Technical economic and environmental assessment of biorefinery schemes by agro-industrial residues approach in Santander

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Research confirms the innumerable benefits of using other biomass to obtain chemical products, biofuels, fuels, and energy, among value-added products. Among the benefits, it is highlighted that using processes incorporating clean technologies makes obtaining added value while conserving the environment possible. This work aimed to evaluate the technical, economic, and environmental feasibility of valuing agro-industrial waste present in Santander (Colombia), such as coffee mucilage, cocoa, and pig manure under biorefinery-type processes, where different products desired by the economic sector of the study area can be obtained. Initially, a basic level of three biorefinery schemes is designed, where the main products are hydrogen, methane, biogas, and biofertilizer. Subsequently, technical, economic, and environmental indicators were evaluated for each scheme to finally integrate these indicators and select the best alternative for the Santander context. Biorefineries Anaerobic Digestion Dark Fermentation Techno-economic evaluation Life Cycle Assessment (LCA) Figures Figure 1 Figure 2 Figure 3 Figure 4 Figure 5 Figure 6 Figure 7 Figure 8 Figure 9 Figure 10 Figure 11 Figure 12 Figure 13 1. Introduction Utilizing sustainable resources is essential for the growth and development of the agro-industrial sector, offering a viable pathway for renewable energy production and the generation of environmentally friendly fuels. Biomass, derived from agro-industrial residues, remains an underutilized resource despite its significant energy potential. Biorefineries can be a sustainable solution by converting waste materials such as coffee mucilage, cocoa mucilage, and pig manure into biofuels and value-added products. In Santander, agro-industrial waste disposal primarily relies on traditional methods, which limit resource efficiency and contribute to environmental pollution (Contreras, 2015). Modernizing these processes by harnessing biomass energy potential could enhance fuel production and support sustainable waste management strategies. The theoretical energy potential of agro-industrial waste in Colombia exceeds 75,000 TJ/year, which could generate up to 6,260 GWh/year, equivalent to 9.4% of the country's total energy production in 2015. However, much of this energy remains untapped due to waste dispersion in extensive agricultural systems (Arboleda & Lora, 2018). Among agro-industrial residues, pig manure is the most exploited for energy generation due to its ease of collection within confined livestock systems. Implementing anaerobic biodigesters in pig farms could efficiently convert manure into biomethane and high-quality organic fertilizers with reduced microbial content (Díaz et al., 2021). Conversely, coffee mucilage, a byproduct of coffee processing, presents significant potential for biogas production, as each kilogram of cherry coffee generates approximately 91 mL of mucilage (Zambrano et al., 1994). Given that Colombia exports approximately one million 60-kg bags of almond coffee annually, an estimated 55,500 tons of fresh mucilage are produced as waste (Rodríguez et al., 2014). Similarly, cocoa mucilage represents a valuable biomass resource due to Santander's dominant role in national cocoa production, contributing 41% of Colombia’s total output (Minagricultura, 2021). Despite its energy potential, cocoa mucilage remains underutilized, emphasizing the need for integrated biorefinery solutions. Pig manure has proven viable for biogas production, supporting sustainable energy initiatives within Santander's agricultural sector (Contexto Ganadero, 2020). This study explores the techno-economic and environmental feasibility of utilizing coffee mucilage, cocoa mucilage, and pig manure within biorefinery systems. This research aims to identify optimal strategies for implementing biorefinery-based waste management solutions in agro-industrial settings by analyzing energy conversion efficiencies, economic viability, and environmental impacts. Table 1 shows the biomass generated by each sector in tons per year, according to the information collected by Velásquez et al. (2018). Table 1 Livestock biomass sector Sector Biomass Ton/year Poultry Manure 6.518.795 Pig Manure 2.745.392 Cattle Manure 83.497.181 Velásquez, M, et, al 2018. Most forms of biomass are potential renewable resources with attractive biorefinery compositions in multiple products, including bioenergy and bioactive compounds, that could reduce dependence on fossil fuels and improve revenue streams. However, the current use of biomass is still low, with an estimated contribution of 14% to global energy (Tursi, A., 2019). Due to the need to satisfy the municipal energy demand, the Biorefinery concept was born to optimize biomass processing, make it more efficient, and minimize its environmental impacts. The economic development of biorefinery has the approach of the sustainable development framework (Cervantes et al., 2017). Feasibility studies of existing processes in biorefineries of agro-industrial wastes such as coffee mucilage, cocoa mucilage, and pig manure are limited in quantity and generate waste streams that need additional treatment. Depending on the origin of the plants, different methodologies can be applied for the recovery of agro-industrial waste; among them are the anaerobic co-digestion processes, where an alternative is offered for the treatment of any biodegradable residue or organic waste (Montenegro et al., 2016). Mosquera et al. (2020) consider the significant influence of the different operating parameters on biogas production during the anaerobic co-digestion of different substrates available in Colombia, creating box-Behnken experiment designs based on the physicochemical characterization of the percentage of nitrogen in digestion processes. Other authors evaluated the valorization of the liquid effluent from the biodigester to obtain struvite through anaerobic digestion, modeling only the reactor in APPEN, another process such as fermentation (for reducing sugars and carbohydrates), transesterification (for oils and fats), and anaerobic digestion (for organic waste). Ethanol, methanol, n-butanol (from sugars), biodiesel (from oils), and biogas (from organic waste) are obtained from these processes (Álvarez, 2009). López Dávila et al. (2012) report that the digestion process is immediately inhibited due to the high nitrogen content of pig manure. However, microorganisms can acclimatize, decreasing volatile fatty acid concentration and producing high volumes of biogas. Anaerobic digestion is the biological oxidation of organic matter through specific microorganisms without molecular oxygen. In this process, organic matter is transformed into stable and inert products, and biogas mainly comprises methane and carbon dioxide (García, 2009, pp. 35–49). This process is considered one of the most useful for reducing greenhouse gas emissions and using organic waste as energy (Flotats et al., 2001, pp. 51–65). Aspen Plus has been used to evaluate the feasibility and limitations of combining unitary processes in the generation of integrated biorefineries for the recovery of multiple products (Aghbashlo et al., 2018; Davila et al., 2015; Humbird et al., 2011; Lohrasbi et al., 2010). The different process simulation models generate mass and energy balances for correctly selecting equipment and estimating costs. When combined with economic modules such as Aspen Plus, this method can be used for cost-benefit analysis and provide research and investment insights for new product development, expansion, and improvement: technology and its economic viability. (Manhongo et al., 2021). By generating models of biorefinery processes, these can be combined with environmental impact assessments to identify relevant environmental bottlenecks and critical points for technological improvements (Kwant et al., 2018). Life cycle assessment (LCA) is a methodology that identifies, quantifies, and characterizes the different potential environmental impacts associated with each of the life cycle stages of a product. It focuses on redesigning products under the criteria that energy resources and raw materials are not unlimited and that, commonly, they are used faster than they are replaced or new alternatives emerge. Implementing clean technologies in Santander, Colombia, is scarce since there is no regulatory surveillance regarding managing this waste (Cendales, 2011, p.4); this contradicts what was expressed in the departmental development plan 2016–2019, in which Santander is proposed as an area of high energy potential (Mendivelso, 2018). In this way, the conservation of resources privileges reducing the amount of waste generated through the product. Since this waste will continue to be produced, the ACV proposed to manage the waste sustainably from the environmental point of view, minimizing all the impacts associated with the management system (Environmental Forum, 2003). 2. Materials and methods Three biorefinery scenarios were proposed for this research. These scenarios were initially simulated using Aspen Plus (Aspen Technology, Inc., USA), a commercial simulation software package. Aspen Plus was chosen due to its extensive library of conventional process equipment models and biological, thermodynamic, and mathematical models. This software also integrates Aspen Economic Analyzer (Aspen Technology, Inc., USA) to evaluate capital and operating costs. Following the simulation, a life cycle analysis was conducted using the ReCiPe 2015 Midpoint (H) methodology implemented in SimaPro v9.0 software. This methodology evaluates emissions and resource depletion, translating them into limited impact categories. The methodological procedures employed to attain the study objectives are described below. 2.1. Capacity and demand of Biorefinery plants. The capacity to be installed was evaluated considering the availability of raw materials in Santander's department. Santander is one of the regions with the highest growth of the two crops studied (coffee and cocoa), with a significant relationship in the amount of valuable mucilage capable of producing biogas. Cocoa production is concentrated in the country's northeast, and the Santander region contributes 28,474 tons/year; coffee production was estimated at 54,203 tons/year; pig production was 92,600 heads/year (DANE, 2017). In general, the above data indicated that the availability of coffee mucilage (CFM), cocoa mucilage (CCM), and pig manure (S.M.) in the study area is 3,545 tons, 4,499 tons, and 57,910 tons, respectively (DANE, 2017). This way, 4.62 t/day of cocoa mucilage was processed, 1.83 t/day of coffee mucilage, and 25.25 t/day of pig manure. Likewise, the plant's general processing capacity was estimated at 238,099 t/day and 902,701 t/day of residual process water for a total AD-OUT LIQ digestate of 1140.8 t/day. The plant's annual operating time is 24 hours/day for 330 days. 2.2. Design and modeling of Processes in ASPEN PLUS Three industrial-scale biorefinery-type process schemes were simulated. The simulation was carried out to validate the proposed three conceptual designs, obtaining productivity and performance indicators of the products obtained in each case study. Additionally, the simulations allowed for calculating and verifying design factors such as the equipment's type, number, size, installed capacity, and approximate cost. (González & Torres, 2019). 2.3. Biorefinery scenario description By comparison, three scenarios were presented for using agro-industrial residues under biorefinery-type processing schemes. The residues used were coffee mucilage, cocoa mucilage, and pig manure. In the first proposed scheme, priority was given to producing hydrogen (H 2 ) and methane (CH 4 ). In addition to H 2 production, operations for reforming the CH 4 produced were incorporated in the second scheme. Finally, in the third biorefinery scheme, the generation of methanol and hydrogen obtained from reforming the residual gases of the separation process was proposed. The main stages of the process of coffee mucilage, cocoa mucilage, and pig manure, the preparation of raw materials, dark fermentation, anaerobic digestion, biogas processing, and digestate processing were implemented. These processes were combined into three biorefinery scenarios described in the following subsections. In the three schemes, the preparation stage or initial scheme begins with mixing the substrates in the proportion described in Section 2.1 . Then, the transported raw materials were preheated (here, an energy consumption of 2,411,423,468 kJ/ h). The transformation began using a specialized dark fermentation reactor where a current of biogas product was obtained, and an effluent was subsequently conducted to a second reactor specialized in anaerobic digestion. The digestate produced after the anaerobic digestion reactor is decanted, and the sludge passes to centrifugal dryers, bringing it to 80% humidity. 2.3.1. Scenario 1 Scenario 1 ( Fig. 1 ) is the biorefinery scheme obtained from the simulation of the process model, that is, without any modification, is characterized because the gases are conducted to an initial heat exchanger and then to a column where filtration is applied to remove H 2 S and NH 3 ; then the gas is compressed and after it experiences a pressure drop when passing through the filter and reaching the three purification columns, through reforming a biogas current of 88% and a bio-hydrogen production of 12% are obtained. 2.3.2 Scenario 2 The second scenario was adopted according to Clauser et al. (2021), which constantly shows how, in biorefineries, the dark fermentation process begins in substrates rich in carbohydrates and starch, helping with the operation of other equipment and prioritizing the production of gas with higher calorific value, such as hydrogen. In scheme 2, shown in Fig. 2 , different conditions were taken for biogas. After the initial stage, the biogas passes through the heat exchanger, and 77,576.51 kJ/h is added to the process, passing through a biofilter column and increasing the pressure in the compressor to 3.0398MPa. Finally, it is removed. H 2 S and NH 3 . Separation columns S103-S104-S105 helped remove CO and CO 2 after hydrogen production. After separating carbon dioxide and carbon dioxide in column S105, a recovery rich in methane is achieved, which is taken to a reforming reactor, obtaining residual water. The mechanization process is inserted into the reforming process to take advantage of the biogas in energy transformation, increasing profitability and entering it back into the system as a recycle-to-exchanger 2. (Fernando et al., 2006). 2.3.2. Scenario 3 Finally, gas treatment was given priority in the simulation of scheme three as the main product since they are a direct energy source for the agroindustry (Fig. 3 ). Currently, 1% of the country's final electricity consumption is consumed yearly (IEA, 2020) once the initial stage of separation and recycling of the methane-rich stream proceeds. An H 2 transformation process is carried out for 88% of the production to treat the gases emitted in the separator tanks S103-S104-S105, increasing the temperature and pressure to 3.0398MPa, helping the cogeneration of METHANOL and subsequently a waste of wastewater. 