Practical method to obtain α-acetoxyketones promoted by (diacetoxyiodo)benzene and acetic acid
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OA: closed
CC-BY-4.0
Abstract
By means of a simple procedure, we prepared α-acetoxyketones from a variety of enolizable ketones with PhI(OAc) 2 in the presence of acetic acid. The selectivity of the reactions depended on steric hindrance, and some other reactions were observed, such as the formation of N=N or C=C double bonds through an oxidation reaction.
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- europepmc
- last seen: 2026-05-19T01:45:01.086888+00:00
- unpaywall
- last seen: 2026-05-22T02:00:06.705733+00:00
License: CC-BY-4.0