efficiently catalyzed by a ruthenium complex featuring proton-responsive phosphine pyridone ligand. Manuscript is available supporting material is available and includes experimental procedures, characterization of compounds, 1H, 13C NMR spectra and chromatograms.

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europepmc
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License: CC-BY-NC-ND-4.0