2.4 Life cycle assessment (LCA) of Biorefinery scenarios Life cycle assessment (LCA) is essential for decision-making and policy formulation related to the valorization of agro-industrial waste proposed in biorefinery schemes. The impacts of product choice on the environmental loads of coffee mucilage, cocoa mucilage, and pig manure residues were thus demonstrated, identifying critical point unit processes along biorefinery process routes. Using data generated from Aspen Plus-based process models and economic analysis, life cycle analysis (LCA) was carried out to evaluate the environmental impacts of the three scenarios presented in section 2.3. The inventory was translated into environmental loads using the ReCiPe 2015 MidPoint (H) methodology available in SimaPro v9.0 software, where emissions and resource disposal are assessed, translating them into a limited number of impact scores. Environmental. Table 2 shows the environmental impact categories and their descriptions. Table 2 Environmental impact categories reported by the ReCiPe 2015 LCA method. Impact Category/ Indicator Unit Description Climate change total. Fossil, biogenic, and land use Kg CO2-eq An indicator of potential global warming due to emissions of greenhouse gases to the air. Divided into 3 subcategories based on the emission source: (1) fossil resources, (2) bio-based resources, and (3) land use change. Ozone depletion Kg CFC-11-eq Indicator of emissions to air that destroys the stratospheric ozone layer. Acidification Kg mol H+ An indicator of the potential acidification of soils and water due to releasing gases such as nitrogen and sulfur oxides. Eutrophication-freshwater Kg PO4-eq An indicator of the freshwater ecosystem enrichment with nutritional elements due to the emission of nitrogen or phosphor-containing compounds. Eutrophication-marine Kg N-eq An indicator of the marine ecosystem enrichment with nutritional elements due to the emission of nitrogen-containing compounds. Eutrophication-terrestrial mol N-eq Indicators of the terrestrial ecosystem enrichment with nutritional elements due to the emission of nitrogen-containing compounds. Photochemical ozone formation Kg NMVOC-eq Indicators of emission of gases that affect the creation of photochemical ozone in the lower atmosphere (smog) catalyzed by sunlight. Depletion of abiotic resources and metals Kg Sb-eq Indicator of the depletion of natural non-fossil resources. Depletion of abiotic resources- fossil fuels M.J., net calorific value. An indicator of the depletion of natural fossil fuel resources. Human toxicity-cancer CTUh Impact on humans of toxic substances emitted to the environment. Ecotoxicity (freshwater) CTUe Impact on freshwater organisms of toxic substances emitted to the environment. Water use m3 world eq. deprived. The indicator of the relative amount of water used is based on regionalized water scarcity factors. Land use Dimensionless Measure the changes in soil quality (Biotoc production, Erosion, resistance, Mechanical Filtration). Ionizing radiation, human health kBq U-235 Damage to human health and ecosystems linked to the emissions of radionuclides. Particulate matter emissions Disease incidence An indicator of the potential incidence of disease due to particulate matter emissions. Source: Ecochain, 2024. The software considers the impact of effluent mass and energy requirements of a chemical process based on the energy and mass balances generated in Aspen Plus. Then, the weighted sum of all impacts determined the total impact per kg, representing each category's potential environmental impact. (Pazmiño, 2018). This method converts life cycle inventories into 18 categories of medium-term effects, translating them into the environmental loads of each process in the different biorefinery schemes proposed to generate valuable products. Global warming potential (GWP), fossil resource scarcity (FRS), and water consumption (WCo) were selected as relevant categories for discussion since first-generation biorefineries would mainly affect land, water, and fossil energy resources (Martinez-Hernandez & Samsatli, 2017). 2.5 Economic Assessment The sustainability evaluation is complemented by a techno-economic assessment of its main processes, demonstrating each proposed scheme's economic viability. The objective is to find the potential to produce or manufacture one or more valuable products that generate benefits according to the investment. The economic benefit is the part of the income that can be obtained from the production process. In this way, by performing a Techno-Economic Analysis (TEA), the different stages of the process can be designed, and the costs associated with the construction and production capital investment can be determined, as well as the operating costs for each stage of the biorefinery process based on agro-industrial waste. Capital costs are represented by the initial investment, considering the sizing of the equipment to calculate its commercial price, including transportation, labor, and installation, among others. The economic evaluation of the three biorefineries shows the total costs, cost allocation associated with each biorefinery, net present value, real profit before taxes URAI, and the percentage of fixed investment capital to be used. Each biorefinery behaves differently. The total cost increases over the 10-year evaluation period as the level of integration is applied and equipment is involved in the production process. Considerations for total production costs include direct production costs or variable operating costs (VOC). These are related to the cost per unit of plant working time (US $ /day), fixed costs (F.C.), and plant overheads (Peters & Timmerhaus, 1991). Variable operating costs include directly related manufacturing costs such as raw material acquisition, utilities, labor, and waste disposal (Seider et al., 2008), while fixed costs include depreciation, property insurance, taxes, and land costs. The net present value, the minimum attractive rate of return (MARR), and the internal rate of return (IRR) were calculated using a discounted cash flow analysis assuming economic parameters relevant to Colombia according to the following Table 3 : Table 3 Inflation Index - TMAR – TIR Parameter Cost Reference Base year 2022 Minimum attractive rate of return (MARR) 29.98% MARR f = i + f + if (Arora et al., 2018; Demichelis et al., 2018; Sy et al., 2018) Inflation index 3% Average inflation years 2017–2022 Biofertilizer price ( $ /t) US $ 90.5 La República (2019) Cost H 2 ( $ /t) US $ 1000 Chacón, T. (2022). Colombia tendría el cuarto precio más bajo de hidrógeno verde en 2025. Recuperado 29 de agosto de 2022, de Rumbo Minero Internacional website: https://www.rumbominero.com/colombia/colombia-precio-hidrogeno-verde-2025/ (Arango, & Álvarez (2013)) Cost CH 4 ( $ /m 3 ) US $ 0.20 Pinoargote & Gallegos (2011) Source: Compiled by Author Total capital investments (TCI) and total production costs (TPC) were queried at the source by referenced product: Biofertilizer (Editorial La República S.A.S., 2019, February 8), Hydrogen (Arango & Alvarez, C. (2013), Methane (Pinoargote & Gallegos, 2011). Total capital investment is the sum of fixed capital cost (FCC) and working capital (W.C.), where fixed capital costs constitute total direct cost (TDC) and total indirect cost (TIC). Total direct costs of TDC include the cost of purchasing and installing equipment, instrumentation, controls, plumbing, and electrical products (Peters & Timmerhaus, 1991). 3. Results and discussion Three biorefinery schemes were analyzed where the products are taken by biological equipment and are determined by a previous study to extract the digestate and the biogas to be reformed through separation, increase in temperature, and energy in each biorefinery process detailed. The production capacities of each process were established based on the amount of waste generated by the agro-industrial processes of coffee, cocoa, and cattle production plantations in the department of Santander, which constitutes the feeding capacity of the designed process. The daily feeding capacity was set at 1140.8 tons/day with a production output of 238,099t/day, translating into a reformed Hydrogen production of 2.38t/day with a 24-hour operation. The mass and energy balance was carried out based on the requirements and implementation of each piece of equipment to extract valuable products efficiently, as shown in Table 4 . Table 4 Specification of the equipment used in the process Equipment Price Mixing tank 25.000 USD Exchanger E101 6.000 USD Exchanger E102 6.000 USD Exchanger E103 6.000 USD Exchanger E104 6.000 USD Exchanger E106 6.000 USD Exchanger E107 6.000 USD Separator S108 12,553,747 USD Reactor F.O. 89,536,124 USD Separator S1046 5.000 USD Settling tank 14.880 USD S105. 2400 L. 35.000 A 50.000 USD XLPM270A- Two-stage air compressor 73.416 USD Source: Compiled by Author, reference price from Alibaba.com Official Website 3.1 Biogas production Initially, for scenario 1 (Fig. 4 ), Through the preparation of the raw material, 4.62 t/day of cocoa mucilage is processed, 1.83 t/day of coffee mucilage, and 25.25 t/day of pig manure; where accelerating the fermentation and distillation process by increasing energy in the heat exchanger provides 2,411,423.468 Kj/h; before entering the mixture into the dark fermentation reactor, initiating the treatment of the digestate to proceed with the treatment of wastewater and sludge. Once the energy of the second exchanger increases, providing 26,190.79 Kj/h, and the pressure in the separator tanks increases, 0.41 t/day of H 2 and 6.58 t/day CH 4 are produced. It is in the initial stage of the process where the mixture of agro-industrial products is fermented and distilled, which is the same process as the biorefinery scheme 1. Biorefinery scheme 2 (Fig. 5 ): By increasing the energy, 77,576.51 KJ/h is contributed to the transformation in exchanger two, and after the separation process and pressure increase in the compressor using 3.0398 MPa, 2.836 tons/day of H 2 are obtained; In the separation process of tanks S103-S104-S105, emissions of 15,888 t/day of CO 2 and 0.37 t/day of C.O. are generated into the environment (Fig. 6 ). CH 4 6.50 tons/day production is reincorporated into the reformed process to take advantage of the biogas in the energy transformation, increasing profitability by entering it back into the system as a recycling to exchanger 2 (Fernando et al., 2006). Biorefinery scheme 3 (Fig. 6 ) proposes reducing emissions into the atmosphere through the production of methanol, satisfying the demand for this compound. In the calculation of mass balances, it is evident that hydrogen production doubles the biorefinery scheme 1, producing 0.90 Ton/day; simultaneously, the mass yield of methanol is 0.22 ton/day. Taking into account the minimum conversion rate proposed by (Lee et al., 2020), The author mentions that the production cost increases considerably when less than 1.64 tons/day is produced, which indicates that the extra cost of biorefinery three would be significantly high; comparing these results with the reforming efficiency in biorefinery one and the methanol production in biorefinery three is very low and agrees with what was supported by (Surendra et al., 2015). Considering the above data, the biorefinery with the lowest CO 2 production is biorefinery 3, with 40% efficiency due to the high carbon dioxide consumption in the methanol production phase. CO 2 e is a factor ASPEN PLUS reported that considers the energy consumption of the analyzed equipment. In this way, the production of CO 2 in biorefinery scheme 3 corresponds to 5% of the production of scheme 1 and 29% of scheme 2. The CO 2 e data is part of the heating services and additional energy increase. To systems: These can be optimized based on the energy integration of the biorefineries' designs. Biorefinery schemes 2 and 3 are more efficient and sustainable since their values ​​are below the values ​​known in traditional methods, thus demonstrating the feasibility of the processes (Lora & Nascimento, 2004). Table 5 shows the mass production results of the three biorefinery schemes. Table 5 Biogas production scheme Biorefinery scheme Product Mass Flow (Ton/day) 1 Hydrogen (H 2 ) 0.41 Methane (CH 4 ) 6.58 2 Hydrogen (H 2 ) 2.84 Carbon monoxide (CO) 0.37 3 Methanol (CH 3 OH) 0.22 Hydrogen (H 2 ) 0.90 Carbon monoxide (CO) 15.13 Source: Author One crucial factor in environmental analysis is the production of CO 2 . Table 6 provides a detailed breakdown of the daily mass of CO 2 obtained from the biorefinery processes and the production of biomass flow, which shows a yield of 40 to 58%. The high production of CO 2 in each biorefinery is a significant concern, particularly the increase in reforming, underscoring the environmental implications of these processes. Table 6 CO 2 production biorefinery schemes. Biorefinery scheme Mass flow (Ton/day) % CO 2 e (Ton/day) 1 13.62 58 194.37 2 15.89 68 33.76 3 9.28 40 9.87 3.2 Life cycle analysis (LCA) The biorefinery valorizes coffee mucilage, cocoa mucilage, and pig manure waste, so the study's functional unit was defined by tons of processed waste and inventories for the agro-industrial waste processes used; these were derived from mass and energy balances generated by Aspen Plus process simulation models for a plant capacity of 238,099 t/day. The environmental evaluation was carried out for each of the three proposed biorefineries, presenting the most significant potential environmental impact and the levels showing the primary influence on the biorefineries: ADF digestion, digestate treatment, and biogas treatment. Within the 18 environmental impact categories analyzed in the LCA, the ReCiPe 2015 MidPoint (H) methodology was used, allowing observation of the processes' behavior and results. Special attention was paid to the categories belonging to the impact group Global warming (Kg CO 2 eq), Fossil resource scarcity (kg oil eq), and Water consumption (m 3 ), detailed in Table 7 . Table 7 Analysis of environmental impact categories in the biorefinery process 1–2–3 Biorefinery Scheme 1 IMPACT CATEGORY ADF E1 Digestate treatment E1 Biogas treatment E1 Global warming (Kg CO 2 eq) 7947.017688 110.2239862 853.8343835 Fossil resource scarcity (Kg oil eq) 2321.270521 34.17633979 263.3083707 Water consumption (m 3 ) 677.5171778 0.244942417 1.814983011 Biorefinery Scheme 2 IMPACT CATEGORY ADF E2 Digestate treatment E2 Biogas treatment E2 Global warming (Kg CO 2 eq) 7947.017688 110.2239862 37906.82774 Fossil resource scarcity (Kg oil eq) 2321.270521 34.17633979 11716.78297 Water consumption (m 3 ) 677.5171778 0.244942417 117.2872976 Biorefinery Scheme 3 IMPACT CATEGORY ADF E3 Digestate treatment E3 Biogas treatment E2 Global warming (Kg CO 2 eq) 7947.017688 110.2239862 56541.69592 Fossil resource scarcity (Kg oil eq) 2321.270521 34.17633979 17614.41944 Water consumption (m 3 ) 677.5171778 0.244942417 172.7802448 3.2.1 Biorefinery 1 Figures 7 and 8 show that of the 18 categories of environmental impact in the Biorefinery 1 process for biogas treatment, the categories that contribute between 80–100% of impact are associated with damage to human health and the ecosystem. These impact categories are global warming, scarcity of fossil resources, and water consumption with values ​​of 7947.017688 kg CO 2 eq; 2321.270521 kg oil eq; 677.5171778 m3, respectively. The high environmental impact of the biorefinery process is critically developed in anaerobic digestion, as presented by Lamnatou et al. (2019) and Surra et al. (2021). In this biorefinery process, the product with the highest quantity processed is CH 4 compared to H 2 , which has a higher calorific value and more excellent commercial value in Colombia. 3.2.2 Biorefinery 2. The LCA results for biorefinery scheme 2 (Figs. 9 and 10 ) were based on the production of Hydrogen, reformed from the pr4 categories. They show a significant impact on global warming, terrestrial ecotoxicity, non-carcinogenic human toxicity, and scarcity of fossil resources, with total values ​​for the biorefinery of 1.90x1008 kg CO 2 eq., 2.11x1008 kg 1.4-DCB, 4.92x1007 kg 1.4-DCB, and 2.89x1007 kg eq. of oil, respectively. The pressure and temperature operating conditions of the biorefinery two process directly impact water consumption in the reforming line by reacting with the methane that reenters the process after the separation tanks. For the production of H 2 , in the reforming stage, an increase is evident in all categories of environmental impact, attributable to high water consumption and excessive generation of CO 2 , affirming the values ​​presented by (Hajjaji et al., 2006). Even so, studies show that gas reforming helps significantly reduce impact categories such as global warming, scarcity of fossil resources, and water consumption (Valente et al., 2021). 3.2.3 Biorefinery 3. The production of H 2 , Methanol, and CO 2 in the biorefinery three processes affected the 18 environmental impact categories with high percentages (Figs. 11 and 12 ), corroborating the equivalence of the percentages between the biological process and the separation of hydrogen (Fig. 12 ). This evidence shows that the design of biorefinery 3 at this stage is more efficient than the biorefinery scheme 2. The categories such as global warming, terrestrial ecotoxicity, non-carcinogenic human toxicity, and scarcity of fossil resources with total values ​​for the biorefinery of 2.16x1008 kg CO2 eq., 2.38x1008 kg 1,4-DCB, 5.55 x1007 kg 1, 4-DCB and 3.27x1007 kg oil eq. Respectively. In this way, reforming methanol under the operating conditions of energy (1595833.692 KJ/h) and pressure (6079500 Pa) of the design demonstrates that the synthesis of methanol and separation of H2 in this stage does not attribute significant increases in impacts corresponding to (Lundgren et al., 2013; Renó et al., 2011; Wu et al., 2021). 3.2 Economic assessment The calculation of unit costs, fixed costs, and implementation of labor required to execute the biorefineries is listed below. It is projected for ten years from moment zero in each scheme. For all economic calculations, the representative market rate (TRM) of 1 USD = 3900 COP is considered, Inflation of 3%, and the Minimum Attractive Rate of Return (MARR) = 29.98%, as described in Table 8 . It is estimated that for the first year, the Biorefinery 2 scheme is a reference, which, according to what has been evaluated, is the scheme that is projected with more definition to the possible execution. Table 8 TMAR projection and inflation index. MINIMUM ATTRACTIVE RATE OF RETURN (MARR) YEAR INFLATION INDEX BANKING ENTITY INTEREST RANK E.A. BANKS 2017 4,63% 1 27,53% 2018 3,06% 2 20,50% 2019 3,49% 3 28,32% 2020 1,17% 4 26,19% 2021 2,61% 5 28,06% AVERAGE 3% 10,08 MARR 29,98% To calculate the project's total required investment capital (TCI), it was initially considered that the biorefinery processes would be divided into different main sections: digestate treatment, biogas purification, reforming, and methanol synthesis. The teams that are part of each technological division are presented. Table 9 Transparent breakdown of labor costs POSITION AMOUNT BR.1 AMOUNT BR.2 AMOUNT BR.3 PERFORMANCE FACTOR SALARY ANNUAL VALUE Plant operators 15 21 27 1,6 265,25 76392,57 Process engineers 4 6 6 1,5 670 48240,00 Environmental engineer 1 2 2 1,5 670 12060,00 Maintenance Engineer 2 3 3 1,5 670 24120,00 Industrial Engineer 1 3 3 1,5 670 12060,00 Accountant 1 1 1 1,5 670 12060,00 RRHH 1 1 1 1,5 700 12600,00 Manager 1 1 1 2 1000 24000,00 Secretary 4 5 5 1,6 300 23040,00 Watchman 6 6 6 1,6 265,25 30557,03 General services 6 6 6 1,6 265,25 30557,03 Biorefinery 1 $ 305.686,631 Biorefinery 2 $ 414.363,660 Biorefinery 3 $ 444.920,690 A capital of US $ 795,177,825 will be injected, a value of US $ 45,886,133 for fixed costs, and a value of US $ 305,686.63 for labor is also estimated. The useful life of the device is 30 years. Equipment depreciation is calculated using the straight-line method, with zero residual value and a recovery period of 10 years. Other assumptions include three years for the acquisition of land, purchase of equipment, and construction; initiation of a 6-month biorefinery operation; 40% equity and 60% loan (loan term of 10% interest and a repayment term of 10 years) (Arora et al., 2018; Demichelis et al., 2018; Sy et al., 2018). Table 10 Income and unit costs. The total costs related to the proposed biorefineries are presented in Table 9 . The distribution of costs for the plants was calculated considering the composition of the raw materials and the capacity of each plant to transform specific fractions of these. The costs listed below include raw materials, public services, and general and operational tasks (operational tasks, workloads, and general expenses). Estimating the configurations of the three scenarios proposed, there is an abrupt difference for each scenario depending on the technical design and increase in machinery to achieve the production objective in each biorefinery. In addition, Fig. 14 also shows the distribution of the profit margin for each biorefinery made from coffee mucilage, cocoa mucilage, and pig manure. The case of biorefinery 3 stands out because even carrying out reforming, CH4 recycling, and methanol-reforming for efficient H2 production increases C.O. emissions into the atmosphere, and the production cost exceeds the expected total income vs. the unit costs of the plant. Finally, Table 10 and Fig. 13 show the economic comparison of the income versus the costs of producing hydrogen in the three biorefineries based on agro-industrial waste in the Santander area of ​​study: coffee mucilage, cocoa mucilage, and pig manure. 4. Conclusions Biorefineries for agricultural waste from the agricultural waste of cocoa, coffee, and pig manure are an attractive alternative strategy for managing agro-industrial waste with the advantages of providing clean and versatile energy, diversifying raw materials, and improving the economic efficiency of the facilities of processing of agro-industrial waste. Replacing existing fossil fuels with bioenergy from waste cocoa, coffee mucilage, and pig manure will help mitigate the gradual depletion of non-renewable fossil fuels to support the bioeconomy. The energy capacity of agro-industrial waste is evaluated based on the economic efficiency and energy analysis of waste bioprocessing plants. Evaluating coffee mucilage, cocoa mucilage, and pig manure residues for the co-production of hydrogen, methanol, and methane is not energetically sufficient or profitable. However, the combined production of biogas and hydrogen is more profitable, leads to global warming, reduces fossil fuel production, and increases investment costs and water consumption. While incorporating methane recovery into the system can increase profits, it also comes with significant environmental impacts and the potential inability to meet the energy needs of biorefineries and other detailed schemes. Therefore, exploring alternative treatment methods that can effectively reduce investment costs and water, and energy consumption is crucial. This will ensure the practical application of agricultural waste treatment methods and the sustainability of biorefinery projects. As explained in section 2.3, the most suitable biorefinery is a plant for hydrogen production and methane recirculation to increase plant efficiency (Scheme 2). This is because raw materials are available from all schemes and do not require any controlled compounds or additives to generate the H 2 value product. Furthermore, although it is more detailed than biorefinery scheme 1, the process is considered more convenient because the recirculation of methane production enters the biorefinery system, considerably reducing the environmental impacts analyzed in the life cycle (LCA). The generation of emissions into the environment is reformed to increase hydrogen production. Regarding the price, the cost of raw materials remains the same for the three cases, and the production cost is also high due to the increase in accessories for the plant. Regarding capital expenditures, scenario 1 is the most favorable, followed by scenario 2 and scenario 3, which is the least attractive. However, Scenario 3 is promising based on cost-effectiveness. While investors may prefer Scenario 3 due to its current profitability, Scenario 2, which has lower levels of global warming and fossil fuel production, would be more environmentally appropriate. Therefore, investment decisions must weigh economic benefits and environmental emissions before implementing bioprocessing plants from coffee, manure, and pig manure. Declarations Funding Information This Project was developed with financing from the Minciencias-ICETEX 2021-1016 contract of 2021. Declaration of interest statements The authors declare no conflict of interest. Data Availability Statement The data that was used as an initial resource in this study is available in the corresponding bibliographic references, which illustrate information obtained in previous studies by various authors. Author Contributions Statement M.sc. Pablo Elías Velásquez Perilla: contributed to the writing of the introduction and was a reviewer. Ph.D. Mónica Amado Villamizar: contributed to the methodology and biorefinery simulations. M.Sc. Juan Carlos Tarazona Romero: contributed with metholody and analysis of results. Written the Spanish version of the paper. M. 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diagram\u003c/p\u003e\n\u003cp\u003eSource: Author\u003c/p\u003e","description":"","filename":"image1.png","url":"https://assets-eu.researchsquare.com/files/rs-7078044/v1/1aa39955a6a306974a3d4d49.png"},{"id":87476866,"identity":"82163e26-a77e-42f5-afb4-f08554158252","added_by":"auto","created_at":"2025-07-24 09:18:36","extension":"png","order_by":2,"title":"Figure 2","display":"","copyAsset":false,"role":"figure","size":149218,"visible":true,"origin":"","legend":"\u003cp\u003eScenario 2 process flow diagram\u003c/p\u003e\n\u003cp\u003eSource: Author\u003c/p\u003e","description":"","filename":"image2.png","url":"https://assets-eu.researchsquare.com/files/rs-7078044/v1/5f3490a5abe6740166baba76.png"},{"id":87476261,"identity":"6855472e-036a-4f4d-9c2b-5a3577ca7fb6","added_by":"auto","created_at":"2025-07-24 09:10:36","extension":"png","order_by":3,"title":"Figure 3","display":"","copyAsset":false,"role":"figure","size":190244,"visible":true,"origin":"","legend":"\u003cp\u003eScenario 3 process flow diagram\u003c/p\u003e\n\u003cp\u003eSource: Author\u003c/p\u003e","description":"","filename":"image3.png","url":"https://assets-eu.researchsquare.com/files/rs-7078044/v1/e2c9f9c5b4d56b0fc4282500.png"},{"id":87478913,"identity":"e630c264-7013-4119-b9e2-c38c3d00a764","added_by":"auto","created_at":"2025-07-24 09:34:36","extension":"png","order_by":4,"title":"Figure 4","display":"","copyAsset":false,"role":"figure","size":54978,"visible":true,"origin":"","legend":"\u003cp\u003eScenario 1 process flow diagram for the biogas production\u003c/p\u003e\n\u003cp\u003eSource: Author\u003c/p\u003e","description":"","filename":"image4.png","url":"https://assets-eu.researchsquare.com/files/rs-7078044/v1/33dd097d7ddcee1fadc5fb66.png"},{"id":87479869,"identity":"a3b9e96c-5c8a-4369-b98a-42aaaa93dac1","added_by":"auto","created_at":"2025-07-24 09:42:36","extension":"png","order_by":5,"title":"Figure 5","display":"","copyAsset":false,"role":"figure","size":125506,"visible":true,"origin":"","legend":"\u003cp\u003eScenario 2 process flow diagram for the biogas production\u003c/p\u003e\n\u003cp\u003eSource: Author\u003c/p\u003e","description":"","filename":"image5.png","url":"https://assets-eu.researchsquare.com/files/rs-7078044/v1/e56089248d7179f34b9264af.png"},{"id":87476267,"identity":"71f1fd6b-6aaf-47d5-b803-6a361ca94a50","added_by":"auto","created_at":"2025-07-24 09:10:36","extension":"png","order_by":6,"title":"Figure 6","display":"","copyAsset":false,"role":"figure","size":123383,"visible":true,"origin":"","legend":"\u003cp\u003eScenario 3 process flow diagram for the biogas production\u003c/p\u003e\n\u003cp\u003eSource: Author\u003c/p\u003e","description":"","filename":"image6.png","url":"https://assets-eu.researchsquare.com/files/rs-7078044/v1/f01fb5ef8dceef69d051d02e.png"},{"id":87476269,"identity":"b4222feb-b8c3-4ae2-a8cb-11b09291c4d3","added_by":"auto","created_at":"2025-07-24 09:10:36","extension":"png","order_by":7,"title":"Figure 7","display":"","copyAsset":false,"role":"figure","size":21751,"visible":true,"origin":"","legend":"\u003cp\u003eACV result to Biorefinery Scheme 1.\u003c/p\u003e","description":"","filename":"image7.png","url":"https://assets-eu.researchsquare.com/files/rs-7078044/v1/776a3c27f2328bcde5d970a3.png"},{"id":87476868,"identity":"b8df0f85-38d8-4662-a45d-8521004c0514","added_by":"auto","created_at":"2025-07-24 09:18:36","extension":"png","order_by":8,"title":"Figure 8","display":"","copyAsset":false,"role":"figure","size":15549,"visible":true,"origin":"","legend":"\u003cp\u003eComparative Analysis Biorefinery Scheme 1.\u003c/p\u003e","description":"","filename":"image8.png","url":"https://assets-eu.researchsquare.com/files/rs-7078044/v1/eb46ce0ab0ae982b4621c67d.png"},{"id":87478500,"identity":"3cda3bbf-24d7-4481-9294-709e40ead03d","added_by":"auto","created_at":"2025-07-24 09:26:36","extension":"png","order_by":9,"title":"Figure 9","display":"","copyAsset":false,"role":"figure","size":17802,"visible":true,"origin":"","legend":"\u003cp\u003eBiorefinery 2 LCA results\u003c/p\u003e","description":"","filename":"image9.png","url":"https://assets-eu.researchsquare.com/files/rs-7078044/v1/5724e7b293007a6f7ba55612.png"},{"id":87476277,"identity":"1747f680-46d1-4cce-a53c-f13e45623e75","added_by":"auto","created_at":"2025-07-24 09:10:36","extension":"png","order_by":10,"title":"Figure 10","display":"","copyAsset":false,"role":"figure","size":22046,"visible":true,"origin":"","legend":"\u003cp\u003eComparative Analysis Biorefinery Scheme 2.\u003c/p\u003e","description":"","filename":"image10.png","url":"https://assets-eu.researchsquare.com/files/rs-7078044/v1/31ee440abf3c5799b51a6e1c.png"},{"id":87478497,"identity":"84842adc-ebe5-4d72-b93f-beaf6379b504","added_by":"auto","created_at":"2025-07-24 09:26:36","extension":"png","order_by":11,"title":"Figure 11","display":"","copyAsset":false,"role":"figure","size":41662,"visible":true,"origin":"","legend":"\u003cp\u003eBiorefinery 3 LCA results\u003c/p\u003e","description":"","filename":"image11.png","url":"https://assets-eu.researchsquare.com/files/rs-7078044/v1/32f254c77397fd9b1b6ffc05.png"},{"id":87476869,"identity":"fcc3caf0-8127-41d4-a137-e0cdf07d810e","added_by":"auto","created_at":"2025-07-24 09:18:36","extension":"png","order_by":12,"title":"Figure 12","display":"","copyAsset":false,"role":"figure","size":20710,"visible":true,"origin":"","legend":"\u003cp\u003eComparative analysis Biorefinery Scheme 2.\u003c/p\u003e","description":"","filename":"image12.png","url":"https://assets-eu.researchsquare.com/files/rs-7078044/v1/165a4ce326ebd9aeae1715d0.png"},{"id":87476273,"identity":"6f9e2ab1-5bc8-47c5-90b2-6f74d3d24721","added_by":"auto","created_at":"2025-07-24 09:10:36","extension":"png","order_by":13,"title":"Figure 13","display":"","copyAsset":false,"role":"figure","size":175552,"visible":true,"origin":"","legend":"\u003cp\u003eExpense analysis\u003c/p\u003e","description":"","filename":"image13.png","url":"https://assets-eu.researchsquare.com/files/rs-7078044/v1/ecb913d24bab0554629298d1.png"},{"id":89203526,"identity":"fb88603e-97f8-4553-a111-a6e4d6fc06e8","added_by":"auto","created_at":"2025-08-16 15:52:32","extension":"pdf","order_by":0,"title":"","display":"","copyAsset":false,"role":"manuscript-pdf","size":2296298,"visible":true,"origin":"","legend":"","description":"","filename":"manuscript.pdf","url":"https://assets-eu.researchsquare.com/files/rs-7078044/v1/2d903e6a-6813-48f2-8d66-cc1a71d01976.pdf"}],"financialInterests":"","formattedTitle":"\u003cp\u003eTechnical economic and environmental assessment of biorefinery schemes by agro-industrial residues approach in Santander\u003c/p\u003e","fulltext":[{"header":"1. Introduction","content":"\u003cp\u003eUtilizing sustainable resources is essential for the growth and development of the agro-industrial sector, offering a viable pathway for renewable energy production and the generation of environmentally friendly fuels. Biomass, derived from agro-industrial residues, remains an underutilized resource despite its significant energy potential. Biorefineries can be a sustainable solution by converting waste materials such as coffee mucilage, cocoa mucilage, and pig manure into biofuels and value-added products.\u003c/p\u003e\u003cp\u003eIn Santander, agro-industrial waste disposal primarily relies on traditional methods, which limit resource efficiency and contribute to environmental pollution (Contreras, 2015). Modernizing these processes by harnessing biomass energy potential could enhance fuel production and support sustainable waste management strategies. The theoretical energy potential of agro-industrial waste in Colombia exceeds 75,000 TJ/year, which could generate up to 6,260 GWh/year, equivalent to 9.4% of the country's total energy production in 2015. However, much of this energy remains untapped due to waste dispersion in extensive agricultural systems (Arboleda \u0026amp; Lora, 2018).\u003c/p\u003e\u003cp\u003eAmong agro-industrial residues, pig manure is the most exploited for energy generation due to its ease of collection within confined livestock systems. Implementing anaerobic biodigesters in pig farms could efficiently convert manure into biomethane and high-quality organic fertilizers with reduced microbial content (D\u0026iacute;az et al., 2021). Conversely, coffee mucilage, a byproduct of coffee processing, presents significant potential for biogas production, as each kilogram of cherry coffee generates approximately 91 mL of mucilage (Zambrano et al., 1994). Given that Colombia exports approximately one million 60-kg bags of almond coffee annually, an estimated 55,500 tons of fresh mucilage are produced as waste (Rodr\u0026iacute;guez et al., 2014).\u003c/p\u003e\u003cp\u003eSimilarly, cocoa mucilage represents a valuable biomass resource due to Santander's dominant role in national cocoa production, contributing 41% of Colombia\u0026rsquo;s total output (Minagricultura, 2021). Despite its energy potential, cocoa mucilage remains underutilized, emphasizing the need for integrated biorefinery solutions. Pig manure has proven viable for biogas production, supporting sustainable energy initiatives within Santander's agricultural sector (Contexto Ganadero, 2020).\u003c/p\u003e\u003cp\u003eThis study explores the techno-economic and environmental feasibility of utilizing coffee mucilage, cocoa mucilage, and pig manure within biorefinery systems. This research aims to identify optimal strategies for implementing biorefinery-based waste management solutions in agro-industrial settings by analyzing energy conversion efficiencies, economic viability, and environmental impacts.\u003c/p\u003e\u003cp\u003eTable\u0026nbsp;\u003cspan refid=\"Tab1\" class=\"InternalRef\"\u003e1\u003c/span\u003e shows the biomass generated by each sector in tons per year, according to the information collected by Vel\u0026aacute;squez et al. (2018).\u003c/p\u003e\u003cp\u003e\u003cdiv class=\"gridtable\"\u003e\u003ctable float=\"Yes\" id=\"Tab1\" border=\"1\"\u003e\u003ccaption language=\"En\"\u003e\u003cdiv class=\"CaptionNumber\"\u003eTable 1\u003c/div\u003e\u003cdiv class=\"CaptionContent\"\u003e\u003cp\u003eLivestock biomass sector\u003c/p\u003e\u003c/div\u003e\u003c/caption\u003e\u003ccolgroup cols=\"3\"\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c1\" colnum=\"1\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c2\" colnum=\"2\"\u003e\u003c/div\u003e\u003cdiv align=\"char\" char=\".\" class=\"colspec\" colname=\"c3\" colnum=\"3\"\u003e\u003c/div\u003e\u003cthead\u003e\u003ctr\u003e\u003cth align=\"left\" colname=\"c1\"\u003e\u003cp\u003eSector\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c2\"\u003e\u003cp\u003eBiomass\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c3\"\u003e\u003cp\u003eTon/year\u003c/p\u003e\u003c/th\u003e\u003c/tr\u003e\u003c/thead\u003e\u003ctbody\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003ePoultry\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003eManure\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c3\"\u003e\u003cp\u003e6.518.795\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003ePig\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003eManure\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c3\"\u003e\u003cp\u003e2.745.392\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eCattle\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003eManure\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c3\"\u003e\u003cp\u003e83.497.181\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003c/tbody\u003e\u003c/colgroup\u003e\u003c/table\u003e\u003c/div\u003e\u003c/p\u003e\u003cp\u003eVel\u0026aacute;squez, M, et, al 2018.\u003c/p\u003e\u003cp\u003eMost forms of biomass are potential renewable resources with attractive biorefinery compositions in multiple products, including bioenergy and bioactive compounds, that could reduce dependence on fossil fuels and improve revenue streams.\u003c/p\u003e\u003cp\u003eHowever, the current use of biomass is still low, with an estimated contribution of 14% to global energy (Tursi, A., 2019). Due to the need to satisfy the municipal energy demand, the Biorefinery concept was born to optimize biomass processing, make it more efficient, and minimize its environmental impacts. The economic development of biorefinery has the approach of the sustainable development framework (Cervantes et al., 2017).\u003c/p\u003e\u003cp\u003eFeasibility studies of existing processes in biorefineries of agro-industrial wastes such as coffee mucilage, cocoa mucilage, and pig manure are limited in quantity and generate waste streams that need additional treatment. Depending on the origin of the plants, different methodologies can be applied for the recovery of agro-industrial waste; among them are the anaerobic co-digestion processes, where an alternative is offered for the treatment of any biodegradable residue or organic waste (Montenegro et al., 2016).\u003c/p\u003e\u003cp\u003eMosquera et al. (2020) consider the significant influence of the different operating parameters on biogas production during the anaerobic co-digestion of different substrates available in Colombia, creating box-Behnken experiment designs based on the physicochemical characterization of the percentage of nitrogen in digestion processes.\u003c/p\u003e\u003cp\u003eOther authors evaluated the valorization of the liquid effluent from the biodigester to obtain struvite through anaerobic digestion, modeling only the reactor in APPEN, another process such as fermentation (for reducing sugars and carbohydrates), transesterification (for oils and fats), and anaerobic digestion (for organic waste). Ethanol, methanol, n-butanol (from sugars), biodiesel (from oils), and biogas (from organic waste) are obtained from these processes (\u0026Aacute;lvarez, 2009).\u003c/p\u003e\u003cp\u003eL\u0026oacute;pez D\u0026aacute;vila et al. (2012) report that the digestion process is immediately inhibited due to the high nitrogen content of pig manure. However, microorganisms can acclimatize, decreasing volatile fatty acid concentration and producing high volumes of biogas.\u003c/p\u003e\u003cp\u003eAnaerobic digestion is the biological oxidation of organic matter through specific microorganisms without molecular oxygen. In this process, organic matter is transformed into stable and inert products, and biogas mainly comprises methane and carbon dioxide (Garc\u0026iacute;a, 2009, pp. 35\u0026ndash;49). This process is considered one of the most useful for reducing greenhouse gas emissions and using organic waste as energy (Flotats et al., 2001, pp. 51\u0026ndash;65).\u003c/p\u003e\u003cp\u003eAspen Plus has been used to evaluate the feasibility and limitations of combining unitary processes in the generation of integrated biorefineries for the recovery of multiple products (Aghbashlo et al., 2018; Davila et al., 2015; Humbird et al., 2011; Lohrasbi et al., 2010). The different process simulation models generate mass and energy balances for correctly selecting equipment and estimating costs. When combined with economic modules such as Aspen Plus, this method can be used for cost-benefit analysis and provide research and investment insights for new product development, expansion, and improvement: technology and its economic viability. (Manhongo et al., 2021).\u003c/p\u003e\u003cp\u003eBy generating models of biorefinery processes, these can be combined with environmental impact assessments to identify relevant environmental bottlenecks and critical points for technological improvements (Kwant et al., 2018). Life cycle assessment (LCA) is a methodology that identifies, quantifies, and characterizes the different potential environmental impacts associated with each of the life cycle stages of a product. It focuses on redesigning products under the criteria that energy resources and raw materials are not unlimited and that, commonly, they are used faster than they are replaced or new alternatives emerge.\u003c/p\u003e\u003cp\u003eImplementing clean technologies in Santander, Colombia, is scarce since there is no regulatory surveillance regarding managing this waste (Cendales, 2011, p.4); this contradicts what was expressed in the departmental development plan 2016\u0026ndash;2019, in which Santander is proposed as an area of high energy potential (Mendivelso, 2018). In this way, the conservation of resources privileges reducing the amount of waste generated through the product. Since this waste will continue to be produced, the ACV proposed to manage the waste sustainably from the environmental point of view, minimizing all the impacts associated with the management system (Environmental Forum, 2003).\u003c/p\u003e"},{"header":"2. Materials and methods","content":"\u003cp\u003eThree biorefinery scenarios were proposed for this research. These scenarios were initially simulated using Aspen Plus (Aspen Technology, Inc., USA), a commercial simulation software package. Aspen Plus was chosen due to its extensive library of conventional process equipment models and biological, thermodynamic, and mathematical models. This software also integrates Aspen Economic Analyzer (Aspen Technology, Inc., USA) to evaluate capital and operating costs. Following the simulation, a life cycle analysis was conducted using the ReCiPe 2015 Midpoint (H) methodology implemented in SimaPro v9.0 software. This methodology evaluates emissions and resource depletion, translating them into limited impact categories.\u003c/p\u003e\u003cp\u003eThe methodological procedures employed to attain the study objectives are described below.\u003c/p\u003e\u003cdiv id=\"Sec3\" class=\"Section2\"\u003e\u003ch2\u003e2.1. Capacity and demand of Biorefinery plants.\u003c/h2\u003e\u003cp\u003eThe capacity to be installed was evaluated considering the availability of raw materials in Santander's department. Santander is one of the regions with the highest growth of the two crops studied (coffee and cocoa), with a significant relationship in the amount of valuable mucilage capable of producing biogas.\u003c/p\u003e\u003cp\u003eCocoa production is concentrated in the country's northeast, and the Santander region contributes 28,474 tons/year; coffee production was estimated at 54,203 tons/year; pig production was 92,600 heads/year (DANE, 2017). In general, the above data indicated that the availability of coffee mucilage (CFM), cocoa mucilage (CCM), and pig manure (S.M.) in the study area is 3,545 tons, 4,499 tons, and 57,910 tons, respectively (DANE, 2017). This way, 4.62 t/day of cocoa mucilage was processed, 1.83 t/day of coffee mucilage, and 25.25 t/day of pig manure.\u003c/p\u003e\u003cp\u003eLikewise, the plant's general processing capacity was estimated at 238,099 t/day and 902,701 t/day of residual process water for a total AD-OUT LIQ digestate of 1140.8 t/day. The plant's annual operating time is 24 hours/day for 330 days.\u003c/p\u003e\u003c/div\u003e\u003cdiv id=\"Sec4\" class=\"Section2\"\u003e\u003ch2\u003e2.2. Design and modeling of Processes in ASPEN PLUS\u003c/h2\u003e\u003cp\u003eThree industrial-scale biorefinery-type process schemes were simulated. The simulation was carried out to validate the proposed three conceptual designs, obtaining productivity and performance indicators of the products obtained in each case study. Additionally, the simulations allowed for calculating and verifying design factors such as the equipment's type, number, size, installed capacity, and approximate cost. (Gonz\u0026aacute;lez \u0026amp; Torres, 2019).\u003c/p\u003e\u003c/div\u003e\u003cdiv id=\"Sec5\" class=\"Section2\"\u003e\u003ch2\u003e2.3. Biorefinery scenario description\u003c/h2\u003e\u003cp\u003eBy comparison, three scenarios were presented for using agro-industrial residues under biorefinery-type processing schemes. The residues used were coffee mucilage, cocoa mucilage, and pig manure. In the first proposed scheme, priority was given to producing hydrogen (H\u003csub\u003e2\u003c/sub\u003e) and methane (CH\u003csub\u003e4\u003c/sub\u003e). In addition to H\u003csub\u003e2\u003c/sub\u003e production, operations for reforming the CH\u003csub\u003e4\u003c/sub\u003e produced were incorporated in the second scheme. Finally, in the third biorefinery scheme, the generation of methanol and hydrogen obtained from reforming the residual gases of the separation process was proposed.\u003c/p\u003e\u003cp\u003eThe main stages of the process of coffee mucilage, cocoa mucilage, and pig manure, the preparation of raw materials, dark fermentation, anaerobic digestion, biogas processing, and digestate processing were implemented. These processes were combined into three biorefinery scenarios described in the following subsections.\u003c/p\u003e\u003cp\u003eIn the three schemes, the preparation stage or initial scheme begins with mixing the substrates in the proportion described in Section \u003cspan refid=\"Sec3\" class=\"InternalRef\"\u003e2.1\u003c/span\u003e. Then, the transported raw materials were preheated (here, an energy consumption of 2,411,423,468 kJ/ h). The transformation began using a specialized dark fermentation reactor where a current of biogas product was obtained, and an effluent was subsequently conducted to a second reactor specialized in anaerobic digestion. The digestate produced after the anaerobic digestion reactor is decanted, and the sludge passes to centrifugal dryers, bringing it to 80% humidity.\u003c/p\u003e\u003cdiv id=\"Sec6\" class=\"Section3\"\u003e\u003ch2\u003e2.3.1. Scenario 1\u003c/h2\u003e\u003cp\u003eScenario 1 ( Fig.\u0026nbsp;\u003cspan refid=\"Fig1\" class=\"InternalRef\"\u003e1\u003c/span\u003e) is the biorefinery scheme obtained from the simulation of the process model, that is, without any modification, is characterized because the gases are conducted to an initial heat exchanger and then to a column where filtration is applied to remove H\u003csub\u003e2\u003c/sub\u003eS and NH\u003csub\u003e3\u003c/sub\u003e; then the gas is compressed and after it experiences a pressure drop when passing through the filter and reaching the three purification columns, through reforming a biogas current of 88% and a bio-hydrogen production of 12% are obtained.\u003c/p\u003e\u003c/div\u003e\u003cdiv id=\"Sec7\" class=\"Section3\"\u003e\u003ch2\u003e2.3.2 Scenario 2\u003c/h2\u003e\u003cp\u003eThe second scenario was adopted according to Clauser et al. (2021), which constantly shows how, in biorefineries, the dark fermentation process begins in substrates rich in carbohydrates and starch, helping with the operation of other equipment and prioritizing the production of gas with higher calorific value, such as hydrogen. In scheme 2, shown in Fig.\u0026nbsp;\u003cspan refid=\"Fig2\" class=\"InternalRef\"\u003e2\u003c/span\u003e, different conditions were taken for biogas. After the initial stage, the biogas passes through the heat exchanger, and 77,576.51 kJ/h is added to the process, passing through a biofilter column and increasing the pressure in the compressor to 3.0398MPa. Finally, it is removed. H\u003csub\u003e2\u003c/sub\u003eS and NH\u003csub\u003e3\u003c/sub\u003e. Separation columns S103-S104-S105 helped remove CO and CO\u003csub\u003e2\u003c/sub\u003e after hydrogen production. After separating carbon dioxide and carbon dioxide in column S105, a recovery rich in methane is achieved, which is taken to a reforming reactor, obtaining residual water. The mechanization process is inserted into the reforming process to take advantage of the biogas in energy transformation, increasing profitability and entering it back into the system as a recycle-to-exchanger 2. (Fernando et al., 2006).\u003c/p\u003e\u003c/div\u003e\u003cdiv id=\"Sec8\" class=\"Section3\"\u003e\u003ch2\u003e2.3.2. Scenario 3\u003c/h2\u003e\u003cp\u003eFinally, gas treatment was given priority in the simulation of scheme three as the main product since they are a direct energy source for the agroindustry (Fig.\u0026nbsp;\u003cspan refid=\"Fig3\" class=\"InternalRef\"\u003e3\u003c/span\u003e). Currently, 1% of the country's final electricity consumption is consumed yearly (IEA, 2020) once the initial stage of separation and recycling of the methane-rich stream proceeds. An H\u003csub\u003e2\u003c/sub\u003e transformation process is carried out for 88% of the production to treat the gases emitted in the separator tanks S103-S104-S105, increasing the temperature and pressure to 3.0398MPa, helping the cogeneration of METHANOL and subsequently a waste of wastewater.\u003c/p\u003e\u003c/div\u003e\u003c/div\u003e\u003cdiv id=\"Sec9\" class=\"Section2\"\u003e\u003ch2\u003e2.4 Life cycle assessment (LCA) of Biorefinery scenarios\u003c/h2\u003e\u003cp\u003eLife cycle assessment (LCA) is essential for decision-making and policy formulation related to the valorization of agro-industrial waste proposed in biorefinery schemes. The impacts of product choice on the environmental loads of coffee mucilage, cocoa mucilage, and pig manure residues were thus demonstrated, identifying critical point unit processes along biorefinery process routes. Using data generated from Aspen Plus-based process models and economic analysis, life cycle analysis (LCA) was carried out to evaluate the environmental impacts of the three scenarios presented in section 2.3. The inventory was translated into environmental loads using the ReCiPe 2015 MidPoint (H) methodology available in SimaPro v9.0 software, where emissions and resource disposal are assessed, translating them into a limited number of impact scores. Environmental. Table\u0026nbsp;\u003cspan refid=\"Tab2\" class=\"InternalRef\"\u003e2\u003c/span\u003e shows the environmental impact categories and their descriptions.\u003c/p\u003e\u003cp\u003e\u003cdiv class=\"gridtable\"\u003e\u003ctable float=\"Yes\" id=\"Tab2\" border=\"1\"\u003e\u003ccaption language=\"En\"\u003e\u003cdiv class=\"CaptionNumber\"\u003eTable 2\u003c/div\u003e\u003cdiv class=\"CaptionContent\"\u003e\u003cp\u003eEnvironmental impact categories reported by the ReCiPe 2015 LCA method.\u003c/p\u003e\u003c/div\u003e\u003c/caption\u003e\u003ccolgroup cols=\"3\"\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c1\" colnum=\"1\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c2\" colnum=\"2\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c3\" colnum=\"3\"\u003e\u003c/div\u003e\u003cthead\u003e\u003ctr\u003e\u003cth align=\"left\" colname=\"c1\"\u003e\u003cp\u003eImpact Category/ Indicator\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c2\"\u003e\u003cp\u003eUnit\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c3\"\u003e\u003cp\u003eDescription\u003c/p\u003e\u003c/th\u003e\u003c/tr\u003e\u003c/thead\u003e\u003ctbody\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eClimate change total. Fossil, biogenic, and land use\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003eKg CO2-eq\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eAn indicator of potential global warming due to emissions of greenhouse gases to the air. Divided into 3 subcategories based on the emission source: (1) fossil resources, (2) bio-based resources, and (3) land use change.\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eOzone depletion\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003eKg CFC-11-eq\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eIndicator of emissions to air that destroys the stratospheric ozone layer.\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eAcidification\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003eKg mol H+\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eAn indicator of the potential acidification of soils and water due to releasing gases such as nitrogen and sulfur oxides.\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eEutrophication-freshwater\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003eKg PO4-eq\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eAn indicator of the freshwater ecosystem enrichment with nutritional elements due to the emission of nitrogen or phosphor-containing compounds.\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eEutrophication-marine\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003eKg N-eq\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eAn indicator of the marine ecosystem enrichment with nutritional elements due to the emission of nitrogen-containing compounds.\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eEutrophication-terrestrial\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003emol N-eq\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eIndicators of the terrestrial ecosystem enrichment with nutritional elements due to the emission of nitrogen-containing compounds.\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003ePhotochemical ozone formation\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003eKg NMVOC-eq\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eIndicators of emission of gases that affect the creation of photochemical ozone in the lower atmosphere (smog) catalyzed by sunlight.\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eDepletion of abiotic resources and metals\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003eKg Sb-eq\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eIndicator of the depletion of natural non-fossil resources.\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eDepletion of abiotic resources- fossil fuels\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003eM.J., net calorific value.\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eAn indicator of the depletion of natural fossil fuel resources.\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eHuman toxicity-cancer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003eCTUh\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eImpact on humans of toxic substances emitted to the environment.\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eEcotoxicity (freshwater)\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003eCTUe\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eImpact on freshwater organisms of toxic substances emitted to the environment.\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eWater use\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003em3 world eq.\u0026nbsp;deprived.\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eThe indicator of the relative amount of water used is based on regionalized water scarcity factors.\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eLand use\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003eDimensionless\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eMeasure the changes in soil quality (Biotoc production, Erosion, resistance, Mechanical Filtration).\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eIonizing radiation, human health\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003ekBq U-235\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eDamage to human health and ecosystems linked to the emissions of radionuclides.\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eParticulate matter emissions\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003eDisease incidence\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eAn indicator of the potential incidence of disease due to particulate matter emissions.\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003c/tbody\u003e\u003c/colgroup\u003e\u003c/table\u003e\u003c/div\u003e\u003c/p\u003e\u003cp\u003eSource: Ecochain, 2024.\u003c/p\u003e\u003cp\u003eThe software considers the impact of effluent mass and energy requirements of a chemical process based on the energy and mass balances generated in Aspen Plus. Then, the weighted sum of all impacts determined the total impact per kg, representing each category's potential environmental impact. (Pazmi\u0026ntilde;o, 2018).\u003c/p\u003e\u003cp\u003eThis method converts life cycle inventories into 18 categories of medium-term effects, translating them into the environmental loads of each process in the different biorefinery schemes proposed to generate valuable products. Global warming potential (GWP), fossil resource scarcity (FRS), and water consumption (WCo) were selected as relevant categories for discussion since first-generation biorefineries would mainly affect land, water, and fossil energy resources (Martinez-Hernandez \u0026amp; Samsatli, 2017).\u003c/p\u003e\u003c/div\u003e\u003cdiv id=\"Sec10\" class=\"Section2\"\u003e\u003ch2\u003e2.5 Economic Assessment\u003c/h2\u003e\u003cp\u003eThe sustainability evaluation is complemented by a techno-economic assessment of its main processes, demonstrating each proposed scheme's economic viability. The objective is to find the potential to produce or manufacture one or more valuable products that generate benefits according to the investment.\u003c/p\u003e\u003cp\u003eThe economic benefit is the part of the income that can be obtained from the production process. In this way, by performing a Techno-Economic Analysis (TEA), the different stages of the process can be designed, and the costs associated with the construction and production capital investment can be determined, as well as the operating costs for each stage of the biorefinery process based on agro-industrial waste. Capital costs are represented by the initial investment, considering the sizing of the equipment to calculate its commercial price, including transportation, labor, and installation, among others.\u003c/p\u003e\u003cp\u003eThe economic evaluation of the three biorefineries shows the total costs, cost allocation associated with each biorefinery, net present value, real profit before taxes URAI, and the percentage of fixed investment capital to be used. Each biorefinery behaves differently. The total cost increases over the 10-year evaluation period as the level of integration is applied and equipment is involved in the production process.\u003c/p\u003e\u003cp\u003eConsiderations for total production costs include direct production costs or variable operating costs (VOC). These are related to the cost per unit of plant working time (US\u003cspan\u003e$\u003c/span\u003e/day), fixed costs (F.C.), and plant overheads (Peters \u0026amp; Timmerhaus, 1991). Variable operating costs include directly related manufacturing costs such as raw material acquisition, utilities, labor, and waste disposal (Seider et al., 2008), while fixed costs include depreciation, property insurance, taxes, and land costs. The net present value, the minimum attractive rate of return (MARR), and the internal rate of return (IRR) were calculated using a discounted cash flow analysis assuming economic parameters relevant to Colombia according to the following Table \u003cspan refid=\"Tab3\" class=\"InternalRef\"\u003e3\u003c/span\u003e:\u003c/p\u003e\u003cp\u003e\u003cdiv class=\"gridtable\"\u003e\u003ctable float=\"Yes\" id=\"Tab3\" border=\"1\"\u003e\u003ccaption language=\"En\"\u003e\u003cdiv class=\"CaptionNumber\"\u003eTable 3\u003c/div\u003e\u003cdiv class=\"CaptionContent\"\u003e\u003cp\u003eInflation Index - TMAR \u0026ndash; TIR\u003c/p\u003e\u003c/div\u003e\u003c/caption\u003e\u003ccolgroup cols=\"3\"\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c1\" colnum=\"1\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c2\" colnum=\"2\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c3\" colnum=\"3\"\u003e\u003c/div\u003e\u003cthead\u003e\u003ctr\u003e\u003cth align=\"left\" colname=\"c1\"\u003e\u003cp\u003eParameter\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c2\"\u003e\u003cp\u003eCost\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c3\"\u003e\u003cp\u003eReference\u003c/p\u003e\u003c/th\u003e\u003c/tr\u003e\u003c/thead\u003e\u003ctbody\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eBase year\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e2022\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u0026nbsp;\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eMinimum attractive rate of return (MARR)\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e29.98%\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eMARR\u003csub\u003ef\u003c/sub\u003e = i + f\u0026thinsp;+\u0026thinsp;if\u003c/p\u003e\u003cp\u003e(Arora et al., 2018; Demichelis et al., 2018; Sy et al., 2018)\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eInflation index\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e3%\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eAverage inflation years 2017\u0026ndash;2022\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eBiofertilizer price (\u003cspan\u003e$\u003c/span\u003e/t)\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003eUS\u003cspan\u003e$\u003c/span\u003e90.5\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eLa Rep\u0026uacute;blica (2019)\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eCost H\u003csub\u003e2\u003c/sub\u003e (\u003cspan\u003e$\u003c/span\u003e/t)\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003eUS\u003cspan\u003e$\u003c/span\u003e1000\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003eChac\u0026oacute;n, T. (2022). Colombia tendr\u0026iacute;a el cuarto precio m\u0026aacute;s bajo de hidr\u0026oacute;geno verde en 2025. Recuperado 29 de agosto de 2022, de Rumbo Minero Internacional website: \u003cspan class=\"ExternalRef\"\u003e\u003cspan class=\"RefSource\"\u003ehttps://www.rumbominero.com/colombia/colombia-precio-hidrogeno-verde-2025/\u003c/span\u003e\u003cspan address=\"https://www.rumbominero.com/colombia/colombia-precio-hidrogeno-verde-2025/\" targettype=\"URL\" class=\"RefTarget\"\u003e\u003c/span\u003e\u003c/span\u003e\u003c/p\u003e\u003cp\u003e(Arango, \u0026amp; \u0026Aacute;lvarez (2013))\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eCost CH\u003csub\u003e4\u003c/sub\u003e (\u003cspan\u003e$\u003c/span\u003e/m\u003csup\u003e3\u003c/sup\u003e)\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003eUS\u003cspan\u003e$\u003c/span\u003e0.20\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003ePinoargote \u0026amp; Gallegos (2011)\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003c/tbody\u003e\u003c/colgroup\u003e\u003c/table\u003e\u003c/div\u003e\u003c/p\u003e\u003cp\u003eSource: Compiled by Author\u003c/p\u003e\u003cp\u003eTotal capital investments (TCI) and total production costs (TPC) were queried at the source by referenced product: Biofertilizer (Editorial La Rep\u0026uacute;blica S.A.S., 2019, February 8), Hydrogen (Arango \u0026amp; Alvarez, C. (2013), Methane (Pinoargote \u0026amp; Gallegos, 2011).\u003c/p\u003e\u003cp\u003eTotal capital investment is the sum of fixed capital cost (FCC) and working capital (W.C.), where fixed capital costs constitute total direct cost (TDC) and total indirect cost (TIC). Total direct costs of TDC include the cost of purchasing and installing equipment, instrumentation, controls, plumbing, and electrical products (Peters \u0026amp; Timmerhaus, 1991).\u003c/p\u003e\u003c/div\u003e"},{"header":"3. Results and discussion","content":"\u003cp\u003eThree biorefinery schemes were analyzed where the products are taken by biological equipment and are determined by a previous study to extract the digestate and the biogas to be reformed through separation, increase in temperature, and energy in each biorefinery process detailed. The production capacities of each process were established based on the amount of waste generated by the agro-industrial processes of coffee, cocoa, and cattle production plantations in the department of Santander, which constitutes the feeding capacity of the designed process.\u003c/p\u003e\u003cp\u003eThe daily feeding capacity was set at 1140.8 tons/day with a production output of 238,099t/day, translating into a reformed Hydrogen production of 2.38t/day with a 24-hour operation. The mass and energy balance was carried out based on the requirements and implementation of each piece of equipment to extract valuable products efficiently, as shown in Table\u0026nbsp;\u003cspan refid=\"Tab4\" class=\"InternalRef\"\u003e4\u003c/span\u003e.\u003c/p\u003e\u003cp\u003e\u003cdiv class=\"gridtable\"\u003e\u003ctable float=\"Yes\" id=\"Tab4\" border=\"1\"\u003e\u003ccaption language=\"En\"\u003e\u003cdiv class=\"CaptionNumber\"\u003eTable 4\u003c/div\u003e\u003cdiv class=\"CaptionContent\"\u003e\u003cp\u003eSpecification of the equipment used in the process\u003c/p\u003e\u003c/div\u003e\u003c/caption\u003e\u003ccolgroup cols=\"2\"\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c1\" colnum=\"1\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c2\" colnum=\"2\"\u003e\u003c/div\u003e\u003cthead\u003e\u003ctr\u003e\u003cth align=\"left\" colname=\"c1\"\u003e\u003cp\u003eEquipment\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c2\"\u003e\u003cp\u003ePrice\u003c/p\u003e\u003c/th\u003e\u003c/tr\u003e\u003c/thead\u003e\u003ctbody\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eMixing tank\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e25.000 USD\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eExchanger E101\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e6.000 USD\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eExchanger E102\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e6.000 USD\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eExchanger E103\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e6.000 USD\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eExchanger E104\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e6.000 USD\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eExchanger E106\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e6.000 USD\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eExchanger E107\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e6.000 USD\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eSeparator S108\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e12,553,747 USD\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eReactor F.O.\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e89,536,124 USD\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eSeparator S1046\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e5.000 USD\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eSettling tank\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e14.880 USD\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eS105. 2400 L.\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e35.000 A 50.000 USD\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eXLPM270A- Two-stage air compressor\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e73.416 USD\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003c/tbody\u003e\u003c/colgroup\u003e\u003c/table\u003e\u003c/div\u003e\u003c/p\u003e\u003cp\u003eSource: Compiled by Author, reference price from Alibaba.com Official Website\u003c/p\u003e\u003cdiv id=\"Sec12\" class=\"Section2\"\u003e\u003ch2\u003e3.1 Biogas production\u003c/h2\u003e\u003cp\u003eInitially, for scenario 1 (Fig.\u0026nbsp;\u003cspan refid=\"Fig4\" class=\"InternalRef\"\u003e4\u003c/span\u003e), Through the preparation of the raw material, 4.62 t/day of cocoa mucilage is processed, 1.83 t/day of coffee mucilage, and 25.25 t/day of pig manure; where accelerating the fermentation and distillation process by increasing energy in the heat exchanger provides 2,411,423.468 Kj/h; before entering the mixture into the dark fermentation reactor, initiating the treatment of the digestate to proceed with the treatment of wastewater and sludge. Once the energy of the second exchanger increases, providing 26,190.79 Kj/h, and the pressure in the separator tanks increases, 0.41 t/day of H\u003csub\u003e2\u003c/sub\u003e and 6.58 t/day CH\u003csub\u003e4\u003c/sub\u003e are produced.\u003c/p\u003e\u003cp\u003eIt is in the initial stage of the process where the mixture of agro-industrial products is fermented and distilled, which is the same process as the biorefinery scheme 1. Biorefinery scheme 2 (Fig.\u0026nbsp;\u003cspan refid=\"Fig5\" class=\"InternalRef\"\u003e5\u003c/span\u003e): By increasing the energy, 77,576.51 KJ/h is contributed to the transformation in exchanger two, and after the separation process and pressure increase in the compressor using 3.0398 MPa, 2.836 tons/day of H\u003csub\u003e2\u003c/sub\u003e are obtained; In the separation process of tanks S103-S104-S105, emissions of 15,888 t/day of CO\u003csub\u003e2\u003c/sub\u003e and 0.37 t/day of C.O. are generated into the environment (Fig.\u0026nbsp;\u003cspan refid=\"Fig6\" class=\"InternalRef\"\u003e6\u003c/span\u003e). CH\u003csub\u003e4\u003c/sub\u003e 6.50 tons/day production is reincorporated into the reformed process to take advantage of the biogas in the energy transformation, increasing profitability by entering it back into the system as a recycling to exchanger 2 (Fernando et al., 2006).\u003c/p\u003e\u003cp\u003eBiorefinery scheme 3 (Fig.\u0026nbsp;\u003cspan refid=\"Fig6\" class=\"InternalRef\"\u003e6\u003c/span\u003e) proposes reducing emissions into the atmosphere through the production of methanol, satisfying the demand for this compound. In the calculation of mass balances, it is evident that hydrogen production doubles the biorefinery scheme 1, producing 0.90 Ton/day; simultaneously, the mass yield of methanol is 0.22 ton/day. Taking into account the minimum conversion rate proposed by (Lee et al., 2020), The author mentions that the production cost increases considerably when less than 1.64 tons/day is produced, which indicates that the extra cost of biorefinery three would be significantly high; comparing these results with the reforming efficiency in biorefinery one and the methanol production in biorefinery three is very low and agrees with what was supported by (Surendra et al., 2015).\u003c/p\u003e\u003cp\u003eConsidering the above data, the biorefinery with the lowest CO\u003csub\u003e2\u003c/sub\u003e production is biorefinery 3, with 40% efficiency due to the high carbon dioxide consumption in the methanol production phase. CO\u003csub\u003e2\u003c/sub\u003ee is a factor ASPEN PLUS reported that considers the energy consumption of the analyzed equipment. In this way, the production of CO\u003csub\u003e2\u003c/sub\u003e in biorefinery scheme 3 corresponds to 5% of the production of scheme 1 and 29% of scheme 2. The CO\u003csub\u003e2\u003c/sub\u003ee data is part of the heating services and additional energy increase. To systems: These can be optimized based on the energy integration of the biorefineries' designs.\u003c/p\u003e\u003cp\u003eBiorefinery schemes 2 and 3 are more efficient and sustainable since their values ​​are below the values ​​known in traditional methods, thus demonstrating the feasibility of the processes (Lora \u0026amp; Nascimento, 2004). Table\u0026nbsp;\u003cspan refid=\"Tab5\" class=\"InternalRef\"\u003e5\u003c/span\u003e shows the mass production results of the three biorefinery schemes.\u003c/p\u003e\u003cp\u003e\u003cdiv class=\"gridtable\"\u003e\u003ctable float=\"Yes\" id=\"Tab5\" border=\"1\"\u003e\u003ccaption language=\"En\"\u003e\u003cdiv class=\"CaptionNumber\"\u003eTable 5\u003c/div\u003e\u003cdiv class=\"CaptionContent\"\u003e\u003cp\u003eBiogas production scheme\u003c/p\u003e\u003c/div\u003e\u003c/caption\u003e\u003ccolgroup cols=\"3\"\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c1\" colnum=\"1\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c2\" colnum=\"2\"\u003e\u003c/div\u003e\u003cdiv align=\"char\" char=\".\" class=\"colspec\" colname=\"c3\" colnum=\"3\"\u003e\u003c/div\u003e\u003cthead\u003e\u003ctr\u003e\u003cth align=\"left\" colname=\"c1\"\u003e\u003cp\u003eBiorefinery scheme\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c2\"\u003e\u003cp\u003eProduct\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c3\"\u003e\u003cp\u003eMass Flow (Ton/day)\u003c/p\u003e\u003c/th\u003e\u003c/tr\u003e\u003c/thead\u003e\u003ctbody\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\" morerows=\"1\" rowspan=\"2\"\u003e\u003cp\u003e1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003eHydrogen (H\u003csub\u003e2\u003c/sub\u003e)\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c3\"\u003e\u003cp\u003e0.41\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003eMethane (CH\u003csub\u003e4\u003c/sub\u003e)\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c3\"\u003e\u003cp\u003e6.58\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\" morerows=\"1\" rowspan=\"2\"\u003e\u003cp\u003e2\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003eHydrogen (H\u003csub\u003e2\u003c/sub\u003e)\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c3\"\u003e\u003cp\u003e2.84\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003eCarbon monoxide (CO)\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c3\"\u003e\u003cp\u003e0.37\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\" morerows=\"2\" rowspan=\"3\"\u003e\u003cp\u003e3\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003eMethanol (CH\u003csub\u003e3\u003c/sub\u003eOH)\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c3\"\u003e\u003cp\u003e0.22\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003eHydrogen (H\u003csub\u003e2\u003c/sub\u003e)\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c3\"\u003e\u003cp\u003e0.90\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003eCarbon monoxide (CO)\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c3\"\u003e\u003cp\u003e15.13\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003c/tbody\u003e\u003c/colgroup\u003e\u003ctfoot\u003e\u003ctr\u003e\u003ctd colspan=\"3\"\u003eSource: Author\u003c/td\u003e\u003c/tr\u003e\u003c/tfoot\u003e\u003c/table\u003e\u003c/div\u003e\u003c/p\u003e\u003cp\u003eOne crucial factor in environmental analysis is the production of CO\u003csub\u003e2\u003c/sub\u003e. Table\u0026nbsp;\u003cspan refid=\"Tab6\" class=\"InternalRef\"\u003e6\u003c/span\u003e provides a detailed breakdown of the daily mass of CO\u003csub\u003e2\u003c/sub\u003e obtained from the biorefinery processes and the production of biomass flow, which shows a yield of 40 to 58%. The high production of CO\u003csub\u003e2\u003c/sub\u003e in each biorefinery is a significant concern, particularly the increase in reforming, underscoring the environmental implications of these processes.\u003c/p\u003e\u003cp\u003e\u003cdiv class=\"gridtable\"\u003e\u003ctable float=\"Yes\" id=\"Tab6\" border=\"1\"\u003e\u003ccaption language=\"En\"\u003e\u003cdiv class=\"CaptionNumber\"\u003eTable 6\u003c/div\u003e\u003cdiv class=\"CaptionContent\"\u003e\u003cp\u003eCO\u003csub\u003e2\u003c/sub\u003e production biorefinery schemes.\u003c/p\u003e\u003c/div\u003e\u003c/caption\u003e\u003ccolgroup cols=\"4\"\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c1\" colnum=\"1\"\u003e\u003c/div\u003e\u003cdiv align=\"char\" char=\".\" class=\"colspec\" colname=\"c2\" colnum=\"2\"\u003e\u003c/div\u003e\u003cdiv align=\"char\" char=\".\" class=\"colspec\" colname=\"c3\" colnum=\"3\"\u003e\u003c/div\u003e\u003cdiv align=\"char\" char=\".\" class=\"colspec\" colname=\"c4\" colnum=\"4\"\u003e\u003c/div\u003e\u003cthead\u003e\u003ctr\u003e\u003cth align=\"left\" colname=\"c1\"\u003e\u003cp\u003eBiorefinery scheme\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c2\"\u003e\u003cp\u003eMass flow (Ton/day)\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c3\"\u003e\u003cp\u003e%\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c4\"\u003e\u003cp\u003eCO\u003csub\u003e2\u003c/sub\u003ee (Ton/day)\u003c/p\u003e\u003c/th\u003e\u003c/tr\u003e\u003c/thead\u003e\u003ctbody\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e13.62\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c3\"\u003e\u003cp\u003e58\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c4\"\u003e\u003cp\u003e194.37\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e2\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e15.89\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c3\"\u003e\u003cp\u003e68\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c4\"\u003e\u003cp\u003e33.76\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e3\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c2\"\u003e\u003cp\u003e9.28\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c3\"\u003e\u003cp\u003e40\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"char\" char=\".\" colname=\"c4\"\u003e\u003cp\u003e9.87\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003c/tbody\u003e\u003c/colgroup\u003e\u003c/table\u003e\u003c/div\u003e\u003c/p\u003e\u003c/div\u003e\u003cdiv id=\"Sec13\" class=\"Section2\"\u003e\u003ch2\u003e3.2 Life cycle analysis (LCA)\u003c/h2\u003e\u003cp\u003eThe biorefinery valorizes coffee mucilage, cocoa mucilage, and pig manure waste, so the study's functional unit was defined by tons of processed waste and inventories for the agro-industrial waste processes used; these were derived from mass and energy balances generated by Aspen Plus process simulation models for a plant capacity of 238,099 t/day.\u003c/p\u003e\u003cp\u003eThe environmental evaluation was carried out for each of the three proposed biorefineries, presenting the most significant potential environmental impact and the levels showing the primary influence on the biorefineries: ADF digestion, digestate treatment, and biogas treatment. Within the 18 environmental impact categories analyzed in the LCA, the ReCiPe 2015 MidPoint (H) methodology was used, allowing observation of the processes' behavior and results. Special attention was paid to the categories belonging to the impact group Global warming (Kg CO\u003csub\u003e2\u003c/sub\u003e eq), Fossil resource scarcity (kg oil eq), and Water consumption (m\u003csup\u003e3\u003c/sup\u003e), detailed in Table\u0026nbsp;\u003cspan refid=\"Tab7\" class=\"InternalRef\"\u003e7\u003c/span\u003e.\u003c/p\u003e\u003cp\u003e\u003cdiv class=\"gridtable\"\u003e\u003ctable float=\"Yes\" id=\"Tab7\" border=\"1\"\u003e\u003ccaption language=\"En\"\u003e\u003cdiv class=\"CaptionNumber\"\u003eTable 7\u003c/div\u003e\u003cdiv class=\"CaptionContent\"\u003e\u003cp\u003eAnalysis of environmental impact categories in the biorefinery process 1\u0026ndash;2\u0026ndash;3\u003c/p\u003e\u003c/div\u003e\u003c/caption\u003e\u003ccolgroup cols=\"4\"\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c1\" colnum=\"1\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c2\" colnum=\"2\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c3\" colnum=\"3\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c4\" colnum=\"4\"\u003e\u003c/div\u003e\u003cthead\u003e\u003ctr\u003e\u003cth align=\"left\" colspan=\"4\" nameend=\"c4\" namest=\"c1\"\u003e\u003cp\u003eBiorefinery Scheme 1\u003c/p\u003e\u003c/th\u003e\u003c/tr\u003e\u003ctr\u003e\u003cth align=\"left\" colname=\"c1\"\u003e\u003cp\u003eIMPACT CATEGORY\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c2\"\u003e\u003cp\u003eADF E1\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c3\"\u003e\u003cp\u003eDigestate treatment E1\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c4\"\u003e\u003cp\u003eBiogas treatment E1\u003c/p\u003e\u003c/th\u003e\u003c/tr\u003e\u003c/thead\u003e\u003ctbody\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e\u003cb\u003eGlobal warming (Kg CO\u003c/b\u003e\u003csub\u003e\u003cb\u003e2\u003c/b\u003e\u003c/sub\u003e \u003cb\u003eeq)\u003c/b\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e7947.017688\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e110.2239862\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e853.8343835\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e\u003cb\u003eFossil resource scarcity (Kg oil eq)\u003c/b\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e2321.270521\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e34.17633979\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e263.3083707\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e\u003cb\u003eWater consumption (m\u003c/b\u003e\u003csup\u003e\u003cb\u003e3\u003c/b\u003e\u003c/sup\u003e\u003cb\u003e)\u003c/b\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e677.5171778\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e0.244942417\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e1.814983011\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colspan=\"4\" nameend=\"c4\" namest=\"c1\"\u003e\u003cp\u003e\u003cb\u003eBiorefinery Scheme 2\u003c/b\u003e\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e\u003cb\u003eIMPACT CATEGORY\u003c/b\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e\u003cb\u003eADF E2\u003c/b\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e\u003cb\u003eDigestate treatment E2\u003c/b\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e\u003cb\u003eBiogas treatment E2\u003c/b\u003e\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e\u003cb\u003eGlobal warming (Kg CO\u003c/b\u003e\u003csub\u003e\u003cb\u003e2\u003c/b\u003e\u003c/sub\u003e \u003cb\u003eeq)\u003c/b\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e7947.017688\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e110.2239862\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e37906.82774\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e\u003cb\u003eFossil resource scarcity (Kg oil eq)\u003c/b\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e2321.270521\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e34.17633979\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e11716.78297\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e\u003cb\u003eWater consumption (m\u003c/b\u003e\u003csup\u003e\u003cb\u003e3\u003c/b\u003e\u003c/sup\u003e\u003cb\u003e)\u003c/b\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e677.5171778\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e0.244942417\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e117.2872976\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colspan=\"4\" nameend=\"c4\" namest=\"c1\"\u003e\u003cp\u003e\u003cb\u003eBiorefinery Scheme 3\u003c/b\u003e\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e\u003cb\u003eIMPACT CATEGORY\u003c/b\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e\u003cb\u003eADF E3\u003c/b\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e\u003cb\u003eDigestate treatment E3\u003c/b\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e\u003cb\u003eBiogas treatment E2\u003c/b\u003e\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e\u003cb\u003eGlobal warming (Kg CO\u003c/b\u003e\u003csub\u003e\u003cb\u003e2\u003c/b\u003e\u003c/sub\u003e \u003cb\u003eeq)\u003c/b\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e7947.017688\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e110.2239862\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e56541.69592\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e\u003cb\u003eFossil resource scarcity (Kg oil eq)\u003c/b\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e2321.270521\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e34.17633979\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e17614.41944\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e\u003cb\u003eWater consumption (m\u003c/b\u003e\u003csup\u003e\u003cb\u003e3\u003c/b\u003e\u003c/sup\u003e\u003cb\u003e)\u003c/b\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e677.5171778\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e0.244942417\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e172.7802448\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003c/tbody\u003e\u003c/colgroup\u003e\u003c/table\u003e\u003c/div\u003e\u003c/p\u003e\u003cdiv id=\"Sec14\" class=\"Section3\"\u003e\u003ch2\u003e3.2.1 Biorefinery 1\u003c/h2\u003e\u003cp\u003eFigures \u003cspan refid=\"Fig7\" class=\"InternalRef\"\u003e7\u003c/span\u003e and \u003cspan refid=\"Fig8\" class=\"InternalRef\"\u003e8\u003c/span\u003e show that of the 18 categories of environmental impact in the Biorefinery 1 process for biogas treatment, the categories that contribute between 80\u0026ndash;100% of impact are associated with damage to human health and the ecosystem. These impact categories are global warming, scarcity of fossil resources, and water consumption with values ​​of 7947.017688 kg CO\u003csub\u003e2\u003c/sub\u003e eq; 2321.270521 kg oil eq; 677.5171778 m3, respectively. The high environmental impact of the biorefinery process is critically developed in anaerobic digestion, as presented by Lamnatou et al. (2019) and Surra et al. (2021).\u003c/p\u003e\u003cp\u003e\u003c/p\u003e\u003cp\u003e\u003c/p\u003e\u003cp\u003eIn this biorefinery process, the product with the highest quantity processed is CH\u003csub\u003e4\u003c/sub\u003e compared to H\u003csub\u003e2\u003c/sub\u003e, which has a higher calorific value and more excellent commercial value in Colombia.\u003c/p\u003e\u003c/div\u003e\u003cdiv id=\"Sec15\" class=\"Section3\"\u003e\u003ch2\u003e3.2.2 Biorefinery 2.\u003c/h2\u003e\u003cp\u003eThe LCA results for biorefinery scheme 2 (Figs.\u0026nbsp;\u003cspan refid=\"Fig9\" class=\"InternalRef\"\u003e9\u003c/span\u003e and \u003cspan refid=\"Fig10\" class=\"InternalRef\"\u003e10\u003c/span\u003e) were based on the production of Hydrogen, reformed from the pr4 categories. They show a significant impact on global warming, terrestrial ecotoxicity, non-carcinogenic human toxicity, and scarcity of fossil resources, with total values ​​for the biorefinery of 1.90x1008 kg CO\u003csub\u003e2\u003c/sub\u003e eq., 2.11x1008 kg 1.4-DCB, 4.92x1007 kg 1.4-DCB, and 2.89x1007 kg eq.\u0026nbsp;of oil, respectively.\u003c/p\u003e\u003cp\u003eThe pressure and temperature operating conditions of the biorefinery two process directly impact water consumption in the reforming line by reacting with the methane that reenters the process after the separation tanks. For the production of H\u003csub\u003e2\u003c/sub\u003e, in the reforming stage, an increase is evident in all categories of environmental impact, attributable to high water consumption and excessive generation of CO\u003csub\u003e2\u003c/sub\u003e, affirming the values ​​presented by (Hajjaji et al., 2006). Even so, studies show that gas reforming helps significantly reduce impact categories such as global warming, scarcity of fossil resources, and water consumption (Valente et al., 2021).\u003c/p\u003e\u003cp\u003e\u003c/p\u003e\u003cp\u003e\u003c/p\u003e\u003c/div\u003e\u003cdiv id=\"Sec16\" class=\"Section3\"\u003e\u003ch2\u003e3.2.3 Biorefinery 3.\u003c/h2\u003e\u003cp\u003eThe production of H\u003csub\u003e2\u003c/sub\u003e, Methanol, and CO\u003csub\u003e2\u003c/sub\u003e in the biorefinery three processes affected the 18 environmental impact categories with high percentages (Figs.\u0026nbsp;\u003cspan refid=\"Fig11\" class=\"InternalRef\"\u003e11\u003c/span\u003e and \u003cspan refid=\"Fig12\" class=\"InternalRef\"\u003e12\u003c/span\u003e), corroborating the equivalence of the percentages between the biological process and the separation of hydrogen (Fig.\u0026nbsp;\u003cspan refid=\"Fig12\" class=\"InternalRef\"\u003e12\u003c/span\u003e). This evidence shows that the design of biorefinery 3 at this stage is more efficient than the biorefinery scheme 2.\u003c/p\u003e\u003cp\u003eThe categories such as global warming, terrestrial ecotoxicity, non-carcinogenic human toxicity, and scarcity of fossil resources with total values ​​for the biorefinery of 2.16x1008 kg CO2 eq., 2.38x1008 kg 1,4-DCB, 5.55 x1007 kg 1, 4-DCB and 3.27x1007 kg oil eq.\u0026nbsp;Respectively.\u003c/p\u003e\u003cp\u003eIn this way, reforming methanol under the operating conditions of energy (1595833.692 KJ/h) and pressure (6079500 Pa) of the design demonstrates that the synthesis of methanol and separation of H2 in this stage does not attribute significant increases in impacts corresponding to (Lundgren et al., 2013; Ren\u0026oacute; et al., 2011; Wu et al., 2021).\u003c/p\u003e\u003cp\u003e\u003c/p\u003e\u003cp\u003e\u003c/p\u003e\u003c/div\u003e\u003c/div\u003e\u003cdiv id=\"Sec17\" class=\"Section2\"\u003e\u003ch2\u003e3.2 Economic assessment\u003c/h2\u003e\u003cp\u003eThe calculation of unit costs, fixed costs, and implementation of labor required to execute the biorefineries is listed below. It is projected for ten years from moment zero in each scheme. For all economic calculations, the representative market rate (TRM) of 1 USD\u0026thinsp;=\u0026thinsp;3900 COP is considered, Inflation of 3%, and the Minimum Attractive Rate of Return (MARR)\u0026thinsp;=\u0026thinsp;29.98%, as described in Table\u0026nbsp;\u003cspan refid=\"Tab8\" class=\"InternalRef\"\u003e8\u003c/span\u003e. It is estimated that for the first year, the Biorefinery 2 scheme is a reference, which, according to what has been evaluated, is the scheme that is projected with more definition to the possible execution.\u003c/p\u003e\u003cp\u003e\u003cdiv class=\"gridtable\"\u003e\u003ctable float=\"Yes\" id=\"Tab8\" border=\"1\"\u003e\u003ccaption language=\"En\"\u003e\u003cdiv class=\"CaptionNumber\"\u003eTable 8\u003c/div\u003e\u003cdiv class=\"CaptionContent\"\u003e\u003cp\u003eTMAR projection and inflation index.\u003c/p\u003e\u003c/div\u003e\u003c/caption\u003e\u003ccolgroup cols=\"4\"\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c1\" colnum=\"1\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c2\" colnum=\"2\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c3\" colnum=\"3\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c4\" colnum=\"4\"\u003e\u003c/div\u003e\u003cthead\u003e\u003ctr\u003e\u003cth align=\"left\" colspan=\"4\" nameend=\"c4\" namest=\"c1\"\u003e\u003cp\u003eMINIMUM ATTRACTIVE RATE OF RETURN (MARR)\u003c/p\u003e\u003c/th\u003e\u003c/tr\u003e\u003ctr\u003e\u003cth align=\"left\" colname=\"c1\"\u003e\u003cp\u003eYEAR\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c2\"\u003e\u003cp\u003eINFLATION INDEX\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c3\"\u003e\u003cp\u003eBANKING ENTITY\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c4\"\u003e\u003cp\u003eINTEREST RANK E.A. BANKS\u003c/p\u003e\u003c/th\u003e\u003c/tr\u003e\u003c/thead\u003e\u003ctbody\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e2017\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e4,63%\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e27,53%\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e2018\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e3,06%\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e2\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e20,50%\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e2019\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e3,49%\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e3\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e28,32%\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e2020\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e1,17%\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e4\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e26,19%\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003e2021\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e2,61%\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e5\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e28,06%\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eAVERAGE\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e\u003cb\u003e3%\u003c/b\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e10,08\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eMARR\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colspan=\"3\" nameend=\"c4\" namest=\"c2\"\u003e\u003cp\u003e\u003cb\u003e29,98%\u003c/b\u003e\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003c/tbody\u003e\u003c/colgroup\u003e\u003c/table\u003e\u003c/div\u003e\u003c/p\u003e\u003cp\u003eTo calculate the project's total required investment capital (TCI), it was initially considered that the biorefinery processes would be divided into different main sections: digestate treatment, biogas purification, reforming, and methanol synthesis. The teams that are part of each technological division are presented.\u003c/p\u003e\u003cp\u003e\u003cdiv class=\"gridtable\"\u003e\u003ctable float=\"Yes\" id=\"Tab9\" border=\"1\"\u003e\u003ccaption language=\"En\"\u003e\u003cdiv class=\"CaptionNumber\"\u003eTable 9\u003c/div\u003e\u003cdiv class=\"CaptionContent\"\u003e\u003cp\u003eTransparent breakdown of labor costs\u003c/p\u003e\u003c/div\u003e\u003c/caption\u003e\u003ccolgroup cols=\"7\"\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c1\" colnum=\"1\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c2\" colnum=\"2\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c3\" colnum=\"3\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c4\" colnum=\"4\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c5\" colnum=\"5\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c6\" colnum=\"6\"\u003e\u003c/div\u003e\u003cdiv align=\"left\" class=\"colspec\" colname=\"c7\" colnum=\"7\"\u003e\u003c/div\u003e\u003cthead\u003e\u003ctr\u003e\u003cth align=\"left\" colname=\"c1\"\u003e\u003cp\u003ePOSITION\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c2\"\u003e\u003cp\u003eAMOUNT BR.1\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c3\"\u003e\u003cp\u003eAMOUNT BR.2\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c4\"\u003e\u003cp\u003eAMOUNT BR.3\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c5\"\u003e\u003cp\u003ePERFORMANCE FACTOR\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c6\"\u003e\u003cp\u003eSALARY\u003c/p\u003e\u003c/th\u003e\u003cth align=\"left\" colname=\"c7\"\u003e\u003cp\u003eANNUAL VALUE\u003c/p\u003e\u003c/th\u003e\u003c/tr\u003e\u003c/thead\u003e\u003ctbody\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003ePlant operators\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e15\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e21\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e27\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c5\"\u003e\u003cp\u003e1,6\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c6\"\u003e\u003cp\u003e265,25\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e76392,57\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eProcess engineers\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e4\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e6\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e6\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c5\"\u003e\u003cp\u003e1,5\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c6\"\u003e\u003cp\u003e670\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e48240,00\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eEnvironmental engineer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e2\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e2\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c5\"\u003e\u003cp\u003e1,5\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c6\"\u003e\u003cp\u003e670\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e12060,00\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eMaintenance Engineer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e2\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e3\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e3\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c5\"\u003e\u003cp\u003e1,5\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c6\"\u003e\u003cp\u003e670\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e24120,00\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eIndustrial Engineer\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e3\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e3\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c5\"\u003e\u003cp\u003e1,5\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c6\"\u003e\u003cp\u003e670\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e12060,00\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eAccountant\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c5\"\u003e\u003cp\u003e1,5\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c6\"\u003e\u003cp\u003e670\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e12060,00\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eRRHH\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c5\"\u003e\u003cp\u003e1,5\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c6\"\u003e\u003cp\u003e700\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e12600,00\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eManager\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e1\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c5\"\u003e\u003cp\u003e2\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c6\"\u003e\u003cp\u003e1000\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e24000,00\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eSecretary\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e4\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e5\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e5\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c5\"\u003e\u003cp\u003e1,6\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c6\"\u003e\u003cp\u003e300\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e23040,00\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eWatchman\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e6\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e6\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e6\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c5\"\u003e\u003cp\u003e1,6\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c6\"\u003e\u003cp\u003e265,25\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e30557,03\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colname=\"c1\"\u003e\u003cp\u003eGeneral services\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c2\"\u003e\u003cp\u003e6\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c3\"\u003e\u003cp\u003e6\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c4\"\u003e\u003cp\u003e6\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c5\"\u003e\u003cp\u003e1,6\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c6\"\u003e\u003cp\u003e265,25\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e30557,03\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colspan=\"4\" morerows=\"2\" nameend=\"c4\" namest=\"c1\" rowspan=\"3\"\u003e\u0026nbsp;\u003c/td\u003e\u003ctd align=\"left\" colspan=\"2\" nameend=\"c6\" namest=\"c5\"\u003e\u003cp\u003e\u003cb\u003eBiorefinery 1\u003c/b\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e\u003cb\u003e$ 305.686,631\u003c/b\u003e\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colspan=\"2\" nameend=\"c6\" namest=\"c5\"\u003e\u003cp\u003e\u003cb\u003eBiorefinery 2\u003c/b\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e\u003cb\u003e$ 414.363,660\u003c/b\u003e\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003ctr\u003e\u003ctd align=\"left\" colspan=\"2\" nameend=\"c6\" namest=\"c5\"\u003e\u003cp\u003e\u003cb\u003eBiorefinery 3\u003c/b\u003e\u003c/p\u003e\u003c/td\u003e\u003ctd align=\"left\" colname=\"c7\"\u003e\u003cp\u003e\u003cb\u003e$ 444.920,690\u003c/b\u003e\u003c/p\u003e\u003c/td\u003e\u003c/tr\u003e\u003c/tbody\u003e\u003c/colgroup\u003e\u003c/table\u003e\u003c/div\u003e\u003c/p\u003e\u003cp\u003eA capital of US\u003cspan\u003e$\u003c/span\u003e795,177,825 will be injected, a value of US\u003cspan\u003e$\u003c/span\u003e45,886,133 for fixed costs, and a value of US\u003cspan\u003e$\u003c/span\u003e305,686.63 for labor is also estimated.\u003c/p\u003e\u003cp\u003eThe useful life of the device is 30 years. Equipment depreciation is calculated using the straight-line method, with zero residual value and a recovery period of 10 years. Other assumptions include three years for the acquisition of land, purchase of equipment, and construction; initiation of a 6-month biorefinery operation; 40% equity and 60% loan (loan term of 10% interest and a repayment term of 10 years) (Arora et al., 2018; Demichelis et al., 2018; Sy et al., 2018).\u003c/p\u003e\u003cp\u003eTable 10 Income and unit costs.\u003c/p\u003e\u003cp\u003e\u003cimg 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\" width=\"553\" height=\"346\"\u003e\u003c/p\u003e\u003cp\u003eThe total costs related to the proposed biorefineries are presented in Table\u0026nbsp;\u003cspan refid=\"Tab9\" class=\"InternalRef\"\u003e9\u003c/span\u003e. The distribution of costs for the plants was calculated considering the composition of the raw materials and the capacity of each plant to transform specific fractions of these. The costs listed below include raw materials, public services, and general and operational tasks (operational tasks, workloads, and general expenses). Estimating the configurations of the three scenarios proposed, there is an abrupt difference for each scenario depending on the technical design and increase in machinery to achieve the production objective in each biorefinery.\u003c/p\u003e\u003cp\u003eIn addition, Fig.\u0026nbsp;14 also shows the distribution of the profit margin for each biorefinery made from coffee mucilage, cocoa mucilage, and pig manure. The case of biorefinery 3 stands out because even carrying out reforming, CH4 recycling, and methanol-reforming for efficient H2 production increases C.O. emissions into the atmosphere, and the production cost exceeds the expected total income vs. the unit costs of the plant.\u003c/p\u003e\u003cp\u003eFinally, Table \u003cspan refid=\"Tab10\" class=\"InternalRef\"\u003e10\u003c/span\u003e and Fig.\u0026nbsp;\u003cspan refid=\"Fig13\" class=\"InternalRef\"\u003e13\u003c/span\u003e show the economic comparison of the income versus the costs of producing hydrogen in the three biorefineries based on agro-industrial waste in the Santander area of ​​study: coffee mucilage, cocoa mucilage, and pig manure.\u003c/p\u003e\u003cp\u003e\u003c/p\u003e\u003c/div\u003e"},{"header":"4. Conclusions","content":"\u003cp\u003eBiorefineries for agricultural waste from the agricultural waste of cocoa, coffee, and pig manure are an attractive alternative strategy for managing agro-industrial waste with the advantages of providing clean and versatile energy, diversifying raw materials, and improving the economic efficiency of the facilities of processing of agro-industrial waste. Replacing existing fossil fuels with bioenergy from waste cocoa, coffee mucilage, and pig manure will help mitigate the gradual depletion of non-renewable fossil fuels to support the bioeconomy.\u003c/p\u003e\u003cp\u003eThe energy capacity of agro-industrial waste is evaluated based on the economic efficiency and energy analysis of waste bioprocessing plants. Evaluating coffee mucilage, cocoa mucilage, and pig manure residues for the co-production of hydrogen, methanol, and methane is not energetically sufficient or profitable. However, the combined production of biogas and hydrogen is more profitable, leads to global warming, reduces fossil fuel production, and increases investment costs and water consumption.\u003c/p\u003e\u003cp\u003eWhile incorporating methane recovery into the system can increase profits, it also comes with significant environmental impacts and the potential inability to meet the energy needs of biorefineries and other detailed schemes. Therefore, exploring alternative treatment methods that can effectively reduce investment costs and water, and energy consumption is crucial. This will ensure the practical application of agricultural waste treatment methods and the sustainability of biorefinery projects.\u003c/p\u003e\u003cp\u003eAs explained in section 2.3, the most suitable biorefinery is a plant for hydrogen production and methane recirculation to increase plant efficiency (Scheme 2). This is because raw materials are available from all schemes and do not require any controlled compounds or additives to generate the H\u003csub\u003e2\u003c/sub\u003e value product. Furthermore, although it is more detailed than biorefinery scheme 1, the process is considered more convenient because the recirculation of methane production enters the biorefinery system, considerably reducing the environmental impacts analyzed in the life cycle (LCA). The generation of emissions into the environment is reformed to increase hydrogen production. Regarding the price, the cost of raw materials remains the same for the three cases, and the production cost is also high due to the increase in accessories for the plant.\u003c/p\u003e\u003cp\u003eRegarding capital expenditures, scenario 1 is the most favorable, followed by scenario 2 and scenario 3, which is the least attractive. However, Scenario 3 is promising based on cost-effectiveness. While investors may prefer Scenario 3 due to its current profitability, Scenario 2, which has lower levels of global warming and fossil fuel production, would be more environmentally appropriate. Therefore, investment decisions must weigh economic benefits and environmental emissions before implementing bioprocessing plants from coffee, manure, and pig manure.\u003c/p\u003e"},{"header":"Declarations","content":"\u003cp\u003e\u003cstrong\u003eFunding Information\u003c/strong\u003e\u003c/p\u003e\n\u003cp\u003eThis Project was developed with financing from the Minciencias-ICETEX 2021-1016 contract of 2021.\u003c/p\u003e\n\u003cp\u003e\u003cstrong\u003eDeclaration of interest statements\u003c/strong\u003e\u003c/p\u003e\n\u003cp\u003eThe authors declare no conflict of interest.\u003c/p\u003e\n\u003cp\u003e\u003cstrong\u003eData Availability Statement\u003c/strong\u003e\u003c/p\u003e\n\u003cp\u003eThe data that was used as an initial resource in this study is available in the corresponding bibliographic references, which illustrate information obtained in previous studies by various authors.\u003c/p\u003e\n\u003cp\u003e\u003cstrong\u003eAuthor Contributions Statement\u003c/strong\u003e\u003c/p\u003e\n\u003cp\u003eM.sc. Pablo El\u0026iacute;as Vel\u0026aacute;squez Perilla: contributed to the writing of the introduction and was a reviewer.\u003c/p\u003e\n\u003cp\u003ePh.D. M\u0026oacute;nica Amado Villamizar: contributed to the methodology and biorefinery simulations.\u003c/p\u003e\n\u003cp\u003eM.Sc. Juan Carlos Tarazona Romero: contributed with metholody and analysis of results. Written the Spanish version of the paper.\u003c/p\u003e\n\u003cp\u003eM. Sc Carol Jhulieth Rangel Villegas: contributed with translate the paper, contributed with methodology and results.\u003c/p\u003e\n\u003cp\u003ePh. D. Johanna Karina Solano Meza: contributed with reviews of the document and data analysis.\u003c/p\u003e\n\u003cp\u003ePh.D. Paola Andrea Acevedo Pab\u0026oacute;n: contributed with design of the biorefinery and analysis.\u003c/p\u003e"},{"header":"References","content":"\u003col\u003e\n\u003cli\u003eAghbashlo, M., Mandegari, MA, Tabatabaei, M., Farzad, S., Mojarab Soufiyan, M.,Gorgens, JF, 2018. 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Cenicaf\u0026eacute;, 45(3), 106-118.\u003c/li\u003e\n\u003c/ol\u003e"}],"fulltextSource":"","fullText":"","funders":[],"hasAdminPriorityOnWorkflow":false,"hasManuscriptDocX":true,"hasOptedInToPreprint":true,"hasPassedJournalQc":"","hasAnyPriority":false,"hideJournal":true,"highlight":"","institution":"","isAcceptedByJournal":false,"isAuthorSuppliedPdf":false,"isDeskRejected":"","isHiddenFromSearch":false,"isInQc":false,"isInWorkflow":false,"isPdf":false,"isPdfUpToDate":true,"isWithdrawnOrRetracted":false,"journal":{"display":true,"email":"[email protected]","identity":"researchsquare","isNatureJournal":false,"hasQc":true,"allowDirectSubmit":true,"externalIdentity":"","sideBox":"","snPcode":"","submissionUrl":"/submission","title":"Research Square","twitterHandle":"researchsquare","acdcEnabled":true,"dfaEnabled":false,"editorialSystem":"","reportingPortfolio":"","inReviewEnabled":false,"inReviewRevisionsEnabled":true},"keywords":"Biorefineries, Anaerobic Digestion, Dark Fermentation, Techno-economic evaluation, Life Cycle Assessment (LCA)","lastPublishedDoi":"10.21203/rs.3.rs-7078044/v1","lastPublishedDoiUrl":"https://doi.org/10.21203/rs.3.rs-7078044/v1","license":{"name":"CC BY 4.0","url":"https://creativecommons.org/licenses/by/4.0/"},"manuscriptAbstract":"\u003cp\u003eThe global interest in using waste from agro-industrial processes through implementing new clean technologies is rapidly increasing. Research confirms the innumerable benefits of using other biomass to obtain chemical products, biofuels, fuels, and energy, among value-added products. Among the benefits, it is highlighted that using processes incorporating clean technologies makes obtaining added value while conserving the environment possible. This work aimed to evaluate the technical, economic, and environmental feasibility of valuing agro-industrial waste present in Santander (Colombia), such as coffee mucilage, cocoa, and pig manure under biorefinery-type processes, where different products desired by the economic sector of the study area can be obtained. Initially, a basic level of three biorefinery schemes is designed, where the main products are hydrogen, methane, biogas, and biofertilizer. Subsequently, technical, economic, and environmental indicators were evaluated for each scheme to finally integrate these indicators and select the best alternative for the Santander context.\u003c/p\u003e","manuscriptTitle":"Technical economic and environmental assessment of biorefinery schemes by agro-industrial residues approach in Santander","msid":"","msnumber":"","nonDraftVersions":[{"code":1,"date":"2025-07-24 09:10:31","doi":"10.21203/rs.3.rs-7078044/v1","editorialEvents":[{"type":"communityComments","content":0}],"status":"published","journal":{"display":true,"email":"[email protected]","identity":"researchsquare","isNatureJournal":false,"hasQc":true,"allowDirectSubmit":true,"externalIdentity":"","sideBox":"","snPcode":"","submissionUrl":"/submission","title":"Research Square","twitterHandle":"researchsquare","acdcEnabled":true,"dfaEnabled":false,"editorialSystem":"","reportingPortfolio":"","inReviewEnabled":false,"inReviewRevisionsEnabled":true}}],"origin":"","ownerIdentity":"497098ad-d801-45ad-98ae-0dcb4ea87037","owner":[],"postedDate":"July 24th, 2025","published":true,"recentEditorialEvents":[],"rejectedJournal":[],"revision":"","amendment":"","status":"posted","subjectAreas":[],"tags":[],"updatedAt":"2025-08-16T15:44:24+00:00","versionOfRecord":[],"versionCreatedAt":"2025-07-24 09:10:31","video":"","vorDoi":"","vorDoiUrl":"","workflowStages":[]},"version":"v1","identity":"rs-7078044","journalConfig":"researchsquare"},"__N_SSP":true},"page":"/article/[identity]/[[...version]]","query":{"redirect":"/article/rs-7078044","identity":"rs-7078044","version":["v1"]},"buildId":"XKTyCvWXoU3ODBz1xrDgd","isFallback":false,"isExperimentalCompile":false,"dynamicIds":[84888],"gssp":true,"scriptLoader":[]}